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硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (9): 3462-3471.DOI: 10.16552/j.cnki.issn1001-1625.2025.0225

• 道路材料 • 上一篇    下一篇

多孔Mg-Al基水滑石温拌剂的制备及其对沥青混合料性能的影响

谢君, 杜雨阳, 吴少鹏, 李梦林, 李超   

  1. 武汉理工大学硅酸盐科学与先进建材全国重点试验室,武汉 430070
  • 收稿日期:2025-03-03 修订日期:2025-04-11 出版日期:2025-09-15 发布日期:2025-09-19
  • 通信作者: 杜雨阳,硕士研究生。E-mail:139997574@qq.com
  • 作者简介:谢 君(1986—),男,教授。主要从事道路建筑材料的研究。E-mail:xiejun3970@whut.edu.cn
  • 基金资助:
    国家自然科学基金(52478465);广西自治区交通运输厅科技项目(2021-MS5-125);河北省交通运输厅科学技术项目(202319)

Preparation of Porous Mg-Al-Based Layered Double Hydrotalcites Warm Mix Agent and Its Effect on Performance of Asphalt Mixture

XIE Jun, DU Yuyang, WU Shaopeng, LI Menglin, LI Chao   

  1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China
  • Received:2025-03-03 Revised:2025-04-11 Published:2025-09-15 Online:2025-09-19

摘要: 温拌沥青混合料是一种具有广阔应用前景的道路材料,但低温抗裂性能和水稳定性能不足,限制了其工程应用。本研究通过水热合成法和焙烧复原法,成功制备出经十二烷基硫酸钠(SDS)插层的多孔Mg-Al基水滑石(SDS-LDHs)。通过扫描电子显微镜(SEM)及热重-差示扫描量热仪(TG-DSC)试验研究了SDS-LDHs的微观结构和释水行为,并利用布氏黏度试验确定SDS-LDHs最佳掺量。在此基础上采用高温车辙、半圆弯曲及汉堡车辙试验,研究了温拌沥青混合料的路用性能。结果表明,SDS-LDHs 为三维多孔结构,含水率达到13.64%。将SDS-LDHs添加到沥青中时,能够迅速且均匀地释放水分,有效降低沥青黏度。加入占沥青质量2%的SDS-LDHs 后,温拌沥青混合料的拌和温度和压实温度相较热拌沥青混合料分别降低了 20和15 ℃。此外,相较于热拌沥青混合料,SDS-LDHs能使混合料的高温稳定性能和水稳定性能分别提高了36.0%和51.4%,而低温断裂能仅降低了3.1%。SDS-LDHs不仅会吸收沥青轻组分,还与集料表面硅氧基团发生化学作用,从而增强沥青与集料的黏附性,进而改善温拌沥青混合料的路用性能。

关键词: 多孔水滑石, 温拌剂, 沥青混合料, 有机改性, 路用性能

Abstract: Warm mix asphalt mixture is a road material with broad application prospects, but its insufficient low-temperature crack resistance and water stability performance limit its engineering applications. This study successfully prepared porous Mg-Al-based layered double hydrotalcites (SDS-LDHs) intercalated with sodium dodecyl sulfate (SDS) through hydrothermal synthesis and calcination restoration methods. The microstructure and water release behavior of SDS-LDHs were investigated using scanning electron microscopy (SEM) and thermogravimetric-differential scanning calorimetry (TG-DSC), and the optimal SDS-LDHs content was determined by Brookfield viscosity tests. The pavement performance of warm mix agent was further evaluated through high-temperature rut, semi-circular bending, and Hamburg rut tests. The results show that SDS-LDHs exhibit a three-dimensional porous structure with a water content of 13.64%. When incorporated SDS-LDHs into asphalt, they rapidly and uniformly release water, effectively reducing asphalt viscosity. With 2% (by asphalt mass) SDS-LDHs, the mix temperature and compaction temperature of warm mix asphalt mixture decrease by 20 and 15 ℃ respectively compared to hot mix asphalt mixture. Moreover, SDS-LDHs enhance the high-temperature performance stability and water stability of mixture by 36.0% and 51.4% respectively compared to hot mix asphalt mixture, while only reducing low-temperature fracture energy by 3.1%. SDS-LDHs not only absorb light components of asphalt but also chemically interact with siloxane groups on aggregate surfaces, thereby improving asphalt-aggregate adhesion and ultimately enhancing the pavement performance of warm mix asphalt mixture.

Key words: porous hydrotalcite, warm mix agent, asphalt mixture, organic modification, pavement performance

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