纳米纤丝制备及其对油井水泥浆抗水侵性能的影响

doi:10.16552/j.cnki.issn1001-1625.2024.0379

硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (1): 40-48.DOI: 10.16552/j.cnki.issn1001-1625.2024.0379

纳米纤丝制备及其对油井水泥浆抗水侵性能的影响

马疆¹, 唐文丽², 宋会光¹, 刘开强^2,3, 邓林¹, 裴雪峰¹, 张兴国³

1.中国石油集团西部钻探工程有限公司工程技术研究院,克拉玛依 834000;
2.西南石油大学新能源与材料学院,成都 610500;
3.西南石油大学油气藏地质及开发工程全国重点实验室,成都 610500

收稿日期:2024-03-28 修订日期:2024-10-11 出版日期:2025-01-15 发布日期:2025-01-23
通信作者: 刘开强,博士,副教授。E-mail:kaiqiangliu@swpu.edu.cn
作者简介:马疆(1979—),男,高级工程师。主要从事固井外加剂及水泥浆体系的研究。E-mail:sasmajiang@163.com
基金资助:
国家自然科学基金青年基金(52104007);全国重点实验室开放基金(PLN2023-35)

Preparation of Nanofiber and Its Effect on Water Invasion Resistance of Oil Well Cement Paste

MA Jiang¹, TANG Wenli², SONG Huiguang¹, LIU Kaiqiang^2,3, DENG Lin¹, PEI Xuefeng¹, ZHANG Xingguo³

1. Engineering Technology Research Institute of China Petroleum Western Drilling Engineering Co., Ltd, Karamay 834000, China;
2. School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China;
3. National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, China

Received:2024-03-28 Revised:2024-10-11 Published:2025-01-15 Online:2025-01-23

摘要/Abstract

摘要： 针对油田特高含水期原油采出率低以及聚合物抗水侵处理剂会降低水泥浆早期水化速率、降低高压含水地层固井质量的问题,以纤维素纤维为原料,结合湿式超细球磨和2,2,6,6-四甲基哌啶氧化物(TEMPO)氧化法制备纳米纤丝作为新型抗水侵处理剂,研究了纳米纤丝对水泥浆流变性、稠化时间、抗压强度以及抗水侵性能的影响。结果表明,纳米纤丝对水泥浆具有增黏以及促进水泥水化的效果。当水泥浆中纳米纤丝质量分数增至0.2%时,水泥浆流性指数由0.849降低至0.557,屈服应力由2.305 Pa增至10.061 Pa,稠化时间由260 min缩短至219 min,14 d抗压强度由26.8 MPa增至41.0 MPa。纳米纤丝通过吸附及桥接等作用提升了水泥浆内聚力,通过改变早期水化产物形核位置增加了水泥早期水化速率与抗压强度,有利于提高水泥石与地层岩石的胶结能力及固井质量。

关键词: 纳米纤丝, 油井水泥, 高含水地层, 固井, 抗水侵性能

Abstract: Aiming at the problems that the oil-recovery-efficiency of oilfield in very high water-cut stage is low and polymer water invasion resistance agents reduce the early hydration rate of cement paste and cementing quality of high-pressure water-cut stratum, this study was carried out to prepare nanofiber as a new type of water invasion resistance agent using plant cellulose fibers combining wet ultrafine ball milling and 2,2,6,6-tetramethylpiperidine oxide (TEMPO) oxidation methods. The effect of nanofiber on the rheological properties, consistency time, compressive strength and water invasion resistance of cement paste was investigated. The results show that the nanofiber have the effects of increasing viscosity and promoting early hydration of cement paste. When the mass fraction of nanofiber increases to 0.2%, the liquidity index of cement paste decreases from 0.849 to 0.557, the yield stress increases from 2.305 Pa to 10.061 Pa, the consistency time slightly reduces from 260 min to 219 min, and the 14 d compressive strength improves from 26.8 MPa to 41.0 MPa. The nanofiber could enhance the cohesion of cement paste by bridging and adsorption, and increase the hydration rate and early compressive strength of cement by changing nucleation site, which is beneficial for improving the bonding quality between cement stone and stratum rocks and cementing quality.

Key words: nanofiber, oil well cement, high water-cut stratum, cementing, water invasion resistance

中图分类号:

TQ172

马疆, 唐文丽, 宋会光, 刘开强, 邓林, 裴雪峰, 张兴国. 纳米纤丝制备及其对油井水泥浆抗水侵性能的影响[J]. 硅酸盐通报, 2025, 44(1): 40-48.

MA Jiang, TANG Wenli, SONG Huiguang, LIU Kaiqiang, DENG Lin, PEI Xuefeng, ZHANG Xingguo. Preparation of Nanofiber and Its Effect on Water Invasion Resistance of Oil Well Cement Paste[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(1): 40-48.

参考文献

[1] 孙龙德, 刘合, 孙焕泉, 等. 中国高含水老油田可持续发展战略[M]. 北京: 石油工业出版社, 2023.
SUN L D, L H, SUN H Q, et al. Sustainable development strategy of high water cut old oilfields in China[M]. Beijing: Petroleum Industry Press, 2023 (in Chinese).
[2] 王海滨, 刘开强, 廖兴松, 等. 大港油田段六拔区块调整井固井技术[J]. 石油钻采工艺, 2016, 38(2): 166-170.
WANG H B, LIU K Q, LIAO X S, et al. Cementing technology of adjustment wells in Duanliuba of Dagang Oilfield[J]. Oil Drilling & Production Technology, 2016, 38(2): 166-170 (in Chinese).
[3] 刘开强, 赵殊勋, 李炜, 等. 提高固井第二界面质量的技术研究与应用[J]. 油田化学, 2018, 35(1): 16-21.
LIU K Q, ZHAO S X, LI W, et al. Research and application on improving the cementing quality of second-interface[J]. Oilfield Chemistry, 2018, 35(1): 16-21 (in Chinese).
[4] 张兴国, 袁中涛, 李永刚, 等. 水侵压力对调整井固井二界面性能的影响[J]. 硅酸盐通报, 2018, 37(11): 3678-3683.
ZHANG X G, YUAN Z T, LI Y G, et al. Effect of the water intrusion pressure on two interface of adjusting the well cementing[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(11): 3678-3683 (in Chinese).
[5] 刘开强, 于骏杰, 王海平, 等. 地层渗流水对凝固过程固井水泥浆的侵扰机理[J/OL]. 材料导报, 1-14(2024-01-06)[2024-11-27]. http://kns.cnki.net/kcms/detail/50.1078.TB.20240116.1025.004.html.
LIU K Q, YU J J, WANG H P, et al. The invasion mechanism of formation seepage water on cementing cement slurry during solidification process[J/OL]. Materials Reports, 1-14(2024-01-06)[2024-11-27]. http://kns.cnki.net/kcms/detail/50.1078.TB.20240116.1025.004.html (in Chinese).
[6] RAMIREZ H B, SANTRA A, MARTINEZ C, et al. Water-gas migration control and mechanical properties comparison with a quick-setting slurry design QSSD to be applied in a production cementing job for ecuador[C]//Cartagena de Indias, Colombia, 2009.
[7] 李治衡, 张晓诚, 董平华, 等. 调整井固井用聚合物型抗水侵材料的制备及其性能评价[J]. 化工进展, 2021, 40(3): 1565-1573.
LI Z H, ZHANG X C, DONG P H, et al. Preparation and performance evaluation of polymer anti water invasion material for adjustment well cementing[J]. Chemical Industry and Engineering Progress, 2021, 40(3): 1565-1573 (in Chinese).
[8] 辛海鹏, 吴达华, 张明辉, 等. 固井用防水窜自愈合剂的探索[J]. 钻井液与完井液, 2020, 37(2): 221-225.
XIN H P, WU D H, ZHANG M H, et al. Explore and study on well cementing anti-water-channeling self-healing agent[J]. Drilling Fluid & Completion Fluid, 2020, 37(2): 221-225 (in Chinese).
[9] 王建瑶, 涂思琪, 梅明佳, 等. 水不分散水泥浆的机理探讨与性能评价[J]. 钻井液与完井液, 2020, 37(3): 358-362.
WANG J Y, TU S Q, MEI M J, et al. Mechanism investigation and performance evaluation of water indispersible cement slurries[J]. Drilling Fluid & Completion Fluid, 2020, 37(3): 358-362 (in Chinese).
[10] 李成, 张谦, 刘欢. 动态压力固井用疏水缔合聚合物防窜剂的合成与性能[J]. 合成化学, 2020, 28(8): 722-727.
LI C, ZHANG Q, LIU H. Synthsis and performance of hydrophobically associating polymer anti channeling agent for dynamic pressure cementing[J]. Chinese Journal of Synthetic Chemistry, 2020, 28(8): 722-727 (in Chinese).
[11] FENG Q, YANG X, PENG Z G, et al. Preparation and performance evaluation of hydrophobically associating polymer anti-water channeling agent for oil well cement[J]. Cement and Concrete Research, 2021, 138(24): 1-13.
[12] SUN X X, WU Q L, ZHANG J L, et al. Rheology, curing temperature and mechanical performance of oil well cement: combined effect of cellulose nanofibers and graphene nano-platelets[J]. Materials & Design, 2017, 114: 92-101.
[13] NASSIRI S, CHEN Z, JIAN G Q, et al. Comparison of unique effects of two contrasting types of cellulose nanomaterials on setting time, rheology, and compressive strength of cement paste[J]. Cement and Concrete Composites, 2021, 123: 104201.
[14] GWON S, SHIN M. Rheological properties of cement pastes with cellulose microfibers[J]. Journal of Materials Research and Technology, 2021, 10: 808-818.
[15] HOYOS C G, ZULUAGA R, GAÑÁN P, et al. Cellulose nanofibrils extracted from fique fibers as bio-based cement additive[J]. Journal of Cleaner Production, 2019, 235: 1540-1548.
[16] GONCALVES J, BOLUK Y, BINDIGANAVILE V. Turbidity-based measurement of bleeding in fresh cement paste as affected by cellulose nanofibers[J]. Cement and Concrete Composites, 2021, 123: 104197.
[17] 陈欢, 钟洪浩, 王鲁峰. TEMPO氧化-高压均质联用制备柑橘纳米纤维素及其性质表征[J]. 食品科学技术学报, 2022, 40(4): 35-44.
CHEN H, ZHONG H H, WANG L F. Preparation of citrus nanofibers by TEMPO oxidation-high pressure homogenization and its characterization[J]. Journal of Food Science and Technology, 2022, 40(4): 35-44 (in Chinese).
[18] YANG M, LUO H, XIE R X, et al. Estimating and optimizing wellbore pressure during primary cementing in low pressure and leakage formations[J]. Journal of Petroleum Science and Engineering, 2022, 208: 109236.
[19] 卢海川, 赵岳, 宋伟宾, 等. 新型固井用防水窜材料的研究与性能评价[J]. 钻井液与完井液, 2017, 34(4): 75-79.
LU H C, ZHAO Y, SONG W B, et al. Research and performance evaluation of new waterproof channeling materials for cementing[J]. Drilling fluid and completion fluid, 2017, 34(4): 75-79 (in Chinese).
[20] 孔祥明, 卢子臣, 张朝阳. 水泥水化机理及聚合物外加剂对水泥水化影响的研究进展[J]. 硅酸盐学报, 2017, 45(2): 274-281.
KONG X M, LU Z C, ZHANG C Y. Recent development on understanding cement hydration mechanism and effects of chemical admixtures on cement hydration[J]. Journal of the Chinese Ceramic Society, 2017, 45(2): 274-281 (in Chinese).
[21] LOWKE D, GEHLEN C. The Zeta potential of cement and additions in cementitious suspensions with high solid fraction[J]. Cement and Concrete Research, 2017, 95: 195-204.

纳米纤丝制备及其对油井水泥浆抗水侵性能的影响

Preparation of Nanofiber and Its Effect on Water Invasion Resistance of Oil Well Cement Paste

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	周剑峰, 杨涛, 张菁燕, 周文平, 高璇. 早期水热养护对铝酸钙水泥结构稳定性的影响[J]. 硅酸盐通报, 2023, 42(3): 802-807.
[2]	师伟, 龚泽相, 刘开强, 马疆, 王军, 代红, 邓林. 铝酸钙水泥-矿渣体系的CO₂腐蚀行为及微观结构研究[J]. 硅酸盐通报, 2023, 42(10): 3695-3702.
[3]	李成, 耿晨梓, 代丹, 王春雨, 宋维凯, 姚晓. 废弃玻璃粉对水泥石高温抗压强度和微观结构的影响[J]. 硅酸盐通报, 2022, 41(9): 3219-3226.
[4]	倪修成, 程小伟, 黎俊吾, 王晶, 高显束, 张高寅, 张春梅, 刘开强. 新型油井水泥物相组成调控及力学性能研究[J]. 硅酸盐通报, 2021, 40(8): 2534-2545.
[5]	郑冠一;郭小阳;李早元;赵军;王希勇;罗德明. 基于分形理论的高温固井水泥浆体系设计及评价[J]. 硅酸盐通报, 2020, 39(6): 1742-1750.
[6]	王胜翔;张易航;林枫;许明标;杨培龙;王浪. 自愈合油井水泥研究进展[J]. 硅酸盐通报, 2020, 39(5): 1377-1383.
[7]	程小伟;余杨;张曲;黄坤;张军;谢盛;张高寅;张春梅;黄盛;刘开强. 新型螯合物型缓凝剂的合成与性能研究[J]. 硅酸盐通报, 2020, 39(11): 3683-3690.
[8]	刘慧婷;付家文;丛谧;陈艺鑫;李志芳. 高强度低密度水泥石的微观结构和力学性能[J]. 硅酸盐通报, 2020, 39(11): 3432-3437.
[9]	李延伟. 聚羧酸超塑化剂与纳米SiO2颗粒协同作用对固井水泥浆性能的影响[J]. 硅酸盐通报, 2020, 39(10): 3121-3125.
[10]	王涛, 吴金桥, 李伟, 杨先伦, 王波. 高水灰比高掺量粉煤灰环保型低成本固井水泥浆的研制[J]. 硅酸盐通报, 2019, 38(7): 2260-2267.
[11]	刘鉴增;刘硕琼;刘慧婷. 纳米压痕研究碳纳米管固井水泥石微观力学性能[J]. 硅酸盐通报, 2019, 38(4): 1263-126.
[12]	张毅;陈东;邓钧耀;张慧;胡千红;王鼎. 煤层气低温早强低密度水泥浆体系研究[J]. 硅酸盐通报, 2019, 38(11): 3681-368.
[13]	窦倩;王涛;张书勤;王珊珊;张新庄. 碳纳米管固井水泥复合材料抗腐蚀及力学性能研究[J]. 硅酸盐通报, 2019, 38(11): 3703-371.
[14]	吴宇萌;许明标;宋建建;王晓亮;周俊. 碳纤维与胶乳液协同作用对固井水泥浆力学性能的影响[J]. 硅酸盐通报, 2019, 38(1): 253-258.
[15]	李早元;祁凌;辜涛;孙劲飞;郭小阳. 微米与纳米级CaCO3对油井水泥石酸溶特性的影响[J]. 硅酸盐通报, 2018, 37(8): 2576-2582.