高强度Li2O-Al2O3-SiO2体系微晶玻璃研究进展

摘要/Abstract

摘要： Li₂O-Al₂O₃-SiO₂(LAS)体系微晶玻璃因具有优异的力学性能和光学性能,近年来得到了广泛应用。本文针对LAS微晶玻璃的析出晶相、制备工艺和应用进行了介绍。鉴于当前对高硬耐划玻璃材料的迫切需求,重点阐述了LAS微晶玻璃强韧化技术和表面增强方法的研究进展,对今后研发高强度LAS微晶玻璃具有重要指导作用。

关键词: 微晶玻璃, Li₂O-Al₂O₃-SiO₂, β-锂辉石, 热处理工艺, 强韧化技术, 化学强化

Abstract: Li₂O-Al₂O₃-SiO₂(LAS) system glass-ceramics have been widely used in recent years, as their excellent mechanical and optical properties. In this work, the precipitated crystal phase, preparation technique and application of LAS glass-ceramics were introduced. In view of the current urgent demand for high-hard scratch-resistant glass, the current research progress on LAS glass-ceramics strengthening and toughening technology and surface enhancement methods was emphatically expounded. This paper plays an important guiding role in the development of high-strength LAS glass-ceramics in the future.

Key words: glass-ceramics, Li₂O-Al₂O₃-SiO₂, β-spodumene, heat treatment process, strengthening and toughening technology, chemical strengthening

中图分类号:

TQ171

李溦长, 王欣, 胡丽丽, 陈树彬, 陈辉宇, 张旭丰, 蒋晓琦. 高强度Li₂O-Al₂O₃-SiO₂体系微晶玻璃研究进展[J]. 硅酸盐通报, 2022, 41(11): 3795-3805.

LI Weichang, WANG Xin, HU Lili, CHEN Shubin, CHEN Huiyu, ZHANG Xufeng, JIANG Xiaoqi. Research Progress on High-Strength Li₂O-Al₂O₃-SiO₂ System Glass-Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3795-3805.

参考文献

[1] HÖLAND W, BEALL G H. Glass-ceramic technology[M]. Westerville: The American Ceramic Society, 2019.
[2] 赵运才,刘小梅.玻璃陶瓷复合材料的研究进展[J].机械工程材料,2007,31(11):10-12+35.
ZHAO Y C, LIU X M. Development of glass-ceramic composites research[J]. Materials for Mechanical Engineering, 2007, 31(11): 10-12+35 (in Chinese).
[3] ZHONG J S, CHEN D Q, PENG Y Z, et al. A review on nanostructured glass ceramics for promising application in optical thermometry[J]. Journal of Alloys and Compounds, 2018, 763: 34-48.
[4] DENRY I, KELLY J R. Emerging ceramic-based materials for dentistry[J]. Journal of Dental Research, 2014, 93(12): 1235-1242.
[5] JAMES P F. Glass ceramics: new compositions and uses[J]. Journal of Non-Crystalline Solids, 1995, 181(1/2): 1-15.
[6] KARMAKAR B. Functional glasses and glass-ceramics: processing, properties and applications [M]. Amsterdam: Elsevier, 2017.
[7] CHATTERJEE M, NASKAR M K. Sol-gel synthesis of lithium aluminum silicate powders: the effect of silica source[J]. Ceramics International, 2006, 32(6): 623-632.
[8] 范仕刚.超低膨胀微晶玻璃:助力空天探测,实现关键材料自主可控[J].硅酸盐通报,2021,40(11):3877.
FAN S G. Ultra low expansion glass-ceramics: to assist aerospace exploration and achieve autonomous control of key materials[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(11): 3877 (in Chinese).
[9] 刘攀,刘红刚,何进.建筑微晶玻璃的发展与应用[J].玻璃,2022,49(6):35-38+42.
LIU P, LIU H G, HE J. Development and application of architectural glass-ceramic[J]. Glass, 2022, 49(6): 35-38+42 (in Chinese).
[10] BEALL G H, FU Q, SMITH C M, et al. Manufacture of glass ceramic for e.g. kitchen articles, involves heating crystallizable glass containing specified amount of silicon dioxide and aluminum trioxide at nucleation temperature and heating glass to crystallization temperature: US2017327406-A1[P]. 2017-11-16 (in Chinese).
[11] CAO D, WAN P, CHEN W, et al. Crystallized glass for panel, and for cooking appliance such as induction cooker or a multi-head gas stove, is a lithium oxide-aluminum oxide-silicon oxide system crystallized glass, and includes specified range of lithium oxide, CN111302631-A[P]. 2020-06-19 (in Chinese).
[12] 王裕芳,鄢春根,肖卓豪,等.基于专利分析的微晶玻璃技术发展态势研究[J].陶瓷学报,2021,42(3):389-398.
WANG Y F, YAN C G, XIAO Z H, et al. Technological innovation trend of glass-ceramics: a study based on patent information analysis[J]. Journal of Ceramics, 2021, 42(3): 389-398 (in Chinese).
[13] CHENG K G. Determining crystallization kinetic parameters of Li₂O-Al₂O₃-SiO₂ glass from derivative differential thermal analysis curves[J]. Materials Science and Engineering: B, 1999, 60(3): 194-199.
[14] SHI J, HE F, XIE J L, et al. Kinetic analysis of crystallization in Li₂O-Al₂O₃-SiO₂-B₂O₃-BaO glass-ceramics[J]. Journal of Non-Crystalline Solids, 2018, 491: 106-113.
[15] HUMMEL F A. Thermal expansion properties of some synthetic lithia minerals[J]. Journal of the American Ceramic Society, 1951, 34(8): 235-239.
[16] LI C T, PEACOR D R. Crystal structure of LiAlSi₂O₆-2 (β spodumene)[J]. Zeitschrift fur Kristallographie, 1968, 126(1-3): 46.
[17] TICK P A, BORRELLI N F, REANEY I M. The relationship between structure and transparency in glass-ceramic materials[J]. Optical Materials, 2000, 15(1): 81-91.
[18] WINKLER H. Synthese und kristallstruktur des eukryptits, LiAlSiO₄[J]. Acta Crystallographica, 1948, 1: 27-34.
[19] ZHENG W H, CHENG J S, TANG L Y, et al. Effect of Y₂O₃ addition on viscosity and crystallization of the lithium aluminosilicate glasses[J]. Thermochimica Acta, 2007, 456(1): 69-74.
[20] CUI L, HAO X J, HU X L, et al. Effects of Y₂O₃ addition on structure and properties of LZAS vitrified bond for CBN grinding tools application[J]. Ceramics International, 2015, 41(8): 9916-9922.
[21] LU P, ZHENG Y, CHENG J S, et al. Effect of La₂O₃ addition on crystallization and properties of Li₂O-Al₂O₃-SiO₂ glass-ceramics[J]. Ceramics International, 2013, 39(7): 8207-8212.
[22] HU A M, LIANG K M, ZHOU F, et al. Phase transformations of Li₂O-Al₂O₃-SiO₂ glasses with CeO₂ addition[J]. Ceramics International, 2005, 31(1): 11-14.
[23] NORDMANN A, CHENG Y B. Microstructure and properties of spodumene based Li-Si-Al-O-N glass ceramics[J]. British Ceramic Transactions, 1997, 96: 141-148.
[24] DECEANNE A V, FRY A L, WILKINSON C J, et al. Experimental analysis and modeling of the Knoop hardness of lithium disilicate glass-ceramics containing lithium tantalate as a secondary phase[J]. Journal of Non-Crystalline Solids, 2022, 585: 121540.
[25] HUANG X, ZHENG X, ZHAO G, et al. Microstructure and mechanical properties of zirconia-toughened lithium disilicate glass-ceramic composites[J]. Materials Chemistry and Physics, 2014, 143(2): 845-852.
[26] FU L, ENGQVIST H, XIA W. Glass-ceramics in dentistry: a review[J]. Materials, 2020, 13(5): 1049.
[27] LI B, DUAN D N, LONG Q Y. Influences of ZrO₂ on microstructures and properties of Li₂O-Al₂O₃-SiO₂ glass-ceramics for LTCC applications[J]. Journal of Materials Science: Materials in Electronics, 2016, 27(1): 134-139.
[28] KLEEBUSCH E, PATZIG C, KRAUSE M, et al. The formation of nanocrystalline ZrO₂ nuclei in a Li₂O-Al₂O₃-SiO₂ glass-a combined XANES and TEM study[J]. Scientific Reports, 2017, 7: 10869.
[29] KLEEBUSCH E, RÜSSEL C, PATZIG C, et al. Evidence of epitaxial growth of high-quartz solid solution on ZrTiO₄ nuclei in a Li₂O-Al₂O₃-SiO₂ glass[J]. Journal of Alloys and Compounds, 2018, 748: 73-79.
[30] BRENNAN J J, PREWO K M. Silicon carbide fibre reinforced glass-ceramic matrix composites exhibiting high strength and toughness[J]. Journal of Materials Science, 1982, 17(8): 2371-2383.
[31] PYZIK A J, BEAMAN D R. Microstructure and properties of self-reinforced silicon nitride[J]. Journal of the American Ceramic Society, 1993, 76(11): 2737-44.
[32] PREWO K, BRENNAN J, LAYDEN G. Fiber reinforced glasses and glass-ceramics for high performance applications[J]. American Ceramic Society Bulletin, 1986, 65: 305-322.
[33] FANG J, ZHANG J, LIU C F, et al. A novel glass-ceramic with high crystallinity for joining of SiC ceramic[J]. Materials Letters, 2020, 277: 128318.
[34] FU Q G, JIA B L, LI H J, et al. SiC nanowires reinforced MAS joint of SiC coated carbon/carbon composites to LAS glass ceramics[J]. Materials Science and Engineering: A, 2012, 532: 255-259.
[35] ZHANG Y M, GUO H X, ZHANG H, et al. Effect of added mullite whisker on properties of lithium aluminosilicate (LAS) glass-ceramics prepared for dental restoration[J]. Journal of Biomedical Nanotechnology, 2018, 14(11): 1944-1952.
[36] YAN J Y, LIU X M, WU X P, et al. Microstructure and mechanical properties of Li₂Si₂O₅ whisker-reinforced glass-ceramics [J]. Frontiers in Materials, 2022, 9, 849601.
[37] 程金树,朱连英,楼贤春.玻璃钢化方法的探讨[J].材料导报,2012,26(s2):135-137+162.
CHENG J S, ZHU L Y, LOU X C. Method discussion of glass tempering[J]. Materials Review, 2012, 26(s2): 135-137+162 (in Chinese).
[38] 孟满,高琳.物理钢化玻璃裂纹的形态特征分析[J].法制博览,2017(11):23-25.
MENG M, GAO L. Analysis on morphological characteristics of physical tempered glass cracks[J]. Legality Vision, 2017(11): 23-25 (in Chinese).
[39] LACZKA K, CHOLEWA-KOWALSKA K, ŚRODA M, et al. Glass-ceramics of LAS (Li₂O-Al₂O₃-SiO₂) system enhanced by ion-exchange in KNO₃ salt bath[J]. Journal of Non-Crystalline Solids, 2015, 428: 90-97.
[40] ZHANG Y M, LI B B, LI D, et al. Microstructure, cytocompatibility, and chemical durability of chemically strengthened LAS (Li₂O-Al₂O₃-SiO₂) glass-ceramic materials[J]. Journal of the European Ceramic Society, 2022, 42(13): 6110-6118.
[41] 王佑鹏.一种微晶玻璃的研制过程[J].玻璃搪瓷与眼镜,2021,49(2):38-41.
WANG Y P. Preparation process for one kind of glass ceramics[J]. Glass Enamel ＆ Ophthalmic Optics, 2021, 49(2): 38-41 (in Chinese).
[42] QIN G, QIN X, XU G, et al. Production of glass-ceramic using all-electric fusing rolling process, involves using fly ash as main material, and light burned magnesium, trisodium phosphate, soda ash, and titanium dioxide as aid: CN105924014-A[P]. 2016-09-07 (in Chinese).
[43] 殷海荣,王明华,方俊.溶胶-凝胶制备Li₂O-Al₂O₃-SiO₂微晶玻璃的研究进展[J].硅酸盐通报,2006,25(4):146-149+179.
YIN H R, WANG M H, FANG J. Development of Li₂O-Al₂O₃-SiO₂ system glass-ceramic prepared by sol-gel method[J]. Bulletin of the Chinese Ceramic Society, 2006, 25(4): 146-149+179 (in Chinese).
[44] 章钊,李宏,杜芸,等.硅/微晶玻璃阳极键合工艺对键合强度的影响[J].武汉理工大学学报,2009,31(24):5-8.
ZHANG Z, LI H, DU Y, et al. Influence of silicon/glass-ceramic anodic bonding technology on bonding intensity[J]. Journal of Wuhan University of Technology, 2009, 31(24): 5-8 (in Chinese).
[45] SHOJI S, KIKUCHI H, TORIGOE H. Low-temperature anodic bonding using lithium aluminosilicate-β-quartz glass ceramic[J]. Sensors and Actuators A: Physical, 1998, 64(1): 95-100.

高强度Li₂O-Al₂O₃-SiO₂体系微晶玻璃研究进展

Research Progress on High-Strength Li₂O-Al₂O₃-SiO₂ System Glass-Ceramics

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