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硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (7): 2429-2436.DOI: 10.16552/j.cnki.issn1001-1625.2024.1414

• 水泥混凝土 • 上一篇    下一篇

海水干湿循环作用下铁铝酸盐水泥混凝土的力学性能和微观性能研究

张普1, 齐冬有2, 王小可3, 陈鹤元1, 何昌毓2, 张巍3, 谢亚斌3, 张冬4   

  1. 1.郑州大学土木工程学院,郑州 450001;
    2.建筑材料工业技术监督研究中心,北京 100024;
    3.中核国电漳州能源有限公司,漳州 363300;
    4.福州大学土木工程学院,福州 350108
  • 收稿日期:2024-11-19 修订日期:2025-02-06 出版日期:2025-07-15 发布日期:2025-07-24
  • 通信作者: 张 冬,博士,教授。E-mail:zhangdong_ce@fzu.edu.cn
  • 作者简介:张 普(1982—),男,博士,教授。主要从事交通土建新材料及新型结构方面的研究。E-mail:zhpu@zzu.edu.cn
  • 基金资助:
    国家重大科技专项(202203001);国家自然科学基金-河南省联合基金项目(U1904177);河南省自然科学优秀青年基金(212300410079);河南省公路工程局横向项目(20230352A)

Mechanical and Microscopic Properties of Ferroaluminate Cement Concrete under Action of Seawater Dry-Wet Cycle

ZHANG Pu1, QI Dongyou2, WANG Xiaoke3, CHEN Heyuan1, HE Changyu2, ZHANG Wei3, XIE Yabin3, ZHANG Dong4   

  1. 1. School of Civil Engineering, Zhengzhou University, Zhengzhou 450001, China;
    2. Building Materials Industry Technical Supervision Research Center, Beijing 100024, China;
    3. CNNC Guodian Zhangzhou Energy Co., Ltd., Zhangzhou 363300, China;
    4. College of Civil Engineering, Fuzhou University, Fuzhou 350108, China
  • Received:2024-11-19 Revised:2025-02-06 Published:2025-07-15 Online:2025-07-24

摘要: 随着近年来海洋基础设施建设的推进,水泥基材料在海洋环境中的耐久性要求日益提高。铁铝酸盐水泥是我国研发的“第三代水泥”,具有抗海水侵蚀的优异性能。本研究旨在探讨海水干湿循环下铁铝酸盐水泥混凝土(FACC)与普通硅酸盐水泥混凝土(OPCC)的力学性能和微观结构变化,并特别关注水胶比对性能的影响。通过试验对比分析FACC和OPCC的质量损失率、相对动弹性模量和立方体抗压强度等物理力学性能指标,并结合扫描电子显微镜和压汞法对微观结构进行分析。结果表明,在海水干湿循环过程中,FACC的质量损失率较低,相对动弹性模量在海水干湿循环初期有所增加,随后趋于稳定,而OPCC的相对弹性模量则在海水干湿循环后期出现明显下降。抗压强度方面,FACC在海水干湿循环后有所增加,而OPCC则有所降低。总体上,FACC展现出比OPCC更优异的耐久性和更强的抗海水侵蚀性能。微观分析显示,FACC具有更低的孔隙率和更精细的孔隙结构,这有助于提高耐久性。

关键词: 铁铝酸盐水泥, 海水干湿循环, 质量损失率, 相对弹性模量, 抗压强度, 微观性能

Abstract: With the development of marine infrastructure construction in recent years, the durability requirements of cement-based materials in marine environments have been increasingly raised. Ferroaluminate cement is the "third-generation cement" in China, which has excellent performance of resistance to seawater erosion. The purpose of this study was to explore the mechanical properties and microstructural changes of ferroaluminate cement concrete (FACC) and ordinary Portland cement concrete (OPCC) under the seawater dry-wet cycle, with particular attention to the influence of water-to-cement ratio on the properties. The physical and mechanical properties such as mass loss rate, relative dynamic elastic modulus and cube compressive strength of FACC and OPCC were compared and analyzed by experiments, and the microstructure was analyzed by scanning electron microscope and mercury intrusion method. The results show that during the seawater dry-wet cycle, FACC has a lower mass loss rate, and the relative dynamic elastic modulus of FACC increases at the beginning of the seawater dry-wet cycle and then tends to be stable, while relative dynamic elastic modulus of OPCC shows a significant decrease in the later stage of the seawater dry-wet cycle. In terms of compressive strength, FACC increases after seawater dry-wet cycle, while OPCC decreases. Overall, FACC demonstrates superior durability and stronger resistance to seawater erosion compared to OPCC. Microscopic analysis reveals that FACC has lower porosity and finer pore structure, which contributes to improve its durability.

Key words: ferroaluminate cement, seawater dry-wet cycle, mass loss rate, relative elastic modulus, compressive strength, microscopic property

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