CO2养护硅酸钙板的研究进展

doi:10.16552/j.cnki.issn1001-1625.2025.1248

硅酸盐通报 ›› 2026, Vol. 45 ›› Issue (6): 1851-1863.DOI: 10.16552/j.cnki.issn1001-1625.2025.1248

• 水泥混凝土 • 下一篇

CO₂养护硅酸钙板的研究进展

叶俊豪¹^,²(), 陈阁¹, 房晶瑞¹(), 白锋³, 秦贺胜⁴, 王丽娜⁴

^1.中国建筑材料科学研究总院有限公司，绿色建筑材料国家重点实验室，北京 100024
^2.武汉理工大学，建筑材料硅酸盐国家重点实验室，武汉 430070
^3.中材节能（武汉）有限公司，武汉 430200
^4.武汉建筑材料工业设计研究院有限公司，武汉 430074

收稿日期:2025-12-12 修订日期:2026-01-26 出版日期:2026-06-15 发布日期:2026-07-14
通信作者: 房晶瑞，博士，教授。E-mail：fangjingrui@cbma.com.cn
作者简介:叶俊豪（1999—），男，博士研究生。主要从事固废利用及碳矿化技术方面的研究。E-mail：yejunhao2025@163.com
基金资助:
中国建材集团关键核心技术攻关“揭榜挂帅”项目(2023YYSF08);绿色建筑材料国家重点实验室自立项目(ZA-131);中国国家重点研发计划(2024YFE0210400)

Research Progress of CO₂ Curing for Calcium Silicate Board

YE Junhao¹^,²(), CHEN Ge¹, FANG Jingrui¹(), BAI Feng³, QIN Hesheng⁴, WANG Lina⁴

^1.State Key Laboratory of Green Building Materials，China Building Materials Academy Co.，Ltd.，Beijing 100024，China
^2.State Key Laboratory of Silicate Materials for Architectures，Wuhan University of Technology，Wuhan 430070，China
^3.Sinoma Energy Conservation （Wuhan） Co.，Ltd.，Wuhan 430200，China
^4.Wuhan Research and Design Institute of Building Materials Industry Co.，Ltd.，Wuhan 430074，China

Received:2025-12-12 Revised:2026-01-26 Published:2026-06-15 Online:2026-07-14

摘要/Abstract

摘要：

硅酸钙板主流工艺的蒸压养护环节能耗高、碳排放占比高，CO₂养护技术能够同时实现硅酸钙基材料界面强化与CO₂封存，但目前该技术在硅酸钙板领域的应用缺乏系统总结，制约了其工艺优化与工程推广。本文系统综述CO₂养护硅酸钙板的研究进展：首先阐述蒸压养护工艺关键步骤及制品常见缺陷，进而阐明CO₂养护中硅酸钙矿物的碳化过程、产物特性与多尺度机理。在此基础上，从力学性能和碳封存效率等方面对比CO₂养护与蒸压养护板的性能，分析该技术的优势与局限。最后展望工艺参数协同优化及纤维-基体界面定向调控碳化机理等未来研究方向。研究表明，CO₂养护通过产物填充孔隙和界面增强来提升材料性能，并实现CO₂稳定封存，但仍存在养护效率偏低、长期稳定性不足等挑战。本文可为硅酸钙板绿色制造升级与建材行业降碳路径提供参考与实践依据。

关键词: 硅酸钙, 碳酸钙, 纤维板, 碳矿化, CO₂养护

Abstract:

The autoclaved curing process， a mainstream step in calcium silicate board production， is characterized by high energy consumption and a significant proportion of carbon emissions. Meanwhile， CO₂ curing technology offers a dual advantage： it simultaneously enhances the interfacial properties of calcium silicate-based materials and enables CO₂ sequestration. However， the lack of a systematic summary of this technology’s application in the calcium silicate board field currently hinders its process optimization and engineering promotion. This work provides a systematic review of the research progress of CO₂-cured calcium silicate boards. It begins by outlining the key steps of the autoclaved curing process and the common defects in the resulting products. It then elucidates the carbonation process of calcium silicate minerals during CO₂ curing， along with the characteristics of the reaction products and the multi-scale mechanisms involved. Building on this foundation， the performance of CO₂-cured boards is compared with that of autoclave-cured boards in terms of mechanical properties and CO₂ sequestration efficiency， analyzing the technology's advantages and limitations. Finally， future research directions are proposed， including the synergistic optimization of process parameters and the targeted regulation of carbonation mechanisms at the fiber-matrix interface. The study indicates that CO₂ curing enhances material performance through pore filling by products and interface strengthening， while achieving stable CO₂ sequestration. Nevertheless， challenges such as low curing efficiency and insufficient long-term stability still exist. This review can provide theoretical reference and practical basis for the green manufacturing upgrade of calcium silicate boards and decarbonization pathways of the construction materials industry.

Key words: calcium silicate, calcium carbonate, fiberboard, carbon mineralization, CO₂ curing

中图分类号:

TU525

叶俊豪, 陈阁, 房晶瑞, 白锋, 秦贺胜, 王丽娜. CO₂养护硅酸钙板的研究进展[J]. 硅酸盐通报, 2026, 45(6): 1851-1863.

YE Junhao, CHEN Ge, FANG Jingrui, BAI Feng, QIN Hesheng, WANG Lina. Research Progress of CO₂ Curing for Calcium Silicate Board[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(6): 1851-1863.

图/表 11

图1 典型的Hatscheck工艺简图

Fig.1 Typical schematic diagram of Hatscheck process

图2 硅酸钙板水化反应及水热反应简图

Fig.2 Simplified diagram of hydration reaction and hydrothermal reaction of calcium silicate board

图3 典型的CO2养护装置示意图

Fig.3 Schematic diagram of a typical CO2 curing device

图4 20 ℃时不同时间的β-C2S钙浸出［52］

Fig.4 Calcium leaching of β-C2S at different time at 20 ℃［52］

图5 常温条件下不同时间的C3S的钙浸出［59］

Fig.5 Calcium leaching of C3S at different time under normal temperature conditions［59］

图6 硅酸钙矿物的CO2养护过程示意图［39］

Fig.6 Schematic diagram of CO2 curing process of calcium silicate minerals［39］

图7 20 ℃下不同搅拌时间段矿物的钙浸出情况［52］

Fig.7 Calcium leaching of minerals at different stirring time periods at 20 ℃［52］

图8 碳化72 h后Ca（OH）2的SEM照片［52］

Fig.8 SEM image of Ca（OH）2 after 72 h of carbonation［52］

图9 碳化条件下C-S-H变化示意图［72］

Fig.9 Schematic diagram of C-S-H changes under carbonation conditions［72］

图10 CO2氧护及传统养护后样品的SEM照片［80］

Fig.10 SEM images of samples under CO2 curing and traditional curing［80］

图11 含水量与二氧化碳吸收量的关系［80］

Fig.11 Relationship between water content and carbon dioxide absorption capacity［80］

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CO₂养护硅酸钙板的研究进展

Research Progress of CO₂ Curing for Calcium Silicate Board

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