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BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2022, Vol. 41 ›› Issue (7): 2564-2573.

• New Functional Materials • Previous Articles     Next Articles

High-Temperature Properties of Si/(Yb1-xYx)2Si2O7/LaMgAl11O19 Thermal/Environmental Barrier Coatings

MAO Chuanyong, DONG Shujuan, JIANG Jianing, DENG Longhui, CAO Xueqiang   

  1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China
  • Received:2022-03-02 Revised:2022-05-01 Online:2022-07-15 Published:2022-08-01

Abstract: Si/(Yb1-xYx)2Si2O7/LaMgAl11O19(x=0, 0.5) thermal/environmental barrier coatings (T/EBCs) were prepared by plasma sprayingmethod on the surface of SiC fiber reinforced SiC ceramic composites (SiCf/SiC-CMCs). The thermal cycle performance and water-oxygen corrosion resistance at 1 300 ℃ of T/EBCs systems with different components were investigated by means of SEM, EDS and XRD. And failure mechanisms of the thermal cycle and water-oxygen corrosion were further discussed. The results indicate that the thermal cycle life of Si/Yb2Si2O7/LMA coating system is 403 cycles and water-oxygen corrosion resistance is 50 h. The thermal cycle life of Si/YbYSi2O7/LMA system decreases to 277 cycles, while the water-oxygen corrosion resistance increases to 80 h. The larger thermal mismatch stress and the formation of Al-containing compounds or solid solutions between YbYSi2O7 and LMA are the main factors that reduce the thermal cycle life of Si/YbYSi2O7/LMA. The less oxide impurities in the YbYSi2O7-EBC layer reduce the probability of reaction with water to generate volatile substances, and improve the water-oxygen corrosion resistance of Si/YbYSi2O7/LMA.

Key words: SiCf/SiC-CMCs, thermal/environmental barrier coating, thermal barrier coating, environmental barrier coating, thermal cycle, high temperature water-oxygen corrosion, Yb2Si2O7, YbYSi2O7

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