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硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (2): 666-672.

所属专题: 陶瓷

• 陶瓷 • 上一篇    下一篇

熔融石英陶瓷材料介电性能影响因素分析

崔唐茵1,2, 王鹏1,2,3, 刘瑞祥2, 王洪升2, 曹俊倡2, 陈东杰2   

  1. 1.山东理工大学材料科学与工程学院,淄博 255000;
    2.山东工业陶瓷研究设计院有限公司,淄博 255000;
    3.国防科技大学新型陶瓷纤维及其复合材料重点实验室,长沙 410073
  • 收稿日期:2023-08-15 修订日期:2023-10-23 出版日期:2024-02-15 发布日期:2024-02-05
  • 作者简介:崔唐茵(1980—),女,高级工程师。主要从事多频段高透波率陶瓷透波材料的设计与制备技术的研究。E-mail:2291355787@qq.com
  • 基金资助:
    山东省自然科学基金(ZR2023ME035,ZR2020ME027);国防科工局国防科技重点实验室稳定支持科研项目(WDZC20215250504);国家自然科学基金(51802176)

Analysis of Influencing Factors on Dielectric Properties of Fused Quartz Ceramics

CUI Tangyin1,2, WANG Peng1,2,3, LIU Ruixiang2, WANG Hongsheng2, CAO Junchang2, CHEN Dongjie2   

  1. 1. School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, China;
    2. Shandong Industrial Ceramic Research and Design Institute Co., Ltd., Zibo 255000, China;
    3. Key Laboratory of New Ceramic Fibers and Composites, National University of Defense Technology, Changsha 410073, China
  • Received:2023-08-15 Revised:2023-10-23 Online:2024-02-15 Published:2024-02-05

摘要: 采用凝胶注模成型工艺制备熔融石英陶瓷,通过XRD、SEM和电性能网络分析仪对陶瓷样品的晶体结构、微观形貌、介电性能进行分析,研究了熔融石英陶瓷介电性能的影响因素,为筛选制备石英陶瓷材料最优工艺方案提供依据。研究结果表明:材料制备工艺一定时,制备不同厚度的石英陶瓷板,平铺烧结,同一块方板沿垂直方向自上而下,密度逐渐下降,密度与介电常数呈正相关,密度每上升0.01 g/cm3,介电常数对应上升0.01~0.02,密度对损耗角正切数值影响不大;同一块板同样厚度位置,边角与中间位置的密度几乎没有变化;同一块板,同样厚度方向,介电常数变化不大;石英陶瓷板中引入松香导致试样更致密,密度升高,介电常数随之增大;相同密度的试样,采用不同的介电测试方式计算所得的介电常数有约0.03的偏差。

关键词: 熔融石英陶瓷, 凝胶注模成型, 坯板厚度, 坯板密度, 松香, 介电性能

Abstract: Fused silica ceramics were prepared by gel-casting molding process. The crystal structure, micro-morphology and dielectric properties of ceramic samples were analyzed by XRD, SEM and electrical network analyzer, and the influencing factors on dielectric properties of fused silica ceramics were studied to provide basis for screening the optimal preparation technology of fused silica ceramics. The results show that quartz ceramic slabs of different thicknesses are prepared and sintered horizontally with certain material preparation, the density of the same square slab decreases from top to bottom along the vertical direction, and the density has a positive correlation with the dielectric constant, for every 0.01 g/cm3 increase in density, the dielectric constant increases by 0.01~0.02. And the density has little effect on the tangent value of the loss angle. For the same slab of the same thickness, the density of the edge and the middle position barely unchanged. For the same slab and the same thickness direction, the dielectric constant does not change much. The rosin in the quartz ceramic slab makes the sample denser and the dielectric constant increases with the increase of the density, the calculated permittivity has a deviation of about 0.03.

Key words: fused silica ceramics, gel-casting molding, slab thickness, slab density, rosin, dielectric property

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