基于团簇加连接原子模型的一种工业微晶玻璃成分优化初探

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (4): 1257-1266.

• “玻璃材料与玻璃技术”专题(II) • 上一篇下一篇

基于团簇加连接原子模型的一种工业微晶玻璃成分优化初探

尚楷浡¹, 李铭涵^2,3, 李军葛^4,5, 马艳平^2,3, 姜宏^2,3,4,5, 赵亚军¹, 张吉亮¹, 董闯¹

1.大连交通大学材料科学与工程学院,大连 116024;
2.海南大学,海南省特种玻璃重点实验室,海口 570228;
3.海南大学,南海海洋资源利用国家重点实验室,海口 570228;
4.海南海控特玻科技有限公司,澄迈 571924;
5.特种玻璃国家重点实验室,澄迈 571924

收稿日期:2023-10-11 修订日期:2023-12-12 出版日期:2024-04-15 发布日期:2024-04-17
通信作者: 董闯,博士,教授。E-mail:dong@djtu.edu.cn姜宏,博士,教授。E-mail:184444@hainanu.edu.cn
作者简介:尚楷浡(2000—),男,博士研究生。主要从事微晶玻璃的研究。E-mail:2579814466@qq.com
基金资助:
国家自然科学基金(U22A20124);海南省重大科技计划项目(ZDKJ2021049)

A Preliminary Study on Composition Optimization of an Industrial Glass-Ceramics Based on Cluster-Plus-Glue-Atom Model

SHANG Kaibo¹, LI Minghan^2,3, LI Junge^4,5, MA Yanping^2,3, JIANG Hong^2,3,4,5, ZHAO Yajun¹, ZHANG Jiliang¹, DONG Chuang¹

1. School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116024, China;
2. Key Laboratory of Specialty Glass of Hainan Province, Hainan University, Haikou 570228, China;
3. State Key Laboratory of South China Sea Marine Resources Utilization, Hainan University, Haikou 570228, China;
4. Hainan Holdings Special Glass Technology Co., Ltd., Chengmai 571924, China;
5. State Key Laboratory of Special Glass, Chengmai 571924, China

Received:2023-10-11 Revised:2023-12-12 Online:2024-04-15 Published:2024-04-17

摘要/Abstract

摘要： 本团队提出的团簇加连接原子模型从结构根源上揭示了硅酸盐玻璃的成分载体,即硅酸盐玻璃的成分式由总数为16个的三价单元{M₂O₃}和四价单元{Si₂O₄}构成。本工作引入该模型,对一种工业微晶玻璃MT3A进行了成分优化,并进行玻璃制备和晶化,最后对样品进行结构和性能表征。在获得的新的透明微晶玻璃中,MT3C的透过率为89%,抗弯强度和硬度分别为155 MPa和652 HV;MT3D的透过率为92%,抗弯强度和硬度分别为134 MPa和655 HV。

关键词: 透明微晶玻璃, 团簇加连接原子模型, 锂铝硅酸盐, 力学性能, 结构单元, 结构表征

Abstract: The cluster-plus-glue-atom model proposed by our team identifies the structural unit that carriers the composition of any structure. Specifically, for silicate glasses, the composition unit is composed of 16 trivalent-cation {M₂O₃} and quadrivalent units {Si₂O₄}. In this work, an industrial glass-ceramic product MT3A was optimized by the cluster-plus-glue-atom model, and the glass was prepared and crystallized. Finally, the structure and properties of the sample were characterized. Among the transparent glass-ceramics thus obtained, MT3C and MT3D show optical transmittance of 89% and 92%, flexural strength of 155 and 134 MPa, and hardness of 652 and 655 HV, respectively.

Key words: transparent glass-ceramics, cluster-plus-glue-atom model, lithium-aluminosilicate, mechanical property, structural unit, structural characterization

中图分类号:

TQ171

尚楷浡, 李铭涵, 李军葛, 马艳平, 姜宏, 赵亚军, 张吉亮, 董闯. 基于团簇加连接原子模型的一种工业微晶玻璃成分优化初探[J]. 硅酸盐通报, 2024, 43(4): 1257-1266.

SHANG Kaibo, LI Minghan, LI Junge, MA Yanping, JIANG Hong, ZHAO Yajun, ZHANG Jiliang, DONG Chuang. A Preliminary Study on Composition Optimization of an Industrial Glass-Ceramics Based on Cluster-Plus-Glue-Atom Model[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1257-1266.

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基于团簇加连接原子模型的一种工业微晶玻璃成分优化初探

A Preliminary Study on Composition Optimization of an Industrial Glass-Ceramics Based on Cluster-Plus-Glue-Atom Model

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