硅酸盐通报 ›› 2026, Vol. 45 ›› Issue (6): 2092-2103.DOI: 10.16552/j.cnki.issn1001-1625.2025.1222
赵毅1,2(
), 冉东升1, 靳一航1,3, 夏晨渝4, 程璐1, 刘文凤1(
)
收稿日期:2025-12-08
修订日期:2026-01-04
出版日期:2026-06-15
发布日期:2026-07-14
通信作者:
刘文凤,博士,教授。E-mail:liuwenfeng@mail.xjtu.edu.cn作者简介:赵 毅(1997—),男,博士。主要从事非线性介电材料的研究。E-mail:thomas611@stu.xjtu.edu.cn
基金资助:
ZHAO Yi1,2(
), RAN Dongsheng1, JIN Yihang1,3, XIA Chenyu4, CHENG Lu1, LIU Wenfeng1(
)
Received:2025-12-08
Revised:2026-01-04
Published:2026-06-15
Online:2026-07-14
摘要:
钛酸锶钡(Ba1-x Sr x TiO3)陶瓷作为一种环境友好型铁电材料,具有介电性能优异、介电非线性显著、化学稳定性良好、居里温度可调等优势,在无铅介电调谐材料中备受关注。因制备工艺简单、生产成本相对低廉,钛酸锶钡陶瓷在现代通信系统、电子信息装备及可调谐微波器件中展现出广阔的应用前景。近年来,为满足新一代可调谐微波器件的应用需求,围绕钛酸锶钡陶瓷调谐性能的提升与综合介电特性的优化开展了大量研究。本文从掺杂改性、设计多相复合材料及制备工艺优化三个关键方向,系统综述了钛酸锶钡陶瓷调谐性能的研究进展与发展现状,为未来高性能介电调谐材料的研发与应用提供了参考。
中图分类号:
赵毅, 冉东升, 靳一航, 夏晨渝, 程璐, 刘文凤. 钛酸锶钡陶瓷调谐性能的研究进展[J]. 硅酸盐通报, 2026, 45(6): 2092-2103.
ZHAO Yi, RAN Dongsheng, JIN Yihang, XIA Chenyu, CHENG Lu, LIU Wenfeng. Research Progress on Tunable Properties of Barium Strontium Titanate Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(6): 2092-2103.
| Doping type | Composition | Tr/% | tan δ | FOM | Reference |
|---|---|---|---|---|---|
| — | Pure BST | 45 | 0.010 1 | 44 | [ |
| Donor doping | Nb-doping | 12 | 0.012 0 | 10 | [ |
| Donor doping | Y-doping | 36 | 0.025 0 | 14 | [ |
| Donor doping | La-doping | 33 | 0.034 0 | 9 | [ |
| Acceptor doping | Al-doping | 30 | 0.004 5 | 66 | [ |
| Acceptor doping | Fe-doping | 20 | 0.003 0 | 67 | [ |
| Acceptor doping | Mg-doping | 22 | 0.007 0 | 31 | [ |
| Acceptor doping | Mn-doping | 27 | 0.004 5 | 60 | [ |
| Co-doping | Mg/Zn doping | 47 | 0.007 3 | 64 | [ |
| Co-doping | Y/Mn doping | 63 | 0.007 8 | 81 | [ |
| Co-doping | Li/Nb doping | 15 | 0.001 7 | 86 | [ |
| Co-doping | Y/Mn doping | 43 | 0.003 0 | 143 | [ |
| Co-doping | La/Mn doping | 85 | 0.001 8 | 472 | [ |
| Co-doping | La/Cr doping | 84 | 0.004 1 | 204 | [ |
表1 异价掺杂BST陶瓷的调谐性能参数
Table 1 Parameters of tunable properties in aliovalent-doped BST ceramics
| Doping type | Composition | Tr/% | tan δ | FOM | Reference |
|---|---|---|---|---|---|
| — | Pure BST | 45 | 0.010 1 | 44 | [ |
| Donor doping | Nb-doping | 12 | 0.012 0 | 10 | [ |
| Donor doping | Y-doping | 36 | 0.025 0 | 14 | [ |
| Donor doping | La-doping | 33 | 0.034 0 | 9 | [ |
| Acceptor doping | Al-doping | 30 | 0.004 5 | 66 | [ |
| Acceptor doping | Fe-doping | 20 | 0.003 0 | 67 | [ |
| Acceptor doping | Mg-doping | 22 | 0.007 0 | 31 | [ |
| Acceptor doping | Mn-doping | 27 | 0.004 5 | 60 | [ |
| Co-doping | Mg/Zn doping | 47 | 0.007 3 | 64 | [ |
| Co-doping | Y/Mn doping | 63 | 0.007 8 | 81 | [ |
| Co-doping | Li/Nb doping | 15 | 0.001 7 | 86 | [ |
| Co-doping | Y/Mn doping | 43 | 0.003 0 | 143 | [ |
| Co-doping | La/Mn doping | 85 | 0.001 8 | 472 | [ |
| Co-doping | La/Cr doping | 84 | 0.004 1 | 204 | [ |
| Composition | Tr/% | tan δ | FOM | Reference |
|---|---|---|---|---|
| BST-Y2O3 | 28 | 0.003 8 | 74 | [ |
| BST-ZnAl2O4 | 46 | 0.005 6 | 83 | [ |
| BST-Ba2SiO4 | 33 | 0.002 3 | 140 | [ |
| BST-Li2ZnTi3O8 | 28 | 0.002 7 | 102 | [ |
| BST-BaCuSi4O10 | 37 | 0.000 9 | 411 | [ |
| BST-Zn2P2O7 | 53 | 0.001 9 | 277 | [ |
| BST-SiO2 | 71 | 0.007 0 | 101 | [ |
| BST-MgTi2O4 | 32 | 0.002 1 | 112 | [ |
| BST-MgAl2O4 | 23 | 0.001 4 | 164 | [ |
| BST-MgAl2O4 | 24 | 0.003 0 | 80 | [ |
| BST-Mg2SiO4-MgO | 13 | 0.001 0 | 130 | [ |
表2 BST基复合陶瓷的调谐性能参数
Table 2 Parameters of tunable properties in BST-based composite ceramics
| Composition | Tr/% | tan δ | FOM | Reference |
|---|---|---|---|---|
| BST-Y2O3 | 28 | 0.003 8 | 74 | [ |
| BST-ZnAl2O4 | 46 | 0.005 6 | 83 | [ |
| BST-Ba2SiO4 | 33 | 0.002 3 | 140 | [ |
| BST-Li2ZnTi3O8 | 28 | 0.002 7 | 102 | [ |
| BST-BaCuSi4O10 | 37 | 0.000 9 | 411 | [ |
| BST-Zn2P2O7 | 53 | 0.001 9 | 277 | [ |
| BST-SiO2 | 71 | 0.007 0 | 101 | [ |
| BST-MgTi2O4 | 32 | 0.002 1 | 112 | [ |
| BST-MgAl2O4 | 23 | 0.001 4 | 164 | [ |
| BST-MgAl2O4 | 24 | 0.003 0 | 80 | [ |
| BST-Mg2SiO4-MgO | 13 | 0.001 0 | 130 | [ |
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