硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (9): 3255-3271.DOI: 10.16552/j.cnki.issn1001-1625.2025.0122
易世蓉, 张苗苗, 陈思思, 王琳琳, 倪宇航, 韩志伟, 赵丹
收稿日期:2025-02-07
修订日期:2025-04-14
出版日期:2025-09-15
发布日期:2025-09-19
通信作者:
王琳琳,博士,高级工程师。E-mail:wllxjau@outlook.com
作者简介:易世蓉(2004—),女。主要从事天然材料资源化利用方面的研究。E-mail:3327308041@qq.com
基金资助:YI Shirong, ZHANG Miaomiao, CHEN Sisi, WANG Linlin, NI Yuhang, HAN Zhiwei, ZHAO Dan
Received:2025-02-07
Revised:2025-04-14
Published:2025-09-15
Online:2025-09-19
摘要: 膨润土是天然的非金属矿产资源,通过技术改性将其转化为有附加值产品,广泛应用于工业、农业和环境治理等领域,是实现资源循环利用和减少环境负面影响的重要途径。本文对当前国内外膨润土改性材料的制备方法、表征技术及应用现状进行了综述,总结了膨润土性能提升的方法、原理及表征测试方法,分析了改性膨润土在土壤改良、环境修复、农业应用(肥料添加剂、农药吸附剂)及电子、汽车和航空航天等领域的应用潜力及不足,并展望了改性膨润土材料未来发展方向,为高性能改性膨润土材料的研发提供了参考。
中图分类号:
易世蓉, 张苗苗, 陈思思, 王琳琳, 倪宇航, 韩志伟, 赵丹. 膨润土改性材料的制备、表征及应用研究进展[J]. 硅酸盐通报, 2025, 44(9): 3255-3271.
YI Shirong, ZHANG Miaomiao, CHEN Sisi, WANG Linlin, NI Yuhang, HAN Zhiwei, ZHAO Dan. Research Progress on Preparation, Characterization and Application of Modified Bentonite Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(9): 3255-3271.
| [1] 黄荣强, 阙绍娟. 我国膨润土资源开发应用现状[J]. 西部资源, 2010(5): 36-38. HUANG R Q, QUE S J. Development and application status of bentonite resources in China[J]. Western Resources, 2010(5): 36-38 (in Chinese). [2] 夏意峻. 富水砂层顶管泥浆减阻特性研究[D]. 北京: 中国地质大学(北京), 2023. XIA Y J. Study on drag reduction characteristics of pipe jacking mud in water-rich sand layer[D]. Beijing: China University of Geosciences (Beijing), 2023 (in Chinese). [3] 刘承帅, 万洪富, 侯梅芳, 等. 我国主要产地膨润土颗粒组成和蒙脱石含量研究[J]. 非金属矿, 2005, 28(1): 40-43. LIU C S, WAN H F, HOU M F, et al. Study on particle size distribution & montmorillonite content of bentonite in main deposits of China[J]. Non-metallic Mines, 2005, 28(1): 40-43 (in Chinese). [4] 郭传杰, 祝琳华. 插层膨润土复合材料制备及应用的研究进展[J]. 硅酸盐通报, 2011, 30(1): 125-128. GUO C J, ZHU L H. Development in preparation and application of bentonite composites by intercalation[J]. Bulletin of the Chinese Ceramic Society, 2011, 30(1): 125-128 (in Chinese). [5] 古丽娜尔·巴合提别克, 王 瑛, 苏金娟, 等. 膨润土-甘草渣复合材料保水效应[J]. 新疆农业科学, 2021, 58(2): 361-374. GULINAER B, WANG Y, SU J J, et al. Study on water retention effect of bentonite and licorice residue composites material[J]. Xinjiang Agricultural Sciences, 2021, 58(2): 361-374 (in Chinese). [6] 孙 艳, 张士荣, 丁效东, 等. 肥料添加剂NAM对盐渍土壤理化性质及水稻氮肥农学利用效率的影响[J]. 山东农业科学, 2020, 52(4): 86-91. SUN Y, ZHANG S R, DING X D, et al. Effects of fertilizer additive NAM on physical and chemical properties of saline soil and agronomic utilization efficiency of nitrogen fertilizer in rice[J]. Shandong Agricultural Sciences, 2020, 52(4): 86-91 (in Chinese). [7] AL-ZAYADI L R S, ALI HUSSEIN A. The impact of adding bentonite and organic fertilizer on the growth and yield of sorghum in desert soil under the conditions of the badia Al-samawa[J]. IOP Conference Series: Earth and Environmental Science, 2024, 1371(8): 082007. [8] 张梅琪, 娄现芬, 陈利标, 等. 丙草胺在有机膨润土的等温吸附和吸附动力学研究[J]. 广西大学学报(自然科学版), 2022, 47(3): 756-762. ZHANG M Q, LOU X F, CHEN L B, et al. Isotherms and kinetics of pretilachlor adsorption onto organobentonites[J]. Journal of Guangxi University (Natural Science Edition), 2022, 47(3): 756-762 (in Chinese). [9] SHISHKIN R, ARKHIPOVA V, ZHIRENKINA N, et al. Exploring graphite-based thermal greases for optimal microelectronic device cooling[J]. International Journal of Thermophysics, 2024, 45(10): 141. [10] 曹明伦. 助分散剂极性对膨润土润滑脂性能的影响[J]. 合成润滑材料, 2024, 51(2): 17-22. CAO M L. The influence of the polarity of auxiliary dispersant on the performance of bentonite-based lubricating greases[J]. Synthetic Lubricants, 2024, 51(2): 17-22 (in Chinese). [11] 郑长文, 管俊芳, 郑佳敏, 等. 矿业领域膨润土应用的研究进展[J]. 矿产综合利用, 2020(3): 22-27. ZHENG C W, GUAN J F, ZHENG J M, et al. Progress in the application of bentonite in mining industry[J]. Multipurpose Utilization of Mineral Resources, 2020(3): 22-27 (in Chinese). [12] SHEN Z. Performance analysis of bentonite-PVA fiber cement-based composites for building based on BP neural network[J]. Key Engineering Materials, 2020, 852: 209-219. [13] 郭宏斌. 膨润土浆液配比对软土地层CSM水泥土搅拌墙成墙质量影响[J]. 建筑施工, 2024, 46(3): 317-321. GUO H B. Effect of bentonite slurry ratio on the quality of CSM cement-soil mixing wall in soft soil layer[J]. Building Construction, 2024, 46(3): 317-321 (in Chinese). [14] DINIZ C V, NASCIMENTO J V, BINATTI I, et al. Hybrid catalysts based on waste electrical and electronic equipment supported on bentonite for the removal of contaminants compounds in liquid phase[J]. Catalysis Today, 2020, 344: 75-83. [15] 周 萍, 李 明, 武元鹏. 聚合物/膨润土纳米复合材料的研究进展[J]. 功能材料, 2022, 53(7): 7058-7068. ZHOU P, LI M, WU Y P. Research progress of polymer/bentonite nanocomposites[J]. Journal of Functional Materials, 2022, 53(7): 7058-7068 (in Chinese). [16] 姜璐莎, 李超越, 卢光华, 等. 聚合物改性膨润土在阻隔屏障中酸碱盐条件下的防渗效果[J]. 太原理工大学学报, 2023, 54(6): 959-968. JIANG L S, LI C Y, LU G H, et al. Hydraulic performance of polymer-modified bentonite in containment barriers under aggressive conditions[J]. Journal of Taiyuan University of Technology, 2023, 54(6): 959-968 (in Chinese). [17] SCALIA J IV, BENSON C H, BOHNHOFF G L, et al. Long-term hydraulic conductivity of a bentonite-polymer composite permeated with aggressive inorganic solutions[J]. Journal of Geotechnical and Geoenvironmental Engineering, 2014, 140(3): 04013025. [18] ONIKATA M, KONDO M, HAYASHI N, et al. Complex formation of cation-exchanged montmorillonites with propylene carbonate: osmotic swelling in aqueous electrolyte solutions[J]. Clays and Clay Minerals, 1999, 47(5): 672-677. [19] DI EMIDIO G. Hydraulic and chemico-osmotic performance of polymer treated clays[D]. Ghent: Ghent University, 2010. [20] MAZZIERI F, DI EMIDIO G, VAN IMPE P O. Diffusion of calcium chloride in a modified bentonite: impact on osmotic efficiency and hydraulic conductivity[J]. Clays and Clay Minerals, 2010, 58(3): 351-363. [21] KOLSTAD D C, BENSON C H, EDIL T B. Hydraulic conductivity and swell of nonprehydrated geosynthetic clay liners permeated with multispecies inorganic solutions[J]. Journal of Geotechnical and Geoenvironmental Engineering, 2004, 130(12): 1236-1249. [22] MUHAMMAD N, SIDDIQUA S. Calcium bentonite vs sodium bentonite: the potential of calcium bentonite for soil foundation[J]. Materials Today: Proceedings, 2022, 48: 822-827. [23] 陆启财, 陈铁军, 罗艳红, 等. 低品位膨润土改性及其在球团中的应用研究[J]. 烧结球团, 2021, 46(3): 39-46. LU Q C, CHEN T J, LUO Y H, et al. Research on modification of low-grade bentonite and its application in pellets[J]. Sintering and Pelletizing, 2021, 46(3): 39-46 (in Chinese). [24] 马俊英, 杨 静, 蔺尾燕, 等. 盐酸改性膨润土处理含镉废水的研究[J]. 应用化工, 2019, 48(2): 357-360. MA J Y, YANG J, LIN W Y, et al. Study on treatment of cadmium wastewater by the acid modified bentonite[J]. Applied Chemical Industry, 2019, 48(2): 357-360 (in Chinese). [25] 苏成政. 膨润土的改性及吸湿性能研究[J]. 中国非金属矿工业导刊, 2023(3): 55-57+60. SU C Z. Modification and humidity adsorption property of bentonite[J]. China Non-metallic Minerals Industry, 2023(3): 55-57+60 (in Chinese). [26] 武雷杰, 杨秀娟, 张 路, 等. 聚合氯化铝(PAC)改性膨胀土的胀缩特性试验研究[J]. 长江科学院院报, 2020, 37(1): 84-89. WU L J, YANG X J, ZHANG L, et al. Experimental study on swelling and shrinkage of polyaluminum chloride (PAC) modified expansive soil[J]. Journal of Yangtze River Scientific Research Institute, 2020, 37(1): 84-89 (in Chinese). [27] 马锋锋, 牛雪妍. 磁性膨润土对甲基橙的吸附特性研究[J]. 水处理技术, 2023, 49(8): 71-76+81. MA F F, NIU X Y. Adsorption of methyl orange on magnetic bentonite from aqueous solution[J]. Technology of Water Treatment, 2023, 49(8): 71-76+81 (in Chinese). [28] MOCKOVĞIAKOVÁ A, OROLÍNOVÁ Z, KVARLA J. Enhancement of the bentonite sorption properties[J]. Journal of Hazardous Materials, 2010, 180(1/2/3): 274-281. [29] LACERDA E, MONTEIRO F C, KLOSS J R, et al. Bentonite clay modified with Nb2O5: an efficient and reused photocatalyst for the degradation of reactive textile dye[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2020, 388: 112084. [30] SONG R M, LI Z M, LI W L, et al. Improved adsorption and desorption behavior of Cd on thiol-modified bentonite grafted with cysteamine hydrochloride[J]. Research on Chemical Intermediates, 2022, 48(6): 2721-2744. [31] GHEZALI S, MAHDAD-BENZERDJEB A, AMERI M, et al. Adsorption of 2,4,6-trichlorophenol on bentonite modified with benzyldimethyltetradecylammonium chloride[J]. Chemistry International, 2018, 4(1): 24-32. [32] HE H J, XU E P, QIU Z H, et al. Phenol adsorption mechanism of organically modified bentonite and its microstructural changes[J]. Sustainability, 2022, 14(3): 1318. [33] 蔡杰慧, 杨英全, 李致宝, 等. 改性蔗渣纤维素-海藻酸钙-膨润土微球制备及吸附[J]. 化学工程, 2024, 52(5): 39-45. CAI J H, YANG Y Q, LI Z B, et al. Preparation and adsorption of modified bagasse cellulose-calcium alginate-bentonite microspheres[J]. Chemical Engineering (China), 2024, 52(5): 39-45 (in Chinese). [34] EMIDIO G, MAZZIERI F, VERASTEGUI-FLORES R D, et al. Polymer-treated bentonite clay for chemical-resistant geosynthetic clay liners[J]. Geosynthetics International, 2015, 22(1): 125-137. [35] CHIKWE T N, EWUZIE H E, NGOBIRI N C, et al. Competitive adsorption of xylene and toluene on modified and unmodified magnesium exchanged bentonite clay mineral[J]. Journal of Applied Sciences and Environmental Management, 2018, 22(3): 298. [36] ABDELKRIM S, MOKHTAR A, DJELAD A, et al. Chitosan/Ag-bentonite nanocomposites: preparation, characterization, swelling and biological properties[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2020, 30(3): 831-840. [37] 范日东, 吴俊楠, 杨爱武, 等. 苯酚作用下有机改性膨润土化学相容性试验研究[J/OL]. 土木工程学报, 2023: 1-10 (2023-11-15) [2025-01-01]. https://kns.cnki.net/KCMS/detail/detail.aspx?filename=TMGC20231113005&dbname=CJFD&dbcode=CJFQ. FAN R D, WU J N, YANG A W, et al. Experimental study on chemical compatibility of organically modified bentonite under the action of phenol[J/OL]. China Industrial Economics, 2023: 1-10 (2023-11-15) [2025-01-01]. https://kns.cnki.net/KCMS/detail/detail.aspx?filename=TMGC20231113005&dbname=CJFD&dbcode=CJFQ (in Chinese). [38] 江 旭, 刘全军, 纪慧超, 等. 不同改性膨润土对含磷废水的吸附试验研究[J]. 非金属矿, 2018, 41(2): 20-22. JIANG X, LIU Q J, JI H C, et al. Adsorption experiment of different modified bentonites on wastewater containing phosphorus[J]. Non-Metallic Mines, 2018, 41(2): 20-22 (in Chinese). [39] 许小龙, 刘兰俊. 膨润土钠化改性无机柱撑研究进展及应用[J]. 当代化工, 2013, 42(9): 1261-1263. XU X L, LIU L J. Research progress and application of sodium modified and inorganic pillared bentonite[J]. Contemporary Chemical Industry, 2013, 42(9): 1261-1263 (in Chinese). [40] 慕利梅, 王图锦, 曹 琳, 等. 改性膨润土对水中磷和藻类的同步去除[J]. 环境污染与防治, 2023, 45(3): 310-315+321. MU L M, WANG T J, CAO L, et al. Simultaneous removal of phosphorus and algae in water by modified bentonite[J]. Environmental Pollution & Control, 2023, 45(3): 310-315+321 (in Chinese). [41] EL-NAGAR D A, SARY D H. Synthesis and characterization of nano bentonite and its effect on some properties of sandy soils[J]. Soil and Tillage Research, 2021, 208: 104872. [42] 张泽雨, 周仲魁, 张益硕, 等. CTAB改性铁柱撑膨润土的制备及其对废水中低浓度铀(Ⅵ)的吸附性能研究[J]. 湿法冶金, 2023, 42(5): 522-531. ZHANG Z Y, ZHOU Z K, ZHANG Y S, et al. Preparation of iron-pillared montmorillonite modified with CTAB and its adsorption properties for uranium(Ⅵ) adsorption from low-concentration wastewater[J]. Hydrometallurgy of China, 2023, 42(5): 522-531 (in Chinese). [43] TANGESTANIFARD M, GHAZIASKAR H. Arenesulfonic acid-functionalized bentonite as catalyst in glycerol esterification with acetic acid[J]. Catalysts, 2017, 7(7): 211. [44] MOTSHEKGA S C, RAY S S, ONYANGO M S, et al. Microwave-assisted synthesis, characterization and antibacterial activity of Ag/ZnO nanoparticles supported bentonite clay[J]. Journal of Hazardous Materials, 2013, 262: 439-446. [45] 何建雄, 潘浣钰, 叶竹林, 等. 膨润土吸蓝量测定方法的改进[J]. 广东化工, 2017, 44(4): 116-117. HE J X, PAN H Y, YE Z L, et al. Improvement on bentonite blue suction quantity determination method[J]. Guangdong Chemical Industry, 2017, 44(4): 116-117 (in Chinese). [46] 吴 涛, 韩书华, 张春光, 等. 电导法测定粘土矿物的阳离子交换容量[J]. 油田化学, 2002, 19(3): 205-207+221. WU T, HAN S H, ZHANG C G, et al. Determination of cationic exchange capacity of clay minerals by conductometric titration[J]. Oilfield Chemistry, 2002, 19(3): 205-207+221 (in Chinese). [47] 胡梦颖, 张鹏鹏, 徐进力, 等. CEC前处理系统——凯氏定氮仪快速测定土壤中的阳离子交换量[J]. 物探与化探, 2023, 47(2): 458-463. HU M Y, ZHANG P P, XU J L, et al. Rapid determination of soil cation exchange capacity using a cation exchange capacity pretreatment system and a Kjeldahl apparatus[J]. Geophysical and Geochemical Exploration, 2023, 47(2): 458-463 (in Chinese). [48] ABDULLAHI S, AUDU A. Comparative analysis on chemical composition of bentonite clays obtained from Ashaka and tango deposits in Gombe State, Nigeria[J]. ChemSearch Journal, 2017, 8(2): 35-40. [49] 王泽龙, 李顺义, 吴朕君. 膨润土改性和复配及在废水处理中的应用进展[J]. 工业水处理, 2022, 42(2): 11-18. WANG Z L, LI S Y, WU Z J. Application development of modification and compounding of bentonite in wastewater[J]. Industrial Water Treatment, 2022, 42(2): 11-18 (in Chinese). [50] 曹春艳, 赵莹莹. 羟基铁柱撑膨润土处理含磷废水的研究[J]. 环境科学与技术, 2013, 36(4): 164-167+194. CAO C Y, ZHAO Y Y. Disposal of phosphorus wastewater by hydroxyl Fe pillared bentonite[J]. Environmental Science & Technology, 2013, 36(4): 164-167+194 (in Chinese). [51] KUMARARAJA P, SUVANA S, SARASWATHY R, et al. Mitigation of eutrophication through phosphate removal by aluminium pillared bentonite from aquaculture discharge water[J]. Ocean & Coastal Management, 2019, 182: 104951. [52] MAHADEVAN H, ANOOP KRISHNAN K, PILLAI R R, et al. Stirring-ageing technique to develop zirconium-pillared bentonite clay along with its surface profiling using various spectroscopic techniques[J]. Research on Chemical Intermediates, 2020, 46(1): 639-660. [53] RAVARI M H, SARRAFI A, TAHMOORESI M. Synthesizing and characterizing the mixed Al, Cu-pillared and copper doped Al-pillared bentonite for electrocatalytic reduction of CO2[J]. South African Journal of Chemical Engineering, 2020, 31: 1-6. [54] SUZUKI R. Effect of adding bentonite to porous silica via the sol-gel method[J]. ACS Omega, 2024, 9(9): 10577-10582. [55] ROSTAMI-VARTOONI A, ALIZADEH M, BAGHERZADEH M. Green synthesis, characterization and catalytic activity of natural bentonite-supported copper nanoparticles for the solvent-free synthesis of 1-substituted 1H-1, 2, 3, 4-tetrazoles and reduction of 4-nitrophenol[J]. Beilstein Journal of Nanotechnology, 2015, 6: 2300-2309. [56] GARCÍA-GARCÍA F A, CRISTIANI-URBINA E, MORALES-BARRERA L, et al. Spectroscopic and microestructural evidence for T-2 toxin adsorption mechanism by natural bentonite modified with organic cations[J]. Toxins, 2023, 15(7): 470. [57] KLIMEK A, GAWEŁ A, GÓRNIAK K, et al. CO2 sorption on Ti-, Zr-, and [Ti, Zr]-pillared montmorillonites[J]. Materials, 2024, 17(16): 4036. [58] AUMNATE C, LIMPANART S, SOATTHIYANON N, et al. PP/organoclay nanocomposites for fused filament fabrication (FFF) 3D printing[J]. Express Polymer Letters, 2019, 13(10): 898-909. [59] 姜葱葱, 高子栋, 李国忠. 用于墙体建筑节能的复合相变材料的试验研究[J]. 砖瓦, 2010(12): 10-12. JIANG C C, GAO Z D, LI G Z. Study on composite phase change material in the energy-conservation wall[J]. Block-Brick-Tile, 2010(12): 10-12 (in Chinese). [60] 李明珠. 砂型铸造发动机缸体表面粘砂研究[D]. 哈尔滨: 哈尔滨工业大学, 2017: 43-44. LI M Z. Surface bonding sand of sand casting cylinder block[D]. Harbin: Harbin Institute of Technology, 2017: 43-44 (in Chinese). [61] 马清亮. 磁性膨润土改性吸附材料的制备及其应用研究[D]. 太原: 太原理工大学, 2016: 69-70. MA Q L. Synthesis of magnetic modified bentonite Adsorbents and its application[D]. Taiyuan: Taiyuan University of Technology, 2016: 69-70 (in Chinese). [62] GHIDIU M, LUKATSKAYA M R, ZHAO M Q, et al. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance[J]. Nature, 2014, 516(7529): 78-81. [63] 刘 冰. 改性膨润土对土壤中有机质的固定作用及其生物效应研究[D]. 泰安: 山东农业大学, 2023: 20-21. LIU B. Study on the fixation effect of modified bentonite on soil organic matter and biological effects[D]. Taian: Shandong Agricultural University, 2023: 20-21 (in Chinese). [64] 陈卫琴, 黄树梅, 李 杨, 等. 改性膨润土对污水中重金属离子吸附实验研究[J]. 矿产综合利用, 2024(3): 50-57. CHEN W Q, HUANG S M, LI Y, et al. Experimental study on the adsorption of heavy metal ions in wastewater by modified bentonite[J]. Multipurpose Utilization of Mineral Resources, 2024(3): 50-57 (in Chinese). [65] 晏全香, 房 博, 蓝灿文, 等. 改性膨润土矿物材料制备试验[J]. 福州大学学报(自然科学版), 2020, 48(2): 257-262. YAN Q X, FANG B, LAN C W, et al. Preparation of modified bentonite mineral materials[J]. Journal of Fuzhou University (Natural Science Edition), 2020, 48(2): 257-262 (in Chinese). [66] WERSIN P, HADI J, KICZKA M, et al. Unravelling the corrosion processes at steel/bentonite interfaces in in situ tests[J]. Materials and Corrosion, 2023, 74(11/12): 1716-1727. [67] ADEBOJE A O, KUPOLATI W K, SADIKU E R, et al. Experimental investigation of modified bentonite clay-crumb rubber concrete[J]. Construction and Building Materials, 2020, 233: 117187. [68] LI Z F, DONG H P, ZHANG Y L, et al. Enhanced removal of Ni(II) by nanoscale zero valent iron supported on Na-saturated bentonite[J]. Journal of Colloid and Interface Science, 2017, 497: 43-49. [69] JÚNIOR R M S, DE OLIVEIRA T A, ARAQUE L M, et al. Thermal behavior of biodegradable bionanocomposites: influence of bentonite and vermiculite clays[J]. Journal of Materials Research and Technology, 2019, 8(3): 3234-3243. [70] REITZEL K, ANDERSEN F Ø, EGEMOSE S, et al. Phosphate adsorption by lanthanum modified bentonite clay in fresh and brackish water[J]. Water Research, 2013, 47(8): 2787-2796. [71] 强 瑀. EDTA钙基膨润土的制备及其对铅锌矿区土壤重金属的修复效果[D]. 贵阳: 贵州师范大学, 2022. QIANG Y. Preparation of EDTA calcium-based bentonite and its remediation effect on soil heavy metals in lead-zinc mine area[D]. Guiyang: Guizhou Normal University, 2022 (in Chinese). [72] 孟兴锐. 巯基膨润土对水稻土中镉形态转化的影响研究[D]. 成都: 成都理工大学, 2019. MENG X R. Effect of mercaptobentonite on speciation transformation of cadmium in paddy soil[D]. Chengdu: Chengdu University of Technology, 2019 (in Chinese). [73] 张梦雪. 生物炭、膨润土、有机肥改良风沙土对土壤微生物量的影响研究[D]. 阜新: 辽宁工程技术大学, 2020. ZHANG M X. Effect of biochar, organic fertilizer and bentonite on oil microbial iomass of aeolian sandy soil[D]. Fuxin: Liaoning Technical University, 2020 (in Chinese). [74] 汤家喜, 李 玉, 朱永乐, 等. 生物炭与膨润土对辽西北风沙土理化性质的影响研究[J]. 干旱区资源与环境, 2022, 36(3): 143-150. TANG J X, LI Y, ZHU Y L, et al. Effect of biochar and bentonite on physicochemical properties of sandy soil in northwestern Liaoning province[J]. Journal of Arid Land Resources and Environment, 2022, 36(3): 143-150 (in Chinese). [75] 李婧男, 孙向阳, 张 贺, 等. 暗管排盐条件下园林废弃物与膨润土对滨海盐土的改良效果研究[J]. 应用基础与工程科学学报, 2021, 29(3): 562-574. LI J N, SUN X Y, ZHANG H, et al. Study on the amelioration effect of garden waste and bentonite on coastal saline soil under subsurface drainage[J]. Journal of Basic Science and Engineering, 2021, 29(3): 562-574 (in Chinese). [76] 马 帅. 纳米级膨润土的改性制备及其性能研究[D]. 阜新: 辽宁工程技术大学, 2022. MA S. Study on the modification, preparation and properties of nanoscale bentonite[D]. Fuxin: Liaoning Technical University, 2022 (in Chinese). [77] 章青芳. 磁性膨润土的制备及其在水处理中的应用研究[D]. 太原: 太原理工大学, 2016. ZHANG Q F. Study on modified preparation and properties of nano-bentonite[D]. Taiyuan: Taiyuan University of Technology, 2016 (in Chinese). [78] VU T T T, NGUYEN N T T, DUONG L H, et al. Coaggregation assisted by cationic polyelectrolyte and clay minerals as a strategy for the removal of polystyrene microplastic particles from aqueous solutions[J]. Applied Clay Science, 2023, 233: 106820. [79] HOU Y Z, WANG Y G, ZHU L, et al. Different inhibitory mechanisms of flexible and rigid clay minerals on the transport of microplastics in marine porous media[J]. Environmental Pollution, 2024, 356: 124246. [80] HAN F, WANG Y, AN S Y, et al. Poly(dimethyldiallylammonium chloride)-modified magnetic bentonite for removal of polystyrene nanoplastics[J]. Journal of Environmental Chemical Engineering, 2024, 12(5): 114013. [81] PUSCH R. Highly compacted sodium bentonite for isolating rock-deposited radioactive waste products[J]. Nuclear Technology, 1979, 45(2): 153-157. [82] 叶为民, 王 琼, 陈永贵, 等. 缓冲/回填材料: 砂-膨润土混合物研究进展[J]. 铀矿地质, 2010, 26(2): 95-100. YE W M, WANG Q, CHEN Y G, et al. Advances in the research on buffer/backfilling materials: sand-bentonite mixture[J]. Uranium Geology, 2010, 26(2): 95-100 (in Chinese). [83] 王 文. 不同阳离子基膨润土在盐分作用下的膨胀特性[D]. 桂林: 桂林理工大学, 2021. WANG W. Swelling characteristics of different cationic bentonites under salt solutions[D]. Guilin: Guilin University of Technology, 2021 (in Chinese). [84] 陈 龙. 复杂化学环境下膨润土膨胀变形研究[D]. 绵阳: 西南科技大学, 2021. CHEN L. Study on the swelling deformation of bentonite in complex chemical environment[D]. Mianyang: Southwest University of Science and Technology, 2021 (in Chinese). [85] 张东浩, 陈汉林, 蒋明俊, 等. 基于有机膨润土稠化剂润滑脂的制备工艺研究[J]. 重庆理工大学学报(自然科学), 2015, 29(8): 48-54. ZHANG D H, CHEN H L, JIANG M J, et al. Study on preparation processes of bentonite grease based on ammonium-modified bentonite thickener[J]. Journal of Chongqing University of Technology (Natural Science), 2015, 29(8): 48-54 (in Chinese). [86] 张卓翔. 膨润土和玄武岩纤维改性水泥砂浆性能的试验研究[D]. 重庆: 西南大学, 2022. ZHANG Z X. Experimental study on properties of bentonite and basalt fiber modified cement mortar[D]. Chongqing: Southwest University, 2022 (in Chinese). [87] 郑 振. 水泥-膨润土复合固化污泥的强度及重金属迁移特性研究[D]. 抚州: 东华理工大学, 2022. ZHENG Z. Study on the strength and heavy metal migration characteristics of cement-bentonite composite solidified sludge[D]. Fuzhou: East China Institute of Technology, 2022 (in Chinese). [88] 廖松泽. 羟乙基纤维素丙烯酰胺改性膨润土钻井液的研制[D]. 抚顺: 辽宁石油化工大学, 2020. LIAO S Z. Development of bentonite drilling fluid modified by hydroxyethyl cellulose acrylamide[D]. Fushun: Liaonign Shihua University, 2020 (in Chinese). [89] 米红英, 郭小川, 杨庭栋, 等. 新型膨润土润滑脂的研制[J]. 石油学报(石油加工), 2009, 25(增刊1): 26-31. MI H Y, GUO X C, YANG T D, et al. The development of a new bentonite grease[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2009, 25(supplement 1): 26-31 (in Chinese). [90] 张 洁. 膨润土柔性防渗材料缓膨特性研究[D]. 天津: 天津大学, 2017. ZHANG J. Research on delaying expansion of flexible anti-seepage materials with bentonite[D]. Tianjin: Tianjin University, 2017 (in Chinese). [91] JAVED U, KHUSHNOOD R A, ALI MEMON S, et al. Sustainable incorporation of lime-bentonite clay composite for production of ecofriendly bricks[J]. Journal of Cleaner Production, 2020, 263: 121469. [92] 胡 倩, 景 宜. 壳聚糖-膨润土微粒助留助滤体系性能的影响因素研究[J]. 中国造纸学报, 2019, 34(2): 25-32. HU Q, JING Y. Research on factors affecting the efficiency of chitosan-bentonite microparticle retention system[J]. Transactions of China Pulp and Paper, 2019, 34(2): 25-32 (in Chinese). [93] 袁明昆, 周景辉. (CSPI-PEI)-膨润土微粒助留助滤体系在废纸造纸中的应用[J]. 中国造纸, 2016, 35(4): 12-17. YUAN M K, ZHOU J H. Application of CSPI-PEI-bentonite microparticle retention and drainage system in deinked pulp[J]. China Pulp & Paper, 2016, 35(4): 12-17 (in Chinese). [94] FAVERO J, SANTOS V, WEISS-ANGELI V, et al. Evaluation and characterization of Melo Bentonite clay for cosmetic applications[J]. Applied Clay Science, 2019, 175: 40-46. [95] BABAHOUM N, OULD HAMOU M. Characterization and purification of Algerian natural bentonite for pharmaceutical and cosmetic applications[J]. BMC Chemistry, 2021, 15(1): 50. [96] 温 鹏. 基于膨润土的保水型缓释氮肥的制备及其性能研究[D]. 石河子: 石河子大学, 2017. WEN P. Synthesis and characterization of bentonite-based slow-release nitrogen fertilizers with the function of water retention[D]. Shihezi: Shihezi University, 2017 (in Chinese). [97] AN X F, WU Z S, YU J Z, et al. Copyrolysis of biomass, bentonite, and nutrients as a new strategy for the synthesis of improved biochar-based slow-release fertilizers[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(8): 3181-3190. [98] YOMGIROVNA R G. Agrobiological properties of bentonite in agriculture[J]. Gospodarka I Innowacje, 2023, 40: 179-183. [99] 王红斌, 冯桂权, 陈海云, 等. 金银花提取物缓释固体分散体的表征和释放行为研究[J]. 云南大学学报(自然科学版), 2011, 33(4): 458-462. WANG H B, FENG G Q, CHEN H Y, et al. Characterization and releasing profile of extraction of honeysuckle sustained release solid dispersions[J]. Journal of Yunnan University (Natural Sciences Edition), 2011, 33(4): 458-462 (in Chinese). [100] 姜丰艳. 含钠基膨润土的新方阿司匹林片的研制及其对胃黏膜保护作用研究[D]. 乌鲁木齐: 新疆医科大学, 2011. JIANG F Y. New preseription aspirin with sodium bentonite tablets and its protective effect of gastric mucosa[D]. Urumqi: Xinjiang Medical University, 2011 (in Chinese). [101] SHETTI N P, MALODE S J, NAYAK D S, et al. Hetero-nanostructured iron oxide and bentonite clay composite assembly for the determination of an antiviral drug acyclovir[J]. Microchemical Journal, 2020, 155: 104727. [102] PRASHANTH S N, TERADAL N L, SEETHARAMAPPA J, et al. Fabrification of electroreduced graphene oxide-bentonite sodium composite modified electrode and its sensing application for linezolid[J]. Electrochimica Acta, 2014, 133: 49-56. [103] ALI B, YUSUP S, QUITAIN A T, et al. Synthesis of novel graphene oxide/bentonite bi-functional heterogeneous catalyst for one-pot esterification and transesterification reactions[J]. Energy Conversion and Management, 2018, 171: 1801-1812. [104] MOFRAD B, REZAEI M, HAYATI-ASHTIANI M. Preparation and characterization of Ni catalysts supported on pillared nanoporous bentonite powders for dry reforming reaction[J]. International Journal of Hydrogen Energy, 2019, 44(50): 27429-27444. [105] ZHENG M, TAJVIDI M, TAYEB A H, et al. Effects of bentonite on physical, mechanical and barrier properties of cellulose nanofibril hybrid films for packaging applications[J]. Cellulose, 2019, 26(9): 5363-5379. [106] RAZAVI S H, KAVUSSI A. The role of nanomaterials in reducing moisture damage of asphalt mixes[J]. Construction and Building Materials, 2020, 239: 117827. [107] WANG Z, CHEN G H, WANG X R, et al. Removal of hexavalent chromium by bentonite supported organosolv lignin-stabilized zero-valent iron nanoparticles from wastewater[J]. Journal of Cleaner Production, 2020, 267: 122009. [108] LI A, FENG W Q, CHEN Z J, et al. Investigation and analysis of the macro- and micro-responses of bentonite-sand mixtures to temperature[J]. Geomechanics for Energy and the Environment, 2024, 38: 100565. [109] IACOB M, TIRON V, STIUBIANU G T, et al. Bentonite as an active natural filler for silicone leading to piezoelectric-like response material[J]. Journal of Materials Research and Technology, 2022, 17: 79-94. [110] KHANSILI N, KRISHNA P M. Curcumin functionalized TiO2 modified bentonite clay nanostructure for colorimetric Aflatoxin B1 detection in peanut and corn[J]. Sensing and Bio-Sensing Research, 2022, 35: 100480. |
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