基于脉冲喷射技术的硫系玻璃光纤制备方法探索

硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (11): 3756-3760.

所属专题：玻璃

基于脉冲喷射技术的硫系玻璃光纤制备方法探索

郭永昶^1,2,3, 李粲^2,4, 冯少尉^1,2,3, 陶海征⁴, 王会^2,3,5, 李建强^1,2,3,5

1.北京科技大学材料科学与工程学院,北京 100083;
2.中国科学院过程工程研究所,多相复杂系统国家重点实验室,北京 100190;
3.中国科学院大学化学工程学院,北京 100049;
4.武汉理工大学,硅酸盐建筑材料国家重点实验室,武汉 430070;
5.中国科学院绿色过程制造创新研究院,北京 100190

收稿日期:2022-08-16 修订日期:2022-09-16 出版日期:2022-11-15 发布日期:2022-12-12
通信作者: 李建强,博士,教授。E-mail:jianqiangli@ustb.edu.cn
作者简介:郭永昶(1995—),男,博士研究生。主要从事玻璃与氧化物功能陶瓷方面的研究。E-mail:guoyongchang18@mails.ucas.ac.cn
基金资助:
北京市科学技术委员会、中关村科技园区管理委员会资助课题(Z221100006722022);国家自然科学基金(51972304,51971208);北京市科技项目(Z191100004819002);中国载人空间站科学实验项目;高校基本科研业务费

Exploration of Chalcogenide Glass Fiber Preparation Method Based on Pulse Injection Technology

GUO Yongchang^1,2,3, LI Can^2,4, FENG Shaowei^1,2,3, TAO Haizheng⁴, WANG Hui^2,3,5, LI Jianqiang^1,2,3,5

1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
2. State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;
4. State Key Laboratory Silicate Materials Architectures, Wuhan University of Technology, Wuhan 430070, China;
5. Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190, China

Received:2022-08-16 Revised:2022-09-16 Online:2022-11-15 Published:2022-12-12

摘要/Abstract

摘要： 硫系玻璃光纤因具有独特的红外光学特性,在红外成像、激光传输和传感等诸多领域具有广阔的应用前景。目前,硫系玻璃光纤的拉制方法主要包括双坩埚法和预制棒拉制法。其中,双坩埚法装置复杂,预制棒拉制法需要提前制备高质量的预制棒。此外,这两种方法均要求玻璃具有较高的抗析晶能力,限制了硫系玻璃光纤新材料的开发。本工作创新性地将脉冲喷射技术引入到硫系玻璃光纤制备领域,通过硫系玻璃光纤纤芯的拉制,探索该方法在玻璃光纤制备上的可行性。通过对玻璃熔体施加持续性的脉冲扰动,坩埚底部小孔处能产生连续的射流,并且在下落过程中发生凝固,从而获得玻璃纤芯。采用该方法,成功制备了一种组成为Ge₂₈Sb₁₂Se₆₀的玻璃光纤纤芯。脉冲喷射法具有装置简单、操作容易等优点,通过连续且规律的脉冲和坩埚内外压力差实现硫系玻璃光纤的拉制,与传统依靠重力拉制的方法相比,脉冲喷射法具有更为丰富的调控手段,从而为新型硫系玻璃光纤的制备提供参考。

关键词: 红外玻璃, 玻璃光纤, 硫系玻璃, Ge-Sb-Se玻璃, 光纤纤芯制备, 脉冲喷射法

Abstract: Due to their unique infrared optical properties, such as excellent transmission in infrared band, low phonon energy and good chemical stability, chalcogenide glass fiber has promising applications in many fields such as infrared imaging, laser transmission and sensing. At present, the preparation of chalcogenide glass optical fiber mainly includes double-crucible method and rod-in-tube method. The double-crucible method is complicated, and the rod-in-tube method needs to prepare high-quality preforms in advance. In addition, both methods require high crystallization resistance of glass, which limits the development of new materials for chalcogenide glass optical fiber. In this work, the pulse injection technology was innovatively introduced into the field of chalcogenide glass fiber preparation, and the feasibility of this method for glass fiber preparation by drawing chalcogenide glass fiber core was explored. By applying continuous pulse perturbation to glass melt, a continuous jet was generated at the bottom hole of the crucible and solidified during falling, resulting in glass fiber core. Using this method, a chalcogenide glass fiber with the composition of Ge₂₈Sb₁₂Se₆₀ was successfully prepared. The pulse injection method is simple and easy to operate, and the pulling of chalcogenide glass fiber is achieved by continuous and regular pulses and pressure difference between the inside and outside of crucible, which has more abundant control means than traditional gravity-based glass fiber pulling. This method provides a potential reference for the preparation of new chalcogenide glass fiber.

Key words: infrared glass, glass fiber, chalcogenide glass, Ge-Sb-Se glass, fiber core preparation, pulse injection method

中图分类号:

TQ171

郭永昶, 李粲, 冯少尉, 陶海征, 王会, 李建强. 基于脉冲喷射技术的硫系玻璃光纤制备方法探索[J]. 硅酸盐通报, 2022, 41(11): 3756-3760.

GUO Yongchang, LI Can, FENG Shaowei, TAO Haizheng, WANG Hui, LI Jianqiang. Exploration of Chalcogenide Glass Fiber Preparation Method Based on Pulse Injection Technology[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3756-3760.

参考文献

[1] SNOPATIN G E, SHIRYAEV V S, PLOTNICHENKO V G, et al. High-purity chalcogenide glasses for fiber optics[J]. Inorganic Materials, 2009, 45(13): 1439-1460.
[2] ADAM J L, ZHANG X. Chalcogenide glasses: preparation, properties and applications[M]. Cambridge: Woodhead Publishing, 2014.
[3] SANGHERA J S, AGGARWAL I D. Active and passive chalcogenide glass optical fibers for IR applications: a review[J]. Journal of Non-Crystalline Solids, 1999, 256/257: 6-16.
[4] 王小虎,薛建强,陶海征,等.硫系玻璃材料的研究进展[J].建材发展导向,2003,1(2):28-31.
WANG X H, XUE J Q, TAO H Z, et al. Progress of research on chalcogenide glass materials [J]. Development Guide to Building Materials, 2003, 1(2): 28-31 (in Chinese).
[5] 周鹏,赵华,祖成奎,等.若干硫系玻璃黏度变化速率的结构起源探索[J].硅酸盐通报,2021,40(5):1692-1697.
ZHOU P, ZHAO H, ZU C K, et al. Structural origin of change rate in viscosity for several chalcogenide glasses[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(5): 1692-1697 (in Chinese).
[6] ZAKERY A, ELLIOT S R. Optical nonlinearities in chalcogenide glasses and their applications[M]. Berlin: Springer Berlin Heidelberg, 2007.
[7] ZAKERY A, ELLIOTT S R. Optical properties and applications of chalcogenide glasses: a review[J]. Journal of Non-Crystalline Solids, 2003, 330(1/2/3): 1-12.
[8] ASOBE M. Nonlinear optical properties of chalcogenide glass fibers and their application to all-optical switching[J]. Optical Fiber Technology, 1997, 3(2): 142-148.
[9] 尹冬梅,戴世勋,王训四,等.红外硫系玻璃光纤在传感领域的研究进展[J].激光与光电子学进展,2013,50(2):92-99.
YIN D M, DAI S X, WANG X S, et al. Research progress of infrared chalcogenide glass fibers in sensing fields[J]. Laser ＆ Optoelectronics Progress, 2013, 50(2): 92-99 (in Chinese).
[10] SHIRYAEV V S, CHURBANOV M F. Trends and prospects for development of chalcogenide fibers for mid-infrared transmission[J]. Journal of Non-Crystalline Solids, 2013, 377: 225-230.
[11] 许彦涛,郭海涛,陆敏,等.低损耗芯包结构Ge-Sb-Se硫系玻璃光纤的制备与性能研究[J].红外与激光工程,2015,44(1):182-187.
XU Y T, GUO H T, LU M, et al. Preparation and properties of low-loss core-cladding structural Ge-Sb-Se chalcogenide glass fibers[J]. Infrared and Laser Engineering, 2015, 44(1): 182-187 (in Chinese).
[12] SANGHERA J S, AGGARWAL I D. Infrared fiber optics[M]. Boca Raton: CRC Press, 1998.
[13] CHURBANOV M F. High-purity chalcogenide glasses as materials for fiber optics[J]. Journal of Non-Crystalline Solids, 1995, 184: 25-29.
[14] DEVYATYKH G G, DIANOV E M, PLOTNICHENKO V G, et al. Fiber waveguides based on high-purity chalcogenide glasses[J]. High-Purity Substances, 1991, 5: 1-27.
[15] KETKOVA L A, CHURBANOV M F. Heterophase inclusions as a source of non-selective optical losses in high-purity chalcogenide and tellurite glasses for fiber optics[J]. Journal of Non-Crystalline Solids, 2018, 480: 18-22.
[16] CHURBANOV M F, PLOTNICHENKO V G. Optical fibers from high-purity arsenic chalcogenide glasses[J]. Semiconductors and Semimetals, 2004, 80: 209-230.
[17] SHIRYAEV V S, CHURBANOV M F. Recent advances in preparation of high-purity chalcogenide glasses for mid-IR photonics[J]. Journal of Non-Crystalline Solids, 2017, 475: 1-9.
[18] NGUYEN V Q, SANGHERA J S, COLE B, et al. Fabrication of arsenic sulfide optical fiber with low hydrogen impurities[J]. Journal of the American Ceramic Society, 2002, 85: 2056-2058.
[19] 郭海涛,崔健,许彦涛,等.低损耗硫系红外光纤制备及其应用研究进展[J].激光与光电子学进展,2019,56(17):93-111.
GUO H T, CUI J, XU Y T, et al. Progress in preparation and applications of low-loss chalcogenide infrared fibers[J]. Laser ＆ Optoelectronics Progress, 2019, 56(17): 93-111 (in Chinese).
[20] SHIRYAEV V S, MISHINOV S V, CHURBANOV M F. Investigation of adhesion of chalcogenide glasses to silica glass[J]. Journal of Non-Crystalline Solids, 2015, 408: 71-75.
[21] MISHINOV S, CHURBANOV M, GOROKHOV A N, et al. Adhesion mechanism of destruction of silica-glass surface during the preparation and treatment of optical glassy arsenic chalcogenides[J]. Inorganic Materials, 2016, 52: 716-720.
[22] WU Z H, XU Y S, QI D F, et al. Progress in preparation and applications of Te-As-Se chalcogenide glasses and fibers[J]. Infrared Physics & Technology, 2019, 102: 102981.
[23] MASUDA S, TAKAGI K, DONG W, et al. Solidification behavior of falling germanium droplets produced by pulsated orifice ejection method[J]. Journal of Crystal Growth, 2008, 310(11): 2915-2922.
[24] LI C, LI J Q, HU Y Y, et al. Preparation and solidification process of mono-sized Cu-Ni-Sn microspheres by pulsated orifice ejection method[J]. Materials Research Express, 2019, 6(5): 056517.
[25] GUO Y C, LI C, DENG N, et al. Preparation of high sphericity monodisperse aluminum microspheres by pulsated orifice ejection method[J]. Materials Today Communications, 2022, 30: 103110.

基于脉冲喷射技术的硫系玻璃光纤制备方法探索

Exploration of Chalcogenide Glass Fiber Preparation Method Based on Pulse Injection Technology

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