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BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2025, Vol. 44 ›› Issue (5): 1824-1833.DOI: 10.16552/j.cnki.issn1001-1625.2024.1323

• Solid Waste and Eco-Materials • Previous Articles     Next Articles

Preparation and Performance of Ultrafine and High Active Mineral Admixture by Multiple Solid Wastes Synergy

MA Shaolin1, MING Yang2, LI Wenjun1, REN Hao2, LIU Yongdao3, TIAN Wei4, ZHANG Guozhi4, CHEN Feixiang4, DOU Guangyuan5, FAN Zhihong6   

  1. 1. China Railway Tunnel Group Special High-Tech Co., Ltd., Shanghai 200120, China;
    2. Guangxi Key Laboratory of Green Building Materials and Construction, Guilin University of Technology, Guilin 541004, China;
    3. Guangxi Zhongjian Western Construction Co., Ltd., Nanning 530000, China;
    4. CCCC Second Harbour Engineering Co., Ltd., Wuhan 430040, China;
    5. Guangxi Beigang Construction and Development Co., Ltd., Nanning 530000, China;
    6. China Communications Construction Fourth Harbour Engineering Research Institute Co., Ltd., Guangzhou 510230, China
  • Received:2024-11-05 Revised:2025-01-15 Published:2025-05-20

Abstract: An green ultrafine and high active mineral admixture was developed through the synergistic utilization of various industrial solid wastes. This study systematically investigated the effects of raw material ratios and milling parameters on the performance of admixture, with hydration products and microstructural characteristics analyzed using XRD, TGA, and SEM techniques. The results demonstrate that when water quenched manganese slag, steel slag, fly ash, and desulfurization gypsum are mixed in a mass ratio of 8:3:8:1 with 0.10% (mass fraction) of a milling aid and jointly ground to a specific surface area of 800 m2/kg, the admixture achieves a 7 d activity index of 97.4% and a 28 d activity index of 110.0%, along with a flowability ratio of 95.1%. In the early stage, the admixture minimizes strength loss through physical filling and the formation of calcium aluminate hydrates, while in the later stage, synergistic hydration and pozzolanic reactions enhance strength development. The research results are of great significance for realizing high value-added utilization of low active solid waste and sustainable development of building materials industry.

Key words: industrial solid waste, mineral admixture, ultrafine milling, activity index, hydration product, microstructure

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