气藏型低密度陶粒支撑剂的制备与性能研究

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (2): 673-681.

所属专题：陶瓷

气藏型低密度陶粒支撑剂的制备与性能研究

邢莉¹, 孙晓思¹, 白频波², 王凯悦³, 田玉明³

1.山西工程职业学院,太原 030001;
2.阳泉市长青石油压裂支撑剂有限公司,阳泉 045200;
3.太原科技大学材料科学与工程学院,太原 030024

收稿日期:2023-09-18 修订日期:2023-11-21 出版日期:2024-02-15 发布日期:2024-02-05
通信作者: 孙晓思,副教授。E-mail:sxs8696@163.com
作者简介:邢莉(1988—),女。主要从事结构陶瓷及复合材料方面的研究。E-mail:13682151139@163.com
基金资助:
晋城市重点研发项目(20220102);阳泉市科技重大专项(2022JH004);教育部高等学校科学研究发展中心《虚拟仿真技术在职业教育教学中的创新应用》专项课题(ZJXF2022070)

Preparation and Performance of Gas Reservoir Ceramic Proppant with Low Density

XING Li¹, SUN Xiaosi¹, BAI Pinbo², WANG Kaiyue³, TIAN Yuming³

1. Shanxi Engineering Vocational College, Taiyuan 030001, China;
2. Changqing Fracturing Proppant Co., Ltd., Yangquan 045200, China;
3. School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China

Received:2023-09-18 Revised:2023-11-21 Online:2024-02-15 Published:2024-02-05

摘要/Abstract

摘要： 在开采煤层气、页岩气等气藏资源过程中,陶粒支撑剂的产品性能尤为关键,合成密度小、强度高的支撑剂是实现气藏高产率的重要指标。本文在传统矾土系陶粒支撑剂的基础上,添加煤矸石(RCG)、羧甲基纤维素钠(CMC)和白云石(DOL)进行固相烧结,借助以上造孔剂多温区的热解作用以及高温液相快速填充机制改善支撑剂的基体孔隙分布特征,降低支撑剂的结构密度并提升基体强度。当掺入质量分数为15%RCG+1%CMC+1%DOL添加剂时,支撑剂表现出最佳的综合性能并满足气藏资源开采的参数要求。

关键词: 气藏开采, 陶粒支撑剂, 多元造孔剂, 结构密度, 破碎率, 固相烧结

Abstract: In the process of extracting coalbed methane, shale gas and other gas reservoir resources, the product performance of ceramic proppants is particularly crucial. Low synthetic density and high strength of proppant are important indicators for achieving high gas reservoir productivity. On the basis of traditional ceramic proppants, by adding raw coal gangue (RCG), sodium carboxymethyl cellulose (CMC), and dolomite (DOL) for solid state sintering, the matrix pore distribution characteristics of the proppants were improved, the structural density of the proppants was reduced, and the matrix strength was enhanced, with the help of the multi temperature pyrolysis effect of the pore forming agents and the high-temperature liquid phase rapid filling mechanism. When a mass fraction of 15%RCG+1%CMC+1%DOL additive is added, the proppant exhibits the best comprehensive performance and meets the parameter requirements for gas reservoir resource extraction.

Key words: gas reservoir production, ceramic proppant, multi-pore former, structural density, breakage rate, solid state sintering

中图分类号:

TQ174.75

邢莉, 孙晓思, 白频波, 王凯悦, 田玉明. 气藏型低密度陶粒支撑剂的制备与性能研究[J]. 硅酸盐通报, 2024, 43(2): 673-681.

XING Li, SUN Xiaosi, BAI Pinbo, WANG Kaiyue, TIAN Yuming. Preparation and Performance of Gas Reservoir Ceramic Proppant with Low Density[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 673-681.

参考文献

[1] 田玉明, 朱保顺, 力国民, 等. 煤矸石掺量对陶粒支撑剂性能的影响[J]. 硅酸盐学报, 2019, 47(3): 365-369.
TIAN Y M, ZHU B S, LI G M, et al. Influence of coal gangue amount on properties of ceramic proppants[J]. Journal of the Chinese Ceramic Society, 2019, 47(3): 365-369 (in Chinese).
[2] 赵学松, 刘琦. 煤基固体废弃物制备压裂支撑剂研究进展[J]. 洁净煤技术, 2023, 29(6): 161-172.
ZHAO X S, LIU Q. Review on the preparation of fracturing proppant from coal-based solid waste[J]. Clean Coal Technology, 2023, 29(6): 161-172 (in Chinese).
[3] 王云珠. 山西能源体制机制改革重点任务研究[J]. 煤炭经济研究, 2018, 38(4): 37-43.
WANG Y Z. Research on key tasks of Shanxi energy system mechanism reform[J]. Coal Economic Research, 2018, 38(4): 37-43 (in Chinese).
[4] 胡志中. 山西开启由“黑”变“绿”能源革命[J]. 能源研究与利用, 2019(5): 4-6.
HU Z Z. Shanxi opens energy revolution from “black” to “green”[J]. Energy Research & Utilization, 2019(5): 4-6 (in Chinese).
[5] 国家能源局. 水力压裂和砾石充填作业用支撑剂性能测试方法: SY/T 5108—2014[S]. 北京: 石油工业出版社, 2015.
National Energy Administration. Performance testing method for proppants used in hydraulic fracturing and gravel filling operations: SY/T 5108—2014[S]. Beijing: Petroleum Industry Press, 2015 (in Chinese).
[6] 罗啸. 深层页岩气大型压裂工艺技术研究[D]. 成都: 西南石油大学, 2018.
LUO X. Study on large-scale fracturing technology of deep shale gas[D]. Chengdu: Southwest Petroleum University, 2018 (in Chinese).
[7] 赵金洲, 王松, 李勇明. 页岩气藏压裂改造难点与技术关键[J]. 天然气工业, 2012, 32(4): 46-49+122.
ZHAO J Z, WANG S, LI Y M. Difficulties and key techniques in the fracturing treatment of shale gas reservoirs[J]. Natural Gas Industry, 2012, 32(4): 46-49+122 (in Chinese).
[8] 张东晓, 杨婷云. 页岩气开发综述[J]. 石油学报, 2013, 34(4): 792-801.
ZHANG D X, YANG T Y. An overview of shale-gas production[J]. Acta Petrolei Sinica, 2013, 34(4): 792-801 (in Chinese).
[9] 王一可. 页岩气勘探开发技术综述[J]. 石油知识, 2019(2): 42-43.
WANG Y K. Summary of shale gas exploration and development technology[J]. Petroleum Knowledge, 2019(2): 42-43 (in Chinese).
[10] 刘春杰, 王莹, 范利华, 等. 矸石山自燃的成因分析及防治措施[J]. 煤炭技术, 2006, 25(11): 3-6.
LIU C J, WANG Y, FAN L H, et al. Analysis on the reason of gangue mountain spontaneous combustion and measure in prevention and cure[J]. Coal Technology, 2006, 25(11): 3-6 (in Chinese).
[11] 宋学磊. 利用工业固体废料制备石油压裂陶粒支撑剂的研究[D]. 济南: 齐鲁工业大学, 2019.
SONG X L. Study on preparation of ceramsite proppant for oil fracturing from industrial solid waste[D]. Jinan: Qilu University of Technology, 2019 (in Chinese).
[12] HAO J Y, HU T, CHENG G J, et al. Effect of feldspar milling on the properties of low-density ceramic proppants[J]. Materials Research Innovations, 2022, 26(1): 1-7.
[13] 赵紫石, 崔李鹏, 赵旭, 等. 利用固废煤矸石制备陶粒支撑剂的研究[J]. 山西煤炭, 2019, 39(1): 1-4.
ZHAO Z S, CUI L P, ZHAO X, et al. Preparation of ceramic proppant using solid waste coal gangue[J]. Shanxi Coal, 2019, 39(1): 1-4 (in Chinese).
[14] 孟凡生, 孙亚诺, 刘丽. 我国煤炭资源供给情景分析[J]. 中国能源, 2016, 38(1): 40-42.
MENG F S, SUN Y N, LIU L. Analysis of China's coal resource supply situation[J]. Energy of China, 2016, 38(1): 40-42 (in Chinese).
[15] 郑林会. 煤矸石基陶粒支撑剂的制备与性能研究[D]. 太原: 太原理工大学, 2019.
ZHENG L H. Preparation and properties of gangue-based ceramsite proppant[D]. Taiyuan: Taiyuan University of Technology, 2019 (in Chinese).
[16] HAO J Y, MA H Q, FENG X, et al. Low-temperature sintering of ceramic proppants by adding solid wastes[J]. International Journal of Applied Ceramic Technology, 2018, 15(2): 563-568.
[17] 孔祥辰, 白频波, 宋伟, 等. 煅烧煤矸石添加量对陶粒支撑剂力学性能的影响[J]. 硅酸盐通报, 2022, 41(6): 2039-2046.
KONG X C, BAI P B, SONG W, et al. Effect of calcined coal gangue addition on mechanical properties of ceramic proppant[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(6): 2039-2046 (in Chinese).
[18] XIE X K, NIU S X, MIAO Y, et al. Preparation and properties of resin coated ceramic proppants with ultra light weight and high strength from coal-series kaolin[J]. Applied Clay Science, 2019, 183: 105364.
[19] ZHAO X, ZHANG Z X, LI W X, et al. Basic principle, progress, and prospects of coal gangue ceramic proppants[J]. International Journal of Applied Ceramic Technology, 2023, 20(5): 2681-2699.
[20] FENG Y C, MA C Y, DENG J G, et al. A comprehensive review of ultralow-weight proppant technology[J]. Petroleum Science, 2021, 18(3): 807-826.
[21] SPEIGHT J G. Handbook of hydraulic fracturing[M]. Hoboken: Wiley, 2016.
[22] DING D H, FANG Y F, XIAO G Q, et al. Effects of sinteringtemperature on microstructure and properties of low-grade bauxite-based ceramic proppant[J]. International Journal of Applied Ceramic Technology, 2021, 18(5): 1832-1844.
[23] ABD EL-KADER M, ABDOU M I, FADL A M, et al. Novel light-weight glass-ceramic proppants based on frits for hydraulic fracturing process[J]. Ceramics International, 2020, 46(2): 1947-1953.
[24] 邱龙会, 王励生, 金作美. 钾长石矿热分解过程的研究[J]. 高等学校化学学报, 1998, 19(3): 345-349.
QIU L H, WANG L S, JIN Z M. Studies on the thermal dissociative process of microcline[J]. Chemical Research in Chinese Universities, 1998, 19(3): 345-349 (in Chinese).
[25] 陈勇, 于景坤, 高杰. 烧结温度对合成镁橄榄石性能的影响[J]. 硅酸盐通报, 2012, 31(3): 622-625.
CHEN Y, YU J K, GAO J. Effect of sinterring temperature on the properties of synthetic forsterite[J]. Bulletin of the Chinese Ceramic Society, 2012, 31(3): 622-625 (in Chinese).

气藏型低密度陶粒支撑剂的制备与性能研究

Preparation and Performance of Gas Reservoir Ceramic Proppant with Low Density

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