固废基注浆材料的性能与硬化机理研究

doi:10.16552/j.cnki.issn1001-1625.2024.1016

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (4): 1328-1336.DOI: 10.16552/j.cnki.issn1001-1625.2024.1016

固废基注浆材料的性能与硬化机理研究

任才富¹, 王栋民¹, 房奎圳², 王吉祥¹, 张信龙³, 陈伟⁴

1.中国矿业大学(北京)化学与环境工程学院,北京 100083;
2.清华大学土木工程系,北京 100084;
3.中国建筑东北设计研究院有限公司,沈阳 110000;
4.武汉理工大学材料科学与工程学院,武汉 430070

收稿日期:2024-09-02 修订日期:2024-09-28 出版日期:2025-04-15 发布日期:2025-04-18
通信作者: 王栋民,博士,教授。E-mail:wangdongmin@cumtb.edu.cn
作者简介:任才富(1993—),男,博士研究生。主要从事工业固废建材资源化利用的研究。E-mail:Rencaifu2015@163.com
基金资助:
国家重点研发计划(2019YFC19072);中央高校基本科研业务费(中国矿业大学(北京)博士研究生拔尖创新人才培育基金)(BBJ2024056)

Properties and Hardening Mechanism of Solid Waste Based Grouting Materials

REN Caifu¹, WANG Dongmin¹, FANG Kuizhen², WANG Jixiang¹, ZHANG Xinlong³, CHEN Wei⁴

1. School of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing 100083, China;
2. School of Civil Engineering, Tsinghua University, Beijing 100084, China;
3. CSCEC Northeast Design and Research Institute Co., Ltd., Shenyang 110000, China;
4. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China

Received:2024-09-02 Revised:2024-09-28 Published:2025-04-15 Online:2025-04-18

摘要/Abstract

摘要： 本文以钢渣、矿渣和脱硫石膏为原料开发了一种低碳、低成本的固废基注浆材料,系统研究了固废基注浆材料的工作性能、力学性能和抗渗性能,通过XRD、SEM和MIP等微观测试手段分析了其硬化机理,并与水泥基注浆材料进行了对比。结果表明,与水泥相比,固废基胶凝材料提高了注浆材料的工作性能和结石率,富水环境下显著降低了注浆材料的泌水率,但使凝结时间大幅延长。固废基注浆材料的早期强度偏低,后期强度大幅提升,两者均高于堵水用注浆材料28 d强度2.5 MPa的要求。固废基注浆材料水化生成了更多的水化产物钙矾石(AFt)和水化硅酸钙(C-S-H)凝胶,二者相互穿插、搭接,填充了内部孔隙,微观结构更加致密,凝胶孔含量增加,孔隙率降低,从而使抗渗性能和力学性能大幅提升。

关键词: 固废基胶凝材料, 注浆材料, 力学性能, 微观结构, 硬化机理

Abstract: In this paper, a low carbon and low cost solid waste based grouting material was developed using steel slag, slag and desulfurization gypsum. The workability, mechanical properties and impermeability of the solid waste based grouting materials were systematically studied. The hardening mechanism was analyzed by XRD, SEM and MIP, and compared with cement based grouting materials. The results show that compared with cement, the solid waste based cementitious materials can improve the workability and stone rate of the grouting material, reduce the bleeding rate significantly in water-rich environment, but the setting time is greatly extended. The early strength of solid waste based grouting materials is low, and the late strength is greatly increased, which exceeds the requirement of 2.5 MPa for 28 d strength of grouting materials used for water plugging. More hydration products ettringite (AFt) and hydrated calcium silicate (C-S-H) gels are generated from the hydration of solid waste based grouting materials, which interpenetrate and overlap with each other, fill the internal pores, make the microstructure more dense, increase the content of gel pores, and decrease the porosity, thus greatly improving the impermeability and mechanical properties

Key words: solid waste based cementitious material, grouting material, mechanical property, microstructure, hardening mechanism

中图分类号:

TU528

任才富, 王栋民, 房奎圳, 王吉祥, 张信龙, 陈伟. 固废基注浆材料的性能与硬化机理研究[J]. 硅酸盐通报, 2025, 44(4): 1328-1336.

REN Caifu, WANG Dongmin, FANG Kuizhen, WANG Jixiang, ZHANG Xinlong, CHEN Wei. Properties and Hardening Mechanism of Solid Waste Based Grouting Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(4): 1328-1336.

参考文献

[1] 张永成. 注浆技术[M]. 北京: 煤炭工业出版社, 2012.
ZHANG Y C. Grouting technology[M]. Beijing: China Coal Industry Publishing House, 2012 (in Chinese).
[2] LI S C, LIU R T, ZHANG Q S, et al. Protection against water or mud inrush in tunnels by grouting: a review[J]. Journal of Rock Mechanics and Geotechnical Engineering, 2016, 8(5): 753-766.
[3] 刘红彬, 唐伟奇, 肖凯璐, 等. 水泥基注浆材料的研究进展[J]. 混凝土, 2016(3): 71-75.
LIU H B, TANG W Q, XIAO K L, et al. Research progress of cement-based grouting materials[J]. Concrete, 2016(3): 71-75 (in Chinese).
[4] 路阳, 何小芳, 吴永豪, 等. 煤矿井下新型水泥基注浆材料的应用研究进展[J]. 硅酸盐通报, 2014, 33(1): 97-102.
LU Y, HE X F, WU Y H, et al. Research progress on application of new cement-based grouting materials in coal mine underground[J]. Bulletin of the Chinese Ceramic Society, 2014, 33(1): 97-102 (in Chinese).
[5] 方刚, 梁向阳, 黄浩, 等. 巴拉素井田煤层富水机理与注浆堵水技术[J]. 煤炭学报, 2019, 44(8): 2470-2483.
FANG G, LIANG X Y, HUANG H, et al. Water-rich mechanism of coal seam and grouting and blocking water technology in Balasu mine feild[J]. Journal of China Coal Society, 2019, 44(8): 2470-2483 (in Chinese).
[6] YANG Z P, ZHANG X F, LIU X, et al. Flexible and stretchable polyurethane/waterglass grouting material[J]. Construction and Building Materials, 2017, 138: 240-246.
[7] 王燕峰, 刘松辉, 韩康, 等. 超细碳酸钙对硫铝酸盐水泥基双液注浆材料性能的影响[J]. 硅酸盐通报, 2021, 40(2): 368-376.
WANG Y F, LIU S H, HAN K, et al. Effect of superfine CaCO₃ on properties of sulphoaluminate cement-based double fluid grouting material[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(2): 368-376 (in Chinese).
[8] 董小娟. 工业固废基防治水注浆材料的制备方法及研究[J]. 煤炭与化工, 2023, 46(11): 94-96+110.
DONG X J. Preparation method and research of industrial solid waste based grouting material for water prevention and control[J]. Coal and Chemical Industry, 2023, 46(11): 94-96+110 (in Chinese).
[9] 郭凌志, 周梅, 王丽娟, 等. 煤基固废地聚物注浆材料的制备及性能[J]. 建筑材料学报, 2022, 25(10): 1092-1100.
GUO L Z, ZHOU M, WANG L J, et al. Preparation and properties of coal-based solid waste geopolymer grouting materials[J]. Journal of Building Materials, 2022, 25(10): 1092-1100 (in Chinese).
[10] CHO B, CHOI H. Physical and chemical properties of concrete using GGBFS-KR slag-gypsum binder[J]. Construction and Building Materials, 2016, 123: 436-443.
[11] 王红喜, 张高展, 丁庆军, 等. 碱激发-工业废渣双液注浆材料性能研究[J]. 建筑材料学报, 2007, 10(3): 374-378.
WANG H X, ZHANG G Z, DING Q J, et al. Research on the performance of double solution grouting material with alkali-activated industry waste slag[J]. Journal of Building Materials, 2007, 10(3): 374-378 (in Chinese).
[12] ZHANG J, LI S C, LI Z F, et al. Properties of fresh and hardened geopolymer-based grouts[J]. Ceramics-Silikty, 2019, 63(2): 164-173.
[13] XU D, NI W, WANG Q H, et al. Ammonia-soda residue and metallurgical slags from iron and steel industries as cementitious materials for clinker-free concretes[J]. Journal of Cleaner Production, 2021, 307: 127262.
[14] WANG X, NI W, LI J J, et al. Carbonation of steel slag and gypsum for building materials and associated reaction mechanisms[J]. Cement and Concrete Research, 2019, 125: 105893.
[15] 崔孝炜, 倪文, 狄燕清. 钢渣矿渣基全固废胶凝材料的化学活化[J]. 硅酸盐通报, 2018, 37(4): 1411-1417.
CUI X W, NI W, DI Y Q. Chemical activation of cementitious materials with all solid waste based of steel slag and blast furnace slag[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(4): 1411-1417 (in Chinese).
[16] 马旭明, 倪文, 刘轩. 钢渣粉性能优化及制备无熟料混凝土的试验研究[J]. 材料导报, 2016, 30(16): 135-140.
MA X M, NI W, LIU X. Experimental study on performance optimization of steel slag powder and preparation of non-clinker concrete[J]. Materials Reports, 2016, 30(16): 135-140 (in Chinese).
[17] REN C F, WANG J X, DUAN K R, et al. Effects of steel slag on the hydration process of solid waste-based cementitious materials[J]. Materials, 2024, 17(9): 1999.
[18] 杜野, 裴向军, 黄润秋, 等. 黏度时变性注浆材料流动特性与应用研究[J]. 岩土力学, 2017, 38(12): 3498-3504.
DU Y, PEI X J, HUANG R Q, et al. Study on flow characteristics and application of viscosity time-varying grouting material[J]. Rock and Soil Mechanics, 2017, 38(12): 3498-3504 (in Chinese).
[19] 陈伟, 余匡迪, 袁波. 聚合硫酸铝调控硫酸盐激发尾砂充填材料工作性能与微观结构的研究[J]. 硅酸盐通报, 2020, 39(6): 1822-1827+1834.
CHEN W, YU K D, YUAN B. Controlling the workability and microstructure of sulfate activated tailings based backfills using polyaluminum sulfate[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(6): 1822-1827+1834 (in Chinese).
[20] GRUSKOVNJAK A, LOTHENBACH B, WINNEFELD F, et al. Hydration mechanisms of super sulphated slag cement[J]. Cement and Concrete Research, 2008, 38(7): 983-992.
[21] MATSCHEI T, BELLMANN F, STARK J. Hydration behaviour of sulphate-activated slag cements[J]. Advances in Cement Research, 2005, 17(4): 167-178.
[22] 刘新, 冯攀, 沈叙言, 等. 水泥水化产物: 水化硅酸钙(C-S-H)的研究进展[J]. 材料导报, 2021, 35(9): 9157-9167.
LIU X, FENG P, SHEN X Y, et al. Advances in the understanding of cement hydrate: calcium silicate hydrate (C-S-H)[J]. Materials Reports, 2021, 35(9): 9157-9167 (in Chinese).
[23] ZHANG Z H, LI L F, MA X, et al. Compositional, microstructural and mechanical properties of ambient condition cured alkali-activated cement[J]. Construction and Building Materials, 2016, 113: 237-245.

固废基注浆材料的性能与硬化机理研究

Properties and Hardening Mechanism of Solid Waste Based Grouting Materials

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