硫化镍颗粒引发钢化玻璃自爆风险的数值模拟研究

摘要/Abstract

摘要： 为研究硫化镍颗粒引发钢化玻璃自爆的风险,提出“等效临界体积膨胀率”概念,采用数值模拟的方法,分析了硫化镍颗粒尺寸、形状、所处位置对钢化玻璃自爆的影响程度。为模拟硫化镍相变过程并定量分析钢化玻璃自爆现象,该模拟通过提高硫化镍颗粒的温度使之产生温度膨胀,来等效现实中硫化镍的相变过程。通过观察硫化镍颗粒周边应力及温度变化,判断钢化玻璃自爆时最大主应力分布情况和硫化镍颗粒的体积膨胀率。结果表明:硫化镍颗粒所处位置越偏向中心位置,钢化玻璃自爆风险越大,而当硫化镍颗粒处于压应力区时,钢化玻璃几乎不发生自爆;当硫化镍颗粒形状趋于长球体时,钢化玻璃自爆风险变大,当硫化镍颗粒形状趋于扁球体时,钢化玻璃自爆风险应视颗粒的最大轴长方向来确定;安全起见,建议将硫化镍颗粒粒径大于0.12 mm时钢化玻璃自爆风险标记为极高。

关键词: 钢化玻璃, 硫化镍颗粒, 玻璃自爆, 数值模拟, 风险评估, 应力集中, 体积膨胀率

Abstract: To investigate the risk of nickel sulfide particles inducing the spontaneous breakage of tempered glass, this study introduced the concept of "equivalent critical volume expansion" and employed numerical simulation to analyze the effects of particle size, shape, and location on spontaneous breakage of tempered glass. The phase transition of nickel sulfide was modeled through thermal expansion induced by temperature increase, allowing quantitative analysis of phenomena breakage of tempered glass. Stress and temperature variations surrounding the nickel sulfide particles were examined to determine the distribution of maximum principal stress and the volume expansion of nickel sulfide particles at the onset of spontaneous breakage. The findings indicate that the risk of spontaneous breakage increases as the nickel sulfide particle moves closer to the center of tempered glass, while spontaneous breakage is nearly absent when nickel sulfide particles are located in compressive stress zones. The spontaneous breakage risk intensifies with nickel sulfide particle shapes approaching prolate spheroids, whereas in oblate spheroids, the risk must be assessed based on the orientation of the particle's major axis. For safety considerations, it is recommended that tempered glass be classified as having a high risk of spontaneous breakage when nickel sulfide particle size exceeds 0.12 mm.

Key words: tempered glass, nickel sulfide particle, glass spontaneous breakage, numerical simulation, risk evaluation, stress concentration, volume expansion

中图分类号:

TQ171

武子鹤, 杨璐, 徐克龙. 硫化镍颗粒引发钢化玻璃自爆风险的数值模拟研究[J]. 硅酸盐通报, 2025, 44(3): 1142-1151.

WU Zihe, YANG Lu, XU Kelong. Numerical Simulation on Spontaneous Breakage Risk of Tempered Glass Induced by Nickel Sulfide Particles[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(3): 1142-1151.

参考文献

[1] SWAIN M V. A fracture mechanics description of the microcracking about NiS inclusions in glass[J].Journal of Non-Crystalline Solids, 1980, 38: 451-456.
[2] BORDEAUX F, KASPER A. Reliable and shorter heat soak test to avoid spontaneous fracture of heat strengthened and tempered glasses[C]//Glass Processing Days, 1997, 13: 15.
[3] 包亦望, 刘正权. 钢化玻璃自爆机理与自爆准则及其影响因素[J].无机材料学报, 2016, 31(4): 401-406.
BAO Y W, LIU Z Q. Mechanism and criterion of spontaneous breakage of tempered glass[J].Journal of Inorganic Materials, 2016, 31(4): 401-406 (in Chinese).
[4] 张振华, 刘东阳, 赖博渊, 等. 钢化应力与硫化镍结石对钢化玻璃自爆率的影响[J].硅酸盐通报, 2020, 39(11): 3677-3682.
ZHANG Z H, LIU D Y, LAI B Y, et al. Effects of toughened stress and nickel sulfide calculi on the spontaneous break rate of toughened glass[J].Bulletin of the Chinese Ceramic Society, 2020, 39(11): 3677-3682 (in Chinese).
[5] POURMOGHADDAM N, SCHNEIDER J. Finite-element analysis of the residual stresses in tempered glass plates with holes or cut-outs[J].Glass Structures & Engineering, 2018, 3(1): 17-37.
[6] ILIEV V. Influence of the geometric shape of the nickel-sulfide inclusion on the stress-strain state caused by phase transformation[J].Science, Engineering and Education, 2017, 2(1): 23-30.
[7] VOCIALTA M, CORRADO M, MOLINARI J F. Numerical analysis of fragmentation in tempered glass with parallel dynamic insertion of cohesive elements[J].Engineering Fracture Mechanics, 2018, 188: 448-469.
[8] 刘小根, 包亦望, 邱岩, 等. 夹杂物附近应力场分布及其对玻璃可靠性影响[J].中国建材科技, 2010, 19(增刊2): 157-162.
LIU X G, BAO Y W, QIU Y, et al. Analysis of stress fields around the glass inclusions and influence on glass reliability[J].China Building Materials Science & Technology, 2010, 19(supplement 2): 157-162 (in Chinese).
[9] 国家市场监督管理总局, 国家标准化管理委员会. 玻璃缺陷检测方法光弹扫描法: GB/T 30020—2023[S].北京: 中国标准出版社, 2023.
State Administration for Market Regulation, National Standardization Administration. Test method for determing defects of glass—photoelastic scanning method: GB/T 30020—2023[S].Beijing: Standards Press of China, 2023 (in Chinese).
[10] ANTON J, ABEN H. A compact scattered light polariscope for residual stress measurement in glass plates[C]//Glass Processing Days, 2003: 86-88.
[11] NIELSEN J H, THIELE K, SCHNEIDER J, et al. Compressive zone depth of thermally tempered glass[J].Construction and Building Materials, 2021, 310: 125238.
[12] LOHR K, WELLER B. Residual stress distribution in tempered glass with reground edges[J].Glass Structures & Engineering, 2019, 4(1): 99-115.
[13] POURMOGHADDAM N, KRAUS M A, SCHNEIDER J, et al. Relationship between strain energy and fracture pattern morphology of thermally tempered glass for the prediction of the 2D macro-scale fragmentation of glass[J].Glass Structures & Engineering, 2019, 4(2): 257-275.
[14] 刘小根, 包亦望, 万德田, 等. 硫化镍引发钢化玻璃自爆的临界尺寸及影响[J].无机材料学报, 2020, 35(2): 211-216.
LIU X G, BAO Y W, WAN D T, et al. Critical size on spontaneous breakage of tempered glass initiated by NiS particle[J].Journal of Inorganic Materials, 2020, 35(2): 211-216 (in Chinese).
[15] YANG H, LIU F X, DUAN R Z, et al. Spray cooling heat transfer during glass tempering process and influencing factors on the quality of tempered glass[J].International Journal of Thermal Sciences, 2022, 175: 107475.
[16] SHETH N, HOWZEN A, CAMPBELL A, et al. Effects of tempering and heat strengthening on hardness, indentation fracture resistance, and wear of soda lime float glass[J].International Journal of Applied Glass Science, 2019, 10(4): 431-440.
[17] BAO Y W, LIU C C, HUANG J L. Effects of residual stresses on strength and toughness of particle-reinforced TiN/Si₃N₄ composite: theoretical investigation and FEM simulation[J].Materials Science and Engineering: A, 2006, 434(1/2): 250-258.
[18] 卢金山, 刘望子, 杜建亮, 等. 混合酸溶液中腐蚀时间对玻璃的表面显微结构及其性能影响[J].南昌航空大学学报(自然科学版), 2013, 27(2): 79-84.
LU J S, LIU W Z, DU J L, et al. Effect of etching time on surface microstructure and properties of glass treated in a mixed acid solution[J].Journal of Nanchang Hangkong University (Natural Sciences), 2013, 27(2): 79-84 (in Chinese).
[19] BENITEZ T, GÓMEZ S Y, DE OLIVEIRA A P N, et al. Transparent ceramic and glass-ceramic materials for armor applications[J].Ceramics International, 2017, 43(16): 13031-13046.
[20] KATO Y, YAMAZAKI H, YOSHIDA S, et al. Effect of densification on crack initiation under Vickers indentation test[J].Journal of Non-Crystalline Solids, 2010, 356(35/36): 1768-1773.
[21] JACOB L. A review of the nickel sulphide induced fracture in tempered glass[C]//Glass Performance Days, 2001: 108-110.
[22] TÖLKE T, BARZ A, STACHEL D. Behaviour and phase transformations of nickel sulphide inclusions in glass melts[J].Journal of Physics and Chemistry of Solids, 2007, 68(5/6): 830-834.
[23] YOUSFI O, DONNADIEU P, BRÉCHET Y, et al. Phase transformations in nickel sulphide: microstructures and mechanisms[J].Acta Materialia, 2010, 58(9): 3367-3380.
[24] 王衍行, 杨鹏慧, 李现梓, 等. 物理钢化玻璃的研究进展[J].材料导报, 2024, 38(11): 62-69.
WANG Y H, YANG P H, LI X Z, et al. Research progress on physical tempered glass[J].Materials Reports, 2024, 38(11): 62-69 (in Chinese).
[25] KARLSSON K, WONDRACZEK L. Strengthening of oxide glasses[J].Encyclopedia of Glass Science, Technology, History, and Culture, 2021, 1: 391-404.
[26] 国家质量监督检验检疫总局, 国家标准化管理委员会. 建筑用安全玻璃第2部分:钢化玻璃: GB 15763.2—2005[S].北京: 中国标准出版社, 2006.
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, National Standardization Administration. Safety glazing materials in building—Part 2: tempered glass: GB 15763.2—2005[S].Beijing: Standards Press of China, 2006 (in Chinese).
[27] KASPER A. Spontaneous cracking of thermally toughened safety glass. part one: properties of nickel sulphide inclusions[J].Glass Structures & Engineering, 2019, 4(3): 279-313.
[28] BALAYEVA O O, AZIZOV A A, MURADOV M B, et al. Effect of thermal annealing on the properties of nickel sulfide nanostructures: structural phase transition[J].Materials Science in Semiconductor Processing, 2017, 64: 130-136.
[29] JANA S, MUKHERJEE N, CHAKRABORTY B, et al. Electrodeposited polymer encapsulated nickel sulphide thin films: frequency switching material[J].Applied Surface Science, 2014, 300: 154-158.
[30] 李文竹. 含有机玻璃中间层双中空玻璃板物理性能与温度效应研究[D].太原: 太原理工大学, 2023.
LI W Z. Study on physical properties and temperature effect of double hollow glass plate with plexiglass interlayer[D].Taiyuan: Taiyuan University of Technology, 2023 (in Chinese).
[31] 刘忠伟, 孙加林, 洪彦若. 建筑玻璃热炸裂机理的研究[J].中国建材科技, 1999, 8(1): 22-24.
LIU Z W, SUN J L, HONG Y R. Study on thermal cracking mechanism of architectural glass[J].China Building Materials Science & Technology, 1999, 8(1): 22-24 (in Chinese).