BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2026, Vol. 45 ›› Issue (4): 1175-1183.DOI: 10.16552/j.cnki.issn1001-1625.2025.0968
• Cement and Concrete • Previous Articles Next Articles
WANG Jiefang1(
), XU Dejin2(
), LI Sheng1, REN Wanli1, CHEN Peiyuan2
Received:2025-09-30
Revised:2025-11-11
Online:2026-04-20
Published:2026-05-14
Contact:
XU Dejin
CLC Number:
WANG Jiefang, XU Dejin, LI Sheng, REN Wanli, CHEN Peiyuan. Influence of Cellulose Ether on Mechanical and Workability Properties of Lining Concrete[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(4): 1175-1183.
| Material | Mass fraction/% | |||||||
|---|---|---|---|---|---|---|---|---|
| SiO2 | CaO | Fe2O3 | Al2O3 | MgO | K2O | SO3 | Other | |
| Cement | 25.22 | 53.21 | 4.03 | 5.61 | 3.84 | 0.80 | 0.81 | 6.48 |
| Fly ash | 59.34 | 3.36 | 3.81 | 25.17 | 1.12 | 1.11 | 2.01 | 4.08 |
| Expansive agent | 26.83 | 27.21 | 2.80 | 22.03 | 1.35 | 0.75 | 17.25 | 1.78 |
Table 1 Chemical composition of cement, fly ash, and expansive agent
| Material | Mass fraction/% | |||||||
|---|---|---|---|---|---|---|---|---|
| SiO2 | CaO | Fe2O3 | Al2O3 | MgO | K2O | SO3 | Other | |
| Cement | 25.22 | 53.21 | 4.03 | 5.61 | 3.84 | 0.80 | 0.81 | 6.48 |
| Fly ash | 59.34 | 3.36 | 3.81 | 25.17 | 1.12 | 1.11 | 2.01 | 4.08 |
| Expansive agent | 26.83 | 27.21 | 2.80 | 22.03 | 1.35 | 0.75 | 17.25 | 1.78 |
| Sample No. | Mix proportion/(kg·m-3) | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Water | Cement | Fly ash | Sand | 5~<10 mm stone | 10~20 mm stone | Expansive agent | HPMC | Water-reducing agent | Air-entraining agent | |
| CC0 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0 | 4.03 | 0.13 |
| CC1 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.13 | 4.03 | 0.13 |
| CC2 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.22 | 4.03 | 0.13 |
| CC3 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.31 | 4.03 | 0.13 |
| CC4 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.40 | 4.03 | 0.13 |
| CC5 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.49 | 4.03 | 0.13 |
Table 2 Mix proportion of sample
| Sample No. | Mix proportion/(kg·m-3) | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Water | Cement | Fly ash | Sand | 5~<10 mm stone | 10~20 mm stone | Expansive agent | HPMC | Water-reducing agent | Air-entraining agent | |
| CC0 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0 | 4.03 | 0.13 |
| CC1 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.13 | 4.03 | 0.13 |
| CC2 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.22 | 4.03 | 0.13 |
| CC3 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.31 | 4.03 | 0.13 |
| CC4 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.40 | 4.03 | 0.13 |
| CC5 | 166 | 332 | 83 | 764 | 423 | 631 | 33 | 0.49 | 4.03 | 0.13 |
| Sample No. | Slump/mm | Flow/mm | Inverted slump cone emptying time/s | Slump after 1 h/mm | Flow after 1 h/mm |
|---|---|---|---|---|---|
| CC0 | 255 | 560 | 5.9 | 235 | 545 |
| CC1 | 250 | 530 | 7.2 | 235 | 520 |
| CC2 | 240 | 515 | 9.8 | 230 | 505 |
| CC3 | 240 | 500 | 13.1 | 230 | 490 |
| CC4 | 235 | 480 | 17.2 | 225 | 470 |
| CC5 | 230 | 460 | 20.5 | 225 | 455 |
Table 3 Test results of fresh mixing properties of lining concrete
| Sample No. | Slump/mm | Flow/mm | Inverted slump cone emptying time/s | Slump after 1 h/mm | Flow after 1 h/mm |
|---|---|---|---|---|---|
| CC0 | 255 | 560 | 5.9 | 235 | 545 |
| CC1 | 250 | 530 | 7.2 | 235 | 520 |
| CC2 | 240 | 515 | 9.8 | 230 | 505 |
| CC3 | 240 | 500 | 13.1 | 230 | 490 |
| CC4 | 235 | 480 | 17.2 | 225 | 470 |
| CC5 | 230 | 460 | 20.5 | 225 | 455 |
| Sample No. | CC0 | CC1 | CC2 | CC3 | CC4 | CC5 |
|---|---|---|---|---|---|---|
| C-S-H mass loss (80~200 ℃)/% | 58.01 | 58.05 | 66.92 | 67.95 | 70.33 | 78.83 |
| Ca(OH)2 mass loss (400~500 ℃)/% | 4.86 | 6.87 | 7.16 | 7.60 | 7.68 | 8.40 |
| CaCO3 mass loss (650~800 ℃)/% | 4.77 | 5.05 | 5.56 | 5.85 | 5.86 | 6.08 |
Table 4 TGA semi-quantitative analysis results for 28 d paste samples
| Sample No. | CC0 | CC1 | CC2 | CC3 | CC4 | CC5 |
|---|---|---|---|---|---|---|
| C-S-H mass loss (80~200 ℃)/% | 58.01 | 58.05 | 66.92 | 67.95 | 70.33 | 78.83 |
| Ca(OH)2 mass loss (400~500 ℃)/% | 4.86 | 6.87 | 7.16 | 7.60 | 7.68 | 8.40 |
| CaCO3 mass loss (650~800 ℃)/% | 4.77 | 5.05 | 5.56 | 5.85 | 5.86 | 6.08 |
| Sample No. | CC0 | CC5 | ||||
|---|---|---|---|---|---|---|
| π | μ/GPa | σ/GPa | π | μ/GPa | σ/GPa | |
| <10 GPa | 0.12 | 3.81 | 1.68 | 0.10 | 5.52 | 2.20 |
| 10~<30 GPa | 0.46 | 23.04 | 8.55 | 0.48 | 25.53 | 6.70 |
| 30~50 GPa | 0.25 | 41.06 | 3.58 | 0.28 | 42.81 | 3.94 |
| >50 GPa | 0.17 | 54.64 | 1.87 | 0.14 | 54.32 | 3.61 |
Table 5 Elastic modulus of different phases from grid of nanoindentation
| Sample No. | CC0 | CC5 | ||||
|---|---|---|---|---|---|---|
| π | μ/GPa | σ/GPa | π | μ/GPa | σ/GPa | |
| <10 GPa | 0.12 | 3.81 | 1.68 | 0.10 | 5.52 | 2.20 |
| 10~<30 GPa | 0.46 | 23.04 | 8.55 | 0.48 | 25.53 | 6.70 |
| 30~50 GPa | 0.25 | 41.06 | 3.58 | 0.28 | 42.81 | 3.94 |
| >50 GPa | 0.17 | 54.64 | 1.87 | 0.14 | 54.32 | 3.61 |
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