硅酸盐通报 ›› 2026, Vol. 45 ›› Issue (9): 3027-3042.DOI: 10.16552/j.cnki.issn1001-1625.2026.0280
邹颖杰1,2(
), 李化建1,2(
), 黄法礼1,2, 冯俊杰3, 石贺男1,2, 董昊良1,2, 易忠来1,2
收稿日期:2026-03-25
修订日期:2026-05-07
出版日期:2026-09-15
发布日期:2026-10-09
通信作者:
李化建,博士,研究员。E-mail:chinasailor@163.com作者简介:邹颖杰(2000—),男,博士研究生。主要从事高铁土木工程材料及其耐久性方面的研究。E-mail:zyj10281030@163.com
基金资助:
ZOU Yingjie1,2(
), LI Huajian1,2(
), HUANG Fali1,2, FENG Junjie3, SHI Henan1,2, DONG Haoliang1,2, YI Zhonglai1,2
Received:2026-03-25
Revised:2026-05-07
Published:2026-09-15
Online:2026-10-09
摘要:
为应对地下水中硫酸盐对盾构隧道注浆材料的侵蚀问题,研发了抗硫酸盐侵蚀双液注浆材料。研究了水胶比(w/b)、磨细高炉矿渣(GGBS)掺量和A、B液体积比(A液为胶凝材料浆体,B液为硅酸钠溶液)对双液注浆材料工作性能、力学性能、抗硫酸盐侵蚀性能的影响规律,并结合XRD、SEM-EDS、TG-DTG和FTIR揭示了抗硫酸盐侵蚀性能提升机理。结果表明,该注浆材料流动性良好,28 d抗压强度为9.38~17.17 MPa,耐蚀系数超过0.8,在满足施工流动性要求的同时具有优异的力学性能和抗硫酸盐侵蚀性能。GGBS掺量对注浆材料抗压强度及其耐蚀系数的影响最显著,其原因是GGBS发挥填料效应和火山灰活性,生成更多C-S-H凝胶,促进致密微结构形成,提升力学性能。通过降低w/b和提高GGBS掺量可促进物理屏障形成阻滞外部SO
中图分类号:
邹颖杰, 李化建, 黄法礼, 冯俊杰, 石贺男, 董昊良, 易忠来. 盾构隧道抗硫酸盐侵蚀双液注浆材料性能及微结构演变[J]. 硅酸盐通报, 2026, 45(9): 3027-3042.
ZOU Yingjie, LI Huajian, HUANG Fali, FENG Junjie, SHI Henan, DONG Haoliang, YI Zhonglai. Performance and Microstructure Evolution of Sulfate-Resistant Double-Liquid Grouting Material for Shield Tunnel[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(9): 3027-3042.
| Material | Mass fraction/% | |||||||
|---|---|---|---|---|---|---|---|---|
| CaO | SiO2 | Al2O3 | MgO | SO3 | Fe2O3 | K2O | TiO2 | |
| Cement | 52.67 | 21.08 | 6.85 | 3.34 | 3.05 | 1.99 | 0.89 | 0.46 |
| GGBS | 36.78 | 28.77 | 14.82 | 8.19 | 1.99 | 0.45 | 0.20 | 0.57 |
表1 水泥和GGBS的主要化学组成
Table 1 Main chemical composition of cement and GGBS
| Material | Mass fraction/% | |||||||
|---|---|---|---|---|---|---|---|---|
| CaO | SiO2 | Al2O3 | MgO | SO3 | Fe2O3 | K2O | TiO2 | |
| Cement | 52.67 | 21.08 | 6.85 | 3.34 | 3.05 | 1.99 | 0.89 | 0.46 |
| GGBS | 36.78 | 28.77 | 14.82 | 8.19 | 1.99 | 0.45 | 0.20 | 0.57 |
| Sample | Proportion/(kg·m-3) | Sodium silicate content/(L·m-3) | ||||
|---|---|---|---|---|---|---|
| Cement | GGBS | Bentonite | Stabilizer | Water | ||
| 1(w1.2G40V12) | 355.9 | 237.2 | 30.0 | 3.5 | 711.7 | 77.0 |
| 2(w1.2G60V15) | 241.0 | 361.5 | 30.0 | 3.5 | 723.0 | 62.6 |
| 3(w1.2G80V18) | 121.8 | 487.1 | 30.0 | 3.5 | 730.0 | 52.7 |
| 4(w1.5G40V15) | 302.3 | 201.6 | 30.0 | 3.5 | 755.9 | 62.6 |
| 5(w1.5G60V18) | 203.7 | 305.6 | 30.0 | 3.5 | 763.9 | 52.7 |
| 6(w1.5G80V12) | 99.2 | 396.8 | 30.0 | 3.5 | 744.0 | 77.0 |
| 7(w1.8G40V18) | 262.6 | 175.1 | 30.0 | 3.5 | 787.8 | 52.7 |
| 8(w1.8G60V12) | 170.5 | 255.8 | 30.0 | 3.5 | 767.3 | 77.0 |
| 9(w1.8G80V15) | 86.6 | 346.4 | 30.0 | 3.5 | 779.5 | 62.6 |
表2 正交试验配合比
Table 2 Orthogonal experimental mix proportion
| Sample | Proportion/(kg·m-3) | Sodium silicate content/(L·m-3) | ||||
|---|---|---|---|---|---|---|
| Cement | GGBS | Bentonite | Stabilizer | Water | ||
| 1(w1.2G40V12) | 355.9 | 237.2 | 30.0 | 3.5 | 711.7 | 77.0 |
| 2(w1.2G60V15) | 241.0 | 361.5 | 30.0 | 3.5 | 723.0 | 62.6 |
| 3(w1.2G80V18) | 121.8 | 487.1 | 30.0 | 3.5 | 730.0 | 52.7 |
| 4(w1.5G40V15) | 302.3 | 201.6 | 30.0 | 3.5 | 755.9 | 62.6 |
| 5(w1.5G60V18) | 203.7 | 305.6 | 30.0 | 3.5 | 763.9 | 52.7 |
| 6(w1.5G80V12) | 99.2 | 396.8 | 30.0 | 3.5 | 744.0 | 77.0 |
| 7(w1.8G40V18) | 262.6 | 175.1 | 30.0 | 3.5 | 787.8 | 52.7 |
| 8(w1.8G60V12) | 170.5 | 255.8 | 30.0 | 3.5 | 767.3 | 77.0 |
| 9(w1.8G80V15) | 86.6 | 346.4 | 30.0 | 3.5 | 779.5 | 62.6 |
图5 双液浆在水中和自然成型时的抗折强度、抗压强度及其影响因素和水平
Fig.5 Flexural strength and compressive strength of double-liquid slurry in water and natural molding and their influencing factors and levels
图6 双液浆抗折强度、抗压强度水陆强度比及其影响因素和水平
Fig.6 Water-land strength ratio of flexural strength and compressive strength of double-liquid slurry and their influencing factors and levels
图7 双液浆经水和5% Na2SO4浸泡后的抗折、抗压强度及其影响因素和水平
Fig.7 Flexural strength and compressive strength of double-liquid slurry after soaking in water and 5% Na2SO4 and their influencing factors and levels
图8 标准养护28 d的9个试样和经5% Na2SO4溶液浸泡后3个试样的XRD谱
Fig.8 XRD patterns of 9 samples after standard curing for 28 d and 3 samples after soaking in 5% Na2SO4 solution
图11 经5% Na2SO4溶液浸泡后试样3、5和7表层C-S-H的EDS点扫描测试结果
Fig.11 EDS point scan test results of C-S-H on surface of samples 3, 5, and 7 soaked in 5% Na2SO4 solution
图12 标准养护28 d的9个试样和经5% Na2SO4溶液浸泡后3个试样的TG-DTG测试结果
Fig.12 TG-DTG test results of 9 samples after standard curing for 28 d and 3 samples after soaking in 5% Na2SO4 solution
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