Effect of Fe2O3 on Phase Structure and Chemical Stability of  Cerium-Containing Perovskite Glass-Ceramics

Abstract

Abstract: In this paper, based on the typical SiO₂-B₂O₃-CaO-Na₂O-TiO₂ borosilicate glass, the cerium-containing perovskite glass-ceramic waste form was prepared by heat treatment crystallization method. The effect of different Fe₂O₃ content on the phase structure and chemical stability of the waste form was studied by DSC, XRD, FTIR, SEM-EDS and ICP. The results show that with the addition of Fe₂O₃, the diffraction peak intensity of CeO₂ crystal gradually decreases, the uniform of perovskite (CaTiO₃) grain distribution shows a trend of increasing first and then decreasing, and the normalized leaching rates of all elements show a trend of decreasing first and then increasing. When the content of Fe₂O₃ is 6% (mass fraction), the CeO₂ crystal disappears, the distribution of grains is the most uniform, and the normalized leaching rate of elements is the lowest. After 28 d, the normalized leaching rates (g·m^-2·d^-1) of elements in all samples are lower than the order of magnitude of 10^-3, indicating that the prepared glass-ceramic waste form has excellent chemical stability. The findings of this research offer theoretical support and experimental guidance for the study of perovskite glass-ceramics solidified high-level liquid waste.

Key words: Fe₂O₃, perovskite, cerium oxide, glass-ceramics, phase structure, chemical stability

CLC Number:

TQ171

PU Boyang, LIAO Qilong, WANG Fu, GU Yuxin, XU Youli, ZHU Hanzhen. Effect of Fe₂O₃ on Phase Structure and Chemical Stability of Cerium-Containing Perovskite Glass-Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1308-1317.

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Effect of Fe₂O₃ on Phase Structure and Chemical Stability of Cerium-Containing Perovskite Glass-Ceramics

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