Effect of Co-Existence of FeS and TiO2 on Solidification and Migration of Ti and Mineral Composition in Cement Clinker

Abstract

Abstract: To investigate the effect of co-existence of FeS and TiO₂ on the solidification and migration of Ti and mineral composition in cement clinker, the content and distribution of Ti in cement clinker and the mineral composition of clinker were measured by inductively coupled plasma emission spectrum (ICP-OES), energy dispersive spectrum (EDS), X-ray diffraction (XRD) and Rietveld full spectrum fitting. The existence forms of S and Ti in cement clinker were investigated by X-ray photoelectron spectroscopy (XPS), structural difference factor D and Hume-Rothery empirical formula. The results show that the incorporation of FeS has little influence on the curing capacity of cement clinker to solidify Ti, but it makes Ti migrate from intermediate phase to silicate phase. With the increase of FeS content, the content of Ti in C₂S increases by 46.9%. The incorporation of FeS promotes the formation of α-C₂S, thus enhancing the curing ability of silicate phase to solidify Ti. Meanwhile, with the increase of FeS content, the increase of Fe²⁺/Fe³⁺ mole ratio and the generation of CaSO₄ in clinker are the main reasons for the decrease of C₃S and C₄AF content and the increase of C₂S and C₃A content.

Key words: cement clinker, FeS, Ti, solidification, migration, mineral composition

CLC Number:

TQ172

FENG Qingge, LIANG Siliang, YANG Yi, BAI Xiukui, WANG Dongbo, ZHAO Zhengshu, HUANG Lilin. Effect of Co-Existence of FeS and TiO₂ on Solidification and Migration of Ti and Mineral Composition in Cement Clinker[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1453-1461.

References

[1] BUCCHI R. Features on the role of minor compounds in cement clinker. Part I[J]. World Cem Techlol, 1981, 12(6): 210-231.
[2] KOLOVOS K, LOUTSI P, TSIVILIS S, et al. The effect of foreign ions on the reactivity of the CaO-SiO₂-Al₂O₃-Fe₂O₃ system: part I. Anions[J]. Cement and Concrete Research, 2001, 31(3): 425-429.
[3] 张巨松,张添华,郑万荣,等.氧化钛对硅酸二钙形成的影响[J].沈阳建筑大学学报(自然科学版),2006,22(3):423-427.
ZHANG J S, ZHANG T H, ZHENG W R, et al. The influence of titania on bicalcium silicate formation[J]. Journal of Shenyang Jianzhu University (Natural Science), 2006, 22(3): 423-427 (in Chinese).
[4] BUCCHI R. Effect on reactivity of raw mix of properties and preparation of raw material[M]. Beijing: Building Industry Press of China, 1980: 3-46.
[5] VOLKONSKII B V, MAKASHEV S D, SHTEJERT N P. Effect of phosphorus, titanium, manganese and chromium compounds on the clinkering processes and the quality of cement [J]. Tsement, 1974, 6: 17-19.
[6] SHANG D C, WANG M G, XIA Z S, et al. Incorporation mechanism of titanium in Portland cement clinker and its effects on hydration properties[J]. Construction and Building Materials, 2017, 146: 344-349.
[7] LI X R, XU W L, WANG S P, et al. Effect of SO₃ and MgO on Portland cement clinker: formation of clinker phases and alite polymorphism[J]. Construction and Building Materials, 2014, 58: 182-192.
[8] 陈友德,程亮,郑德喜,等.硫对水泥熟料煅烧的影响(上)[J].水泥技术,2016(5):23-27.
CHEN Y D, CHENG L, ZHENG D X, et al. Effect of sulfur on the sintering of cement clinker (Ⅰ)[J]. Cement Technology, 2016(5): 23-27 (in Chinese).
[9] 陈友德,程亮,郑德喜,等.硫对水泥熟料煅烧的影响(下)[J].水泥技术,2016(6):24-28.
CHEN Y D, CHENG L, ZHENG D X, et al. Effect of sulfur on the sintering of cement clinker (Ⅱ)[J]. Cement Technology, 2016(6): 24-28 (in Chinese).
[10] 黄黎明,杨正宏,宋文娟,等.2CaSO₄·K₂SO₄复盐对硅酸盐水泥熟料烧成及水化的影响[J].硅酸盐学报,2017,45(11):1629-1634.
HUANG L M, YANG Z H, SONG W J, et al. Effect of 2CaSO₄·K₂SO₄ double salt on sintering performance and hydration of Portland cement clinker[J]. Journal of the Chinese Ceramic Society, 2017, 45(11): 1629-1634 (in Chinese).
[11] 宋文娟,曲生华,黄黎明,等.原生硫酸盐对水泥熟料矿物形成的影响[J].新型建筑材料,2018,45(5):79-83.
SONG W J, QU S H, HUANG L M, et al. The influence of original sulfate on mineral formation of cement clinker[J]. New Building Materials, 2018, 45(5): 79-83 (in Chinese).
[12] LUAN J D, LI R D, ZHANG Z H, et al. Influence of chlorine, sulfur and phosphorus on the volatilization behavior of heavy metals during sewage sludge thermal treatment[J]. Waste Management & Research, 2013, 31(10): 1012-1018.
[13] ZHANG B, BOGUSH A, WEI J X, et al. Influence of sulfur on the fate of heavy metals during clinkerization[J]. Construction and Building Materials, 2018, 182: 144-155.
[14] ZHANG B, WEI J X, ZENG Z X, et al. Effects of sulfur on the solidification of cadmium during clinkerization[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(8): 10645-10653.
[15] LIU J Y, LIU C, SUN G, et al. Thermodynamic behaviors of Cu in interaction with chlorine, sulfur, phosphorus and minerals during sewage sludge co-incineration[J]. Chinese Journal of Chemical Engineering, 2018, 26(5): 1160-1170.
[16] COOMBS P G, MUNIR Z A. The mechanism of oxidation of ferrous sulfide (FeS) powders in the range of 648 K to 923 K[J]. Metallurgical Transactions B, 1989, 20(5): 661-670.
[17] KOLOVOS K, TSIVILIS S, KAKALI G. SEM examination of clinkers containing foreign elements[J]. Cement and Concrete Composites, 2005, 27(2): 163-170.
[18] 沈威,黄文熙,闵盘荣.水泥工艺学[M].北京:中国建筑工业出版社,1986.
SHEN W, HUANG W X, MIN P R. Cement technology[M]. Beijing: China Building Industry Press, 1986 (in Chinese).
[19] 张联盟,黄学辉,宋晓岚.材料科学基础[M].2版.武汉:武汉理工大学出版社,2008.
ZHANG L M, HUANG X H, SONG X F. Fundamentals of materials science[M]. Version 2. Wuhan: Wuhan University of Technology Press, 2008 (in Chinese).
[20] 张文生,任雪红,欧阳世翕.离子固溶对硅酸三钙结构及性能影响的研究进展[J].硅酸盐学报,2011,39(10):1666-1672.
ZHANG W S, REN X H, OUYANG S X. Development on ion substitution effect on the crystal structure and properties of tricalcium silicate[J]. Journal of the Chinese Ceramic Society, 2011, 39(10): 1666-1672 (in Chinese).
[21] 商得辰.重金属离子在水泥熟料中的固化行为及作用机理研究[D].武汉:武汉理工大学,2017.
SHANG D C. Study on the solidification behavior and incorporation mechanism of heavy metal ions in cement clinker[D]. Wuhan: Wuhan University of Technology, 2017 (in Chinese).
[22] 黄可龙.无机化学[M].北京:科学出版社,2007.
HUANG K L. Inorganic chemistry[M]. Beijing: Science Press, 2007 (in Chinese).
[23] 朱晓燕,郭随华,陈益民,等.还原气氛对水泥熟料矿物组成及显微结构的影响[J].水泥,2006(11):1-3.
ZHU X Y, GUO S H, CHEN Y M, et al. Effect of reducing atmosphere on composition and microstructure of cement clinker[J]. Cement, 2006(11): 1-3 (in Chinese).
[24] 建筑材料科学研究院.水泥岩相检验[M].北京:中国建筑工业出版社,1975.
Research Institute of Building Materials Science. Cement lithofacies inspection[M]. Beijing: China Building Industry Press, 1975 (in Chinese).

Effect of Co-Existence of FeS and TiO₂ on Solidification and Migration of Ti and Mineral Composition in Cement Clinker

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHANG Chao, DENG Zhicong, MA Lei, LIU Chao, CHEN Yuning, WANG Zhibin, JIA Zijian, WANG Xianggang, JIA Lutao, CHEN Chun, SUN Zhengming, ZHANG Yamei. Research Progress and Application of 3D Printing Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1769-1795.
[2]	ZHANG Yi, ZHU Yanmei, REN Qiang, JIANG Zhengwu. Progress on 3D Printing Construction Technology and Its Cement-Based Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1796-1807.
[3]	LIU Junli, REN Jie, TRAN Phuong Jonathan. A Review of Recent Research Progress of 3D-Printed Concrete in Australia [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1808-1813.
[4]	WANG Li, LI Danli, YE Kehan, GUAN Jingyuan, FENG Duo. Quantification, Optimization and Standardization of 3D Printability of Cementitious Composites [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1814-1820.
[5]	JIAO Zekun, WANG Dongmin, WANG Qibao, HUANG Tianyong, WANG Jixiang, LI Linkun. Influencing Factors and Testing Methods of Printability of 3D Printing Concrete Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1821-1831.
[6]	SUN Kaili, WU Xiangqiang, LIN Xiqiang, LI Guoyou, LI Xinjian, SUN Zhipeng. Research Progress on Concrete Materials for 3D Printing and 3D Printing Formwork Technology [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1832-1843.
[7]	WANG Yuling, WANG Chunfu, ZHANG Feiyan. Review on Performance Requirements and Related Admixtures of 3D Printed Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1844-1854.
[8]	JIN Yuan, XU Jiabin, SUN Dengtian, CHEN Mingxu, HUANG Yongbo, LU Lingchao, CHENG Xin. Effect of Nano-Silica on Structural Deformation, Rheological and Mechanical Properties of 3D Printed White Portland Cement-Based Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1855-1862.
[9]	XU Jiabin, JIN Yuan, ZHAO Zhihui, CHEN Mingxu, LU Lingchao, CHENG Xin. Effect of Iron Oxide Red Pigment on Rheological Property and Printability of 3D Printed White Portland Cement-Based Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1863-1869.
[10]	ZHANG Chao, DENG Zhicong, WANG Zhibin, HOU Zeyu, JIA Zijian, WANG Xianggang, JIA Lutao, CHEN Chun, SUN Zhengming, ZHANG Yamei, PAN Jinlong. Effects of Fibers on Printing Performance and Mechanical Properties of 3D Printing Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1870-1878.
[11]	CAO Qianfei, CUI Dong, SHI Xiaohan, WAN Yi, ZUO Xiaobao, LAI Jianzhong. Effect of Humidity Evolution on Microstructure and Mechanical Properties of Alternate 3D Printing Specimens [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1879-1888.
[12]	XIAO Bofeng, LI Gu, ZHANG Guanghu. Effect of Alkali-Resistant Glass Fiber Content on Performance of 3D Printed Mortar [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1889-1894.
[13]	LIU Xiongfei, LI Qi, WANG Li, WANG Nan. Bonding Behavior of Spray-Based 3D Printing Magnesium Phosphate Cement and Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1895-1904.
[14]	LIU Xiaopeng, FENG Jingjing, LIU Zhongqiu, ZHOU Jing. Discussion on Statics Numerical Simulation of 3D Printed Concrete Hollow Gravity Dam [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1905-1910.
[15]	XIE Xiaojie, WANG Shen. Effect of Nano-Alumina on Rheological Property, Hydration and Hardening Strength of Portland Cement Paste [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1911-1917.