Effect of CsCl on Structure and Properties of Ge20Sb10Se65Te5 Glass

Abstract

Abstract: CsCl is the most commonly used nucleating agent for preparing chalcogenide glass-ceramics. In this paper, different content of CsCl was added to Ge₂₀Sb₁₀Se₆₅Te₅ glass, and glass samples were prepared by different cooling methods. The effect of CsCl on the structure and properties of Ge₂₀Sb₁₀Se₆₅Te₅ glass was studied by X-ray diffraction, infrared transmission spectra, differential scanning calorimetry, thermal expansion and Raman spectra. The results show that (100-x)Ge₂₀Sb₁₀Se₆₅Te₅-xCsCl(x%=0%, 1%, 2%, 3%, 4%, mass fraction) glass prepared by salt bath cooling has a typical amorphous structure and good infrared transmittance. After adding CsCl into Ge₂₀Sb₁₀Se₆₅Te₅ glass, the long-wave cut-off wavelength of the glass has no obvious change, but the average linear expansion coefficient increases obviously. With the increase of CsCl content, the density, micro Vickers hardness, initial crystallization temperature, crystallization peak temperature, yield point and softening point of the glass gradually decrease, and the thermal stability of the glass decreases. With the increase of CsCl content, the content of Sb—Se bond in glass decreases, and the packing degree of the glass structure decreases, which is also the reason for the decrease of the glass density and micro Vickers hardness.

Key words: chalcogenide glass, CsCl, cooling method, infrared transmittance, thermal stability, Raman spectra

CLC Number:

TN213
TQ171

ZHANG Baodong, XU Junfeng, ZHAO Hua, ZU Chengkui, LIU Yonghua, ZHANG Yiyi, PAN Feng, ZHOU Peng. Effect of CsCl on Structure and Properties of Ge₂₀Sb₁₀Se₆₅Te₅ Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1318-1324.

References

[1] 戴世勋, 陈惠广, 李茂忠, 等. 硫系玻璃及其在红外光学系统中的应用[J]. 红外与激光工程, 2012, 41(4): 847-852.
DAI S X, CHEN H G, LI M Z, et al. Chalcogenide glasses and their infrared optical applications[J]. Infrared and Laser Engineering, 2012, 41(4): 847-852 (in Chinese).
[2] 常芳娥, 朱仲飞, 许军锋, 等. 冷却方式对硫系玻璃性能的影响[J]. 功能材料, 2015, 46(17): 17092-17096.
CHANG F E, ZHU Z F, XU J F, et al. Influence of cooling methods on the properties of chalcogenide glass[J]. Journal of Functional Materials, 2015, 46(17): 17092-17096 (in Chinese).
[3] 赵华, 金扬利, 祖成奎, 等. 温度自适应红外热成像系统用硫系玻璃表面镀膜的研究进展[J]. 材料导报, 2017, 31(增刊2): 72-76.
ZHAO H, JIN Y L, ZU C K, et al. Research progress of chalcogenide glass surface coating for temperature adaptive infrared thermal imaging system[J]. Materials Reports, 2017, 31(supplement 2): 72-76 (in Chinese).
[4] MASSELIN P, LE COQ D, CALVEZ L, et al. CsCl effect on the optical properties of the 80GeS₂-20Ga₂S₃ base glass[J]. Applied Physics A, 2012, 106(3): 697-702.
[5] ZHAO X H, LONG N B, SUN X, et al. Relationship between composition, crystallization, and phase separation behavior of GeS₂-Sb₂S₃-CsCl chalcogenide glasses[J]. Infrared Physics & Technology, 2019, 102: 102978.
[6] 张花, 聂秋华, 戴世勋, 等. CsCl对GeS₂-Sb₂S₃硫系玻璃光学及析晶特性的影响[J]. 硅酸盐学报, 2009, 37(1): 98-102.
ZHANG H, NIE Q H, DAI S X, et al. Effect of CsCl on optical and crystallization properties of GeS₂-Sb₂S₃ chalcogenide glasses[J]. Journal of the Chinese Ceramic Society, 2009, 37(1): 98-102 (in Chinese).
[7] 沈祥, 聂秋华, 徐铁峰, 等. GeSe₂-Sb₂Se₃-CsCl玻璃的光学性质与析晶动力学研究[J]. 物理学报, 2010, 59(3): 2045-2050.
SHEN X, NIE Q H, XU T F, et al. Optical properties and crystallization of GeSe₂-Sb₂Se₃-CsCl glasses[J]. Acta Physica Sinica, 2010, 59(3): 2045-2050 (in Chinese).
[8] 魏文猴. Ge-Sb-Se硫系玻璃的制备、结构及性能研究[D]. 重庆: 重庆大学, 2014.
WEI W H. Preparation, structure and properties of Ge-Sb-Se chalcogenide glass[D]. Chongqing: Chongqing University, 2014 (in Chinese).
[9] YAN J W, ZHOU T F, MASUDA J, et al. Modeling high-temperature glass molding process by coupling heat transfer and viscous deformation analysis[J]. Precision Engineering, 2009, 33(2): 150-159.
[10] 许军锋, 郑超, 杨伟, 等. Ge-Se-Sb 玻璃的热膨胀分析[J]. 西安工业大学学报, 2016, 36(10): 816-821.
XU J F, ZHENG C, YANG W, et al. Analysis of thermal expansion of Ge-Se-Sb chalcogenide glass[J]. Journal of Xi'an Technological University, 2016, 36(10): 816-821 (in Chinese).
[11] 许思维, 王丽, 沈祥. Ge_xSb₂₀Se_80-x玻璃的拉曼光谱和X射线光电子能谱[J]. 物理学报, 2015, 64(22): 121-127.
XU S W, WANG L, SHEN X. Raman scattering and X-ray photoelectron spectra of Ge_xSb₂₀Se_80-x glasses[J]. Acta Physica Sinica, 2015, 64(22): 121-127 (in Chinese).
[12] YIN H W, LI L, LIU Y Y, et al. Impact of tellurium on glass transition and crystallization in the Ge-Se-Te-Bi system[J]. Ceramics International, 2017, 43(4): 3556-3561.
[13] 罗宝华. Ge-Sb-Se硫系拉锥光纤制备及其非线性特性研究[D]. 宁波: 宁波大学, 2017.
LUO B H. Study on preparation and nonlinear properties of Ge-Sb-Se chalcogenide glass fiber taper[D]. Ningbo: Ningbo University, 2017 (in Chinese).
[14] 甘渝林, 王丽, 苏雪琼, 等. 用拉曼光谱测量GeSbSe玻璃的热导率[J]. 物理学报, 2014, 63(13): 310-315.
GAN Y L, WANG L, SU X Q, et al. Thermal conductivity measurement on GeSbSe glasses: Raman scattering spectra method[J]. Acta Physica Sinica, 2014, 63(13): 310-315 (in Chinese).
[15] 杨振. 掺铒硫系玻璃的光谱特性和稀土离子的局域环境研究[D]. 宁波: 宁波大学, 2019.
YANG Z. Study on spectral characteristics of erbium-doped chalcogenide glasses and local environment of rare earth ions[D]. Ningbo: Ningbo University, 2019 (in Chinese).

Effect of CsCl on Structure and Properties of Ge₂₀Sb₁₀Se₆₅Te₅ Glass

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHOU Peng, LIU Yonghua, ZHAO Hua, ZHANG Jiaying. Research Progress of Single Point Diamond Turning Technology for Chalcogenide Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1237-1245.
[2]	GUO Wei, PANG Laixue, WANG Wenchao, ZHANG Jiali, WANG Hua, BAI Shuxia. New Method and Effect Verification for Synthesizing Sodalite from Fly Ash Using Solvent-Free Method [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 584-592.
[3]	XU Minghao, HUA Kaihui, ZENG Qun, DI Bo, ZHENG Yu, WANG Hongxiang, ZHANG Guoxiang. Research Progress of Barium Titanate and Potassium Sodium Niobate Lead-Free Piezoelectric Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 649-658.
[4]	XUE Xingyong, HAN Yaocong, SU Qiaoqiao, XU Mengxue, CUI Xuemin. Mechanical Properties and Microstructure of Copper Slag-Based Phosphate Cementitious Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(5): 1750-1757.
[5]	LIU Hongjun, LI Chengkang, ZHOU Gangjie, CHEN Jinjin, LIN Changgui. Fabrication and Properties of Infrared Gradient Refractive Index GeS₂-In₂S₃-CsCl Chalcogenide Glass-Ceramics [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(11): 4131-4135.
[6]	LI Runfeng, LIU Yanjun, TU Yubo, WANG Linjun, WEN Xiaoqing, REN Lei. Thermal Properties of Graphene Enhanced Composite Phase Change Materials for Energy Storage [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(7): 2542-2548.
[7]	ZHAO Hua, ZHANG Huihui, ZU Chengkui, LIU Yonghua, ZHOU Peng, ZHANG Baodong, PAN Feng, HE Kun, HAN Bin. Research Progress on Preparation Technology of Long Wave Infrared Chalcogenide Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3719-3732.
[8]	GUO Yongchang, LI Can, FENG Shaowei, TAO Haizheng, WANG Hui, LI Jianqiang. Exploration of Chalcogenide Glass Fiber Preparation Method Based on Pulse Injection Technology [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3756-3760.
[9]	MA Cheng, YANG Anping, LI Lei, CHEN Qian, TIAN Kangzhen, LIU Zijun, SHEN Xiang, YANG Zhiyong. Preparation of As₂Se₃ Chalcogenide Glasses by Powder Hot Pressing Method [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3761-3767.
[10]	LI Xiuying, TAO Xinyue, XIAO Zhuohao, HE Yifeng, LI Chaoyuan, XIA Ying, KONG Lingbing. Preparation and Characterization of High Stability SrF₂-Na₂O-Fe₂O₃-P₂O₅ System Fluorphosphate Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(10): 3699-3707.
[11]	LIU Qian, DENG Lei, GAO Yulei, QI Yanyong. Effects of Cooling Methods on Clinker Mineral and C₃S Crystal Form [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(9): 2877-2883.
[12]	ZHANG Baodong, XU Junfeng, CHANG Fang'e. Preparation of Ge₂₀Sb₁₀Se₆₅Te₅ Chalcogenide Glass and Impurity Removal Mechanism of Ti Wire [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(9): 3145-3151.
[13]	XU Siwei, YANG Xiaoning, SHEN Xiang. Effect of Chemical Composition of Ge_xAs₂₀Se_80-x Glass on Structure and Physical Properties [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(7): 2368-2373.
[14]	ZHOU Peng, ZHAO Hua, ZU Chengkui, TAO Haizheng, LIU Yonghua, ZHANG Rui, CHEN Wei. Structural Origin of Change Rate in Viscosity for Several Chalcogenide Glasses [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1692-1697.
[15]	SHANG Ke, WANG Junsheng, ZHAO Bi, WU Yingjie, LIN Guide, ZHAO Jing, JIN Xing, LIU Dan. High-Solid Potassium Polysilicate Based Fire-Resistant Gel and Its Application in Composite Fireproof Glass [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(4): 1344-1351.