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Table of Content

    15 July 2022, Volume 41 Issue 7
    Cement and Concrete
    Research Progress on Nucleating Agent for Cement-Based Materials
    QI Shuai, TIAN Qing, ZHANG Miao, QU Mengjiao, YAO Tianshuai, WANG Cheng
    2022, 41(7):  2223-2234. 
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    The boom of building industrialization requires the strength formation of concrete as soon as possible. Compared with steam curing or autoclaved maintenance, nucleating agent in cement-based materials can not only effectively promote the hydration and hardening process, but also help to modify the interface structure and improve the durability. Therefore, nucleating agent is widely used in practical engineering and has attracted great attention. This review offered a retrospection of research efforts on the nucleation mechanism of different nucleating agents, namely inorganic salt nucleating agents, organic matter nucleating agents, nanomaterial nucleating agents and compoundnucleating reagents. The thermodynamics and kinetics characteristics of nucleation behavior were analyzed in detail. Then the influences of temperature, dosage and particle size on the nucleation were discussed. Subsequently, the effect of nucleation on the properties of cement-based materials were summarized. Finally, the challenges of nucleating agent development and the possible direction of further research were proposed. The purpose of this study is to provide reference for the efficient utilization and in-depth study of nucleating agents.
    Effects of Different Measures on Performance of Cement Stabilized Macadam Mixture
    TIAN Xiaoge, YU Shui, LI Guangyao, MIN Xuefeng, REN Quan, YANG Fan
    2022, 41(7):  2235-2243. 
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    Through compressive rebound modulus tests, strength tests, shrinkage tests and durability tests, the improvement effects of four different measures, including vibration mixing technology, adding basalt fiber, adding expansion agent and increasing the amount of cement, on the performance of cement stabilized macadam mixture were studied. The effect degrees of different technical measures on the properties of cement stabilized macadam mixture were evaluated based on multivariate analysis of variance. The results show that these four measures have significant impact on the performance of cement stabilized macadam mixture. Increasing the amount of cement has the most significant effect on the improvement of its strength, compressive rebound modulus and durability, but the anti-shrinkage cracking performance is unfavorable. The addition of expansive agent and basalt fiber significantly improve the dry shrinkage performance of cement stabilized macadam mixture, and compared with the benchmark cement stabilized macadam mixture at the age of 31 d, the dry shrinkage coefficient is reduced by 57.7% and 18.8%, respectively.
    Effects of Calcium Sulphoaluminate Expansion Agent and Magnesia Expansion Agent on Properties of Styrene-Butadiene Copolymer Dispersion Modified Mortar
    WEI Kuo, LIU Sifeng
    2022, 41(7):  2244-2250. 
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    The effects of calcium sulphoaluminate expansive agent (CSA) and magnesium oxide expansive agent (MEA) on the workability, mechanical properties and shrinkage properties of styrene-butadiene copolymer dispersion modified mortar were studied at 20 ℃, relative humidity 90% (RH90%) and 60% (RH60%). The results show that the fluidity of styrene-butadiene copolymer dispersion modified mortar increases first and then decreases with the increase of the dosage of the two expansion agents. At 90%RH and RH60%, the mortar with CSA mass content of 6% and 10% has the highest flexural and compressive strength, respectively. CSA effectively reduces the drying shrinkage of mortar under two kinds of humidity. At 90%RH, 8%MEA improve the flexural and compressive strength of mortar, and also effectively compensate the drying shrinkage of mortar in later period. At RH60%, 8%MEA reduce the mortar flexural and compressive strength, and can not effectively compensate the dry shrinkage of mortar.
    Synthesis of Polycarboxylate Superplasticizer Based on Hydrophobic-Modified Polyoxyethylene Ether and Its Viscosity-Reducing Performance
    LI Shentong, YANG Yong, ZHOU Dongliang, HU Cong, LIU Jinzhi, ZHANG Zhiyong
    2022, 41(7):  2251-2257. 
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    Hydrophobic-modified polyoxyethylene ether macromonomers were prepared by alkaline ring opening reaction of butyl glycidyl ether at the ends of isoprenyl oxy poly (ethylene glycol) ether. Base on this, a series of hydrophobic-modified polycarboxylate superplasticizers were synthesized by the copolymerization of acrylic acid, maleic anhydride and hydrophobic-modified macromonomers. The effect of the adduct number (3, 5, 8) of butyl glycidyl ether on the dispersion and adsorption performance of modified polycarboxylate was studied.And the effect of modified polycarboxylate on the viscosity of cement pastes was investigated through cement mortar and concrete experiments. The results show the optimum adduct number is 3, the dispersion performance is not affected, and the adsorption performance increases by 21%. If the adduct number continues to grow, the dispersion performance gets worse while the adsorption performance is not improved markedly. The modified polycarboxylate reduces the viscosity of cement mortar by more than 30%, increases the flow velocity of cement mortar by 40%, shortens the V-funnel efflux time of cement mortar by 27% and the inverted slump tube efflux time of concrete by 34%, which unquestionably confirms that the hydrophobic-modified polycarboxylate can effectly reduce the viscosity of cement pastes.
    Effect of Initial Damage on Sulfate Attack Resistance of Shotcrete
    JIA Fei, YAN Wanghu, PAN Huimin, TANG Jianhua, WANG Xuanming, GAO Kun
    2022, 41(7):  2258-2267. 
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    In order to reveal the performance degradation law of shotcrete with initial damage under sulfate attack, the initial damage degree was defined according to the change of ultrasonic wave velocity. The initial damage of concrete specimens was prefabricated by pressure testing machine, and the initial damage presented five different gradients: 0.10, 0.15, 0.20, 0.25 and 0.30. The dry-wet cycle sulfate attack test was carried out on shotcrete, and the appearance, mass change rate and relative dynamic elastic modulus were used as evaluation indexes. The effect of initial damage on the sulfate attack resistance of shotcrete was systematically studied by means of micro-morphology analysis and chemical composition analysis. The mechanism of damage effect was discussed and the damage evolution model of initial damaged shotcrete under sulfate attack was established. The results show that with the extension of erosion time, the mass and relative dynamic elastic modulus of shotcrete specimens increase first and then decrease in the whole erosion process. When the initial damage degree is 0.10,the sulfate attack process has little effect on concrete, which can be basically ignored. After the initial damage exceeds 0.10, the deterioration speed of specimens under sulfate attack is accelerated. After 180 dry-wet cycles, compared with reference group, the mass of specimens with initial damage of 0.15, 0.20, 0.25, and 0.30 decreases by 2.9%, 3.4%, 4.0%, and 4.7%, respectively. The relative dynamic elastic modulus drops to 0.42, 0.34, 0.28, and 0.16, respectively. The mortar microcracks and aggregate displacement caused by the initial damage of prefabrication provide favorable conditions for the intrusion of sulfate. There is a small amount of erosion on the surface of the specimens with a damage degree of 0.10. And the internal microcracks of specimens are slightly more than reference group, but the erosion deterioration is not serious. The epidermis of specimens with a damage degree of 0.30 almost fall off. There are a large number of through cracks in the interior, which are wide and deep. Among the reaction products, the diffraction peak intensity of gypsum and ettringite crystal is the highest, and the erosion damage is the most serious. The erosion damage factor is defined in terms of relative dynamic elastic modulus changes. The established damage model curves are in good agreement with the test results, and the fitting correlation coefficients are all above 0.94. The model can better reflect the damage deterioration law of shotcrete with different initial damage.
    Bending Properties of Polyoxymethylene Fiber Airport Pavement Concrete under Different Strain Rates
    WANG Zhenhui, GUO Rongxin, YAN Yong, ZHANG Jiuchang, LI Lishan
    2022, 41(7):  2268-2274. 
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    The mechanical behavior of airport pavement concrete structure under different loads is greatly affected by strain rate. In order to study the effect of strain rate on the bending properties of polyoxymethylene fiber airport pavement concrete (PFAPC), the bending deflection, bending modulus, bending strength and toughness index of PFAPC under different strain rates (10-5~10-1 s-1) were analyzed by four-point bending test, and the microstructure of fracture fibers was observed and the failure mode of fibers under different strain rates was summarized. The test results show that the bending peak strength, ultimate bending deflection, and bending modulus of PFAPC increase with the increase of strain rate. Compared with the peak strength, the strain rate has little effect on the residual strength of PFAPC, but the overall trend is upward with the increase of strain rate. Compared with the ultimate bending deflection, the peak deflection fluctuates with the increase of strain rate. The bending modulus increases with the increase of strain rate. The polyoxymethylene fiber is mainly in the pull-out failure mode under the action of each strain rate. PFAPC absorbs a large amount of energy under the impact of vehicles and aircraft, showing a certain ductile failure characteristics, and a good bending toughness.
    Experimental Study on Uniaxial Compression Performance of High Strength Coral Concrete (HSCC)
    ZHANG Jiwang, HUANG Manfeng, SU Shican, YI Jin, QIN Qinglong, WANG Lei
    2022, 41(7):  2275-2282. 
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    Low strength and obvious defects in the aggregate lead to the difficulty of applying the coral concrete in high strength or special protective structures. The coral sand with small particle size gradation was used to completely replace coarse aggregate to prepare high strength coral concrete (HSCC). The basic mechanical properties, uniaxial compression properties and porosity of HSCC were systematically tested. The results show that the strength grade of HSCC prepared by optimizing the aggregate particle size and mix ratio is C105, and the ratio of axial compressive strength to cube compressive strength is between 0.86 and 0.94. The failure mode of HSCC without fiber is explosive failure, and the HSCC with 0.43% volume rate of polypropylene fiber (PPF) shows obvious ductile failure characteristics. After failure, it enters the turning point of residual strength at 20%~30% ultimate strength. The porosity of HSCC is about 4.7%~6.9%, and the dry apparent density is 2 230~2 310 kg/m3. There are few macroscopic pores on the surface, and it is found that the aggregate edge filling is good by scanning electron microscope.
    Meso-Numerical Simulation of Dynamic Compressive Performance and Failure Mode of Wet-Screened Concrete
    ZHANG Qingfang, HONG Hexuan, SHEN Lu
    2022, 41(7):  2283-2291. 
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    Wet-screened concrete is usually used to replace hydraulic fully graded concrete which is inconvenient to carry out physical test due to the large aggregate size. In order to study the influence of loading rate on the mechanical properties and failure modes of wet-screened concrete, the meso-numerical specimen of wet-screened two-graded concrete was established by using particle flow discrete element software PFC2D. The meso-parameters of mortar particles, coarse aggregate particles and the interface between mortar particles and coarse aggregate particles in the numerical specimen were calibrated according to the quasi-static uniaxial compression test data with strain rate of 10-5 s-1. Then dynamic loading with strain rates of 10-4 s-1, 10-3 s-1 and 10-2 s-1 was carried out, and numerical simulation and mechanism analysis of dynamic mechanical properties and failure modes were conducted. The results show that the shapes of stress-strain curves under different strain rates are similar, the peak stress increases by 7.3%~37.9% with the increase of strain rate, and the strain at the peak stress increases little. The failure mode of the specimen is in good agreement with the physical test phenomenon. With the increase of strain rate, the number of cracks continues to increase, and the cracks distribution tend to be uniform. The growth rate of the number of cracks is 4.2 times of the growth rate of peak stress. In addition, with the increase of strain rate, the non-uniformity of particle contact force in the numerical specimen decreases, which indicates that the increase of dynamic strength is related to the non-uniformity of stress in the concrete.
    Compressive Strength Test and Energy Characteristics Analysis of Alkali Slag Ceramsite Concrete at Different Ages
    YUAN Pu, ZHU Yisheng
    2022, 41(7):  2292-2298. 
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    Alkali slag ceramsite concrete made by coal gangue ceramsite and slag can realize the reuse of solid wastes such as coal gangue and slag. To investigate the influences of curing age and ceramsite content on compressive strength and energy characteristics of alkali slag ceramsite concrete, uniaxial compression tests were carried out for alkali slag ceramsite concrete under different curing ages (1 d, 3 d, 7 d, 14 d, and 28 d) and different ceramsite volume content (0%, 25%, 50%, 75%, and 100%). Test results show that stress-strain curves of concrete under different ages and ceramsite content all undergo four stages, including compaction stage, elastic deformation stage, crack propagation stage, and failure stage. Moreover, the addition of coal gangue ceramsite makes the concrete show a certain ductility characteristic. Both compressive strength and elastic modulus are positively related to curing age in an exponential function, and negatively related to ceramsite content in a quadratic function. With the increase of curing age, total energy and elastic energy increase, while dissipative energy decreases first and then increases. With the increase of ceramsite content, total energy and elastic energy decrease, while dissipative energy increases first and then deceases.
    Performance of Hybrid Fiber Reinforced High-Strength Concrete
    ZHAO Yaming, ZHANG Mingfei, ZHANG Zhen, LUO Yaofei
    2022, 41(7):  2299-2307. 
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    In order to clarify the effects mode of hybrid ratio of steel fiber and polyvinyl alcohol fiber on the performance of high-strength concrete, the effects on workability, flexural strength, shrinkage, cracking resistance, resistance to chloride ion erosion were comparatively evaluated by slump test, mechanical strength test, shrinkage test, crack resistance test and chloride ion erosion resistance test. The following conclusions are drawn from the study. Steel fibers and polyvinyl alcohol fibers have a detrimental effect on the workability of fresh mixes. The addition of mixed fibers does not have a greater improvement effect on the mechanical properties of high-strength concrete than the addition of a single fiber, but it significantly improves the cracking resistance of concrete, with a maximum cracking area inhibition of 95.8%. Meanwhile, the addition of hybrid fibers reduces the shrinkage and permeability of high-strength concrete by 27.7% and 66.5%, respectively, indicating that the durability performance of high-strength concrete can be significantly improved. The mechanism of effects of fiber-reinforced concrete was explored by scanning electron microscope test, which shows that the improvement of the internal structure of the matrix by blended fibers realizes the improvement of macroscopic properties of concrete. Finally, 0.75% (volume fraction) steel fiber and 0.25% (volume fraction) polyvinyl alcohol fiber are recommended as the optimum admixture.
    Solid Waste and Eco-Materials
    Research and Application Progress on Aluminum Dross Recycling and Harmless Treatment
    WEI Jie, LIU Zhanwei, YAN Hengwei, YANG Wanzhang, LI Mengnan, LIU Shuxin
    2022, 41(7):  2308-2320. 
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    Aluminum dross is a hazardous waste produced in aluminum smelting process. Aluminum nitride, fluoride and chloride in aluminum dross have the characteristics of easy leaching, which aggravates the pollution to the environment, and the utilization of aluminum dross resources has become an urgent problem to be solved. In this paper, the sources, components and hazards of different aluminum dross were described, and the mineralogical properties of aluminum dross studied by previous researchers were summarized. The harmless treatment and recovery of alumina, aluminum nitride, fluoride and chloride by pyrometallurgical/hydrometallurgical process were introduced. The author summarized the harmless treatment and recycling process of aluminum dross and put forward the conception of three steps to realize zero waste discharge of aluminum dross, namely, water washing pretreatment-hydrometallurgical leaching of aluminum resources-waste utilization. Finally, the future development direction of comprehensive utilization of aluminum dross was prospected.
    Effects of Air-Entraining Agent and Desert Sandon Properties of Concrete
    LYU Shenghui, Sawulet·BEKEY, Almas·YERBOLAT, QIN Sen
    2022, 41(7):  2321-2326. 
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    In order to investigate the effects of desert sand replacement rate and air-entraining agent dosage on C30 concrete, desert sand (six replacement rates) and air-entraining agent (five dosages) were mixed into concrete in quantitative combinations to determine their effects on the air content of fresh concrete, slump, gas content after 1 h and 28 d compressive strength. The test results show that desert sand has a certain inhibitory effect on the gas content of fresh air-entrained concrete, and the inhibition effect increases with the increase of desert sand replacement rate, but it has no obvious effected on the gas content of air-entrained concrete after 1 h. With the increase of air-entraining agent dosage and desert sand replacement rate, the slump and 28 d compressive strength of concrete both increase first and then decrease. The compressive strength reaches the maximum when the replacement rate of desert sand is 40% (mass fraction) and the dosage of air-entraining agent is 0.002% (mass fraction). Reasonable combination of air-entraining agent and desert sand into concrete can significantly improve the working performance and compressive strength of concrete.
    Effect of Fly Ash on PVA Fiber/Cementitious Matrix Interfacial Interactions and Tensile Properties of Composites
    YAO Zhigao, LIN Chang, CAI Shu, XU Shuying, PAN Lisha
    2022, 41(7):  2327-2336. 
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    The effects of fly ash content on matrix strength, the interfacial interactions between polyvinyl alcohol (PVA) fiber and cementitious matrix, and the tensile properties of strain-hardening cementitious composites (SHCC) with non-surface-modified PVA fibers were investigated. The results show that with the increase of fly ash content, the 28 d compressive strength of the matrix declines within the range of 18~93 MPa. The uniaxial tensile test results show that the effect of fly ash on SHCC at 20% (mass fraction, the same below) and 50% dosages is insignificant. With the fly ash dosage increasing to 67% and 80%, the multiple-microcracks and strain-hardening characteristics of SHCC tend to be enhanced, and the corresponding ultimate strain increases, up to 7.2%, and SHCC has a characteristic of light weight. The results of fiber pullout test display that the high content of fly ash not only reduces the chemical bond between PVA fibers and the matrix, but also weakens the interfacial friction, which effectively inhibits the premature rupture of PVA fibers during the pullout process, and enhances the ductility of SHCC with non-surface-modified PVA fibers.
    Influence of Fineness Change of Limestone Powder-Fly Ash on Hydration Kinetics of Cement-Based Cementitious Material System
    CHENG Gaoli, LI Xiaoguang, WANG Panqi, MA Ronggui
    2022, 41(7):  2337-2343. 
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    In order to analyze the influence of different fineness of limestone powder-fly ash on the hydration process and early mechanical properties of cement-based cementitious materials. In this study, isothermal calorimetry was used to determine the total heat release and heat release rate of composite binders with different fineness at 20 ℃. According to the hydration kinetic model proposed by Krstulovic-Dabic, the values of kinetic parameters for each stage of the hydration reaction were calculated. The results show that the increase fineness of limestone powder and fly ash will promote the crystal nucleation and crystal growth of the hydration products. At the same time, the increase of fineness will shorten the end time of hydration induction period and the time to reach the maximum exothermic rate, and accelerate the hydration reaction rate of cement. Limestone powder and fly ash refinement shorten the process time of phase boundary reaction. When the degree of hydration is higher, the reaction control mechanism in the cementitious material system changes. The compressive strength test shows that increasing the fineness can significantly improve the early strength of the mortar specimen, and the later strength remains stable.
    Preparation and Thermodynamic Analysis of Steel Slag-Coal Based Solid Waste Controllable Low-Strength Materials
    LU Mingyang, PANG Laixue, YANG Da, SONG Di, ZHANG Jiali, TIAN Xiaofeng, ZHANG Yiyang
    2022, 41(7):  2344-2351. 
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    Cement-free controllable low strength material (CLSM) was prepared by coal gangue (CG), steel slag (SS) and fly ash (FA) under the condition of NaOH, Na2SO4 synergistic alkali-activation. The microstructure and phase composition of CLSM were analyzed by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) technique. The results show that there is a linear relationship between the molar ratio of Ca/(Ca+Si) and 7 d, 28 d unconfined compressive strength ratio. When the molar ratio of Ca/(Ca+Si) is greater than 0.407, the unconfined compressive strength of CLSM curing for 7 d can reach more than 70% of that of 28 d, which shows the material has early strength feature. When the fly ash is below 40% (mass fraction), the CLSM performance (flow ability) meets the requirements of ACI specification. The different mass proportions of SS/FA change the phase composition of the reaction products in the CLSM system, and the dense chimeric structures of ettringite and calcium silicate hydrate (C-S-H) gel provide the microstructure ground for mechanical properties. Finally, based on the Gibbs free energy minimization method, the amount of two crystal types of hydrated calcium silicate in the hydration products is simulated.
    Effect of C-S-H Nanocrystalline Nucleus on Hydration Properties of Mineral Admixture Composite Cementitious Materials
    WANG Kun, LIU Fengdong, YANG Feihua, LYU Minwang, YANG Lu, WANG Fazhou
    2022, 41(7):  2352-2359. 
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    A high-volume replacement of mineral admixtures to cement usually causes low early strength, inducing a long construction period. In this study, the effects of C-S-H nanocrystalline nucleus on the hydration properties of cementitious materials mixed with high-volume mineral admixtures were studied. Through thermodynamic calculation, the mechanism of reduction of nucleation barrier for adding C-S-H nanocrystalline nucleus was explained. The ions dissolution and precipitation behavior were tested. The results show that the hydration depth of mineral admixtures mixed cementitious materials is low because the dissolution of Ca2+ is restricted, inducing the slow hydration of C3S. The dissolution-precipitation of silicate phases is greatly enhanced when the C-S-H nanocrystalline nucleus is added. Furthermore, the addition of C-S-H nanocrystalline nucleus promote the hydration activity of mineral admixtures mixed cementitious materials, reaching a similar hydration activity as pure cement. The results indicate that the C-S-H nanocrystalline nucleus significantly solve the insufficient hydration problem for a high-volume mineral admixtures replacement of cementitious materials.
    Optimization of Preparation Process Conditions for Sodium Ion Adsorbent Based on Box-Behnken Response Surface Methodology
    XIONG Mengxue, YANG Min, CHEN Qianlin
    2022, 41(7):  2360-2367. 
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    Red mud contains a certain amount of sodium ion, which has a great impact on red mud’s application performance. In this study, an adsorbent was prepared to separate sodium ion, and the Box-Behnken program in the response surface methodology of the Design-Expert software was used to optimize the preparation conditions of the adsorbent. The appropriate range of three factors including calcination temperature, calcination time and Al content was determined by single factor experiment with sodium ion removal rate as the evaluation index. On this basis, though the Box-Behnken center combined test, the response surface analysis was carried out with the sodium ion removal rate as the response value, and the preparation process conditions were optimized. The result shows that the optimal preparation conditions are calcination temperature of 400 ℃, calcination time of 5 h, and Al content of 40%. Under these conditions, the sodium ion removal rate is 95.30%, which provides a method for the separation of sodium ions in red mud.
    Experiment and Mechanism Analysis of Dealkalization of Red Mud by Calcium-Based Hydrothermal Leaching
    WANG Tao, LI Wang, ZHU Xiaobo, YAN Xudong
    2022, 41(7):  2368-2375. 
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    Red mud is a solid waste residue produced in the process of alumina production, which has caused serious environmental pollution, but due to strong alkalinity, it is difficult to utilize resources. In this paper, hydrothermal leaching of red mud with Ca(OH)2 as the dealkalization agent was carried out. The effects of the Ca(OH)2 dosage, reaction temperature and liquid-solid ratio on the dealkalization rate were investigated. Meanwhile, the mechanim and leaching kinetics of the dealkalization process of red mud were analyzed. The results show that the dealkalization rate of red mud reaches 96.3% under the conditions of the Ca(OH)2 dosage of 60% (mass fraction), reaction temperature of 250 ℃, liquid-solid ratio of 8 mL/g. Ca(OH)2 effectively removes free alkali and structural alkali from red mud. The cancrinite and katoite in the red mud are decomposed. New phase andradite(hydrated) in the dealkalized residue is the main diffraction peak. Meanwhile, the diffraction peak of hematite is obviously weakened and the diffraction of calcite is enhanced. The leaching process is controlled by the key steps of diffusion in the solid film. The linear correlation coefficients are all greater than 0.97, the characteristic constant is n<1, and the apparent activation energy is 5.20 kJ/mol.
    Effect of Steel Slag Powder on Hydration Process of Calcium Sulfoaluminate Cement and Thermodynamic Modelling
    LIAO Yishun, HUANG Weifeng, LI Hao, WANG Sichun
    2022, 41(7):  2376-2383. 
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    The influence of variable steel slag powder content on the hydration behavior of calcim sulfoaluminate cement was investigated through the setting time test, compressive strength test and electrical resistivity test, combined with hydration products analysis and thermodynamic modelling. The results show that with the increase of the mass content of steel slag powder, the initial setting time shows a trend of first extending and then shortening, and reaches the maximum when the content of steel slag is 20%. In 28 d, the compressive strength of cement paste with steel slag powder is lower than the hardened paste without steel slag powder, but at the age of 60 d and 90 d, the compressive strength of cement paste with 40% steel slag powder content is higher than the sample without steel slag powder. The resistivity of steel slag powder and calcium sulfoaluminate cement composite paste increases with the increase of steel slag powder content in the initial hydration stage, and decreases with the increase of steel slag powder content in the late hydration stage (after about 3 h). In the age of 1 d, the hydration reaction of steel slag powder occurs in the sample with 40% steel slag powder content, which makes the hydration rate of cement paste reach the maximum in the deceleration period. According to thermodynamic modelling results, in the sample mixes with 40% steel slag powder, C2S began to react after 10 h, forming C2ASH8 after 168 h. When the steel slag content is more than 15%, with the increase of the steel slag powder content, the production of ettringite and AH3 gradually decreases, and the production of C2ASH8 gradually increases.
    Mechanical Properties and Interface Characteristics of Iron Tailings Sand-Based Epoxy Resin Permeable Material
    CAO Ganghao, JIAN Shouwei, WEI Bo, LI Baodong, ZHAO Jinpeng
    2022, 41(7):  2384-2392. 
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    Manufacturing of permeable materials via solid waste is a potential direction in the development of sponge cities. However, the poor mechanical properties become one of the key difficulties for the application of permeable materials. In this study, polymer permeable material combined with iron tailings sand as aggregate and epoxy resin as cementitious material was designed. The effects of epoxy resin content on the mechanical properties and water permeability of permeable materials were investigated. Additionally, the effects of different organic-inorganic admixtures such as nano-SiO2, TiO2, Al2O3 and silane coupling agent KH-560 on the mechanical properties were discussed. The results show that when the mass fraction of epoxy resin is 6%, a high performance permeable material is obtained, the compressive strength, flexural strength and water permeability rates are 17.5 MPa, 5.3 MPa and 1.12 mm/s, respectively. When the addition amount of nano-SiO2, TiO2, Al2O3 is 3%, 4%, 4% (mass fraction) of epoxy resin, the improvement of the compressive strength is 33.1%, 30.5%, 28.6%, respectively. The reason is concluded that nanoparticles absorb part of the energy in the resin matrix during the compression of the permeable material, inhibiting or eliminating the diffusion of microcracks in the resin. When the addition amount of the silane coupling agent KH-560 is 0.9% of epoxy resin, the compressive strength increased by 36.5%.SEM and FTIR analysis show that silane coupling agent KH-560 has a significant effect on improving the interface between iron tailings sand and epoxy resins. This research provides significant guidance to development of high-performance solid waste-based permeable materials.
    Experimental Study on Influence of Nano-SiO2 on Properties of MgO-Activated Slag Material
    FANG Hu, CHEN Peiyuan, ZHANG Liheng
    2022, 41(7):  2393-2399. 
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    In order to improve the mechanical properties of MgO-activated slag material (MASM), nano-SiO2 (NS) was used to promote the strength development of MASM. The effects of NS dosage on the setting time, compressive strength, hydration process, hydration products and microstructure of MASM were investigated and the mechanism of action of NS was revealed. Experimental results show that the addition of NS changes the performance of MASM obviously. A higher dosage of NS results in a shorter setting time and a lower flowability of MASM. The larger the NS content is, the faster the slag hydration is, the earlier the main hydration peak appears, and the higher the peak value is. The addition of NS not only promotes the reaction degree of MgO and the production of C-(A)-S-H gel products, but also contributes to more densified microstructure of MASM. The compressive strengths of MASM increases by 7.12%~33.37% (3 d), 12.44%~26.29% (7 d) and 12.49%~31.09% (28 d) by adding 1%~2% (mass fraction) NS.
    Modification and Mechanism of Phosphorus Building Gypsum Using Admixtures
    LI Long, LI Beixing, CHEN Pengbo, YIN Shi
    2022, 41(7):  2400-2410. 
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    Preparation of phosphorus building gypsum (PBG) products is an important way for the resource utilization of phosphogypsum, and the appropriate modification technology is the key to ensure the industrialization of PBG products. PBG was modified by three water reducers, three retarders, two binders and two water retaining agents respectively, the adaptability of admixture varieties to PBG was discussed, and the influence rules of admixture content on the properties of PBG were studied. Moreover, the modification mechanism of the optimized admixture on PBG was analyzed by scanning electron microscope. The results indicate that the polycarboxylate water reducer (PC), vinyl acetate ethylene copolymer redispersible polymer powder binder (VAE), hydroxypropyl methyl cellulose water retaining agent (HPMC) and bone glue retarder (BG) have good adaptability to PBG, and improve the dry strength, bond strength, water retention and prolong the setting time of PBG, respectively. PC and VAE improve the compactness of the internal crystal structure in the hardened PBG, while BG and HPMC make the structure of the hardened PBG more loose.
    Effect of Retarder on Properties of β-Hemihydrate Phosphogypsum-Ordinary Portland Cement Composite System and Its Mechanism
    MA Baoguo, WU Lei, CHEN Pian, QI Huahui, JIN Zihao, YANG Qi
    2022, 41(7):  2411-2420. 
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    β-hemihydrate phosphogypsum (β-HPG) has poor mechanical properties and fast setting and hardening. Previous studies have shown that replacing part of β-HPG by ordinary Portland cement (OPC) can improve the mechanical properties of the composite system, but the regulation and mechanism on the workability of this composite system are still unclear. The effects of three retarders on the properties of β-HPG-OPC composite system were investigated in this paper. The macro-performance was characterized by setting time and compressive strength test. The mechanism was discussed by hydrating exothermic curve, conductivity curve, XRD pattern and SEM image. The results show that sodium tripolyphosphate (STPP) has no retarding effect on the composite system. Protein SC retarder (SC) and citric acid (CA) have excellent retarding effect on the composite system, among which SC has better retarding effect on the initial setting time, and CA has better delaying effect on the final setting time. The incorporation of CA changes the morphology of dihydrate gypsum, resulting in a significant decrease of compressive strength of the system. The coarsening effect of SC on dihydrate gypsum makes the system to form a relatively dense microstructure, which has little influence on the compressive strength. The research results will provide an important reference for the engineering application of the β-HPG-OPC composite system, and help to promote the high value-added utilization of β-HPG in the engineering.
    Mechanical Properties of Recycled Fine Powder Foamed Cementitious Materials for Brick and Concrete
    CUI Ning, LUAN Zhonghao
    2022, 41(7):  2421-2429. 
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    The recycled fine powder from construction waste can effectively replace cement, reduce the use of cement resources, and improve the resource utilization rate of construction waste. In this paper, the effects of brick-concrete recycled fine powder and foaming agent content on the mechanical properties of low-strength foamed cementitious materials were studied by methods such as bubble parameter analysis and mechanical property test. The results show that the addition of recycled fine powder leads to a reduction in the compressive strength of the cementitious material. The strength of the cementitious material increases slightly with the addition of recycled fine powder, when the amount of fine powder is higher than that of cement. At the same time, the flowability of slurry decreases first and then increases with the increase of recycled fine powder. When the amount of recycled fine powder is small, the amount of foaming agent has a great effect on the flowability of slurry, but when the amount of recycled fine powder is large, the amount of foaming agent has no significant influence on the flowability of slurry. The performance of different batches of recycled fine powder is almost the same. By adjusting the content of recycled fine powder and the foaming agent, foam cementitious materials that meet the requirements of different mechanical properties and have good fluidity can be prepared, which can meet the large-scale promotion in low-grade backfill materials.
    Effect of Glutinous Rice Slurry on Shear Strength of Lime Soil under Freeze-Thaw Cycle
    ZHANG Yang, MA Mengmeng, LIU Jiaxin, DENG Jie
    2022, 41(7):  2430-2437. 
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    The construction of road projects in seasonal frozen soil areas needs to protect the fragile ecological environment while mechanically modifying the soil. In this paper, the effect of glutinous rice slurry on the shear strength of lime soil under freeze-thaw cycles was studied. The characteristics of stress-strain curves, shear strength, cohesion and internal friction angle of modified soil with glutinous rice slurry under different freeze-thaw cycles (0 times, 1 times, 3 times, 6 times, 10 times) were studied by adding glutinous rice slurry with different mass concentration (0%, 2%, 4%, 6%, 8%) into lime soil (lime mass concentration was 10%). The results show that the shear strength of modified soil can be improved by adding glutinous rice slurry into lime soil, but excessive concentration of glutinous rice slurry results in reduced shear strength. When the concentration of glutinous rice slurry is 6%, the shear strength of modified soil is large. Freeze-thaw cycles lead to the decrease of shear strength of modified soil, glutinous rice slurry can reduce the strength loss of modified soil under freeze-thaw cycles. Under the action of freeze-thaw cycle, the change trends of cohesion and internal friction angle of modified soil are different. The test results provide reference for the modification of subgrade soil in seasonal frozen soil area by glutinous rice slurry.
    Research on Frost Damage of Ancient Building Blue Brick Wall of Longshengzhuang in Inner Mongolia
    HAO Yunhong, HE Dandan, WU Rigen, HE Xiaoyan
    2022, 41(7):  2438-2446. 
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    Analysis suggested that freeze-thaw is the main reason of causing severe diseases in the blue brick wall of Longshengzhuang ancient buildings. In order to study the effect of severe cold environment on the deterioration ancient building walls, the freeze-thaw test of blue brick specimen was conducted, and the changes of weight, compressive strength and surface hardness before and after freeze-thaw were analyzed. The Weibull distribution theory was used to establish the damage model of the blue brick in freeze-thaw environment under the three indexes of weight, compressive strength and hardness, and the model were modified by unifying the format factor m value of the three damage models. The results show that the compressive strength, mass loss amount, and surface Vickers hardness show an exponential decline with the increase of freeze-thaw cycles; the damage degree of surface hardness is higher than weight and compressive strength under the same freeze-thaw cycles. The Weibull damage model of blue brick under freeze-thaw cycle has a high degree of consistency with the experimental curves. The modified freeze-thaw damage model also reflects the damage law of blue brick in severe cold environment.
    Ceramics
    Research Progress of Oxygen Ion Electrolyte for Solid Oxide Cells
    FENG Bin, LIU Peng, YANG Xianfeng, XIE Zhipeng
    2022, 41(7):  2447-2457. 
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    As a green and efficient all-solid-state energy conversion device, solid oxide cells (SOCs) can convert the chemical energy of hydrogen, carbon, hydrocarbons, alcohols or other fuels into electrical energy in the mode of fuel cells, and produce hydrogen via water splitting in the mode of electrolytic cells. It has great significance in alleviating the global energy crisis and achieving carbon neutrality. However, Y2O3 stabilized ZrO2 (YSZ), the conventional electrolyte material of SOCs, shows a high ionic conductivity above 1 000 ℃. The working temperature is so high that many challenges need to be dealt with, such as high operating costs, limited material choice, and low system stability. Therefore, reducing operating temperature has always been a key issue for the development of SOCs, which can be realized by developing high conductivity electrolyte materials and reducing the thickness of electrolyte film. This paper makes a comprehensive review on the research progress of various oxygen ionic electrolyte materials for intermediate and low temperature SOCs in terms of material development and thin film fabrication. As far as ZrO2, CeO2, Bi2O3 and LaGaO3 based solid electrolytes are concerned, the influence mechanism of heterovalent ion doping on the increase of oxygen ion conductivity and the stability of phase structure is illustrated, and the manufacturing techniques and ionic conductive properties of the electrolyte membranes is summarized. Accordingly, this paper can serve as a reference for the development of high-performance electrolyte materials for solid oxide cells.
    Properties of LSCM-GDC Composite Cathode Impregnatedwith Ni and Cu
    LIU Xinnan, XIAO Yanzhi, HUANG Meiqi, JIANG Han, KONG Jiangrong, ZHOU Tao
    2022, 41(7):  2458-2466. 
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    Solid oxide electrolysis cell can cleanly and efficiently convert electric and thermal energy into chemical energy, which has broad application prospects in the new energy field. La0.75Sr0.25Cr0.5Mn0.5O3-δ (LSCM) has high temperature stability and is one of hotspots in the research of solid oxide electrolysis cell cathode materials. However, the relatively low ionic conductivity of LSCM results in insufficient electrocatalytic performance during electrolysis. In this paper, Ce0.8Gd0.2O2-δ (GDC) with high ionic conductivity was composited on the basis of LSCM to construct a composite electrode, and Ni and Cu were impregnated into the composite electrode as metal catalysts to improve the water vapor adsorption and conversion capacity of the electrode. Ni, Cu co-loaded can keep single Ni or Cu loaded at the same time to improve the electrode electrolysis mechanism. The results show that compared with single Ni or Cu impregnation cathodes, the electrode with Ni and Cu co-impregnation has higher electrochemical performance under reducing atmosphere. The electrochemical performance of the electrode under reducing atmosphere at 800 ℃ is better than that under oxidizing atmosphere. The electrode with the nickel-copper mass ratio of 2∶8 has the best performance among the Ni, Cu-loaded cathodes, which current density reaches 2.36 A·cm-2 at -0.1 V overpotential, and the polarization resistance is 0.92 Ω·cm2.
    Fabrication of High-Density Alumina Green Body by Ceramic Gels Re-Fluidising Combined with Filtrating
    WU Xiaolang, ZHAO Jin, SHIMAI Shunzo, MAO Xiaojian, ZHANG Jian, WANG Shiwei
    2022, 41(7):  2467-2473. 
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    High-density green body is the basis to prepare high performance ceramics. Re-fluidising combined with filtrating was applied to prepare high-density alumina green body, and the effect of re-fluidising combined with filtrating on characteristic of green body was investigated. The results show that the re-fluidising slurry after syneresis for 1 d has better compressibility, and the compressibility of the slurry decreases with the extension of syneresis time. Re-fluidising combined with filtrating is an effective method to improve the physical and mechanical properties of slurry, especially for high solid content slurry. Compared with the green body prepared by direct filtration of slurry with 56.0% solid content, the relative density of the green body manufactured by re-fluidising combined with filtrating increases from 64.5% to 65.7% and the cumulative pore volume decreases from 0.149 mL/g to 0.140 mL/g. Correspondingly, the sintering shrinkage ratio of green body decreases from 13.2% to 12.6% when sintering at 1 550 ℃ for 2 h, and the flexural strength increases from 483 MPa to 545 MPa after sintering at 1 500 ℃ for 6 h. This is important for the preparation of ceramics with large size.
    Study on CMAS Resistance of LaMeAl11O19(Me=Cu,Zn) Ceramic Bulk Materials
    WEI Hailang, CAO Xueqiang, DENG Longhui, JIANG Jianing
    2022, 41(7):  2474-2484. 
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    With the increasing application temperature of gas turbine, the CMAS resistance of ceramic materials is becoming more and more important. In this paper, theCaO-MgO-Al2O3-SiO2 (CMAS) corrosion resistance behavior of LaMeAl11O19 (Me=Cu,Zn) ceramic bulk materials under different temperatures and time was studied by X-ray diffraction (XRD), scanning electron microscope (SEM) and so on. The results show that the corrosion products of both LaZnAl11O19(LZA) and LaCuAl11O19 (LCA) bulk materials include diopside (Ca(Mg,Al)(Si,Al)O7) andanorthite (CaAl2Si2O8). With the increase of corrosion temperature and time, the corrosion depth increases, and Ca(Mg,Al)(Si,Al)O7 gradually transforms into CaAl2Si2O8. The CMAS corrosion of LZA and LCA bulk materials can be explained by “dissolution-precipitation” mechanism. The bulk materials gradually dissolve into the CMAS, forming Ca(Mg,Al)(Si,Al)O7, and then gradually transform into CaAl2Si2O8, so that the diopside phase which is difficult to crystallize is transformed into the anorthite phase which is easy to crystallize. La atom is the crystal nucleus of devitrification, and the interfacial energy exists between the CMAS glass phase and the bulk materials. These factors together promote the precipitation of thick plate-like crystals of CaAl2Si2O8 inside CMAS and at the interface of CaAl2Si2O8 and CMAS.
    Effect of Y2O3 on Microstructure and Properties of High Thermal Conductivity Si3N4 Ceramics
    ZHANG Jing, ZHANG Weiru, SUN Feng, XU Xuemin, WANG Zaiyi, LYU Peiyuan, WANG Mei
    2022, 41(7):  2485-2493. 
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    Cost-effective fabrication of high thermal conductivity Si3N4 ceramics was realized by using low-cost Si3N4 powder with relatively high oxygen content (1.85% (mass fraction)) as raw material and Y2O3-MgO as sintering additives. The effect of Y2O3 addition on the densification, microstructure, mechanical properties and thermal conductivity of Si3N4 ceramics was investigated. The results show that properly increasing the addition of Y2O3 not only promotes the densification and microstructure refinement of Si3N4 ceramics, but also contributes to the decrease of lattice oxygen content and the improvement of thermal conductivity. The sample containing 7% (mass fraction) Y2O3 sintered at 1 900 ℃ has the optimum comprehensive properties, and its relative density, flexural strength, fracture toughness and thermal conductivity are 99.5%, (726±46) MPa, (6.9±0.2) MPa·m1/2 and 95 W·m-1·K-1, respectively.
    3D Printing Process and Properties of Continuous Carbon Fiber Reinforced Thermasetting Phenolic Resin Composites
    LIU Taoxin, BAO Chonggao, DONG Wencai, MA Haiqiang, LU Wenqi
    2022, 41(7):  2494-2501. 
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    In view of the technical difficulties in the 3D printing and molding process of continuous carbon fiber reinforced thermosetting phenolic resin (CCF-TSPR) composites, this paper proposes a 3D printing and molding scheme of impregnation, in-situ pre-curing and post-curing to realize 3D printing of continuous carbon fiber reinforced thermosetting phenolic resin composites. The influence of the immersion temperature on the contact angle and surface tension of the phenolic resin, as well as the printing process on the morphology and mechanical properties of the sample were studied. The results show that when the dipping temperature is 40 ℃ and the pre-curing temperature is 180 ℃, the raw material is available for molding with optimal fiber-resin interface bonding. When the printing spacing is 0.5 mm, the bending strength and modulus of the sample reach the maximum values of 660.00 MPa and 57.99 GPa respectively, and the interlaminar shear strength reaches 20.14 MPa. This integrated preparation process of CCF-TSPR composites solves the difficulty of in-situ molding of 3D printing thermosetting resins, and provides a reference for the preparation of continuous fiber reinforced thermosetting resin composites with complex structures.
    Glass
    Research Progress on Chemical Strengthening Technology of Glass
    TIAN Haodong, XU Chi, XU Shaokun, ZHOU Shaojun, CAO Wenlong, ZU Chengkui
    2022, 41(7):  2502-2510. 
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    Chemical strengthening technology, also known as ion-exchange technology, is widely used in construction, transportation, and other fields. This technology involves the formation of a compressive stress layer on the surface of glass to improve the mechanical strength of glass. Changing the parameters of chemical strengthening process directly affects the properties of glass after chemical strengthening. The effects of the ion-exchange principle, glass composition, chemical strengthening temperature, chemical strengthening time, and molten salt composition on the chemical strengthening process were discussed. The advantages and disadvantages of the electric field-assisted chemical strengthening process and the chemical strengthening process without molten salt were briefly presented. The research progress on chemical strengthening technology at the domestic and international level was summarized, and the shortcomings of the existing chemical glass strengthening technology were highlighted, which provided a reference for the scientific research and development of chemical strengthening technology.
    Effect and Mechanism of WO3 on Fluidity of Zero Expansion Lithium Aluminum Silicon Sealing Glass
    GUO Hongwei, LI Rongyue, CHI Longxing, LIU Shuai, WANG Yi, BAI Yun
    2022, 41(7):  2511-2517. 
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    Sealing connection quartz glass is widely used in aerospace, semiconductor processing and micro-electro-mechanical system vacuum connection, etc. The improved low-expansion Li2O-Al2O3-SiO2 (LAS) glass-ceramics can be used to seal quartz glass, but there is a problem of poor fluidity.LAS glass-ceramics were modified by incorporating WO3. The mechanism of LAS glass sealing quartz glass after incorporating WO3 was investigated by using linear expansion coefficient analyzer, differential scanning calorimeter, X-ray diffractometer, high temperature sintering imager and scanning electron microscope. The results show that the effect of WO3 on the crystallization of LAS glass is strengthening first and then weakening. The more WO3 is added, the greater the thermal expansion coefficient is. When the amount of WO3 reaches 5.0% (mass fraction), the thermal expansion coefficient increases to 5.69×10-7-1.The fluidity and wettability develop with the enlarge of the external doping amount. The spreading area extends with the increase of the external doping amount. The wetting angle decreases with the expand of the external doping amount, which effectively improves the problem of insufficient fluidity of LAS glass itself. The sealing between LAS glass and quartz glass is mainly achieved by the migration of chemical elements.
    Effect of Cr2O3 Content on Viscosity and Melting Characteristics of Glass Melt
    WANG Yici, WANG Yifan, WANG Ruixin, ZHAO Fengguang, CHAI Yifan, LUO Guoping
    2022, 41(7):  2518-2523. 
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    In order to ensure the smooth pouring of liquid glass, and to provide basic technical parameters for the co-preparation of CaO-MgO-Al2O3-SiO2-Cr2O3 architectural glass-ceramics by blast furnace slag and chromium iron alloy slag, FactSage7.1 thermodynamic software was used to draw the five-element phase diagram of CaO-MgO-Al2O3-SiO2-Cr2O3 glass system, and the viscosity and melting characteristics of the base glass melt were investigated through experiments. The results show that in the phase diagram drawn by FactSage7.1, with the increase of Cr2O3 content, the liquid phase region of the phase diagram is shrinking, indicating that the further melting of glass is hindered. When the mass fraction of nucleating agent Cr2O3 increases from 0.85% to 2.05%, the viscosity of glass melt decreases gradually and the melting temperature increases gradually, and the melting temperature should be higher than 1 469 ℃ when the CaO-MgO-Al2O3-SiO2-Cr2O3 base glass is prepared by melting method. The increase of Cr2O3 content will increase the melting temperature of the base glass, which is reflected in the continuous increase of softening temperature, hemisphere temperature and flow temperature of each group of samples. Therefore, the content of Cr2O3 in the raw material ratio of base glass should be reduced as much as possible.
    Experimental and Simulation Research on Bearing Capacity of Connecting of Curtain Wall Glass Ribs
    LEI Keyang, MO Jiyun, JIANG Jieqi, YANG Yinnan
    2022, 41(7):  2524-2532. 
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    All-glass curtain wall is widely used in modern buildings due to its good permeability. For large-size glass ribs, it is usually made by splicing. The bearing capacity of splicing connecting holes has a great influence on the overall bearing capacity of glass ribs. In this paper, the finite element software ANSYS Workbench was used to analyze the contact of the connecting hole and compare it with the test failure load. The influence of two kinds of connecting hole structures, nylon 1010 and Hilti RE-500 reinforced plastic, on the bearing capacity of the glass hole was compared, and then the relationship between the size of the glass hole and the bearing capacity of the connecting hole was analyzed. The results show that the structure using Hilti RE-500 reinforced glue has higher bearing capacity than that using nylon 1010 with elastic medium under the premise of meeting the glass connecting hole structure. The bearing capacity of connecting holes increases with the size of opening holes, and the diameter of glass in the form of Hilti RE-500 reinforced plastic structure is the most suitable: 54~56 mm. In actual engineering, the finishing of the glass should be strictly controlled to avoid affecting the overall bearing capacity of the glass rib due to the defects on the glass surface.
    New Functional Materials
    Preparation and Thermal Performance Enhancement of Shape-Stable Na2SO4·10H2O-Na2HPO4·12H2O Eutectic Salt Phase Change Energy Storage Materials
    WEI Ning, LIU Xin, TIE Shengnian, WANG Chang'an
    2022, 41(7):  2533-2541. 
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    For the purpose of rapid and effective heat exchange between phase change materials and the external environment, carbon nanofibers (CNFs) were introduced to improve the thermal conductivity of composite phase change materials. In this paper, Na2SO4·10H2O and Na2HPO4·12H2O were prepared into eutectic salt phase change materials by melt blending method, three-dimensional polymer network encapsulation phase change materials were constructed with sodium polyacrylate, and CNFs were used to improve the thermal conductivity of the composites. The changes of oxygen functional groups on the surface of CNFs treated by high energy ball milling and wet chemical oxidation were investigated by Raman and XPS; the effects of CNFs on the chemical compatibility, phase transition behavior, thermal stability, latent heat capacity and thermal conductivity of the composites were analyzed by Raman, DSC, Hot disk and TG. The results show that after functionalization of CNFs, the atomic ratio of oxygen and carbon increases to 0.140, and the oxidation effect is remarkable. The introduction of CNFs into composite phase change materials has good chemical compatibility among the components in the system. When the addition amount of CNFs reaches 3% (mass fraction), the solid thermal conductivity of the composites reaches 1.05 W/(m·K), and the liquid thermal conductivity is 0.88 W/(m·K). Compared with the composites without CNFs, the solid-liquid thermal conductivity increases by 69.4% and 60.0%, respectively. After 1 000 cycles, the melting enthalpy of the composite decreases by 56.2% and the crystallization enthalpy decreases by 65.3% compared with that before cycles. The phase change system still has a certain heat storage capacity, indicating that embedding phase change materials into three-dimensional network structure is an effective packaging strategy.
    Thermal Properties of Graphene Enhanced Composite Phase Change Materials for Energy Storage
    LI Runfeng, LIU Yanjun, TU Yubo, WANG Linjun, WEN Xiaoqing, REN Lei
    2022, 41(7):  2542-2548. 
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    Thermal enhanced composite phase change materials for energy storage (TCPCMs) were fabricated by the spontaneous infiltration treatment, with adding graphene and iron tailing porous ceramics as the carrier. Based on the tests of thermal properties and stability, TCPCMs with thermal conductivity of 0.41~0.59 W/(m·K), latent heat of 69~120 kJ/kg, and good stability are obtained by adjusting the porosity of the carrier. Thethermal conductivity of TCPCMs has a linear relationship to the porosity of ceramic carrier by fitting test data. Besides, the latent heat and thermal conductivity of TCPCMs decrease by 3.2% and 16.7% after 100 times melting/solidification cycles. This research provides a new idea for the application of solid iron tailings in thermal and energy storage materials.
    CeO2 Composite Modified ZSM-5 Molecular Sieve for Catalyzing Methanol to Propylene
    YANG Xinxin, LIU Fei, YAO Mengqin
    2022, 41(7):  2549-2557. 
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    In methanol to propylene (MTP) reaction, due to the strong acidity of ZSM-5 molecular sieve, the secondary reactions such as hydrogen transfer and aromatization between methanol and ZSM-5 are easy to block the pores, making its microporous structure more unfavorable to the diffusion of molecules, accelerating the carbon deposition and deactivation of the catalyst, resulting in the decrease of propylene selectivity and propylene/ethylene (P/E) ratio. Therefore, in this paper, ZSM-5 molecular sieve was modified by CeO2 with high catalytic activity to effectively reduce its acidity and increase mesoporous, so as to improve propylene selectivity and P/E ratio. The effects of different n(SiO2)/n(Al2O3) and mass ratio of two phases (m(CeO2)/m(ZSM-5)) on the physicochemical properties of CeO2/ZSM-5 catalysts were investigated by XRD, XRF, NH3-TPD and N2 adsorption and desorption. When the reaction temperature was 480 ℃, the weight hourly space velocity was 2.6 h-1, the nitrogen flow rate was 100 mL·min-1, the pressure was atmospheric and pure methanol was fed, and the MTP catalytic performance of the prepared composite catalyst was investigated. The results indicate that the composite catalyst with n(SiO2)/n(Al2O3) of 250 and m(CeO2)/m(ZSM-5) of 1∶4 exhibits better MTP catalytic performance than the previous research results, with conversion of methanol of 99.9%, selectivity of propylene of 42.78%, and P/E ratio of 6.3.
    Effect of Heat Treatment on GO/HA Bioactive Coating Deposited by Electrophoresis on Titanium Substrate
    HAN Weiwei, LIU Li, YU Benrui, ZHU Qingxia
    2022, 41(7):  2558-2563. 
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    Graphene oxide (GO)/hydroxyapatite (Ca10(PO4)6(OH)2, HA) composite coating was prepared on titanium substrate by electrophoretic deposition. GO/HA coatings obtained under different heat treatment conditions were characterized by XRD, SEM, and so on. The results indicate that heat treatment contributes to improve the crystallinity of HA. The HA in composite coating after heat treatment at 600 ℃ and 800 ℃ is not thermally decomposed, meanwhile, the ordered crystal structure of GO may be destroyed. GO/HA composite coatings haveexcellent bioactivity. However, the wettability and bioactivity of composite coatings are deteriorated with the increase of heat treatment temperature. In addition, the heat treatment process is beneficial to the compactness of GO/HA composite coatings and the bonding with the substrate. The adhesion strength of coating after heat treatment at 800 ℃ reaches 25.31 MPa.
    High-Temperature Properties of Si/(Yb1-xYx)2Si2O7/LaMgAl11O19 Thermal/Environmental Barrier Coatings
    MAO Chuanyong, DONG Shujuan, JIANG Jianing, DENG Longhui, CAO Xueqiang
    2022, 41(7):  2564-2573. 
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    Si/(Yb1-xYx)2Si2O7/LaMgAl11O19(x=0, 0.5) thermal/environmental barrier coatings (T/EBCs) were prepared by plasma sprayingmethod on the surface of SiC fiber reinforced SiC ceramic composites (SiCf/SiC-CMCs). The thermal cycle performance and water-oxygen corrosion resistance at 1 300 ℃ of T/EBCs systems with different components were investigated by means of SEM, EDS and XRD. And failure mechanisms of the thermal cycle and water-oxygen corrosion were further discussed. The results indicate that the thermal cycle life of Si/Yb2Si2O7/LMA coating system is 403 cycles and water-oxygen corrosion resistance is 50 h. The thermal cycle life of Si/YbYSi2O7/LMA system decreases to 277 cycles, while the water-oxygen corrosion resistance increases to 80 h. The larger thermal mismatch stress and the formation of Al-containing compounds or solid solutions between YbYSi2O7 and LMA are the main factors that reduce the thermal cycle life of Si/YbYSi2O7/LMA. The less oxide impurities in the YbYSi2O7-EBC layer reduce the probability of reaction with water to generate volatile substances, and improve the water-oxygen corrosion resistance of Si/YbYSi2O7/LMA.
    Cold Sintering Preparation and Dielectric Properties of 0-3 Type Barium Strontium Titanate/Polytetrafluoroethylene Composites
    YING Xiaoyun, LIU Jun, QIAO Wenhao, ZHOU Ming, LUO Ying
    2022, 41(7):  2574-2583. 
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    0-3 type barium strontium titanate (BST)/polytetrafluoroethylene (PTFE) composites are new types of ceramic/polymer functional composites. They combine advantages of BST ceramic and PTFE polymer, and show high dielectric constant and dielectric adjustability. However, due to the low dielectric constant of polymer phase, the dielectric constant of composites with polymer as matrix and ceramic as filling phase prepared by conventional methods such as flow casting method is basically below 100. In order to further improve the dielectric properties of BST/PTFE composites, a new sintering process (cold sintering process) was used to realize the co-sintering of BST ceramic and PTFE polymer. In the experiment, 0-3 type BST/PTFE composites were prepared by introducing PTFE with a volume ratio of 5% into BST matrix, and solid barium hydroxide octahydrate (Ba(OH)2·8H2O) as transient liquid phase to assist the sintering process. The dielectric properties of the composites under different cold sintering conditions were investigated. The results show that the dielectric constant of the composite samples reach more than 500 (25 ℃, 1 kHz) under the conditions of cold sintering temperature of 275 ℃, pressure of 200 MPa and time of 2.5 h. Compared with the conventional preparation process, the dielectric constant of the composites prepared by cold sintering process has been greatly improved, which has a certain reference significance for the low-temperature preparation and research of ceramic/polymer functional composites.