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Table of Content

    15 April 2021, Volume 40 Issue 4
    Invited
    Review on Frost Damages of Hydraulic Concrete in Cold Region and Its Preventive Control
    SU Huaizhi, XIE Wei
    2021, 40(4):  1053-1071. 
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    As a common aging problem caused by the extreme climate in cold region, frost damages lead the structural performance to deterioration with a high probability, especially on the damming concrete widely used in the hydropower project, evenly resulted in unpredictable damages and an adverse effect to the service life of the project. On the basis of statistics, the problems existed and research situation, emphases on the theory research, test method, numerical simulation, damage identification, suppression and monitoring inhibit repair, etc., are discussed for the research of freeze-thaw diseases on hydraulic concrete. Suggested with the study, the research of the deterioration mechanism and improved test method subjected to freeze-thaw cycles should be strengthened with the coupled action of multiple damage factors, effective 3D multi-scale model, calculation methods and tools need to be developed to realize the fine numerical simulation of the freeze-thaw diseases process of hydraulic concrete in complex environment, in order to form a complete hydraulic concrete from research ideas, methods to engineering practice freeze-thaw preventive control theory.
    Cement and Concrete
    Influences of Loading Conditions on Piezoresistive Properties of Graphene Nanoplatelets Reinforced Cement-Based Composites
    WEI Lihuang, CHEN Jiamin, XIA Haiting, GUO Rongxin, LIN Zhiwei, SUO Yuxia, WU Yichen
    2021, 40(4):  1072-1078. 
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    In this paper, the effects of loading amplitude (15 MPa, 20 MPa, 25 MPa) and loading rate (100 N/s, 300 N/s, 500 N/s) on the piezoresistive properties of graphene nanoplatelets reinforced cement-based composites (GNPs/CC) were studied under different dosages of graphene nanoplatelets (GNPs). The experimental results show that the piezoresistive properties of graphene nanoplatelets reinforced cement-based composites are similar to that of the blank group when the dosage of graphene nanoplatelets is less than 0.25% (mass fraction, the same below). When the dosage reaches 0.3%, the composite has the highest and the most repeatable resistance variation. When the dosage of graphene nanoplatelets is 0.3%, the resistance variation and strain of the composite rise with the increase of the loading amplitude. When the loading amplitude is no more than 20 MPa, the increase of the resistance variation is similar to that of the strain, the gauge factor of the composite changes little. When the loading amplitude reaches 25 MPa, the increase of the resistance variation is larger than that of the strain. And the gauge factor of the composite increases largely. In addition, the loading rate has no significant effect on the piezoresistive properties of the composite when the dosage of graphene nanoplatelets is 0.3%.
    Mechanical-Electrical Response Characteristics of 2-2 Type Cement-Based Piezoelectric Composites under Impact Loading
    CHENG Wenjie, LIU Xinke, XUE Wen, FENG Pengju, ZHANG Long, LI Yi, CHEN Jiangying
    2021, 40(4):  1079-1087. 
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    The mechanical-electrical response characteristics of 2-2 type cement-based piezoelectric composites under impact loading by using the split Hopkinson pressure bar were studied. With the help of ultra-high-speed photography technology, the sample morphological failure was observed. The results indicate that piezoelectric composites have obvious strain rate effect under impact loading and they are strain rate sensitive materials. There is a threshold value of mechanical-electrical response of composites. When the stress is less than the threshold value, there is a good linear relationship between the electrical signal of sample and the applied loading. The dynamic increase factor effectively describes the rate-effect law of compressive strength of composites. In the linear range, with the increase of strain rate, the dynamic increase factor increases and grows with stable growth rate. Based on the Maxwell model, the stress relaxation time of piezoelectric composites decreases monotonously with the increase of strain rate. Under impact loading, the electrical failure of 2-2 type cement-based piezoelectric composites and piezoelectric ceramics occurs before their mechanical failure. All of their morphologies are "explosive" fragmentation and there is obvious arc discharge phenomenon for the piezoelectric ceramics.
    Optimizing Mineral Composition of High Strength Portland Cement Clinker Based on Response Surface Methodology
    LIU Yongyi, REN Zunchao, YUAN Lianwang, LUAN Congqi, WANG Jinbang, ZHOU Zonghui
    2021, 40(4):  1088-1096. 
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    The properties of hydrated Portland cement clinker mostly depend on mineral compositions. The traditional method optimizes the mineral composition of cement clinker by orthogonal test method. The test quantity is large and it is difficult to obtain the optimal point of cement clinker mineral composition. In this paper, the response surface methodology (RSM) was used to optimize the mineral composition of Portland cement clinker. Based on the Box-Behnken test design method, the relationship between lime saturation factor (KH), alumina modulus (IM), silica modulus (SM) and 28 d compressive strength was revealed and established quadratic model to obtain the best values of KH, IM and SM. The results show that the best values of KH, IM, SM are 0.94, 1.7 and 2.2 respectively, and it is found that the cement clinker designed with this modulus value has the lowest porosity of the hardened cement paste. Therefore, RSM is an effective method for optimizing the mineral composition of Portland cement clinker, which improves the mechanical properties of cement, and it is expected to improve the durability of cement.
    Effect of Iron Phase Component on Hydration Performance and Corrosion Resistance of Iron Phase and High-Iron Low-Calcium Cement Clinker
    GAO Jinrui, RAO Meijuan, ZHANG Kechang, DENG Qingshan
    2021, 40(4):  1097-1102. 
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    With the development of marine construction engineering, a large number of cement-based materials have been applied to marine construction, and the impact of the marine environment on cement-based materials has also attracted more and more attention. Studies have shown that the iron phase in cement has good corrosion resistance, and the Al/Fe mole ratio of the iron phase is the main factor affecting the corrosion resistance of the iron phase. This paper designed and burned two kinds of iron phase single ore C4AF and C6A2F (Al/Fe mole ratio were 1 and 2 respectively), and the high-iron low-calcium cement clinker with iron phase only containing C4AF or C6A2F (the iron phase mass fraction were both 20%). Through X-ray diffraction, heat of hydration, compressive strength, resistance to sulfate attack and ability to cure chloride ion, the iron phase single ore C4AF and C6A2F and the corresponding high-iron low-calcium cement clinker were tested to study Al/Fe mole ratio influence on the properties of iron phase single ore and high-iron low-calcium cement clinker. The results show that with the increase of Al/Fe mole ratio, the interplanar spacing of the iron phase becomes less, the chloride ion solidification ability is enhanced, and the sulfate corrosion resistance is reduced. At the same time, the increase of the iron phase content in the clinker promotes the hydration of C3S, and the iron phase with high Al/Fe mole ratio has a better promotion effect. As the Al/Fe mole ratio of the iron phase increases, the chloride ion solidification ability of the cement clinker increases, while the sulfate corrosion resistance decreases less.
    Mechanical Properties of Engineered Cementitious Composites Prepared with Sand in Ulanbuh Desert
    LI Zuo, YAO Qiyao, ZHU Shengyan, GUO Xinhua, PENG Linxin, TENG Xiaodan, LUO Yuejing
    2021, 40(4):  1103-1115. 
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    Engineered cementitious composites (ECC) were completely replaced by Ulanbuh desert sand from Inner Mongolia to conduct a comprehensive study on the mechanical properties of its compressive strength, tensile strength, shear strength and flexural strength. The sand-binder ratio was set as the variable. X-ray diffraction (XRD) was employed in this study to analyze the composition of the desert sand, and scanning electron microscope (SEM) was used to observe the cross section of fiber after the tensile test. The results show that the compressive strength, tensile strength, shear strength and flexural strength of the ECC prepared with desert sand are similar to the ECC prepared with microsilica sand, and the ductility of desert sand ECC is about half of microsilica sand. Except for the shear strength, all of other properties of desert sand ECC are improved with the increase of sand-binder ratio. The ductility of desert sand ECC designed with optimized mix proportion reaches the level of the microsilica sand ECC.
    Preparation of High Corrosion Resistant Cementitious Materials and Its Sulfate Resistance
    CHEN Yiming, LIN Peitong, LI Yunlong, LIU Jinhong, WANG Junfeng, LU Liulei
    2021, 40(4):  1116-1127. 
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    In order to improve the sulfate resistance of concrete pipes in urban sewage treatment system, a series of researches on high corrosion resistant cementitious materials (HCRC) were carried out in this work. Based on the orthogonal test, the ratio of ground granulated blast furnace slag (GGBFS), fly ash (FA), silica fume (SF), and desulfurized gypsum (DG) to replace ordinary Potland cement (OPC) was optimized with the corrosion resistance coefficient as the evaluation index, and the optimal mix proportion of HCRC (HCRC1) was obtained. After that, the sulfate corrosion resistance of HCRC1 was studied by the simulated sewage immersion method, and then the changes of hydration products and pore structure were analyzed by FTIR, XRD, TG-DSC, MIP and BJH. Results indicate that the HCRC1 consists of 26%OPC, 50%GGBFS, 15%FA, 6%SF, and 3%DG (all are mass fraction). Moreover, the compressive strength ratio (Kf) of HCRC1 decreases with the curing age immersed in sewage increasing, and the Kf value of HCRC1 is 37.94%, higher than that of normal cementitious material (NC) after immersing in sewage for 100 d. Furthermore, the microscopic analysis shows that the Ca(OH)2 and C-S-H gel generated in the pastes immersed in sewage are partially consumed by corrosive ions. The corrosion products are mainly gypsum, and HCRC1 produces less gypsum than NC. Further, HCRC1 pastes have smaller pore size compared with NC pastes, in which the harmful and less harmful pores change to smaller pore size, improving the ability of resisting penetration of corrosive ions. Consequently, the developed HCRC has high sulfate resistance and can be used in concrete sewage pipes.
    Evaluation on Frost Resistance of Early Age Magnesium Potassium Phosphate Cement Mortar
    MIAO Hanliang, ZHAO Bin, JI Rongjian, YANG Jianming
    2021, 40(4):  1128-1136. 
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    In order to study the frost resistance of early age magnesium potassium phosphate cement (MKPC) mortar, the strength, volume deformation and water absorption of early age MKPC mortar specimens which were rapidly frozen and thawed in water and 5% (mass fraction) Na2SO4 solution were tested, and the phase composition and micro morphology were analyzed. The results were compared with those of MKPC mortar specimens after 28 d hydration. The results show that the strength attenuation degree of early age MKPC mortar specimens (hydration age more than 1 d) is lower than that of hydration 28 d under rapid freeze-thaw cycle environment. After freeze-thaw cycle 225 times, the residual strength of MKPC mortar specimens at early age is close to that of 28 d hydration age specimens, and the strength attenuation degree of MKPC mortar specimens under sulfate freeze-thaw cycle environment is lower than that of MKPC mortar specimens under water freeze-thaw cycle. The early age MKPC mortar specimens (hydration age more than 1 d) have better deformation resistance under freeze-thaw cycle environment, and it is obviously better than that of MKPC with hydration age of 28 d. The deformation resistance of MKPC mortar specimens under water freeze-thaw cycle is better than that of MKPC mortar specimens under sulfate freeze-thaw cycle. The effect of freeze-thaw cycle on the pore structure of MKPC mortar hardened body after 28 d hydration is stronger than that of 1 d hydration. The open porosity of MKPC mortar hardened body subjected to sulfate freeze-thaw cycle is lower than that of water freeze-thaw cycle.
    Effects of Active Admixtures on Comprehensive Properties of Epoxy Resin Repair Mortar
    GONG Jianqing, LI Falei, LI Ke, QU Zhigang
    2021, 40(4):  1137-1146. 
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    In order to explore the modification effect of active admixtures on epoxy resin repair mortar and provide basis for repair engineering application, the effects of silica fume and fly ash on the mechanical properties, bonding strength, dimensional stability and frost resistance of epoxy resin repair mortar were studied. The influence mechanism was explored and analyzed by the scanning electron microscope (SEM) and mercury intrusion method. The results indicate that epoxy resin reduces the compressive strength of mortar. Adding silica fume can make up for strength loss. The strength of mortar mixed with fly ash increases with the increase of age, but the strength of mortar at 28 d and 56 d is lower than that of the control group. Silica fume and low-content fly ash (≤10%, mass fraction) improve the bonding strength of repair mortar. However, silica fume has a negative effect on the dimensional stability of repair mortar, while fly ash has the opposite effect. The frost resistance of mortar increases first and then decreases along with the increase of silica fume content. And the frost resistance decreases with the increase of fly ash content. When epoxy resin emulsion and active admixture are mixed into mortar, the hydration products and the cured epoxy resin film form an interwoven spatial network structure to improve the compactness. And silica fume and fly ash can refine the pore size of slurry. So the improvement effect of silica fume powder is better.
    Experimental Study on Strength of Split Grouting Pile Core Stone Body in Collapsible Loess Areas
    ZHOU Mingru, LI Ning, ZHONG Lin, LI Shaofei
    2021, 40(4):  1147-1153. 
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    In order to study the mechanical properties of the split grouting pile core stone body in the collapsible loess areas, five different grouting grouts with different mix ratios were carried out to test the compressive strength of test blocks of standard maintenance, test blocks of same conditions and pile core stone body of 3 d, 7 d, 14 d, 28 d, 56 d, 90 d. The results show that the compressive strength of the pile core stone body decreases with the increase of the water-binder ratio, and increases logarithmically with the increase of the curing age. The water separation rate of the grouting slurry has a greater impact on the compressive strength of the pile core stone body. The density and moisture content of the loess and the depth of the pile core stone body in the loess have a slight influence on its compressive strength. Based on the influencing factors, correlation of compressive strength between the pile core stone body and the same grout 3 d standard curing test block is derived, which predicts the effect of the foundation reinforcement project in the collapsible loess area, and provides a reference for the compressive strength of the pile core stone body for the foundation reinforcement project in the collapsible loess area.
    Effects of Chloride Introduced Way and Metakaolin on Chloride Binding Capacity of Mortar
    SUN Ming, SUN Congtao, ZHANG Peng, MA Fubin, LI Yantao, DUAN Jizhou
    2021, 40(4):  1154-1161. 
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    The same amount of chloride ions was introduced to mortars by simulated sea sand and mixed water respectively. The effects of chloride introduced way and metakaolin on chloride binding capacity were analyzed. And the corresponding test methods were used to analyze the different aspects: energy disperse spectroscopy (EDS) was conducted to analyze the distribution of chloride content; the change of hydration product was analyzed by X-ray diffraction (XRD) and derivative thermogravimetric method (DTG); the change of pore structure was evaluated by mercury intrusion porosimetry (MIP). The results show that there is a diffusion process of chloride ions from surface of sea sand to cementitious materials, and that chloride ions introduced by mixed water distribute evenly in mortar. The chloride binding capacity in mortar at different ages was discussed. The chloride binding capacity in mortar made with sea sand is lower than that made with mixed water at 1 d age, but these two chloride binding capacities tend to be same at 28 d age. The acceleration of metakaolin on early cement hydration reaction promotes the binding process of chloride ions introduced by mixed water. The content of Friedel’s salt and Ca(OH)2 decreases with the increase of metakaolin content. The chloride ions introduced by mixed water has a better refinement effect on pore structure at 20% and 30% (mass fraction) metakaolin content.
    Effect of Metakaolin on Mechanical Properties and Microstructure of Reactive Powder Concrete
    CHEN Li, ZHOU Changshun, JIANG Chenhui
    2021, 40(4):  1162-1169. 
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    Reactive powder concrete (RPC) is a promising material which exhibits extrordinary mechanical properties and durability. To investigate the effect of metakaolin (MK) on RPC, the effects of 0%, 5%, 10%, 15% and 20% mass ratio of cementitious materials replaced by MK on the mechanical properties and microstructure of RPC were studied, which included MK pozzolanic activity index test, and the compressive, flexural strength and elastic modulus tests, X-ray diffraction analyzer (XRD), as well as scanning electron microscope (SEM), MIP and nanoindentation measurements. The results show that MK exhibits high pozzolanic activity at the early stage of cement hydration, and the 28 d compressive strength, flexural strength and elastic modulus of RPC with 10% MK increase by 20.1%, 18.0% and 11.4%, respectively, comparing with the reference group. The optimal dosage of MK is 10%. It shows that the incorporation of MK reduces the porosity of RPC matrix, and more additional C-S-H gel filling the pores of RPC matrix is generated by the “secondary hydration” reaction, which improves the microstructure of RPC after the microstructure analysis. Nanoindentation investigation shows that the mass fraction of 10% MK increases the content of high density C-S-H to increase the mechanical properties of RPC. This may be attributed to the pozzolanic activity and the micro-aggregate filling effect of MK.
    Effect of Steam Curing System on Strength and Impermeability of Precast Bridge Deck Concrete
    HUANG An, LI Beixing, YANG Jianbo, WANG Lijing
    2021, 40(4):  1170-1177. 
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    In order to obtain the best steam curing system for precast bridge deck concrete, the effects of steam curing temperature, steam curing time and supplementary curing method after steam curing on strength and chloride ion diffusion coefficient of C55 concrete incorporated with fly ash and slag powder were studied. The phase composition and microstructure of the cementitious paste hydrated under different steam curing systems were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that the higher steam curing temperature and the longer steam curing time promote the hydration of cement and the formation of the paste microstructure, which increase the demoulding strength of concrete, but reduce the later strength and the resistance to chloride ion penetration of concrete. The supplementary moisture curing after steam curing provided hydration water for the continuous hydration of unhydrated cement and mineral admixtures, which helps to improve the later strength and impermeability of concrete. The precast bridge deck concrete has good comprehensive performance when it is steam cured for 6 h at 55 ℃ and then wet cured for 7 d with covering of geotextile.
    Early Strength Study on Recycled Aggregate Concrete of Magnetized Water Steel Fiber
    DING Yahong, CHEN Bing, WU Jun, ZHANG Xianggang, XU Ping
    2021, 40(4):  1178-1185. 
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    In order to study the effect of magnetized water and steel fiber on the early strength of recycled aggregate concrete, the effects of magnetized water with different magnetic field strength (0 mT, 200 mT, 260 mT, 320 mT) and steel fiber with different volume content (0%, 0.6%, 1.2%) on the early compressive strength and splitting tensile strength of recycled aggregate concrete cube were investigated and analyzed based on the C40 strength. Experimental results show that steel fiber significantly improves the early compressive strength and splitting tensile strength of recycled aggregate concrete, and magnetized water improves the compressive strength and splitting tensile strength of recycled aggregate concrete to varying degrees. The early compressive strength of recycled aggregate concrete increases obviously under 0.6% steel fiber content and 260 mT magnetic field strength.
    Performance of High Strength and Low Thermal Conductivity Foamed Concrete
    ZHOU Xuejun, XIAN Guodong, WANG Zhen, LIU Zhe, WANG Xingbo, WANG Weidong
    2021, 40(4):  1186-1192. 
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    In engineering practice, as the wall material of prefabricated buildings, this wall material not only requires better thermal insulation performance, but also meets certain mechanical properties requirements. Light foamed concrete is a good choice for this wall material. But the mechanical properties of light foamed concrete are often poor when it meets the thermal properties requirements. A preparation method of high strength and low thermal conductivity foamed concrete was proposed. The effects of water-binder ratio, foam content, fly ash content and polypropylene (PP) fiber content on the compressive strength and thermal conductivity of foamed concrete were studied through mix ratio experiment. In view of scanning electron microscope (SEM) of foamed concrete, the influences of fly ash and PP fiber on compressive strength and thermal conductivity of foamed concrete are revealed. The results show that when the water-binder ratio is 0.6, the content of foam is 4% (mass fraction, the same below), the content of fly ash is 25% and the content of PP fiber is 0.2%, the foamed concrete has higher compressive strength and lower thermal conductivity.
    Bond Strength Damage Model between Fiber Reinforced Concrete and High-Strength Steel Bars under Thermal-Cold Cycles
    ZHANG Guangtai, LI Ruixiang, LIU Shituo, SAMAT Adil, GENG Tianjiao
    2021, 40(4):  1193-1204. 
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    Through the central pull-out test of ordinary concrete (PC), steel fiber reinforced concrete (SFRC), polypropylene fiber reinforced concrete (PFRC) and HRB500E steel bars after thermal-cold cycles, the deterioration mechanism of different types of concrete was studied, and the influences of thermal-cold cycles on mass loss, relative dynamic elastic modulus and bond strength of PC, SFRC and PFRC were analyzed. The results show that the mass loss and dynamic elastic modulus loss of concrete increase, and the bond strength between reinforcement and concrete decreases after thermal-cold cycles. When steel fiber and polypropylene fiber are added into the specimen, the attenuation of bond strength is weakened, and the inhibition effect of polypropylene fiber is more obvious. Combined with the experimental data, the Petersen model, Xu model and Wu model at home and abroad are compared and analyzed. Considering the influences of thermal-coal cycles on the relative dynamic modulus of elasticity and the relative bond strength, based on Weibull probability distribution theory and strength attenuation model, a bond strength degradation model of fiber reinforced concrete and high-strength steel bar is established, which is verified by the data in this paper. The average value of the ratio between measured value and calculated value is 0.97, and the standard deviation is 0.07, which are in good agreement. The model provides a theoretical reference for the durability design of fiber reinforced concrete structures under thermal-cold environment.
    Influence of Manufactured Sand-Stone Chips Composite Fine Aggregate on Properties of Different Strength Grade Concrete
    TONG Xiaogen, ZHANG Kaifeng, MENG Gang, LUO Zuoqiu, HU Yubo, WANG Jiamin, WANG Bo, WANG Guofeng
    2021, 40(4):  1205-1212. 
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    In order to make rational use of the composite sand composed of manufactured sand and stone chips to alleviate the deficiency of natural river sand, the optimal matching ratio between them was determined quickly by using the method of grade-combination calculation, so as to obtain the composite sand that meets the technical requirements of sand in area II of the national standard. Then, the effects of composite sand with different compound ratio on the workability, mechanical properties and durability of C30 to C50 strength grade concrete were studied respectively. The results show that, different combination ratio of composite sand improve the performance of concrete to different degrees. When the ratio of manufactured sand to stone chips is 6∶4 (mass ratio), the comprehensive performance of each strength grade concrete is the best.
    Anti-Corrosion Techniques of Bridge Pile Foundation Concrete in High-Concentration Sulfate Environment
    MU Song, GUO Zheng, LIU Guangyan, ZHOU Ying, XIE Deqing, CAI Jingshun, LIU Kai
    2021, 40(4):  1213-1219. 
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    As the demand for sulfate resistance of pile foundation concrete of a highway bridge in the Southwest of China, the influences of anti-corrosion techniques on concrete compressive strength, corrosion resistance coefficient of compressive strength and sulfate-ion transport under 10% (mass fraction)-sulfate solution were investigated. The mechanism of anti-corrosion techniques was analyzed by air-void structure and micro morphology. The results show that the corrosion resistance of "expansive agent with supplementary cementitious materials" admixtures is excellent in the early stage but serious in the later period, and the corrosion resistance of "salt crystallization inhibition" admixtures is better in the long term. Supplementary cementitious materials and "expansive agent with supplementary cementitious materials" admixtures delay the corrosion of sulfate mainly by improving the compactness and optimizing the pore size distribution, while "salt crystallization inhibition" admixtures not only optimize the pore structure of concrete to a certain extent, but also inhibit the formation of crystalline expansion products.
    Problems and Suggestions on Computing Methods of Air-Void Characteristics of Concrete in Current Domestic Codes
    CHEN Xin, LI Lihui, LIU Xu, TIAN Bo, GE Yong
    2021, 40(4):  1220-1227. 
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    Computing formulas of air-void spatial distribution density and air-void spacing factor of hardened concrete based on linear traverse method were derived according to geometric interpretations of the two parameters. By the comparison between derived formulas and regulations about air-void characteristics in foreign and domestic codes, current domestic codes were reviewed and revised. In the review, it is found that the critical ratio of cement paste content to air content is 4.33 in domestic codes of railway, highway, waterway and partial power industries. However, it is not as accurate as 4.34. Some coefficients in formula provided by domestic highway code are not in accordance with geometric interpretations. Both codes of highway and waterway industries do not realize that if the air content or paste content is presented as "%" by volume, it would be 100 times of the value of volume ratio and require formula coefficients changes. To keep formula coefficients unchanged, both the air content and paste content are suggested to be presented as values of volume ratio instead of "%" by volume. Except for railway codes, domestic codes of various industries mistakenly define the air-void number in 1 mm3 as air-void number in 1 000 mm3 in the calculation of spatial distribution density. These codes also mistakenly substitute the air-void number (unit: cm-1) intersected by 10 mm traverse for air-void frequency (unit: mm-1) in the calculation formula of spacing factor, the unit of which is millimeter. All the errors mentioned above need to be taken seriously and revised in future editions.
    Comparative Test Study on Work Performance Evaluation Methods of Steel-Shell Submerged Tunnel Used Self-Compacting Concrete
    YU Fang, SONG Shenyou, LI Hanbo, FAN Zhihong, LIN Weicai, LUO Wei
    2021, 40(4):  1228-1237. 
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    There is no unified approach for evaluating the workability of self-compacting concrete. In this paper, comparison tests were carried out to self-compacting concrete with slump expansion of 500 mm to 850 mm by testing three workability indexes: filling ability, passing ability and anti-segregation ability. Evaluation method of concrete performance was then discussed. The results show that the comprehensive evaluation indexes of slump-flow (USF), slump time (T500), L-type instrument passing rate (H2/H1) and visual stability index (AVSI) provide good characterization to the workability of self-compacting concrete. USF and AVSI provide good evaluation to filling ability to self-compacting concrete. L-type instrument or J-ring test provide good evaluation to passing ability of self-compacting concrete. The stability of on-site concrete preliminarily evaluates by visual stability test (VSI) first, and then by segregation rate sieve test (GTM sieve analysis method) when quantitative evaluation is needed. In addition to GTM sieve analysis method, pressure bleeding test should be added when necessary for the anti-segregation evaluation of concrete of vertical members such as side walls.
    Floating Pouring Model of Large-Section Steel-Shell Self-Compacting Concrete Pipe Joint
    CHEN Can, WANG Xuegang, FAN Zhihong, YU Fang, ZENG Junjie
    2021, 40(4):  1238-1242. 
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    The deep-medium passage immersed tube tunnel has the characteristics of super large span, super wide, and large back silt, etc. It adopts a steel-shell wrapped plain concrete structure to separate the steel shell production from the concrete pouring. In order to verify the deep-medium passage steel-shell self-compacting concrete pipe section for the feasibility of construction process, large-section model tests were carried out to study the properties of self-compacting concrete, the precast pouring process of steel-shell floating state and the quality of the model structure to ensure the reliability of pipe joints in the construction process. The results show that, through the preparation of self-compacting concrete, the performance of the concrete mixture meets the basic performance requirements of fluidity, filling and segregation resistance. Through monitoring the temperature and strain of the model concrete and testing the compressive strength in the large-section model floating pouring test, the temperature of the steel-shell self-compacting concrete has been well controlled, and the self-compacting concrete prepared has a good volume stability. The 28 d compressive strength of concrete is above 50 MPa, and its compactness and homogeneity are good, and it meets the requirements of the compounding index. The construction process of floating self-compacting concrete with steel-shell immersed pipe is feasible.
    J-Body Rheological Model of Concrete Fractional Order Stress Relaxation
    QIN Yi
    2021, 40(4):  1243-1249. 
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    In order to better solve the long-term stability problem of concrete structure and study the stress relaxation characteristics of concrete structure, an unsteady fractional order stress relaxation time-dependent model was established. The model used fractional order theory to fractionalize the traditional integer-order stress relaxation model. By constructing the relationship between damage variables, time and model parameters, and considering the effect of time on the fractional order number of model, a new unsteady fractional order stress relaxation time-dependent constitutive model was established. Finally, the correctness and rationality of the model were verified by experimental data. The results show that the model curve is highly consistent with the experimental curve, which indicates that the unsteady fractional order model is suitable for reflecting the deformation process of rock stress relaxation. It can better describe the whole process of stress relaxation change. In general, the fitting degree of the model is much higher than that of the J-body model. In the latter case, the model curve has a large deviation from the test curve under the action of large strain.
    Solid Waste and EcoMaterials
    Mechanical Properties of Geopolymer Mortar Based on Metakaolin and Fly Ash
    GUAN Bolun, GUO Rongxin, QI Rongqing, FU Chaoshu, ZHANG Min, ZHANG Wenshuai
    2021, 40(4):  1250-1257. 
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    In this study, geopolymer mortar specimens were prepared with metakaolin and fly ash as raw materials, potassium sodium silicate with different modulus (0.75, 1.00, 1.25, 1.50) and alkali concentration (mass fraction) (40%, 44%, 48%) as alkali activator, and microbeads, vermiculite and perlite as fine aggregate. The compressive strength of geopolymer mortar specimens at room temperature and 1 000 ℃ high temperature were tested, the influences of the modulus and concentration of alkali activator on the mechanical properties of mortar specimens were explored, and the phase composition and micro-morphology of geopolymer were characterized by XRD and SEM. The test results show that when the alkali concentration is unchanged (except concentration of 40%), the compressive strength of most specimens increase first and then decrease slightly or remain basically unchanged with the increase of modulus. When the modulus remains unchanged (except modulus of 0.75), the compressive strength of most specimens increase first and then decrease with the increase of alkali concentration. When the modulus is 1.00 and the alkali concentration is 44%, the compressive strength of the specimen is the highest. After 1 000 ℃ high temperature, the relative residual strength of the sample still maintains at 42% or above. The hydration products after 1 000 ℃ are leucite (KAlSi2O6) and potassiumnephritic (KAlSiO4). And a large number of flocculent hydration products are formed at room temperature and the microstructure is relatively compact.
    Preparation of Phosphoric Acid-Based Geopolymer Foams and Its Fire-Resistance
    AN Ran, XU Zhonghui, SHUAI Qin, HU Dan, XIANG Yingling, HAN Linpei
    2021, 40(4):  1258-1265. 
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    Phosphoric acid-based geopolymer foams (PAGFs) were prepared from metakaolin with phosphoric acid as activator and hydrogen peroxide as foaming agent. The effects of liquid-solid ratio and manganese dioxide content on the physical properties, thermal conductivity and fire-resistance of PAGFs were studied. As liquid-solid ratio varies from 1.56 to 1.76, the PAGFs with uniform distribution pore and excellent pore structure can be prepared. As the liquid-solid ratio is 1.71, the sample presents maximum compressive strength (2.73 MPa) and minimum thermal conductivity (0.17 W/(m·K)). Furthermore, when the liquid-solid ratio is constant, the addition of manganese dioxide raises the decomposition efficiency and the rate of hydrogen peroxide, improves the pore structure of PAGFs.When the manganese dioxide mass content is 0.10%, the thermal conductivity of the sample decreases, the dry density and porosity increase, and the compressive strength remains at 2.09 MPa. After 3 h fire-resistance test, the backside temperature of the sample remains at about 262 ℃ under the condition of 1.71 liquid-solid ratio and 0.10% manganese dioxide content. The XRD and SEM indicate that lamellar tridymite and tridymite aluminum phosphate (T-AlPO4) phase are detected in samples after fire-resistance test.
    Effects of Activators on Alkali-Silica Reaction in Alkali-Activated Slag Cement Mortars
    WEI Haoguang, GAO Xuan, ZHOU Shiming, ZHANG Fuyang, WANG Xiaojing, YAO Xiao
    2021, 40(4):  1266-1272. 
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    The sodium silicate solution was used as activator to prepare the alkali-activated slag (AAS) cement mortars. The AAS mortars were cured in 1 mol/L NaOH solution at 80 ℃ for purpose of accelerating the alkali-silica reaction (ASR). Effects of alkali content and silicate modulus in activator on ASR expansion failure of AAS mortars were investigated. The results show that the mortars exhibit ASR hazardous expansion failure. When the Na2O content is higher than 4% (mass fraction), the ASR expansion rates of mortars are higher than 0.1%. When the silicate modulus is in the range of 1.2 to 2.0, the ASR expansion rate is further increased. The ASR products are mainly formed in the aggregate-binder interface zone, where microcracks development is also observed. The ASR expansion occurrs in the mortars results in compressive strength loss.
    Preparation of Portland Cement Clinkers by Utilizing Copper Tailings as Siliceous Material
    YAN Jun, NIE Song, LIU Songbai, QIU Tingsheng
    2021, 40(4):  1273-1279. 
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    Portland cement clinkers with different clinker modulus were prepared by utilizing copper tailings as siliceous material at different calcination temperatures (1 350 ℃, 1 400 ℃ and 1 450 ℃). The sinterability of cement raw meal was investigated by the determination of f-CaO in the sample by ethylene glycol-ethanol method. Effect of copper tailings on mineral formation temperature was researched by differential scanning calorimetry (DSC). Mineral composition and microstructure of clinkers were also analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that, compared with sandstone, when copper tailings are utilized as siliceous material to prepare Portland cement clinkers, the temperature of liquid phase and C3S formation are lower, and the sinterability of raw meal is improved. f-CaO conforms to the standard requirement of Portland cement clinkers with lime saturation degree (KH) lower than 0.92 sintered well under 1 400 ℃ were prepared。The size of C3S is about 20 μm, and the structure of clinkers is more compact.
    Preparation and Properties of New Packing Material Contained Red Mud
    WANG Xudong, LI Weibin, ZHAO Jun, ZUO Nannan, SHI Zhuqing, WANG Pengcheng, WANG Weiwei, GAO Weijie
    2021, 40(4):  1280-1285. 
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    In order to make up for the shortage of most packing materials in the process of coal mining due to the high cost of packing materials, and effectively solve the current situation that a large number of solid waste red mud produced in the aluminum industry can not be treated, a new packing material contained red mud utilized in gob-side entry retaining technique was developed through the effective mixing of additives and main raw materials. The performance indexes including compressive strength, setting time, fluidity and stability were studied. The results indicate that the new packing material contained red mud has good single slurry fluidity, and its setting time is more than 6 h. The amount of red mud in the material can be adjusted, and its mass fraction ranges from 0% to 50%. The molding material has early strength and quick hardening, the initial setting time is only 25 min. The compressive strength in 1 d, 3 d, 7 d of packing material with optimum proportion of red mud and additives reaches 8.4 MPa, 10.3 MPa and 12.3 MPa, respectively. After the packing material coated with plastic film impregnates for 14 d, the pH value of leaching liquor keeps at 6, the alkaline substances in the red mud are solidified well, and the probability of pollution is low.
    Correlation of Strength Influencing Factors of Modified Rammed Earth Wall Materials
    LIU Lei, YAO Yong, ZHANG Lingling
    2021, 40(4):  1286-1295. 
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    Rammed earth construction is one of the main forms of Chinese traditional local-style dwelling houses building. It has the advantages of locally-produced raw materials, warm in winter and cool in summer, convenient construction, low energy consumption, green environmental protection, and greatly inherited and applied in the construction of beautiful countryside. However, the traditional rammed earth wall material is composed of plain soil, and has some shortcomings such as low strength and poor water resistance, which limits its popularization and application. In order to improve the compressive bearing capacity of rammed earth wall materials, plain soil in the northwest Sichuan region was used as raw material and cement, sand, gravel, fiber and EFS soil stabilizer were used as modified materials. The correlation between the influence factors and compressive strength andmicrocosmic mechanism were studied. The results show that the partial correlation coefficients of age, cement content, total sand and gravel content, EFS soil stabilizer content, fiber type and compressive strength are 0.77, 0.72, 0.68, 0.64 and 0.61, respectively. The increase of cement, sand and gravel aggregate, EFS soil stabilizer content and the increase of age are conducive to improve the compressive strength of specimens. Through XRD, IR and SEM analysis, the cementing products produced by cement hydration reaction are wrapped, filled and connected with the soil particles, resulting in reduced porosity between the overall structures, forming a more compact and stable microstructure, and improving the compressive bearing capacity of the modified materials.
    Effects of Water and Salt Crystallization Phase Change on Saline Soil Pressure During Freezing Process
    TAN Renyi, WU Daoyong, HUANG Youfen, WU Shiyu
    2021, 40(4):  1296-1303. 
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    Soil deformation caused by frost heave and salt heave is a serious threat to building foundations, roads and railway subgrades. The effects of water and salt crystallization phase change on saline soil pressure during freezing process were studied experimentally. The results show that the ice crystallization pressure increases with the increase of moisture content, while salt crystallization pressure increases with the increase of salt content under a certain dry density and moisture content. During the freezing process, the soil pressure unchanges firstly, then increases rapidly, and finally decreases to stability. The analysis shows that the ice crystallization pressure and salt crystallization pressure act as tensile stress on the pore wall to squeeze the soil particles between each other, after the peak stress, the breaken of soil structure and redistribution of soil particles lead to the soil pressure rapidly decreases to stability. In addition, the applicability of the traditional salt crystallization pressure equation and ice crystallization pressure equation were discussed. Finally, the ice crystallization pressure equation was modified.
    Optimizing Yield Comparison of an Iron Ore Fine Grinding Intermediate Grain Size by Orthogonal Test Method and Response Surface Method
    PEI Yingjie, XIAO Qingfei, ZHANG Qian, MA Shuai, WU Yukai
    2021, 40(4):  1304-1311. 
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    Using the orthogonal test method and response surface method, aiming at the low yield of intermediate easy-to-selection grades of an iron ore grinding product in Shanxi, the single factor test was used to explore the effects of grinding time, grinding concentration and medium filling rate on the yield of intermediate easy-to-selection grades, and the experimental research on optimizing the yield of the fine grinding intermediate grain size was carried out. The results show that the optimal intermediate easy-to-selection grade yields obtained by the orthogonal test method and response surface method are 81.27% and 81.80%, respectively. The optimal grinding condition obtained after optimization by response surface method is as follows: grinding time 14.15 min, grinding concentration 70.80% (mass fraction) and the filling rate 30.50% (volume fraction). This condition is better than the best condition of orthogonal test method, and the response surface method has certain advantages in the influence of the interaction between the analysis factors on the yield of the intermediate easy-to-selection grade. The study clarifies that the response surface method can fully realize the purpose of increasing the yield of intermediate easy-to-selection grades of grinding products, and provide a reference method for similar problems in related factories and mines.
    Research on Leaching of Heavy Metals from Nickel-Iron Slag in Electric Furnace
    SU Qing, XIE Hongbo, CHEN Zhe, MAI Junming, WU Chunli
    2021, 40(4):  1312-1317. 
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    By analyzing the mineral composition and phase composition of electric furnace nickel-iron slag, the heavy metal content of electric furnace nickel-iron slag with different particle sizes was investigated, and the BCR (Bureau Community of Reference) continuous extraction method and adjusting the pH value of extractant were used to test the leaching of electric furnace nickel-iron slag. The results show that the powdered electric furnace nickel-iron slag has the highest heavy metal content, and the complete electric furnace nickel-iron slag has a lower heavy metal content than that of the damaged. The electric furnace nickel-iron slag is a general industrial waste, not a hazardous waste. Heavy metal Cd is more easily leached, heavy metals Cu and Ni are more easily leached in a weak acid environment, heavy metals Cr, Pb and Mn are more easily leached in a reducible state, and Zn and Cu are more easily leached in an oxidizable state. Except for Cu and Pb, the decrease of pH increases the leaching amount of heavy metals in the nickel-iron slag of electric furnace, showing an L-shaped leaching curve. Cu accelerates the leaching in an alkaline environment, while Pb only is leached in a large amount under a strong alkaline environment. Pay attention to the Pb leaching test in a strong alkaline environment.
    Ceramics
    Research Progress of Spinel-Type Cobalt-Free Black Ceramic Pigments
    ZHANG Xiang, LI Zhiqiao, MA Guojun, WANG Qiang, LIU Mengke
    2021, 40(4):  1318-1329. 
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    Black ceramic pigments are currently widely used in the field of ceramic decoration. The traditional processes to produce black ceramic pigments require the addition of cobalt oxide, but the high price of cobalt oxide limits the development of black ceramic pigments. Therefore, the development of cobalt-free black ceramic pigments has become one of the hot spots in the research field of ceramic pigments and the spinel-type cobalt-free black ceramic pigments are favored by many researchers for their excellent high-temperature resistance, atmospheric adaptability and chemical stability. Based on the research progress of spinel-type cobalt-free black ceramic pigments, coloration mechanism, raw material types and preparation technologies of the above ceramic pigments were described and analyzed detailedly in this paper. At present, the raw materials for preparing the spinel-type cobalt-free black ceramic pigments can be mainly divided into chemical raw materials, mineral raw materials and industrial solid wastes. The preparation technologies mainly include the traditional high-temperature solid-state method, the microwave roasting method, the chemical precipitation method, the sol-gel method, the microemulsion method, the solution combustion method, etc. The coloring properties of prepared pigments are mainly affected by the mole ratio among transition metal elements in raw materials, the roasting temperature and the holding time. In comparison, microwave roasting of industrial solid wastes to prepare the above ceramic pigments has a good application prospect, but the formation and evolution mechanism of spinel in the preparation process and the influence of impurity components introduced by industrial solid wastes on the properties of pigments still need to be further studied.
    Effects of Carbon Fiber Length and Content on Properties of SiC Reticulated Porous Ceramics
    JIN Xinxin, LIN Peng, LIU Feng, LI Saisai, LI Minghui, XIA Xiaoyu, LAO Dong, JIA Wenbao, SHAN Qing
    2021, 40(4):  1330-1337. 
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    In order to improve the flexural strength of SiC reticulated porous ceramics prepared by the polymer sponge replica technique, the carbon fiber was used to enhance SiC reticulated porous ceramics. The effects of additives and carbon fiber on the rheology and thixotropy of SiC ceramics slurry were studied. Furthermore, the influences of length and content of carbon fiber on the microstructure, porosity, compressive strength and flexural strength of SiC reticulated porous ceramics were also investigated. The results show that the SiC ceramics slurry with 0.1% (mass fraction) dispersant-FS20, 0.1% (mass fraction) thickness agent-CMC and 0.05% (mass fraction) binder-CL exhibits excellent rheological and thixotropic behavior. The viscosity of slurry increases by adding carbon fiber. In addition, with the increase of carbon fiber content and length, the flexural strength of SiC reticulated porous ceramics first increases and then decreases. When the length and content of carbon fiber are 1 mm and 0.75% (mass fraction) respectively, the flexural strength reaches the maximum.
    Effect of ISOBAM on Rheological Behavior of Alumina Slurries
    LIN Xiaoqing, WANG Haojian, LIANG Ruofan, SONG Xiaojiao, WU Min, GUAN Kang, PENG Cheng, DU Yang
    2021, 40(4):  1338-1343. 
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    ISOBAM is a novel ceramic additive and mainly used for gel-casting processing as dispersant and gelling agent. The effect of pH value, addition of ISOBAM and milling time on the rheological behavior of alumina slurries was investigated. The gelling mechanism of ISOBAM was also studied. The results show that ISOBAM has an apparent dispersing effect on alumina slurries, due to the interaction via hydrogen bonding between carboxyl group and alumina surface and the improvement of Zeta potential. The alumina slurry with 0.2% (mass fraction) ISOBAM gelatinizes rapidly, since its pH value is close to the isoelectric point. Elastic network forms between ISOBAM molecules and alumina particles via hydrogen bonds.
    Glass
    High-Solid Potassium Polysilicate Based Fire-Resistant Gel and Its Application in Composite Fireproof Glass
    SHANG Ke, WANG Junsheng, ZHAO Bi, WU Yingjie, LIN Guide, ZHAO Jing, JIN Xing, LIU Dan
    2021, 40(4):  1344-1351. 
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    In order to obtain the composite fireproof glass with better fire resistance, the high-solid silica sol dispersion was first prepared by evaporating water process. The particle size of inorganic particles and Zeta potential changes of the dispersion before and after evaporation were studied using nanoparticle size and Zeta potential analyzer. The results show that the evaporation process has almost no effect on the particle size and dispersion stability of the nanoparticles. Then, the high-solid potassium silicate based fire-resistant gel and composite fireproof glass were prepared using the high-solid silica sol dispersion and potassium hydroxide solution as raw material and curing agent, respectively. Small refractory test furnace and thermogravimetric analysis were used to investigate the fire resistance of the composite fireproof glass and the thermal stability of the fire-resistant gel. The results show that the increase of the solid content in dispersion greatly improves the fire resistance of the composite fireproof glass, and also enhances the thermal stability of the fire-resistant gel to a certain extent. Furthermore, the scanning electron microscopy and infrared spectroscopy tests were used to reveal the fire resistant mechanism of the fireproof gel. It shows that the evaporation process of fire-resistant gel acts as an endothermic function and the solid carbon residue produced by the fire-resistant gel at high temperature plays a role in blocking heat.
    New Functional Materials
    Research Progress of Cathode Materials for Lithium-Sulfur Battery
    ZHA Cheng, ZHANG Tianyu, JI Yuchen, LIU Shuhe
    2021, 40(4):  1352-1360. 
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    With the world energy shortage crisis becoming more and more serious, the development of renewable energy has become an inevitable trend, and the research of energy storage system has become a key issue. Lithium-ion battery plays an important role in electronic equipment, but its low theoretical specific capacity makes it difficult to meet the needs of large scale electronic equipment. With theoretical specific energy density (2 600 Wh·kg-1) and theoretical specific capacity (1 675 mAh·g-1) several times higher than those of lithium-ion battery, source-abundance and low price of sulfur, lithium-sulfur battery is a very promising energy storage device. Cathode materials have an important impact on the performance of lithium-sulfur batteries, which have been widely studied. In this paper, the recent research progress of sulfur/carbon composites, sulfur@carbon/metal compounds composites, sulfur/heteroatom doped carbon composites and sulfur/carbon composites loaded with catalysts in lithium-sulfur batteries was reviewed, and their future development was prospected.
    Microstructure and Optical Properties of La2Mo2O9 Doped Sodium Bismuth Titanate Ferroelectric Ceramics
    TANG Haipei, ZHOU Changrong, YAO Kai, TAN Yunchuan, ZHONG Mingqiang, YUAN Changlai
    2021, 40(4):  1361-1369. 
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    An internal electric field is created by the polarization of the ferroelectric ceramics, which separates photogenerated carriers and effectively reduces the recombination rate of carriers. However, the light absorption is limited by wide band gap of ferroelectric ceramics, so the further development of ferroelectric ceramics in the field of photovoltaic is hindered. In this paper, doping La2Mo2O9 into Bi0.5Na0.5TiO3 (BNT) ceramics with good ferroelectricity, to reduce the optical band gap and increase the photocurrent density. The samples were prepared by the conventional solid-phase synthesis method, and the XRD, Raman, light absorption, photocurrent, ferroelectric and dielectric properties of the ceramics were analyzed. The results show that the La2Mo2O9 doping significantly increases the light absorption intensity. As the content of La2Mo2O9 doping increases, the optical band gap first decreases significantly, and then slowly increases. The BNT-xLM ceramics with x=0.7% (mole fraction) exhibits the minimum optical band gap values with 1.57 eV, which is much lower than the 2.9 eV of pure BNT ceramics. The corresponding maximum photocurrent density and open circuit voltage are 71.06 nA/cm2 and 4.40 V respectively, and the maximum output power obtained is 312.7 nW/cm2, as well as the variation, is small with time maintaining excellent ferroelectricity. The research results show that La2Mo2O9 modified BNT ferroelectric ceramics is a very promising ferroelectric photovoltaic material.
    Preparation and Thermal Conductivity of ZnO/EP Composites
    LIU Rong, CHEN Guo, LI Liangfeng, GAO Pengfei, WANG Yuping
    2021, 40(4):  1370-1377. 
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    The wurtzite ZnO powders were prepared by the sol-gel method, and the influence of calcination temperature on the quality of ZnO powder was investigated. ZnO as-prepared at different calcination temperatures was filled in epoxy resin (EP) to obtain a series of ZnO/EP composites. The structure and morphology of ZnO/EP composites were characterized and analyzed using FTIR and FESEM. The effects of ZnO particle size and content on the thermal conductivity of ZnO/EP composites were studied. The results show that the higher the calcination temperature is, the bigger the particle size of ZnO is. Specifically speaking, ZnO powder prepared at 700 ℃ has the largest particle size and highest purity. Moreover, when the content of ZnO is fixed, ZnO powder with bigger particle size is conducive to improving the thermal conductivity of ZnO/EP composites. With the content of ZnO increasing, the thermal conductivity of ZnO/EP composites continues to increase. When the volume fraction of ZnO is 30.05%, the thermal conductivity of ZnO/EP composites achieves 0.54 W/(m·K), which is 184% higher than that of pure epoxy, and the mechanical property is still maintained at a good level.
    Preparation and Microwave Absorbing Property of SiC/C Fibers with Shell Core Structure
    WANG Kun, ZHANG Tao, WANG Jian, XIA Long
    2021, 40(4):  1378-1387. 
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    SiC/C fibers with shell core structure were prepared by activated carbon fiber conversion method. The effects of SiC thickness on thermogravimetry and microwave absorption property of SiC/C fibers with shell core structure were studied by Raman spectroscopy, SEM, XRD and thermogravimetric analysis. The results show that the microwave absorbing property of the samples coated with SiC shell are improved. When the thickness of the sample is 3.0 mm, the minimum reflection loss of the sample after holding for 4 h reaches -17.22 dB at 8.24 GHz, and the frequency bandwidth less than -10 dB (90% of electromagnetic wave is absorbed) reaches 4.8 GHz (11.12 GHz to 15.92 GHz) at 2.0 mm. The minimum reflection loss of the sample kept for 3 h reaches -14.45 dB at 8.23 GHz, which is lower than -10 dB (90% of electromagnetic wave is absorped) bandwidth reaches 4.56 GHz at 2.0 mm (10.88 GHz to 15.44 GHz). With the increase of SiC content, the microwave absorption property of the samples are enhanced. The initial oxidation temperature of SiC/C fiber samples with core-shell structure is increased by more than 150 ℃, and the final residual mass is about 50%. That is to say, the oxidation resistance of the samples coated with SiC fibers is greatly improved.
    Refractory Materials
    Influence of Chemical Composition on Structure and Properties of Light-Burned Magnesium-Aluminum Spinel
    CHEN Qingjie, ZHOU Junhu, GUAN Xiping, YANG Bingbing, YANG Jinjiao, LI Nan
    2021, 40(4):  1388-1394. 
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    The aluminum-magnesium castable prepared by the light-burned spinel has better slag penetration resistance due to the larger lattice distortion and higher reaction activity of the light-burned spinel compared with the traditional sintered spinel or fused spinel. The industrial alumina and light-burned magnesia powder were used as raw materials to prepare magnesium-rich spinel (the mass fractions of alumina were 68% and 70%), stoichiometric spinel (the mass fraction of alumina was 72%) and aluminum-rich spinel (the mass fraction of alumina was 76%) after sintered at 1 600 ℃. The influence of Al2O3 content on the cold physical properties, phase composition, crystal structure parameters and microstructure of samples were investigated. The results show that the increase of Al2O3 content increases the apparent porosities and decreases the linear shrinkage of samples, indicating that the sintering properties of magnesium-rich spinel and stoichiometric spinel are better than that of aluminium-rich spinel. Under the experimental conditions, the solid solution of magnesium oxide into spinel is less than 2% (mass fraction), and the solid solution of alumina into spinel is more than 4% (mass fraction). The phase of magnesium-rich spinel sample is spinel and a small amount of periclase, the other samples only have spinel phase. The solid solution of alumina into spinel makes the lattice distortion of aluminum-rich spinel greater than that of magnesium-rich spinel and stoichiometric spinel, and the grain size and average pore size of aluminum-rich spinel are smaller than that of magnesium-rich spinel and stoichiometric spinel due to the delay of solid solution sintering.
    Road Materials
    High and Low Temperature Performance of Warm/Hot-Mixed Crumb Rubber Modified Asphalt Mixture under Salt Freezing-Thawing Cycles
    WANG Lan, GUO Zhixiang, ZHANG Baoxin, SONG Changzhen, HE Liqi
    2021, 40(4):  1395-1404. 
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    Through the triaxial repeated creep test, trabecular bending test, and bending creep test, the high and low temperature performance of the warm-mixed crumb rubber modified asphalt mixture (CR-WMA) and the hot-mixed crumb rubber modified asphalt mixture (CR-HMA) under the action of salt freezing-thawing cycles were studied, and the Burgers model was used to fit and analyze the creep data. The results show that with the increase of number of times of freezing-thawing cycles, the high and low temperature performance of CR-WMA and CR-HMA gradually decreases. When the number of times of freezing-thawing cycles is 0 to 15, the high and low temperature performance reduces the speed fastest, and later the change tends to be gentle. The performance of CR-WMA reduces more slowly and less than that of CR-HMA. With the increase of salt concentration, the high and low temperature performance of CR-WMA and CR-HMA gradually decreases. When the salt concentration is 8%, the decrease amplitude reaches the maximum. The downward trend of CR-WMA is more moderate than that of CR-HMA.The change law of viscoelastic parameters fitted by creep data also verified the above conclusions, indicating that CR-WMA doped with SDYK surfactants has more stable high and low temperature performance than CR-HMA, and has better resistance to salt erosion and crack resistance.
    Automobile Exhaust Degradable Asphalt Mixture Development and Engineering Application
    LI Weirui, PENG Geng, WU Yanhua, DONG Xueqian, XU Shifa
    2021, 40(4):  1405-1412. 
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    A new type of nano-TiO2-based photocatalytic degradation material (WLSF-TiO2) was developed to degrade automobile exhaust in urban areas. The thin-layer overlay asphalt mixture was prepared by the addition of WLSF-TiO2 and applied in the pavement preventive maintenance project of Beijing Jingshan Qian Avenue. The indoor evaluation indicated that, with the addition of WLSF-TiO2, the road performance of asphalt mixture still meets the Chinese specification of asphalt mixture, while the effect of automobile exhaust (NOx, HC, CO) degradation is increased by more than 30% contrast to asphalt mixture with traditional TiO2 additive. The outdoor measurements in pavement site show that the automobile exhaust degradation effect of WLSF-TiO2 reaches about 10%.