Cu2O纳米微晶玻璃的显微结构及性能研究

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (9): 3350-3358.

Cu₂O纳米微晶玻璃的显微结构及性能研究

吴宇欣¹, 吕杰衡², 阮健^1,3, 田晨^1,2, 刘超^1,3, 韩建军^1,3

1.武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070;
2.武汉理工大学材料科学与工程国际化示范学院(材料与微电子学院),武汉 430070;
3.湖北省特种玻璃工程技术研究中心,武汉 430070

收稿日期:2023-05-18 修订日期:2023-07-10 出版日期:2023-09-15 发布日期:2023-09-14
通信作者: 阮健,博士,副研究员。E-mail:jian_ruan@whut.edu.cn
作者简介:吴宇欣(1997—),女,硕士研究生。主要从事功能微晶玻璃及化学性质分析测试的研究。E-mail:3078635423@qq.com
基金资助:
大学生创新创业训练计划(S202210497034)

Microstructure and Properties of Glass-Ceramics Containing Cu₂O Nanocrystallines

WU Yuxin¹, LYU Jieheng², RUAN Jian^1,3, TIAN Chen^1,2, LIU Chao^1,3, HAN Jianjun^1,3

1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China;
2. International School of Materials Science and Engineering (School of Materials and Microelectronics), Wuhan University of Technology, Wuhan 430070, China;
3. Specialty Glass Engineering Technology Research Center of Hubei Province, Wuhan 430070, China

Received:2023-05-18 Revised:2023-07-10 Online:2023-09-15 Published:2023-09-14

摘要/Abstract

摘要： 新型Cu₂O纳米微晶玻璃具有高Cu载量、低成本和易大规模制备等特点,有望成为载银抗菌玻璃较有潜力的替代者。通过采用XRD、Raman光谱、XPS、FESEM和TEM等表征方法重点研究了不同ZnO/K₂O比对SiO₂-Al₂O₃-K₂O-ZnO-P₂O₅-B₂O₃-CuO微晶玻璃显微结构的影响,并分析讨论了其结构-性能关系。结果表明,微晶玻璃中Zn与P元素会富集在Cu元素所在区域的附近,适量的ZnO能使微晶玻璃中析出的Cu₂O晶粒尺寸稳定在纳米级别,并能调节微晶玻璃中Cu元素的浸出速率。Cu₂O纳米微晶玻璃对大肠杆菌和金黄色葡萄球菌均具有显著的抗菌效果,并能实现对维多利亚蓝B溶液的可见光催化降解,是一种极具发展潜力的新型功能微晶玻璃材料。

关键词: 微晶玻璃, 氧化亚铜纳米晶, 显微结构, 抗菌性能, 可见光催化

Abstract: Novel glass-ceramics containing Cu₂O nanocrystallines with features of high Cu loading amount, low cost and easy large scale production is a potential substitute for silver loaded antibacterial glass. In this study, SiO₂-Al₂O₃-K₂O-ZnO-P₂O₅-B₂O₃-CuO glass-ceramics with different ZnO/K₂O were investigated. Their microstructures were characterized by XRD, Raman spectroscopy, XPS, FESEM and TEM. The structure-performance relationship was also discussed. The results indicate that there is an enrichment of Zn and P elements around the region where Cu element locates in the glass-ceramics. An appropriate amount of ZnO makes sure the particles size of Cu₂O crystallines precipitated in glass-ceramics be in nano-scale and regulate the leaching rate of Cu element. Glass-ceramics containing Cu₂O nanocrystallines exhibit significant antibacterial effects on Escherichia coli and Staphylococcus aureus. They also show photocatalysis activity for degradation of Victoria blue B solution under visible light. It should be a novel functional glass-ceramics material with great potential.

Key words: glass-ceramics, Cu₂O nanocrystalline, microstructure, antibacterial property, visible light driven photocatalysis

中图分类号:

TQ171.7

吴宇欣, 吕杰衡, 阮健, 田晨, 刘超, 韩建军. Cu₂O纳米微晶玻璃的显微结构及性能研究[J]. 硅酸盐通报, 2023, 42(9): 3350-3358.

WU Yuxin, LYU Jieheng, RUAN Jian, TIAN Chen, LIU Chao, HAN Jianjun. Microstructure and Properties of Glass-Ceramics Containing Cu₂O Nanocrystallines[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(9): 3350-3358.

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Cu₂O纳米微晶玻璃的显微结构及性能研究

Microstructure and Properties of Glass-Ceramics Containing Cu₂O Nanocrystallines

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