Research Progress on Removal of Heavy Metal Ions by Chemically Modified Zeolite

Abstract

Abstract: With the continuous development of industry, heavy metal pollution is deepening day by day, which seriously endangers human health. In recent years, chemically modified zeolite has been widely used in the field of heavy metal ions treatment because of its large specific surface area and strong ion exchange capacity. However, due to the use of acid, alkali, inorganic salts and organic reagents as modifiers in the chemical modification process, there are still some drawbacks in terms of energy consumption, cost and sustainable development. Therefore, it is of great significance and economic benefit to carry out the research on chemical modification methods of zeolite to make it simple, industrialized and green. In this paper, the methods of chemically modified zeolite were introduced from the structure level of zeolite, the excellent properties of magnetic zeolite and nanometer zeolite were analyzed, the application of modified zeolite in removing heavy metal ions was summarized, and the future development trend of the modified zeolite was prospected.

Key words: chemical modification, zeolite, magnetism, nanocrystallization, heavy metal ion, adsorption

CLC Number:

X703

ZHOU Juanping, LI Xinyu, YANG Xu, HAN Shunyu, MENG Wan, JIANG Nanzhe. Research Progress on Removal of Heavy Metal Ions by Chemically Modified Zeolite[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(9): 2978-2988.

References

[1] 马俊平,赵秋宇,王晨,等.二氧化锰基纳米材料对重金属离子的去除及机理研究进展[J].环境化学,2020,39(3):687-703.
MA J P, ZHAO Q Y, WANG C, et al. Removal of heavy metal ions by manganese dioxide-based nanomaterials and mechanism research: a review[J]. Environmental Chemistry, 2020, 39(3): 687-703 (in Chinese).
[2] 于栋,罗庆,苏伟,等.重金属废水电沉积处理技术研究及应用进展[J].化工进展,2020,39(5):1938-1949.
YU D, LUO Q, SU W, et al. A review on research and application of electrodeposition for heavy metal wastewater treatment[J]. Chemical Industry and Engineering Progress, 2020, 39(5): 1938-1949 (in Chinese).
[3] 黄子茵,管东生,王刚.海南岛社会经济发展对红树林表层土壤重金属污染的影响[J].海洋环境科学,2020,39(6):831-837.
HUANG Z Y, GUAN D S, WANG G. Heavy metal contents of mangrove surface soils affected by the social and economic development in Hainan Island[J]. Marine Environmental Science, 2020, 39(6): 831-837 (in Chinese).
[4] 张涛,阮金锴,程巍.切削液废水处理技术研究进展[J].环境工程学报,2020,14(9):2362-2377.
ZHANG T, RUAN J K, CHENG W. Progresses in the treatment processes and techniques for cutting fluid wastewater[J]. Chinese Journal of Environmental Engineering, 2020, 14(9): 2362-2377 (in Chinese).
[5] JACOB J M, KARTHIK C, SARATALE R G, et al. Biological approaches to tackle heavy metal pollution: a survey of literature[J]. Journal of Environmental Management, 2018, 217: 56-70.
[6] 徐兰芳,王锋,于英豪,等.超亲水/水下超疏油膜功能材料及其研究进展[J].材料导报,2020,34(17):17105-17114.
XU L F, WANG F, YU Y H, et al. Research progress on superhydrophilic/underwater superoleophobic functional membrane materials[J]. Materials Reports, 2020, 34(17): 17105-17114 (in Chinese).
[7] FENG Y, YANG S M, XIA L, et al. In-situ ion exchange electrocatalysis biological coupling (i-IEEBC) for simultaneously enhanced degradation of organic pollutants and heavy metals in electroplating wastewater[J]. Journal of Hazardous Materials, 2019, 364: 562-570.
[8] YANG X D, WAN Y S, ZHENG Y L, et al. Surface functional groups of carbon-based adsorbents and their roles in the removal of heavy metals from aqueous solutions: a critical review[J]. Chemical Engineering Journal, 2019, 366: 608-621.
[9] 李荣,许多,魏杰,等.净水污泥与粉末活性炭复合制备吸附剂去除氨氮研究[J].环境工程,2020,38(9):95-100+112.
LI R, XU D, WEI J, et al. Preparation of adsorbent by combined drinking water treatment sludge and powdered activated carbon and its ammonium removal performance[J]. Environmental Engineering, 2020, 38(9): 95-100+112 (in Chinese).
[10] 曾辉平,王繁烁,于亚萍,等.壳聚糖海藻酸钠铁锰泥吸附剂制备与除As(V)研究[J].中国环境科学,2020,40(3):1146-1155.
ZENG H P, WANG F S, YU Y P, et al. Preparation of chitosan-alginate adsorbent contained Fe-Mn sludge and its potential for As(V) removal[J]. China Environmental Science, 2020, 40(3): 1146-1155 (in Chinese).
[11] 冉海燕,朱叶,顾瑶,等.季铵化壳聚糖/纳米氧化锌杂化胶体粒子的制备及性能[J].功能高分子学报,2020,33(4):390-398.
RAN H Y, ZHU Y, GU Y, et al. Preparation and properties of quaternized chitosan/nano-zinc oxide hybrid colloidal particles[J]. Journal of Functional Polymers, 2020, 33(4): 390-398 (in Chinese).
[12] HASSAN M, NAIDU R, DU J H, et al. Critical review of magnetic biosorbents: their preparation, application, and regeneration for wastewater treatment[J]. Science of the Total Environment, 2020, 702: 134893.
[13] 张娇娇,赵霞,张瑞,等.三维石墨烯的制备及其吸附水中污染物的研究进展[J].化工新型材料,2020,48(8):46-49.
ZHANG J J, ZHAO X, ZHANG R, et al. Progress in the preparation of 3D graphene and its adsorption of pollutant in water[J]. New Chemical Materials, 2020, 48(8): 46-49 (in Chinese).
[14] BLAY V, BOBADILLA L F, GARCÍA A C. Zeolites and metal-organic frameworks[M]. Amsterdam: Amsterdam University Press, 2018.
[15] VALENCIA S, REY F. New developments in adsorption/separation of small molecules by zeolites[M]. Cham: Springer International Publishing, 2020.
[16] 王灿,陈天虎,刘海波,等.纳米矿物材料净化甲醛污染的研究进展[J].材料导报,2020,34(15):15003-15012.
WANG C, CHEN T H, LIU H B, et al. Research progress on application of nanominerals in formaldehyde removal[J]. Materials Reports, 2020, 34(15): 15003-15012 (in Chinese).
[17] HE D W, YUAN D H, SONG Z J, et al. Eco-friendly synthesis of high silica zeolite Y with choline as green and innocent structure-directing agent[J]. Chinese Journal of Catalysis, 2019, 40(1): 52-59.
[18] 李见云,崔节虎,郑宾国,等.秸秆掺杂与煅烧改性沸石吸附铜锌离子的特性[J].应用化工,2019,48(7):1558-1562.
LI J Y, CUI J H, ZHENG B G, et al. Preparation of zeolite modified with doped straw and calcination and adsorption performances by Cu²⁺, Zn²⁺ in simulated wastewaters[J]. Applied Chemical Industry, 2019, 48(7): 1558-1562 (in Chinese).
[19] 何春艳,张翔凌,喻俊,等.Zn系LDHs负载改性石英砂和沸石对Cr(VI)吸附效果对比及其作用机理研究[J].环境科学学报,2019,39(2):399-409.
HE C Y, ZHANG X L, YU J, et al. Study on adsorption performance and mechanism of Cr(VI) by Zn-LDHs coating on zeolites and quartz sands[J]. Acta Scientiae Circumstantiae, 2019, 39(2): 399-409 (in Chinese).
[20] 霍汉鑫,林海,董颖博,等.盐酸改性对天然斜发沸石孔道特征、成分、表面电位及阳离子交换性能的影响[J].工程科学学报,2015,37(6):746-750.
HUO H X, LIN H, DONG Y B, et al. Effects of hydrochloric acid modification on the channel characteristics, composition, surface potential and cation exchange behavior of natural clinoptilolite[J]. Chinese Journal of Engineering, 2015, 37(6): 746-750 (in Chinese).
[21] 彭申来,ULLAH R,白诗扬,等.斜发沸石的水热合成和离子交换性能及其在CH₄/N₂分离中的应用[J].石油学报(石油加工),2019,35(2):348-358.
PENG S L, ULLAH R, BAI S Y, et al. Hydrothermal synthesis of clinoptilolite and its ion exchange performance for CH₄/N₂ separation[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2019, 35(2): 348-358 (in Chinese).
[22] EBADI AMOOGHIN A, OMIDKHAH M, SANAEEPUR H, et al. Preparation and characterization of Ag⁺ ion-exchanged zeolite-Matrimid^®5218 mixed matrix membrane for CO₂/CH₄ separation[J]. Journal of Energy Chemistry, 2016, 25(3): 450-462.
[23] PANAYOTOVA M. Kinetics and thermodynamics of removal of nickel ions from wastewater by use of natural and modified zeolite[J]. Fresenius Environmental Bulletin, 2001, 10(3): 267-272.
[24] ATES A. Role of modification of natural zeolite in removal of manganese from aqueous solutions[J]. Powder Technology, 2014, 264: 86-95.
[25] LI Y R, BAI P, YAN Y, et al. Removal of Zn²⁺, Pb²⁺, Cd²⁺, and Cu²⁺ from aqueous solution by synthetic clinoptilolite[J]. Microporous and Mesoporous Materials, 2019, 273: 203-211.
[26] 刘思远,郝瑞霞,王丽沙,等.分子筛脱硅对其结构与吸附氨氮性能的影响[J].中国环境科学,2019,39(12):5029-5039.
LIU S Y, HAO R X, WANG L S, et al. Effect of molecular sieve desilication on its structure and adsorption of ammonia nitrogen[J]. China Environmental Science, 2019, 39(12): 5029-5039 (in Chinese).
[27] 张晓晓,徐文鹏,徐军,等.碱酸处理ZSM-22分子筛催化剂的MTO性能研究[J].应用化工,2019,48(7):1516-1520.
ZHANG X X, XU W P, XU J, et al. Study on the performance of alkaline acid treatment ZSM-22 catalysts for MTO reaction[J]. Applied Chemical Industry, 2019, 48(7): 1516-1520 (in Chinese).
[28] 勾明雷,王俊锴,宋文生.介孔ZSM-5沸石外表面酸性位选择性钝化及其催化性能[J].硅酸盐学报,2020,48(12):1960-1965.
GOU M L, WANG J K, SONG W S. Mesoporous ZSM-5 zeolites with external acid sites selective passivation and their catalytic performances[J]. Journal of the Chinese Ceramic Society, 2020, 48(12): 1960-1965 (in Chinese).
[29] 王宝宇,杨仁发,艾胜,等.多级孔沸石催化合成聚甲氧基二甲醚[J].石油化工,2020,49(4):327-332.
WANG B Y, YANG R F, AI S, et al. Synthesis of polyoxymethylene dimethyl ethers catalyzed by hierarchical zeolite[J]. Petrochemical Technology, 2020, 49(4): 327-332 (in Chinese).
[30] 王德举,刘仲能,李学礼,等.介孔沸石材料[J].化学进展,2008,20(5):637-643.
WANG D J, LIU Z N, LI X L, et al. Mesoporous zeolite materials[J]. Progress in Chemistry, 2008, 20(5): 637-643 (in Chinese).
[31] AGHEL B, MOHADESI M, GOURAN A, et al. Use of modified Iranian clinoptilolite zeolite for cadmium and lead removal from oil refinery wastewater[J]. International Journal of Environmental Science and Technology, 2020, 17(3): 1239-1250.
[32] ADINEHVAND J, SHOKUHI RAD A, TEHRANI A S. Acid-treated zeolite (clinoptilolite) and its potential to zinc removal from water sample[J]. International Journal of Environmental Science and Technology, 2016, 13(11): 2705-2712.
[33] 张泽,程军,仇亿,等.碱处理脱硅介孔分子筛催化脱氧断键制生物航油研究[J].化工学报,2019,70(8):2919-2927.
ZHANG Z, CHENG J, QIU Y, et al. Hydrodeoxygenation and hydrocracking to produce jet biofuel catalyzed by mesoporous zeolite desilicated with NaOH treatment[J]. CIESC Journal, 2019, 70(8): 2919-2927 (in Chinese).
[34] 张健,万东锦,刘永德,等.碱改性ZSM-5沸石分子筛吸附去除水中Pb²⁺的研究[J].环境工程技术学报,2015,5(4):277-283.
ZHANG J, WAN D J, LIU Y D, et al. Alkali treatment of ZSM-5 molecular sieve and its adsorptive performance of Pb²⁺ from aqueous solution[J]. Journal of Environmental Engineering Technology, 2015, 5(4): 277-283 (in Chinese).
[35] ATES A, AKG ÜL G. Modification of natural zeolite with NaOH for removal of manganese in drinking water[J]. Powder Technology, 2016, 287: 285-291.
[36] GILI M B Z, OLEGARIO E M. Effects of γ-irradiation on the Cu²⁺ sorption behaviour of NaOH-modified Philippine natural zeolites[J]. Clay Minerals, 2020, 55(3): 248-255.
[37] JIMÉNEZ-CASTAÑEDA M, MEDINA D. Use of surfactant-modified zeolites and clays for the removal of heavy metals from water[J]. Water, 2017, 9(4): 235.
[38] ELSHEIKH A F, AHMAD U K, RAMLI Z. Investigations on humic acid removal from water using surfactant-modified zeolite as adsorbent in a fixed-bed reactor[J]. Applied Water Science, 2017, 7(6): 2843-2856.
[39] HAILU S L, NAIR B U, REDI-ABSHIRO M, et al. Preparation and characterization of cationic surfactant modified zeolite adsorbent material for adsorption of organic and inorganic industrial pollutants[J]. Journal of Environmental Chemical Engineering, 2017, 5(4): 3319-3329.
[40] ONYANGO M, KITTINYA J, HADEBE N, et al. Sorption of melanoidin onto surfactant modified zeolite[J]. Chemical Industry and Chemical Engineering Quarterly, 2011, 17(4): 385-395.
[41] SZALA B, BAJDA T, JELEŃ A. Removal of chromium(VI) from aqueous solutions using zeolites modified with HDTMA and ODTMA surfactants[J]. Clay Minerals, 2015, 50(1): 103-115.
[42] ZEKAVAT S R, RAOUF F, TALESH S S A. Simultaneous adsorption of Cu²⁺ and Cr(VI) using HDTMA-modified zeolite: isotherm, kinetic, mechanism, and thermodynamic studies[J]. Water Science and Technology, 2020, 82(9): 1808-1824.
[43] REN H X, JIANG J H, WU D J, et al. Selective adsorption of Pb(II) and Cr(VI) by surfactant-modified and unmodified natural zeolites: a comparative study on kinetics, equilibrium, and mechanism[J]. Water, Air, & Soil Pollution, 2016, 227(4): 1-11.
[44] KAEWPRACHUM W, WONGSAKULPHASATCH S, KIATKITTIPONG W, et al. SDS modified mesoporous silica MCM-41 for the adsorption of Cu²⁺, Cd²⁺, Zn²⁺ from aqueous systems[J]. Journal of Environmental Chemical Engineering, 2020, 8(1): 102920.
[45] TILAMI S E, AZIZI S N. Methionine templated analcime for enhancing heavy metal adsorption[J]. ScienceAsia, 2017, 43(1): 42-46.
[46] ZHANG S Q, LV T, MU Y, et al. High adsorption of Cd(II) by modification of synthetic zeolites Y, A and mordenite with thiourea[J]. Chinese Journal of Chemical Engineering, 2020, 28(12): 3117-3125.
[47] LEYVA-RAMOS R, JACOBO-AZUARA A, DIAZ-FLORES P E, et al. Adsorption of chromium(VI) from an aqueous solution on a surfactant-modified zeolite[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008, 330(1): 35-41.
[48] CHEN F Y, HONG M Z, YOU W J, et al. Simultaneous efficient adsorption of Pb²⁺ and MnO^-₄ ions by MCM-41 functionalized with amine and nitrilotriacetic acid anhydride[J]. Applied Surface Science, 2015, 357: 856-865.
[49] JAVADIAN H, TAGHAVI M. Application of novel polypyrrole/thiol-functionalized zeolite Beta/MCM-41 type mesoporous silica nanocomposite for adsorption of Hg²⁺ from aqueous solution and industrial wastewater: kinetic, isotherm and thermodynamic studies[J]. Applied Surface Science, 2014, 289: 487-494.
[50] 刘帆,张荣斌,王飞,等.鸟粪石-沸石复合材料对水中镉的吸附性能研究[J].环境科学学报,2019,39(9):2988-2996.
LIU F, ZHANG R B, WANG F, et al. Adsorption of cadmium onto struvite-zeolite composite in aqueous solution[J]. Acta Scientiae Circumstantiae, 2019, 39(9): 2988-2996 (in Chinese).
[51] 马文婕,陈天虎,陈冬,等.δ-MnO₂/沸石纳米复合材料同时去除地下水中的铁锰氨氮[J].环境科学,2019,40(10):4553-4561.
MA W J, CHEN T H, CHEN D, et al. Removal of Fe(Ⅱ), Mn(Ⅱ), and NH⁺₄-N by using δ-MnO₂ coated zeolite[J]. Environmental Science, 2019, 40(10): 4553-4561 (in Chinese).
[52] 刘红,程顺,李春侠,等.凹凸棒土负载硫化纳米零价铁的制备及其去除水中As(Ⅲ)性能研究[J].武汉科技大学学报,2020,43(1):30-36.
LIU H, CHENG S, LI C X, et al. Preparation of attapulgite-loaded sulfide-modified nanoscale zero-valent iron and its adsorption of As(Ⅲ) from aqueous solution[J]. Journal of Wuhan University of Science and Technology, 2020, 43(1): 30-36 (in Chinese).
[53] ZHAO S F, FAN X, YANG J S, et al. Enhanced removal of Cr(VI) from wastewater by nanoscale zero valent iron supported on layered double hydroxides[J]. Journal of Porous Materials, 2020, 27(6): 1701-1710.
[54] ZHANG X L, SONG Z, DOU Y K, et al. Removal difference of Cr(VI) by modified zeolites coated with MgAl and ZnAl-layered double hydroxides: efficiency, factors and mechanism[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 621: 126583.
[55] KRSTIĆ N S, DIMITRIJEVIĆ V D, et al. Zero-valent iron nickel modified natural zeolite material: characterization and environmental aspect of application-first results[J]. Studia Universitatis Babeş-Bolyai Chemia, 2021, 66(1): 23-34.
[56] 王晶.GO-4A分子筛复合材料的制备及吸附性能研究[D].西安:西安工程大学,2019.
WANG J. Preparation and adsorption properties of GO-4A zeolite composites[D]. Xi’an: Xi’an Polytechnic University, 2019 (in Chinese).
[57] BAHIRAEI A, BEHIN J. Sonochemical immobilization of MnO₂ nanoparticles on NaP-zeolite for enhanced Hg(II) adsorption from water[J]. Journal of Environmental Chemical Engineering, 2020, 8(3): 103790.
[58] LV G, LI Z H, JIANG W T, et al. Removal of Cr(VI) from water using Fe(II)-modified natural zeolite[J]. Chemical Engineering Research and Design, 2014, 92(2): 384-390.
[59] 毕薇薇,陈娅,马晓雁,等.磁性有序介孔碳的制备及其对水中双酚A的吸附[J].中国环境科学,2020,40(11):4762-4769.
BI W W, CHEN Y, MA X Y, et al. Synthesis of magnetic ordered mesoporous carbon and its adsorption of bisphenol A in water[J]. China Environmental Science, 2020, 40(11): 4762-4769 (in Chinese).
[60] AMJADI M, SAMADI A, MANZOORI J L. A composite prepared from halloysite nanotubes and magnetite (Fe₃O₄) as a new magnetic sorbent for the preconcentration of cadmium(II) prior to its determination by flame atomic absorption spectrometry[J]. Microchimica Acta, 2015, 182(9/10): 1627-1633.
[61] OLIVEIRA L C A, PETKOWICZ D I, SMANIOTTO A, et al. Magnetic zeolites: a new adsorbent for removal of metallic contaminants from water[J]. Water Research, 2004, 38(17): 3699-3704.
[62] PARIS E C, MALAFATTI J O D, MUSETTI H C, et al. Faujasite zeolite decorated with cobalt ferrite nanoparticles for improving removal and reuse in Pb²⁺ ions adsorption[J]. Chinese Journal of Chemical Engineering, 2020, 28(7): 1884-1890.
[63] PENG Z D, LIN X M, ZHANG Y L, et al. Removal of cadmium from wastewater by magnetic zeolite synthesized from natural, low-grade molybdenum[J]. Science of the Total Environment, 2021, 772: 145355.
[64] KRAGOVIĆ M, DAKOVIĆ A, MARKOVIĆ M, et al. Characterization of lead sorption by the natural and Fe(Ⅲ)-modified zeolite[J]. Applied Surface Science, 2013, 283: 764-774.
[65] 张振国,张铭栋,顾平,等.沸石材料吸附水中放射性锶和铯的研究进展[J].化工进展,2019,38(4):1984-1995.
ZHANG Z G, ZHANG M D, GU P, et al. Progress in adsorption of radioactive strontium and cesium from aqueous solution on zeolite materials[J]. Chemical Industry and Engineering Progress, 2019, 38(4): 1984-1995 (in Chinese).
[66] 艾沙·努拉洪,方亚平,高希然,等.不同晶粒ZSM-5沸石分子筛对合成气羰基化反应性能的影响[J].分子催化,2020,34(2):105-115.
NULAHONG A S, FANG Y P, GAO X R, et al. Effect of ZSM-5 zeolites with different grains on carbonylation of syngas[J]. Journal of Molecular Catalysis (China), 2020, 34(2): 105-115 (in Chinese).
[67] LI X, SHEN W L. The influence of pore structure on reaction mechanism of propylene dimerization in zeolite: a theoretical viewpoint[J]. International Journal of Quantum Chemistry, 2019, 119(16): e25962.
[68] 亢玉红,李健,高平强,等.利用粉煤灰基X型沸石去除废水中的铜离子[J].材料科学与工程学报,2018,36(6):975-980.
KANG Y H, LI J, GAO P Q, et al. Removal of Cu²⁺ from waste water with zeolite X synthesized by coal fly ash[J]. Journal of Materials Science and Engineering, 2018, 36(6): 975-980 (in Chinese).
[69] 彭利冲,李素芹.Na-X分子筛对Cu(Ⅱ)吸附性能研究[J].人工晶体学报,2018,47(9):1803-1810.
PENG L C, LI S Q. Study on adsorption properties of Cu(Ⅱ) on Na-X zeolite[J]. Journal of Synthetic Crystals, 2018, 47(9): 1803-1810 (in Chinese).
[70] LUO H W, LAW W W, WU Y C, et al. Hydrothermal synthesis of needle-like nanocrystalline zeolites from metakaolin and their applications for efficient removal of organic pollutants and heavy metals[J]. Microporous and Mesoporous Materials, 2018, 272: 8-15.
[71] YILMAZ Y. NaX nano-taneciklerin ağır metal ve boyar maddelere karşı adsorpsiyon kapasitelerinin belirlenmesi[J]. Journal of the Faculty of Engineering and Architecture of Gazi University, 2019, 34 (4): 2113-2124.
[72] GONCALVES M B, SCHMIDT D V C, DOS SANTOS F S, et al. Nanostructured faujasite zeolite as metal ion adsorbent: kinetics, equilibrium adsorption and metal recovery studies[J]. Water Science and Technology, 2021, 83(2): 358-371.