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硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (9): 3342-3349.

• 陶瓷 • 上一篇    下一篇

3MTM实心陶瓷微球在瓷器补配中的性能研究

宋子贤1, 温建华2   

  1. 1.北京城市学院研究生部,北京 101309;
    2.中央民族大学民族学与社会学学院,北京 101309
  • 收稿日期:2023-05-08 修订日期:2023-07-10 出版日期:2023-09-15 发布日期:2023-09-14
  • 通信作者: 温建华,博士,讲师。E-mail:partice@bcu.edu.cn
  • 作者简介:宋子贤(1998—),男,硕士研究生。主要从事文物保护与修复方面的研究。E-mail:2017172761@qq.com

Performance of 3MTM Solid Ceramic Microspheres in Porcelain Replenishment

SONG Zixian1, WEN Jianhua2   

  1. 1. Graduate Department, Beijing City University, Beijing 101309, China;
    2. School of Ethnology and Sociology, Minzu University of China, Beijing 101309, China
  • Received:2023-05-08 Revised:2023-07-10 Online:2023-09-15 Published:2023-09-14

摘要: 瓷器文物补全时使用的复合材料被称为补配材料,目前常用于瓷器文物修复的补配材料普遍存在耐老化性能差和力学性能不足的问题。3MTM实心陶瓷微球是一款球形陶瓷材料,具有硬度高、白度高和耐腐蚀等特点,能够有效增强材料的耐老化性能和力学性能。本文以三款市售的陶瓷微球(W-210、W-410和W-610)为研究对象,以常用瓷器补配材料碳酸钙作为对照组,在强紫外光辐照老化、弱紫外光辐照老化、湿热干冷交替老化和未老化四种试验条件下,对试样进行抗折测试、抗拉测试、抗冲击测试、硬度测试、色差测试和光泽度测试。结果表明,3MTM实心陶瓷微球的耐老化性能和力学性能均优于碳酸钙,其中陶瓷微球W-410的耐老化性能和力学性能最优。与碳酸钙对照组相比,试验组力学性能综合提升25%~30%,耐老化性能综合提升50%,可作为新型补配材料应用于瓷器修复。

关键词: 3MTM实心陶瓷微球, 碳酸钙, 环氧树脂, 瓷器补配, 力学性能

Abstract: The composite materials used in the restoration of porcelain cultural relics are called porcelain materials. At present, the porcelain materials commonly used in the restoration of porcelain cultural relics generally have the problems of poor aging resistance and insufficient mechanical properties. 3MTM solid ceramic microsphere is a spherical ceramic material with high hardness, high whiteness and corrosion resistance, which can effectively enhance the aging resistance and mechanical properties of material. In this paper, three commercially available ceramic microspheres (W-210, W-410 and W-610) were used as research object, and the commonly used porcelain replenishment material calcium carbonate was used as control group. Under the four experimental conditions of strong ultraviolet irradiation aging, weak ultraviolet irradiation aging, wet-heat dry-cold alternating aging and non-aging, the samples were subjected to bending test, tensile test, impact test, hardness test, color difference test and gloss test. The results show that the aging resistance and mechanical properties of 3MTM solid ceramic microspheres are better than those of calcium carbonate, and the aging resistance and mechanical properties of ceramic microspheres W-410 are the best. Compared with the calcium carbonate control group, the mechanical properties of the experimental group are comprehensively improved by 25%~30%, and the aging resistance is comprehensively improved by 50%. It can be used as a new replenishment material for porcelain restoration.

Key words: 3MTM solid ceramic microsphere, calcium carbonate, epoxy resin, porcelain replenishment, mechanical property

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