利用海南紫金陶泥制备低膨胀耐热紫砂陶的研究

doi:10.16552/j.cnki.issn1001-1625.2025.0078

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (8): 3005-3013.DOI: 10.16552/j.cnki.issn1001-1625.2025.0078

利用海南紫金陶泥制备低膨胀耐热紫砂陶的研究

何梦真^1,2,3, 李月明^1,2,3, 张小娜^1,2,3,4, 王宇晖^1,2,3, 李恺^1,2,3, 黄圆圆^1,2,3

1.景德镇陶瓷大学材料科学与工程学院,景德镇 333403;
2.中国轻工业功能陶瓷材料重点实验室,景德镇 333403;
3.江西省储能与转换陶瓷材料工程实验室,景德镇 333403;
4.中国轻工业陶瓷研究所,景德镇 333301

收稿日期:2025-01-20 修订日期:2025-02-21 出版日期:2025-08-15 发布日期:2025-08-22
通信作者: 李月明,博士,教授。E-mail:lym6329@163.com
作者简介:何梦真(1999—),女,硕士研究生。主要从事传统陶瓷材料方面的研究。E-mail:958275708@qq.com
基金资助:
景德镇市科技局科技项目(20224GY009-03)

Preparation of Low-Expansion and Heat-Resistant Purple Clay Pottery Using Hainan Zijin Clay

HE Mengzhen^1,2,3, LI Yueming^1,2,3, ZHANG Xiaona^1,2,3,4, WANG Yuhui^1,2,3, LI Kai^1,2,3, HUANG Yuanyuan^1,2,3

1. School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, China;
2. China National Light Industry Key Laboratory of Functional Ceramic Materials, Jingdezhen 333403, China;
3. Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, Jingdezhen 333403, China;
4. Ceramic Research Institute of Light Industry of China, Jingdezhen 333301, China

Received:2025-01-20 Revised:2025-02-21 Published:2025-08-15 Online:2025-08-22

摘要/Abstract

摘要： 本文以海南紫金陶泥、锂辉石、锂白石、煅烧滑石、高岭土为原料,通过改变煅烧滑石与高岭土的含量优化配方组成,调节样品的热膨胀系数,制备低膨胀耐热紫砂陶,并通过热膨胀系数和抗折强度表征其抗热震性的变化。结果表明,当紫金陶泥含量为32.8%(质量分数)、锂辉石含量为32.8%(质量分数)、锂白石含量为9.4%(质量分数)、煅烧滑石含量为10.0%(质量分数)、高岭土含量为15.0%(质量分数)时,原料经过9 h的球磨并在1 150 ℃下保温60 min所制得的紫砂陶样品热膨胀系数最低(1.32×10^-6 ℃^-1),吸水率为0.25%,抗折强度为83.89 MPa。

关键词: 海南紫金陶泥, 锂辉石, β-锂辉石固溶体, 热膨胀系数, 抗折强度

Abstract: In this study, the Hainan Zijin clay, spodumene, lithium white stone, burnt talc and kaolin were used as raw materials. The formula composition was optimized by changing the content of burnt talc and kaolin, and the coefficient of thermal expansion of sample was adjusted to prepare low-expansion and heat-resistant purple clay pottery. The change of thermal shock resistance was characterized by coefficient of thermal expansion and flexural strength. The results show that when the content of Zijin clay is 32.8% (mass fraction), the content of spodumene is 32.8% (mass fraction), the content of lithium white stone is 9.4% (mass fraction), the content of burnt talc is 10.0% (mass fraction), and the content of kaolin is 15.0% (mass fraction), the coefficient of thermal expansion of purple clay pottery sample prepared by raw material ball milling for 9 h and holding at 1 150 ℃ for 60 min is the lowest (1.32×10^-6 ℃^-1), the water absorption rate is 0.25%, and the flexural strength is 83.89 MPa.

Key words: Hainan Zijin clay, spodumene, β-spodumene solid solution, coefficient of thermal expansion, flexural strength

中图分类号:

TQ174.73

何梦真, 李月明, 张小娜, 王宇晖, 李恺, 黄圆圆. 利用海南紫金陶泥制备低膨胀耐热紫砂陶的研究[J]. 硅酸盐通报, 2025, 44(8): 3005-3013.

HE Mengzhen, LI Yueming, ZHANG Xiaona, WANG Yuhui, LI Kai, HUANG Yuanyuan. Preparation of Low-Expansion and Heat-Resistant Purple Clay Pottery Using Hainan Zijin Clay[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(8): 3005-3013.

参考文献

[1] CRAIG O E, SAUL H, LUCQUIN A, et al. Earliest evidence for the use of pottery[J]. Nature, 2013, 496(7445): 351-354.
[2] WU X H, ZHANG C, GOLDBERG P, et al. Early pottery at 20 000 years ago in Xianrendong cave, China[J]. Science, 2012, 336(6089): 1696-1700.
[3] AI Q, CHEN E Z, ZHU L Z. Zisha art combined with modern ceramic technology on alleviating anxiety among potters[J]. CNS Spectrums, 2023, 28(supplement 2): S57.
[4] GAO X Y. Unravelling the complex meanings and origins of zisha teapots in the Ming and Qing dynasties[D]. Oxford: University of Oxford, 2023.
[5] LI K, WANG D L, CHEN H, et al. Normalized evaluation of thermal shock resistance for ceramic materials[J]. Journal of Advanced Ceramics, 2014, 3(3): 250-258.
[6] GAO X Y, HEIN A, QUINN P. Tea for two: the dual modes of contemporary Zisha teaware production and their implications for archaeological research[J]. Ethnoarchaeology, 2023, 15(2): 87-109.
[7] YANG C R, KONG J Y, YANG J J, et al. The study of crystal-phase composition and pore structure for Dicaoqing-Zisha compared with porcelain and pottery[J]. Ceramics International, 2021, 47(8): 10650-10657.
[8] NAGA S M, EL-MAGHRABY A A, HASSAN A M. Mullite/β-spodumene composites: preparation and characterization[J]. Ceramics International, 2016, 42(10): 12161-12166.
[9] DONG X, LIU J C, DU H Y, et al. Microstructure characterization of in situ synthesized porous Si₂N₂O ceramics using spodumene additive[J]. Ceramics International, 2013, 39(4): 4657-4662.
[10] HU C, WU J F, XU X H, et al. Investigating the effect of andalusite on mechanical strength and thermal shock resistance of cordierite-spodumene composite ceramics[J]. Ceramics International, 2018, 44(3): 3240-3247.
[11] KUSCER D, BANTAN I, HROVAT M, et al. The microstructure, coefficient of thermal expansion and flexural strength of cordierite ceramics prepared from alumina with different particle sizes[J]. Journal of the European Ceramic Society, 2017, 37(2): 739-746.
[12] KIANI M, EBADZADEH T. Effect of mechanical activation and microwave sintering on crystallization and mechanical strength of cordierite nanograins[J]. Ceramics International, 2015, 41(2): 2342-2347.
[13] ZHANG L F, OLHERO S, FERREIRA J M F. Thermo-mechanical and high-temperature dielectric properties of cordierite-mullite-alumina ceramics[J]. Ceramics International, 2016, 42(15): 16897-16905.
[14] MANDAL S, CHAKRABARTI S, DAS S K, et al. Synthesis of low expansion ceramics in lithia-alumina-silica system with zirconia additive using the powder precursor in the form of hydroxyhydrogel[J]. Ceramics International, 2007, 33(2): 123-132.
[15] WU Y Q, TIAN Y M, WU Y Q, et al. Preparation study for the low thermal expansion spodumene/mullite composites[J]. International Journal of Applied Ceramic Technology, 2022, 19(3): 1702-1712.
[16] 王平, 王俊, 简觉非, 等. 锂辉石质耐热紫砂陶研究[J]. 中国陶瓷, 2012, 48(11): 43-47.
WANG P, WANG J, JIAN J F, et al. A study on heat-resistance zisha pottery[J]. China Ceramics, 2012, 48(11): 43-47 (in Chinese).
[17] SCHNEIDER H, SCHREUER J, HILDMANN B. Structure and properties of mullite: a review[J]. Journal of the European Ceramic Society, 2008, 28(2): 329-344.
[18] 王子健, 左桂鸿, 郑友进, 等. 堇青石合成与改性研究进展[J]. 中国陶瓷, 2023, 59(11): 11-19.
WANG Z J, ZUO G H, ZHENG Y J, et al. Research on synthesis and modification of cordierite[J]. China Ceramics, 2023, 59(11): 11-19 (in Chinese).
[19] 李天伶. β-锂辉石的晶体化学性质及其低热膨胀性的结构解释[J]. 硅酸盐通报, 1995, 14(2): 27-32+44.
LI T L. The crystal chemistry of β-spodumene and the structure explanation to it's low thermal expansion[J]. Bulletin of the Chinese Ceramic Society, 1995, 14(2): 27-32+44 (in Chinese).
[20] 吴智强, 顾幸勇, 罗婷, 等. 紫砂泥对瓷质建筑陶瓷砖性能影响的初步研究[J]. 中国陶瓷工业, 2015, 22(4): 1-4.
WU Z Q, GU X Y, LUO T, et al. Effects of purple clay on the properties of porcelain building tiles[J]. China Ceramic Industry, 2015, 22(4): 1-4 (in Chinese).
[21] MANDAL S, CHAKRABARTI S, GHATAK S. Preparation and characterization of a powder precursor, consisting of oxides of Li—Al—Si in the form of hydroxyhydrogel for synthesis of β-spodumene ceramics[J]. Ceramics International, 2004, 30(3): 357-367.
[22] WU J F, HU C, XU X H, et al. Preparation and thermal shock resistance of cordierite-spodumene composite ceramics for solar heat transmission pipeline[J]. Ceramics International, 2016, 42(12): 13547-13554.
[23] 史志铭, 梁开明, 顾守仁. 元素掺杂对堇青石晶体结构及热膨胀系数的作用[J]. 现代技术陶瓷, 2000, 21(2): 18-23.
SHI Z M, LIANG K M, GU S R. Effects of elements-doping on the crystal structure and thermal expansion coefficient of cordierite[J]. Advanced Ceramics, 2000, 21(2): 18-23 (in Chinese).
[24] CHOTARD T, SORO J, LEMERCIER H, et al. High temperature characterisation of cordierite-mullite refractory by ultrasonic means[J]. Journal of the European Ceramic Society, 2008, 28(11): 2129-2135.
[25] 骞少阳. 高吸收低反射太阳能陶瓷材料的研究[D]. 武汉: 武汉理工大学, 2011.
JIAN S Y. Study on high absorption and low reflection solar ceramic materials[D]. Wuhan: Wuhan University of Technology, 2011(in Chinese).
[26] 杨镓境, 陈海燕, 蒋美平, 等. 清水泥紫砂矿料工艺矿物学研究及其烧成品微观结构研究[J]. 矿产保护与利用, 2022, 42(4): 128-134.
YANG J J, CHEN H Y, JIANG M P, et al. The study of minerology of Qingshui zisha clay mineral and the microstructure of sintering products[J]. Conservation and Utilization of Mineral Resources, 2022, 42(4): 128-134 (in Chinese).
[27] 李智, 田玉明, 孔祥辰, 等. 孔隙结构对紫砂砂器显微组织和性能的影响[J]. 非金属矿, 2025, 48(1): 10-13.
LI Z, TIAN Y M, KONG X C, et al. Effect of pore structure on the microstructure and properties of purple clay sand vessels[J]. Non-Metallic Mines, 2025, 48(1): 10-13 (in Chinese).

利用海南紫金陶泥制备低膨胀耐热紫砂陶的研究

Preparation of Low-Expansion and Heat-Resistant Purple Clay Pottery Using Hainan Zijin Clay

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