Li2O-Al2O3-SiO2系微晶玻璃的研究进展

摘要/Abstract

摘要： Li₂O-Al₂O₃-SiO₂(LAS)系微晶玻璃由于具有热膨胀系数低、透明度高、力学性能优良等特点,被广泛应用于国防、建筑、化工、生物医药等多个领域,近年来受到研究者的广泛关注。本文综述了LAS系微晶玻璃的研究现状,介绍了LAS晶相体系及相关玻璃产品,对比分析了LAS系微晶玻璃各制备工艺的特点,并讨论了LAS系微晶玻璃晶核剂的种类及成核机理,最后总结了LAS系微晶玻璃性能、应用以及相应表征技术和测试手段,并指出了LAS系微晶玻璃存在的问题及未来的发展方向。

关键词: LAS系微晶玻璃, 高铝低锂, 低热膨胀, 组分设计, 晶核剂

Abstract: Li₂O-Al₂O₃-SiO₂ (LAS) system glass-ceramics is widely used in national defense, architecture, chemical industry, biomedicine and other fields due to its low thermal expansion coefficient, high transparency, excellent mechanical properties and other characteristics. In recent years, it has received extensive attention from researchers. This article summarizes the current research status of LAS glass-ceramics, introduces the LAS crystal phase system and related glass products, compares and analyzes the characteristics of various preparation processes of LAS glass-ceramics, and discusses the types of LAS glass-ceramics nucleating agents and their nucleation mechanisms. Finally, the properties, applications, corresponding characterization techniques and testing methods of LAS glass-ceramics are summarized, and the existing problems and future development trends of LAS glass-ceramics are pointed out.

Key words: LAS glass-ceramics, high aluminum and low lithium, low thermal expansion, component design, nucleation agent

中图分类号:

TQ171.73

任贝贝, 刘亚鑫, 黄欣, 王霆, 王娜, 姜宏, 熊春荣, 郝红勋. Li₂O-Al₂O₃-SiO₂系微晶玻璃的研究进展[J]. 硅酸盐通报, 2024, 43(4): 1181-1196.

REN Beibei, LIU Yaxin, HUANG Xin, WANG Ting, WANG Na, JIANG Hong, XIONG Chunrong, HAO Hongxun. Research Progress of Li₂O-Al₂O₃-SiO₂ System Glass-Ceramics[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(4): 1181-1196.

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ZENG L, HUANG S J, LIN H J, et al. Influence of mixed alkali effect on structure and thermal expansion properties of Li₂O-Al₂O₃-SiO₂ glass[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(11): 3813-3821 (in Chinese).
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Li₂O-Al₂O₃-SiO₂系微晶玻璃的研究进展

Research Progress of Li₂O-Al₂O₃-SiO₂ System Glass-Ceramics

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