不同掺合料对水泥基复合材料吸波性能的影响

doi:10.16552/j.cnki.issn1001-1625.2024.0718

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (1): 49-58.DOI: 10.16552/j.cnki.issn1001-1625.2024.0718

不同掺合料对水泥基复合材料吸波性能的影响

张艳¹, 谢建斌^1,2, 王大富¹, 李克努¹, 杨乐¹, 陈自敏¹

1.云南大学建筑与规划学院,昆明 650500;
2.昆明军龙岩土工程有限公司,昆明 650214

收稿日期:2024-06-24 修订日期:2024-08-19 出版日期:2025-01-15 发布日期:2025-01-23
通信作者: 谢建斌,博士,教授。E-mail:kmxiejb@sina.com
作者简介:张艳(1996—),女,硕士研究生。主要从事建筑功能材料的研究。E-mail:overline999@163.com
基金资助:
云南大学推荐免试研究生科研创新项目(TM-23237056);云南大学校级重点科研创新项目(ZC-23233900)

Effects of Different Dopants on Wave-Absorbing Properties of Cement-Based Composites

ZHANG Yan¹, XIE Jianbin^1,2, WANG Dafu¹, LI Kenu¹, YANG Le¹, CHEN Zimin¹

1. School of Architecture and Planning, Yunnan University, Kunming 650500, China;
2. Kunming Junlong Geotechnical Engineering Co., Ltd., Kunming 650214, China

Received:2024-06-24 Revised:2024-08-19 Published:2025-01-15 Online:2025-01-23

摘要/Abstract

摘要： 向水泥中掺入合适的吸波剂并进行适当的电磁改性是实现电磁波吸收的有效途径。本文以矿渣、石墨、铁氧体为吸波剂制备水泥基复合材料,通过力学性能测试、微观结构测试、反射率测试探究不同掺合料和试样厚度对复合材料吸波性能和力学性能的影响。结果表明:当矿渣掺量为30%(质量分数)、石墨掺量为5%(质量分数)时,复合材料的吸波性能最好,且存在最佳匹配层厚度,当厚度为36 mm时,复合材料在2.65 GHz处反射率为-40.84 dB;当矿渣掺量为30%、铁氧体掺量为10%(质量分数)、匹配层厚度为36 mm时,复合材料在2.53 GHz处有最低反射率,为-26.63 dB;矿渣和铁氧体均会降低复合材料的强度,石墨(掺量不超过5%时)在水泥水化早期能够填充在砂浆孔隙中,从而提高了水泥基复合吸波材料早期的力学性能。

关键词: 水泥基复合材料, 矿渣, 石墨, 铁氧体, 力学性能, 吸波性能

Abstract: Incorporating suitable wave-absorbing agents into cement and performing appropriate electromagnetic modification is an effective way to realize electromagnetic wave-absorbing. In this paper, cement-based composites were prepared with slag, graphite and ferrite as wave-absorbing agents, and mechanical property test, microstructure test and reflectance test were carried out to investigate the effects of different dopants and sample thickness on the wave-absorbing properties and mechanical properties of cement-based composites. The results show that the cement-based composites have the best wave-absorbing performance when the doping of slag is 30% (mass fraction) and graphite is 5% (mass fraction), and there exists the best matching layer thickness. The reflection loss is -40.84 dB at 2.65 GHz when the thickness is 36 mm. When the cement-based composite is composed of 30% slag, 10% (mass fraction) ferrite, and the matching layer thickness is 36 mm, the cement-based composites have the lowest reflectivity of -26.63 dB at 2.53 GHz. Both slag and ferrite reduce the strength of cement-based composites, and graphite (no more than 5%) is able to fill in mortar pores at the early stage of cement hydration, which enhances early mechanical properties.

Key words: cement-based composite, slag, graphite, ferrite, mechanical property, absorbing property

中图分类号:

TU528

张艳, 谢建斌, 王大富, 李克努, 杨乐, 陈自敏. 不同掺合料对水泥基复合材料吸波性能的影响[J]. 硅酸盐通报, 2025, 44(1): 49-58.

ZHANG Yan, XIE Jianbin, WANG Dafu, LI Kenu, YANG Le, CHEN Zimin. Effects of Different Dopants on Wave-Absorbing Properties of Cement-Based Composites[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(1): 49-58.

参考文献

[1] XING C, HAO Y, XIA A, et al. Polypyrrole/Fe₃O₄ nanocomposites anchored on graphene toward efficient electromagnetic wave absorption performance[J]. Synthetic Metals, 2024, 306: 117628.
[2] STEFANIUK D, SOBÓTKA M, JARCZEWSKA K, et al. Microstructure properties of cementitious mortars with selected additives for electromagnetic waves absorbing applications[J]. Cement and Concrete Composites, 2022, 134: 104732.
[3] SHI Y, JING H, LIU B, et al. Electromagnetic (EM) wave absorption properties of cementitious building composites containing MnZn ferrite: preferable effective bandwidth and thickness via iron and graphite addition[J]. Journal of Magnetism and Magnetic Materials, 2022, 560: 169555.
[4] LIU H, YANG Q, XIAO H, et al. Influence and mechanism of ultra-high molecular weight polyethylene on mechanical and electromagnetic shielding properties of alkali-activated composite mortar based on magnesium slag, blast-furnace slag and silica fume[J]. Journal of Environmental Chemical Engineering, 2024, 12(2): 112437.
[5] 魏胜斌, 谢建斌, 管洪涛, 等.复合石墨烯-铁氧体砂浆电磁防护性能研究[J/OL]. 建筑材料学报, 1-13(2023-05-05)[2024-06-11].http://kns.cnki.net/kcms/detail/31.1764.tu.20230602.1831.028.html.
WEI S B, XIE J B, GUAN H T, et al. Research on electromagnetic protection performance of composite graphene-ferrite mortar[J/OL]. Journal of Building Materials, 1-13(2023-05-05) [2024-06-11]. http://kns.cnki.net/kcms/detail/31.1764.tu.20230602.1831.028.html (in Chinese).
[6] 张秀芝, 孙伟, 赵俊峰. 铁氧体粉掺量对水泥基材料吸波性能和力学性能的影响[J]. 解放军理工大学学报(自然科学版), 2011, 12(5): 466-471.
ZHANG X Z, SUN W, ZHAO J F. Effects of ferrite powder doping on wave absorption and mechanical properties of cementitious materials[J]. Journal of PLA University of Technology (Natural Science Edition), 2011, 12(5): 466-471 (in Chinese).
[7] 肖万. 矿渣微细粉对水泥基材料性能及水化进程影响的研究[D]. 北京: 中国地质大学(北京), 2013.
XIAO W. Study on the effect of slag microfine powder on the properties and hydration process of cementitious materials[D]. Beijing: China University of Geosciences (Beijing), 2013 (in Chinese).
[8] 倪梦然, 张超智, 高蕾. 石墨烯基吸波材料的研究进展[J]. 南京大学学报(自然科学), 2022, 58(3): 540-559.
NI M R, ZHANG C Z, GAO L. Research progress of graphene-based wave-absorbing materials[J]. Journal of Nanjing University (Natural Science), 2022, 58(3): 540-559 (in Chinese).
[9] 杨国栋, 苑高千, 张竞哲, 等. 多孔电磁波吸收材料[J]. 化学进展, 2023, 35(3): 445-457.
YANG G D, YUAN G Q, ZHANG J Z, et al. Porous electromagnetic wave absorbing materials[J]. Advances in Chemistry, 2023, 35(3): 445-457 (in Chinese).
[10] 张月芳. 纤维增强水泥基电磁波吸收材料制备及性能[D]. 大连: 大连理工大学, 2018.
ZHANG Y F. Preparation and properties of fiber-reinforced cement-based electromagnetic wave absorbing materials [D]. Dalian: Dalian University of Technology, 2018 (in Chinese).
[11] FAROOQ I, ISLAM M U, DANISH M, et al. Synergistic effects of Li-based ferrite and graphene oxide in microwave absorption applications[J]. Synthetic Metals, 2024: 117674.
[12] 马海晶, 王增奎, 潘昊, 等. 膨胀石墨/聚苯胺原位复合材料导电性能研究[J]. 化工新型材料, 2011, 39(9): 78-80+117.
MA H J, WANG Z K, PAN H, et al. Study on the electrical conductivity of expanded graphite/polyaniline in-situ composites[J]. New Chemical Materials, 2011, 39(9): 78-80+117 (in Chinese).
[13] 刘保荣, 黄智斌, 罗发, 等. 碳/氧化铝/二氧化硅涂层的介电和吸波性能研究[J]. 无机材料学报, 2012, 27(8): 817-821.
LIU B R, HUANG Z B, LUO F, et al. Study on dielectric and wave-absorbing properties of carbon/alumina/silica coatings[J]. Journal of Inorganic Materials, 2012, 27(8): 817-821 (in Chinese).
[14] QIN M, ZHANG L, WU H. Dielectric loss mechanism in electromagnetic wave absorbing materials[J]. Advanced Science, 2022, 9(10): 2105553.
[15] SAOTOME H, AZUMA K, KIZUKA H, et al. Properties of dynamic magnetic loss of ferrite[J]. AIP Advances, 2018, 8(5): 1157.
[16] 贾兴文, 张亚杰, 钱觉时, 等. 石墨泡沫混凝土的吸波性能研究[J]. 功能材料, 2012, 43(17): 2397-2400.
JIA X W, ZHANG Y J, QIAN J S, et al. Study on the wave-absorbing properties of graphite foam concrete[J]. Functional Materials, 2012, 43(17): 2397-2400 (in Chinese).
[17] ZHAO Y, WANG W, WANG J, et al. Constructing multiple heterogeneous interfaces in the composite of bimetallic MOF-derivatives and rGO for excellent microwave absorption performance[J]. Carbon, 2021, 173: 1059-1072.

不同掺合料对水泥基复合材料吸波性能的影响

Effects of Different Dopants on Wave-Absorbing Properties of Cement-Based Composites

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	韩子默, 杨国梁, 李峰, 张志飞, 毕京九, 赵康朴, 刘依. 动态荷载下聚乙烯醇纤维混凝土阻裂性能试验研究[J]. 硅酸盐通报, 2025, 44(1): 59-68.
[2]	杨思宇, 黄文, 赵佳琪, 章文明, 王雷, 王剑锋. 矿渣水化与活化研究现状[J]. 硅酸盐通报, 2025, 44(1): 169-179.
[3]	纪璐鑫, 马红瑞, 马哲洋, 王胜, 崔嘉铭, 巴明芳. 二次铝灰烧结渣料对高强混凝土力学性能和收缩性能的影响[J]. 硅酸盐通报, 2025, 44(1): 212-222.
[4]	楚留声, 杜飞翔, 田野, 元成方, 程站起. 物理激发后再生砖粉ECC的力学性能及微观结构[J]. 硅酸盐通报, 2025, 44(1): 253-263.
[5]	李琪, 王亮, 王浩, 王成龙, 徐建, 胡伟. 碳化再生微粉对碱激发矿渣材料的影响[J]. 硅酸盐通报, 2025, 44(1): 289-296.
[6]	马晓亮, 汪桂根, 张孟予, 赵宝军, 钟业盛, 史丽萍, 赫晓东. 莫来石晶须增强硅酸铝纤维复合材料的制备与性能研究[J]. 硅酸盐通报, 2025, 44(1): 321-331.
[7]	陈宇, 宋学伟, 吴佳梁. 抗收缩ECC单轴拉压力学性能及损伤本构模型[J]. 硅酸盐通报, 2024, 43(9): 3137-3148.
[8]	赵国庆, 杨进波, 尹航. C-S-H凝胶无定型纳米孔隙中NaCl蒸发结晶分子动力学分析[J]. 硅酸盐通报, 2024, 43(9): 3173-3181.
[9]	赵燕茹, 龙思睿, 白建文, 刘明. 高温后风积沙混凝土力学性能与微观结构试验研究[J]. 硅酸盐通报, 2024, 43(9): 3182-3191.
[10]	张震洋, 张璐, 伊海赫, 郑润, 马克顺, 张琳, 任梦琪, 王春光. 基于响应面法的地聚物混凝土力学性能试验研究[J]. 硅酸盐通报, 2024, 43(9): 3192-3202.
[11]	王萧萧, 董培森, 杨鑫瑞, 张菊, 闫长旺, 董宇飞. 低温作用下钢纤维地聚合物混凝土力学性能研究[J]. 硅酸盐通报, 2024, 43(9): 3203-3213.
[12]	黄斌, 龚明子, 潘阿馨, 饶先鹏, 王涛, 陈晨, 黄伟. 减水剂与钢纤维对超高性能混凝土流变及力学性能的影响[J]. 硅酸盐通报, 2024, 43(9): 3214-3223.
[13]	王浩, 谭盐宾, 刘星, 杨鲁, 元强, 谢斌福, 刘博. 火成岩质矿物材料对混凝土性能的影响[J]. 硅酸盐通报, 2024, 43(9): 3244-3251.
[14]	李艳艳, 杜晓丽, 王浩伟, 徐锴. 硅灰-聚丙烯纤维双掺混凝土的动静态力学性能[J]. 硅酸盐通报, 2024, 43(9): 3320-3329.
[15]	崔莹莹, 何健辉, 吕民望, 杨露, 刘云鹏. 可完全循环水泥砂浆配料制备贝利特水泥熟料的性能研究[J]. 硅酸盐通报, 2024, 43(9): 3348-3358.