环境温度对硅酸盐改性聚氨酯注浆材料力学性能的影响

doi:10.16552/j.cnki.issn1001-1625.2024.0936

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (2): 774-784.DOI: 10.16552/j.cnki.issn1001-1625.2024.0936

• 道路材料 • 上一篇

环境温度对硅酸盐改性聚氨酯注浆材料力学性能的影响

郭小雄^1,2, 黄钦颢^3,4, 彭旸^1,2, 袁超^3,4, 李树忱⁴

1.中国铁道科学研究院集团有限公司铁道建筑研究所,北京 100081;
2.高速铁路轨道系统全国重点实验室,北京 100081;
3.山东大学未来技术学院,济南 250062;
4.山东大学岩土与结构工程研究中心,济南 250062

收稿日期:2024-08-12 修订日期:2024-09-16 出版日期:2025-02-15 发布日期:2025-02-28
通信作者: 黄钦颢,硕士研究生。E-mail:hqh001215@163.com
作者简介:郭小雄(1985—),男,副研究员。主要从事铁路隧道的研究。E-mail:365073932@qq.com
基金资助:
国家创新平台开放基金(2022YJ124)

Effect of Environmental Temperature on Mechanical Properties of Silicate Modified Polyurethane Grouting Materials

GUO Xiaoxiong^1,2, HUANG Qinhao^3,4, PENG Yang^1,2, YUAN Chao^3,4, LI Shuchen⁴

1. Railway Construction Research Institute of China Academy of Railway Sciences Co., Ltd., Beijing 100081, China;
2. State Key Laboratory of High-Speed Railway Track System, Beijing 100081, China;
3. School of Future Technology, Shandong University, Jinan 250062, China;
4. Geotechnical and Structural Engineering Research Center, Shandong University, Jinan 250062, China

Received:2024-08-12 Revised:2024-09-16 Published:2025-02-15 Online:2025-02-28

摘要/Abstract

摘要： 为分析有机-无机复合注浆材料在高温环境中的适用性,本文以水玻璃、甘油和催化剂为A组分,以异氰酸酯、塑化剂、阻燃剂为B组分,制备了双组分硅酸盐改性聚氨酯注浆材料,讨论了环境温度对新型注浆材料力学性能的影响,研究了硅酸盐改性聚氨酯浆液强度的环境温度响应规律;以石英砂岩为注浆基体材料预制裂隙,采用新材料进行注浆加固,结合微观表征分析了浆-岩界面胶结特征。结果表明,受高温环境的影响,硅酸盐改性聚氨酯浆液固结体的强度与弹性模量出现下降趋势,25 ℃下浆液固结体抗压强度、抗拉强度、抗压弹性模量与抗拉弹性模量分别达到48.16、15.47、507.47和520.10 MPa,当环境温度升高至90 ℃时分别降至38.13、9.63、387.57和410.84 MPa,材料对环境温度敏感性较低。环境温度升高打破了双组分之间化学反应的平衡,降低了有机相交联固化程度与固结体密实度,材料强度下降。

关键词: 改性聚氨酯, 注浆加固, 高温环境, 力学性能, 胶结特征, 微观形貌

Abstract: To analyze the applicability of organic-inorganic composite grouting materials in high temperature environments, this paper prepared a two-component silicate modified polyurethane grouting material with water glass, glycerol, and catalyst as component A, and isocyanate, plasticizer, and flame retardant as component B. The effect of environmental temperature on the mechanical properties of the new grouting material was discussed, and the environmental temperature response law of the strength of silicate modified polyurethane slurry was studied. The quartz-sandstone was used as the grouting matrix material to perform cracks, new materials were reinforced by grouting, and the bonding characteristics of the slurry rock interface were analyzed through microscopic experiments. The results show that under the effect of high temperature environment, the strength and elastic modulus of silicate modified polyurethane slurry consolidated body show a decreasing trend. At 25 ℃, the compressive strength, tensile strength, compressive elastic modulus, and tensile elastic modulus of the slurry consolidated body reach 48.16, 15.47, 507.47, and 520.10 MPa, respectively. When the environmental temperature increases to 90 ℃, they decrease to 38.13, 9.63, 387.57, and 410.84 MPa, respectively. The material has low sensitivity to environmental temperature. The increase in environmental temperature disrupts the equilibrium of chemical reactions between the two components, reduces the degree of organic crosslinking solidification and the compactness of the consolidated body, resulting in a decrease in strength of the materials.

Key words: modified polyurethane, grouting reinforcement, high temperature environment, mechanical property, adhesive characteristic, microstructure

中图分类号:

TQ317

郭小雄, 黄钦颢, 彭旸, 袁超, 李树忱. 环境温度对硅酸盐改性聚氨酯注浆材料力学性能的影响[J]. 硅酸盐通报, 2025, 44(2): 774-784.

GUO Xiaoxiong, HUANG Qinhao, PENG Yang, YUAN Chao, LI Shuchen. Effect of Environmental Temperature on Mechanical Properties of Silicate Modified Polyurethane Grouting Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(2): 774-784.

参考文献

[1] 严健, 何川, 汪波, 等. 雅鲁藏布江缝合带深埋长大隧道群岩爆孕育及特征[J]. 岩石力学与工程学报, 2019, 38(4): 769-781.
YAN J, HE C, WANG B, et al. Inoculation and characters of rockbursts in extra-long and deep-lying tunnels located on Yarlung Zangbo suture[J]. Chinese Journal of Rock Mechanics and Engineering, 2019, 38(4): 769-781 (in Chinese).
[2] 廖安杰, 张岩, 王飞, 等. 实时高温作用下砂岩的热损伤与能量特征[J/OL]. 地球科学, 1-16 (2023-12-26)[2024-08-08]. http://kns.cnki.net/kcms/detail/42.1874.p.20231226.1104.026.html.
LIAO A J, ZHANG Y, WANG F, et al. Thermal damage and energy characteristics of sandstone under real-time high temperatures[J/OL]. Earth Science, 1-16 (2023-12-26)[2024-08-08]. http://kns.cnki.net/kcms/detail/42.1874.p.20231226.1104.026.html (in Chinese).
[3] 王松涛. 高地温隧道施工期热害综合防治关键技术研究[J]. 铁道建筑技术, 2024(3): 137-140.
WANG S T. Research on the key technology of comprehensive prevention and control of heat damage during the construction of high ground temperature tunnels[J]. Railway Construction Technology, 2024(3): 137-140 (in Chinese).
[4] 王志, 秦文静, 张丽娟. 含裂隙岩石注浆加固后静动态力学性能试验研究[J]. 岩石力学与工程学报, 2020, 39(12): 2451-2459.
WANG Z, QIN W J, ZHANG L J. Experimental study on static and dynamic mechanical properties of cracked rock after grouting reinforcement[J]. Chinese Journal of Rock Mechanics and Engineering, 2020, 39(12): 2451-2459 (in Chinese).
[5] 路阳, 何小芳, 吴永豪, 等. 煤矿井下新型水泥基注浆材料的应用研究进展[J]. 硅酸盐通报, 2014, 33(1): 97-102.
LU Y, HE X F, WU Y H, et al. Research progress on application of new cement-based grouting materials in coal mine underground[J]. Bulletin of the Chinese Ceramic Society, 2014, 33(1): 97-102 (in Chinese).
[6] 付宏渊, 付思妮, 邱祥, 等. 纳米Al₂O₃协同水性环氧树脂对水泥基锚固注浆材料改性研究[J]. 硅酸盐通报, 2022, 41(9): 3016-3027.
FU H Y, FU S N, QIU X, et al. Modification of cement-based anchoring grouting material by nano-Al₂O₃ synergistic with waterborne epoxy resin[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(9): 3016-3027 (in Chinese).
[7] 陈城, 彭丽云, 张振华. 超细水泥-水玻璃双液浆的性能研究及砂土注浆效果分析[J]. 硅酸盐通报, 2018, 37(12): 3883-3887.
CHEN C, PENG L Y, ZHANG Z H. Performance of superfine cement-water glass double slurry and effect analysis on sand grouting[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(12): 3883-3887 (in Chinese).
[8] 王文学, 翟守俊. 水泥注浆与化学注浆加固破碎岩石对比试验[C]//中国地质学会工程地质专业委员会. 2010年全国工程地质学术年会暨“工程地质与海西建设”学术大会论文集. 中国矿业大学资源与地球科学学院, 浙江省水利水电勘测设计院. 2010: 5.
WANG W X, ZHAI S J. Comparative experiment of cement grouting and chemical grouting reinforcement for fractured rocks[C]//Engineering Geology Professional Committee of the Geological Society of China. Proceedings of the 2010 National Conference on Engineering Geology and the Academic Conference on "Engineering Geology and Haixi Construction". School of Resources and Earth Sciences, China University of Mining and Technology, Zhejiang Design Institute of Water Conservancy and Hydroelectric Power Co., Ltd. 2010: 5 (in Chinese).
[9] 王志, 李龙, 王朝雅. 含裂隙类岩石注浆加固后破坏试验研究[J]. 中南大学学报(自然科学版), 2018, 49(4): 957-963.
WANG Z, LI L, WANG C Y. Experimental study on failure of cracked rock-like material after grouting reinforcement[J]. Journal of Central South University (Science and Technology), 2018, 49(4): 957-963 (in Chinese).
[10] GALLUCCI E, ZHANG X, SCRIVENER K L. Effect of temperature on the microstructure of calcium silicate hydrate (C-S-H)[J]. Cement and Concrete Research, 2013, 53: 185-195.
[11] WANG M, ZHU Z J, LIU R T, et al. Influence of extreme high-temperature environment and hydration time on the rheology of cement slurry[J]. Construction and Building Materials, 2021, 295: 123684.
[12] 元强, 彭茂庆, 李岳林, 等. 高地热对隧道喷射混凝土力学性能、孔结构和水化产物的影响综述[J]. 铁道建筑, 2021, 61(8): 53-58.
YUAN Q, PENG M Q, LI Y L, et al. Review on the influence of high geothermal on mechanical property, pore structure and hydration product of tunnel shotcrete[J]. Railway Engineering, 2021, 61(8): 53-58 (in Chinese).
[13] 王凯, 王连国, 陆银龙, 等. 微裂隙中水泥浆液渗滤效应的可视化试验研究[J]. 煤炭学报, 2020, 45(3): 990-997.
WANG K, WANG L G, LU Y L, et al. Visual experimental study on the infiltration effect of cement slurry in micro-fractures[J]. Journal of China Coal Society, 2020, 45(3): 990-997 (in Chinese).
[14] TANG Y B, GUO P W. Experimental investigation on spontaneous combustion of coal affected by exothermic reaction of polyurethane in underground coal mines[J]. Journal of Thermal Analysis and Calorimetry, 2022, 147(1): 337-346.
[15] ZHANG B, WANG B L, ZHONG Y H, et al. Experimental study on reducing the heat of curing reaction of polyurethane polymer grouting material[J]. Advances in Polymer Technology, 2021, 2021(1): 9954498.
[16] LI W S, SHAIKH F U A, WANG L G, et al. Experimental study on shear property and rheological characteristic of superfine cement grouts with nano-SiO₂ addition[J]. Construction and Building Materials, 2019, 228: 117046.

编辑推荐

Metrics

阅读次数

全文

HTML			PDF

最新录用	在线预览	正式出版	最新录用	在线预览	正式出版
0	0	0	4	0	12

	来源	本网站

	次数	16
	比例	100%

摘要

最新录用	在线预览	正式出版

3	0	27

	来源	本网站

	次数	31
	比例	100%

环境温度对硅酸盐改性聚氨酯注浆材料力学性能的影响

Effect of Environmental Temperature on Mechanical Properties of Silicate Modified Polyurethane Grouting Materials

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	赵毅, 李宇, 侯东昌, 蒋明旭, 冯奥中, 孙玉周, 闵志宇. 橡胶玻璃粉再生混凝土力学及抗冲击性能研究[J]. 硅酸盐通报, 2025, 44(2): 550-560.
[2]	杨普新, 范明辉, 李薇, 任文渊, 张爱军. 钼尾矿砂自密实混凝土可行性研究及环境成本效益分析[J]. 硅酸盐通报, 2025, 44(2): 540-549.
[3]	孙传庆, 汪洋, 李占峰, 马魁, 王蒙蒙, 刘瑞祥, 刘福田. Al₂O₃-SiO₂气凝胶及其纤维增强复合材料的研究进展[J]. 硅酸盐通报, 2025, 44(2): 732-745.
[4]	王宏亮, 罗冉, 刘夕奇, 雷乐乐, 翁磊, 吴龙骥. 动水冲刷对水泥注浆材料力学性能的影响[J]. 硅酸盐通报, 2025, 44(2): 417-423.
[5]	冯沛洋, 方强, 张华刚, 喻涛, 杨娇娇, 宁攀. 木屑-氯氧镁水泥复合材料力学性能及损伤本构模型研究[J]. 硅酸盐通报, 2025, 44(2): 434-446.
[6]	杨旭清, 王辉, 高尚, 郭美丽, 孟泽浩, 武越宇. 高温作用对粉煤灰-矿渣基多孔地聚合物性能的影响[J]. 硅酸盐通报, 2025, 44(2): 561-568.
[7]	黄梓谕, 丁之尧, 曹丹, 沈锭, 姚瞬雨, 陈益人, 任衍增, 包申旭. 基于响应面法的多固废基地聚合物配比优化及其表征[J]. 硅酸盐通报, 2025, 44(2): 569-578.
[8]	李相国, 龚志雄, 马伟男, 李树国, 张呈山, 但建明, 吕阳. 多源固废基高贝利特铁铝酸盐水泥的制备及其性能[J]. 硅酸盐通报, 2025, 44(2): 579-589.
[9]	胡传奇, 王功, 李珊, 靳宝杰, 刘兵山, 洪义强, 戴珍, 汪体园, 王爽. 光固化3D打印C_sf/SiC坯体的显微结构与力学性能[J]. 硅酸盐通报, 2025, 44(2): 666-678.
[10]	关宏信, 张海翔, 杨海荣, 杨飞, 郑天一. 水泥生物酶复合固化红砂岩土的力学与耐久性能[J]. 硅酸盐通报, 2025, 44(2): 765-773.
[11]	张金龙, 唐孟雄, 衷从浩, 胡家兵, 邵强, 钟开红. 纳米C-S-H晶核早强剂对水泥早期水化的影响[J]. 硅酸盐通报, 2025, 44(1): 21-30.
[12]	张艳, 谢建斌, 王大富, 李克努, 杨乐, 陈自敏. 不同掺合料对水泥基复合材料吸波性能的影响[J]. 硅酸盐通报, 2025, 44(1): 49-58.
[13]	纪璐鑫, 马红瑞, 马哲洋, 王胜, 崔嘉铭, 巴明芳. 二次铝灰烧结渣料对高强混凝土力学性能和收缩性能的影响[J]. 硅酸盐通报, 2025, 44(1): 212-222.
[14]	楚留声, 杜飞翔, 田野, 元成方, 程站起. 物理激发后再生砖粉ECC的力学性能及微观结构[J]. 硅酸盐通报, 2025, 44(1): 253-263.
[15]	马晓亮, 汪桂根, 张孟予, 赵宝军, 钟业盛, 史丽萍, 赫晓东. 莫来石晶须增强硅酸铝纤维复合材料的制备与性能研究[J]. 硅酸盐通报, 2025, 44(1): 321-331.