硅酸盐通报 ›› 2026, Vol. 45 ›› Issue (2): 413-425.DOI: 10.16552/j.cnki.issn1001-1625.2025.0783
所属专题: 水泥混凝土
孔昕1(
), 吴佳明2(
), 宋本腾1, 王振兴3, 叶正茂4(
)
收稿日期:2025-08-04
修订日期:2025-10-22
出版日期:2026-02-15
发布日期:2026-03-09
通信作者:
吴佳明,博士,副教授。E-mail:mse_wujm@ujn.edu.cn作者简介:孔 昕(1984—),女。主要从事建筑科技的研究。E-mail:112315118@qq.com
基金资助:
KONG Xin1(
), WU Jiaming2(
), SONG Benteng1, WANG Zhenxing3, YE Zhengmao4(
)
Received:2025-08-04
Revised:2025-10-22
Published:2026-02-15
Online:2026-03-09
摘要:
本研究针对陶砂轻质砂浆密度与强度之间的矛盾,系统探讨组分配合比对砂浆性能的影响规律及作用机理,重点揭示水胶比与矿粉掺量的协同优化效应。结果表明,随着水胶比增加,砂浆的干密度持续降低,干燥收缩值持续增加,抗氯离子侵蚀能力呈先降低后增加趋势。当水胶比为0.24时,砂浆的吸水率、开口气孔率最低,28 d抗压强度最高,水泥水化程度与孔隙率之间达到最优平衡,水化产物氢氧化钙(CH)与非晶相(C-S-H凝胶)含量的增加显著提高了基体密实度。在此基础上,当矿粉掺量增加至12%(质量分数)时,砂浆的力学性能与耐久性提升显著,干密度达1 465.44 kg/m3,28 d抗压强度为51.6 MPa,吸水率为6.66%,开口气孔率为9.76%,氯离子迁移系数最低,90 d干燥收缩率降低22.88%。矿粉通过二次水化反应与微集料效应填充孔隙,有效降低了孔隙率。本研究为陶砂轻质砂浆的配合比设计提供了参考。
中图分类号:
孔昕, 吴佳明, 宋本腾, 王振兴, 叶正茂. 陶砂轻质砂浆的组分配合比优化及性能研究[J]. 硅酸盐通报, 2026, 45(2): 413-425.
KONG Xin, WU Jiaming, SONG Benteng, WANG Zhenxing, YE Zhengmao. Optimization of Component Mix Proportion and Performance Study of Ceramic Sand Lightweight Mortar[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(2): 413-425.
| Chemical composition | CaO | SiO2 | Fe2O3 | Al2O3 | MgO | SO3 | Na2O |
|---|---|---|---|---|---|---|---|
| Mass fraction/% | 59.67 | 21.01 | 3.28 | 3.84 | 3.36 | 3.24 | 0.21 |
表1 水泥的主要化学组成
Table 1 Main chemical composition of cement
| Chemical composition | CaO | SiO2 | Fe2O3 | Al2O3 | MgO | SO3 | Na2O |
|---|---|---|---|---|---|---|---|
| Mass fraction/% | 59.67 | 21.01 | 3.28 | 3.84 | 3.36 | 3.24 | 0.21 |
| Packing density/(kg·m-3) | Apparent density/(kg·m-3) | Cylinder compressive strength/MPa | 1 h water absorption rate/% | Saturated water absorption rate/% |
|---|---|---|---|---|
| 550 | 880 | 4.3 | 14.70 | 18.00 |
表2 陶砂的物理性质
Table 2 Physical properties of ceramic sand
| Packing density/(kg·m-3) | Apparent density/(kg·m-3) | Cylinder compressive strength/MPa | 1 h water absorption rate/% | Saturated water absorption rate/% |
|---|---|---|---|---|
| 550 | 880 | 4.3 | 14.70 | 18.00 |
| Particle size/μm | Specific surface area/(m2·kg-1) | Density/(g·cm-3) | Loss (mass fraction)/% | |
|---|---|---|---|---|
| D90 | D50 | |||
| ≤27 | ≤16 | ≥470 | ≥2.80 | ≤1.0 |
表3 矿粉的物理性能
Table 3 Physical properties of mineral powder
| Particle size/μm | Specific surface area/(m2·kg-1) | Density/(g·cm-3) | Loss (mass fraction)/% | |
|---|---|---|---|---|
| D90 | D50 | |||
| ≤27 | ≤16 | ≥470 | ≥2.80 | ≤1.0 |
| Sample No. | Water-to-binder ratio | Mass/g | |||
|---|---|---|---|---|---|
| Cement | Ceramic sand | Water reducer | Water | ||
| W1 | 0.22 | 900 | 380 | 3.6 | 198 |
| W2 | 0.24 | 900 | 380 | 3.6 | 216 |
| W3 | 0.26 | 900 | 380 | 3.6 | 234 |
| W4 | 0.28 | 900 | 380 | 3.6 | 252 |
表4 不同水胶比的陶砂轻质砂浆配合比
Table 4 Mix proportion of ceramic sand lightweight mortar with different water-to-binder ratios
| Sample No. | Water-to-binder ratio | Mass/g | |||
|---|---|---|---|---|---|
| Cement | Ceramic sand | Water reducer | Water | ||
| W1 | 0.22 | 900 | 380 | 3.6 | 198 |
| W2 | 0.24 | 900 | 380 | 3.6 | 216 |
| W3 | 0.26 | 900 | 380 | 3.6 | 234 |
| W4 | 0.28 | 900 | 380 | 3.6 | 252 |
| Sample No. | Mineral powder content (mass fraction)/% | Mass/g | ||||
|---|---|---|---|---|---|---|
| Cement | Mineral powder | Ceramic sand | Water reducer | Water | ||
| M1 | 4 | 864 | 36 | 380 | 3.6 | 216 |
| M2 | 8 | 828 | 72 | 380 | 3.6 | 216 |
| M3 | 12 | 792 | 108 | 380 | 3.6 | 216 |
| M4 | 16 | 756 | 144 | 380 | 3.6 | 216 |
表5 不同矿粉掺量的陶砂轻质砂浆配合比
Table 5 Mix proportion of ceramic sand lightweight mortar with different mineral powder content
| Sample No. | Mineral powder content (mass fraction)/% | Mass/g | ||||
|---|---|---|---|---|---|---|
| Cement | Mineral powder | Ceramic sand | Water reducer | Water | ||
| M1 | 4 | 864 | 36 | 380 | 3.6 | 216 |
| M2 | 8 | 828 | 72 | 380 | 3.6 | 216 |
| M3 | 12 | 792 | 108 | 380 | 3.6 | 216 |
| M4 | 16 | 756 | 144 | 380 | 3.6 | 216 |
| [1] |
SAHOO S, SELVARAJU A K, SURIYA PRAKASH S. Mechanical characterization of structural lightweight aggregate concrete made with sintered fly ash aggregates and synthetic fibres[J]. Cement and Concrete Composites, 2020, 113: 103712.
DOI URL |
| [2] | TAYEH B A, ZEYAD A M, AGWA I S, et al. Effect of elevated temperatures on mechanical properties of lightweight geopolymer concrete[J]. Case Studies in Construction Materials, 2021, 15: e00673. |
| [3] |
SHI J, LU Y J, ZHU R, et al. Experimental evaluation of fracture toughness of basalt macro fiber reinforced high performance lightweight aggregate concrete[J]. Construction and Building Materials, 2024, 411: 134638.
DOI URL |
| [4] |
LI H C, WEI Y, MENG K, et al. Mechanical properties and stress-strain relationship of surface-treated bamboo fiber reinforced lightweight aggregate concrete[J]. Construction and Building Materials, 2024, 424: 135914.
DOI URL |
| [5] |
GENG J, NIU S L, HAN K H, et al. Properties of artificial lightweight aggregates prepared from coal and biomass co-fired fly ashes and sewage sludge fly ash[J]. Ceramics International, 2024, 50(16): 28609-28618.
DOI URL |
| [6] | BEEMAMOL U S, NIZAD A, NAZEER M. Investigations on cement mortar using ceramic tailing sand as fine aggregate[J]. American Journal of Engineering Research, 2013, 3: 28-33. |
| [7] |
WANG Z F, SHI M, LI J H, et al. Sorption of dissolved inorganic and organic phosphorus compounds onto iron-doped ceramic sand[J]. Ecological Engineering, 2013, 58: 286-295.
DOI URL |
| [8] | 王 鹏, 严建华, 杜加俊. 双壳层结构氯离子结合陶砂对海砂砂浆性能的影响[J]. 新型建筑材料, 2024, 51(10): 1-7+13. |
| WANG P, YAN J H, DU J J. Effect of chloride ion bonded ceramic sand with bishell structure on the properties of sea sand mortar[J]. New Building Materials, 2024, 51(10): 1-7+13 (in Chinese). | |
| [9] |
MA J, XU G, WU K, et al. Heterogeneous distribution of lightweight porous ceramic sands in a high strength cement grout[J]. Construction and Building Materials, 2023, 409: 134093.
DOI URL |
| [10] |
ZHAO X Z, LI X L. Static and dynamic mechanical response and damage evolution path of lightweight aggregate mortar containing Pisha sandstone pottery sand and desert sand[J]. Construction and Building Materials, 2025, 485: 141966.
DOI URL |
| [11] |
GÜNEYISI E, GESOGLU M, GHANIM H, et al. Influence of the artificial lightweight aggregate on fresh properties and compressive strength of the self-compacting mortars[J]. Construction and Building Materials, 2016, 116: 151-158.
DOI URL |
| [12] |
YANG K H, SONG J K, LEE J S. Properties of alkali-activated mortar and concrete using lightweight aggregates[J]. Materials and Structures, 2010, 43(3): 403-416.
DOI URL |
| [13] | LU J X, ALI H A, JIANG Y, et al. A novel high-performance lightweight concrete prepared with glass-UHPC and lightweight microspheres: towards energy conservation in buildings[J]. Composites Part B: Engineering, 2022, 247: 110295. |
| [14] |
ALSALMAN A, DANG C N, MICAH HALE W. Development of ultra-high performance concrete with locally available materials[J]. Construction and Building Materials, 2017, 133: 135-145.
DOI URL |
| [15] |
HUANG Y J, BIAN Z W, JI W Y, et al. Production of glass-ceramic aggregates from solid wastes for high-strength and low-shrinkage lightweight mortars[J]. Construction and Building Materials, 2024, 416: 135244.
DOI URL |
| [16] |
KALKAN Ş O, YAVAŞ A, GÜLER S, et al. An experimental approach to a cementitious lightweight composite mortar using synthetic wollastonite[J]. Construction and Building Materials, 2022, 341: 127911.
DOI URL |
| [17] |
ALGHAMDI H, SHOUKRY H, MIM N J, et al. Impact of waste rockwool on the performance of LC3-based lightweight mortar: a promising solution for greener construction[J]. Construction and Building Materials, 2024, 443: 137805.
DOI URL |
| [18] |
YANG L, MA X W, HU X, et al. Production of lightweight aggregates from bauxite tailings for the internal curing of high-strength mortars[J]. Construction and Building Materials, 2022, 341: 127800.
DOI URL |
| [19] |
JIANG J Y, QIN J J, CHU H Y. Improving mechanical properties and microstructure of ultra-high-performance lightweight concrete via graphene oxide[J]. Journal of Building Engineering, 2023, 80: 108038.
DOI URL |
| [20] | YOOSUK P, SUKSIRIPATTANAPONG C, SUKONTASUKKUL P, et al. Properties of polypropylene fiber reinforced cellular lightweight high calcium fly ash geopolymer mortar[J]. Case Studies in Construction Materials, 2021, 15: e00730. |
| [21] |
WANG W L, FAN C C, WANG B M, et al. Workability, rheology, and geopolymerization of fly ash geopolymer: role of alkali content, modulus, and water-binder ratio[J]. Construction and Building Materials, 2023, 367: 130357.
DOI URL |
| [22] |
WANG W, ZHANG S Z, ZHANG Y M, et al. Understanding the influence of slag fineness and water-to-binder ratio on the alkali-silica reaction in alkali-activated slag mortars[J]. Cement and Concrete Composites, 2025, 157: 105907.
DOI URL |
| [23] |
SONG P P, LIU Y Z, KONG L J, et al. Research on design and optimization for compositions of ultra-high-performance geopolymer concrete[J]. Journal of Building Engineering, 2025, 100: 111750.
DOI URL |
| [24] |
FENG N Q, FENG X X, HAO T Y, et al. Effect of ultrafine mineral powder on the charge passed of the concrete[J]. Cement and Concrete Research, 2002, 32(4): 623-627.
DOI URL |
| [25] |
BAPAT J D. Performance of cement concrete with mineral admixtures[J]. Advances in Cement Research, 2001, 13(4): 139-155.
DOI URL |
| [26] |
KADRI E H, AGGOUN S, DE SCHUTTER G, et al. Combined effect of chemical nature and fineness of mineral powders on Portland cement hydration[J]. Materials and Structures, 2010, 43(5): 665-673.
DOI URL |
| [27] |
UCHIKAWA H, HANEHARA S, HIRAO H. Influence of microstructure on the physical properties of concrete prepared by substituting mineral powder for part of fine aggregate[J]. Cement and Concrete Research, 1996, 26(1): 101-111.
DOI URL |
| [28] |
TIKKANEN J, CWIRZEN A, PENTTALA V. Effects of mineral powders on hydration process and hydration products in normal strength concrete[J]. Construction and Building Materials, 2014, 72: 7-14.
DOI URL |
| [1] | 王海皓, 甘元初, 侯庆振, 陈振富, 金丹, 付新博. 疏水改性煅烧硅藻土砂浆的制备及性能[J]. 硅酸盐通报, 2026, 45(4): 1122-1131. |
| [2] | 杨雪滢, 王开元, 王耀城, 占宝剑, 邢锋. 自然风化作用下碳化养护水泥基材料的力学性能劣化机制[J]. 硅酸盐通报, 2026, 45(4): 1132-1141. |
| [3] | 李顺凯, 陈荣辉, 董勋, 窦华康, 孙凤品. 促凝早强剂对喷射混凝土性能的影响[J]. 硅酸盐通报, 2026, 45(4): 1184-1192. |
| [4] | 林明智, 陈旸, 陈波. 浅水海砂骨料矿物特征及物理力学性能研究[J]. 硅酸盐通报, 2026, 45(4): 1240-1247. |
| [5] | 邹仁华, 胡小龙, 冯泽平, 牛高辉, 邱继生. 煤矸石混合砂混凝土宏观力学性能及微观机理研究[J]. 硅酸盐通报, 2026, 45(4): 1266-1281. |
| [6] | 郭阳光, 秦拥军, 罗玲, 谌君诚, 李琦, 程昊. 硅灰-玻璃纤维全再生粗骨料混凝土力学性能研究[J]. 硅酸盐通报, 2026, 45(4): 1296-1303. |
| [7] | 谌君诚, 罗玲, 秦拥军, 郭阳光, 李琦, 程昊. 硅灰-聚甲醛纤维再生水工混凝土力学和耐水性能研究[J]. 硅酸盐通报, 2026, 45(4): 1304-1314. |
| [8] | 贾旭赫, 赵仁龙, 张继红, 谢俊. Al2O3/SiO2对Li2O-Al2O3-SiO2-MgO微晶玻璃析晶行为及力学性能的影响[J]. 硅酸盐通报, 2026, 45(3): 845-852. |
| [9] | 王伯昕, 贠炜龙, 李嘉城, 刘泰源, 段思羽. 橡胶混凝土基本力学性能研究进展[J]. 硅酸盐通报, 2026, 45(2): 490-502. |
| [10] | 曹伟, 李新阳, 刘福酉. 氧化镁激发矿粉-玄武岩纤维固化盾构渣土的强度与耐干湿循环性能[J]. 硅酸盐通报, 2026, 45(2): 725-734. |
| [11] | 陈宇, 邱思远, 陈旭升, 张亚梅. 面向海工建设的海水海砂工程水泥基复合材料研究进展[J]. 硅酸盐通报, 2026, 45(2): 367-379. |
| [12] | 许凯钦, 廖宜顺, 张普, 张冬, 齐冬有. -10 ℃条件下硝酸钙对铁铝酸盐水泥性能的影响[J]. 硅酸盐通报, 2026, 45(2): 380-389. |
| [13] | 舒畅, 陈振中, 王伟, 梅友静, 王宁宁, 张亚梅. 流态固化土的固化机理及性能调控研究综述[J]. 硅酸盐通报, 2026, 45(2): 503-516. |
| [14] | 王熠江, 李梓俊, 何智海, 陆俊. 微波养护对香灰-水泥复合胶凝材料强度及微观结构的影响[J]. 硅酸盐通报, 2026, 45(2): 540-548. |
| [15] | 张小龙, 孙为国, 王伟, 王朝晖, 晏茂豪, 刘红强, 杨军宏. 基于响应面法的全固废胶凝材料配合比优化设计及性能研究[J]. 硅酸盐通报, 2026, 45(2): 549-561. |
| 阅读次数 | ||||||
|
全文 |
|
|||||
|
摘要 |
|
|||||