用于石窟岩体裂隙防渗的偏高岭土复合灌浆材料水化性能研究

硅酸盐通报 ›› 2024, Vol. 43 ›› Issue (2): 627-636.

所属专题：资源综合利用

用于石窟岩体裂隙防渗的偏高岭土复合灌浆材料水化性能研究

陈嘉琦¹, 王金华¹, 严绍军², 田野晨曦¹, 杜之岩¹, 江姝¹, 霍晓彤¹

1.复旦大学文物与博物馆学系,上海 200433;
2.陕西省文物保护研究院,西安 710075

收稿日期:2023-05-18 修订日期:2023-07-20 出版日期:2024-02-15 发布日期:2024-02-05
通信作者: 王金华,研究员。E-mail:wjh52841@qq.com
作者简介:陈嘉琦(1991—),女,博士。主要从事石质文物保护方面的研究。E-mail:751132369@qq.com
基金资助:
国家重点研发计划(2021YFC1523400);重庆市技术创新与应用发展重点项目(CSTB2022TIAD-KPX0095);中国博士后基金(2022M720772)

Hydration Properties of Metakaolin Composite Grouting Materials for Anti-Seepage of Grottoes Rock Fissures

CHEN Jiaqi¹, WANG Jinhua¹, YAN Shaojun², TIAN Yechenxi¹, DU Zhiyan¹, JIANG Shu¹, HUO Xiaotong¹

1. Department of Cultural Heritage and Museology, Fudan University, Shanghai 200433, China;
2. Shannxi Institute for the Preservation of Cultural Heritage, Xi'an 710075, China

Received:2023-05-18 Revised:2023-07-20 Online:2024-02-15 Published:2024-02-05

摘要/Abstract

摘要： 偏高岭土复合灌浆材料是一种在水泥中大比例掺入偏高岭土的无机灌浆料,被应用于石窟岩体裂隙防渗灌浆工程领域。本文通过水化热、XRD、FTIR、SEM-EDX测试手段研究了二元和三元偏高岭土复合灌浆材料的水化过程及产物特征,并结合力学性能及水溶盐测试分析了该材料应用于石窟裂隙灌浆的可行性。结果表明,大比例掺入偏高岭土的水泥材料反应程度较低,但偏高岭土的稀释效应、火山灰反应以及活性Al的电荷补偿效应对降低水溶液盐碱含量起到积极作用。硅灰的掺入能提升三元复合灌浆材料的水化程度及力学强度,然而水化产物Al/Si的降低不利于K⁺、Na⁺吸附。偏高岭土复合灌浆材料在石窟水害治理中是一种相比普通硅酸盐水泥更加安全的材料,与石窟环境具有更好的兼容性;作为辅助胶凝材料,偏高岭土在减少K⁺、Na⁺浸出方面相比硅灰更有优势。

关键词: 灌浆材料, 偏高岭土, 火山灰反应, 电荷补偿效应, 石窟保护, 兼容性

Abstract: Metakaolin composite grouting material is an inorganic grouting material mixed with a large proportion of metakaolin in cement, which is used for anti-seepage grouting engineering of rock fissures in grottoes. In this paper, the hydration and product characterization of binary and ternary metakaolin composite grouting material were studied by means of hydration heat, XRD, FTIR, and SEM-EDX test. The feasibility of applying this material to grotto fissure grouting was analyzed by mechanical properties and water-solube salt test. The results indicate that the reaction degree of cement materials with is low. But the dilution effect and pozzolanic reaction of metakaolin and the charge compensation effect of active Al have a significant advantage in reducing the salt and alkali content in leaching solution. The addition of silica fume can enhance the hydration degree and mechanical strength of ternary composite grouting material. However, the decrease in Al/Si of hydrated products is not conducive to the adsorption of K⁺ and Na⁺. The metakaolin composite grouting material is a safer material than ordinary Portland cement in grotto protection, and it exhibits better compatibility with grottoes environment. Additionally, metakaolin, as a supplementary cementitious material, has more advantages over silica fume in reducing K⁺ and Na⁺ leaching.

Key words: grouting material, metakaolin, pozzolanic reaction, charge compensation effect, grotto protection, compatibility

中图分类号:

G264

陈嘉琦, 王金华, 严绍军, 田野晨曦, 杜之岩, 江姝, 霍晓彤. 用于石窟岩体裂隙防渗的偏高岭土复合灌浆材料水化性能研究[J]. 硅酸盐通报, 2024, 43(2): 627-636.

CHEN Jiaqi, WANG Jinhua, YAN Shaojun, TIAN Yechenxi, DU Zhiyan, JIANG Shu, HUO Xiaotong. Hydration Properties of Metakaolin Composite Grouting Materials for Anti-Seepage of Grottoes Rock Fissures[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(2): 627-636.

参考文献

[1] 孙兵. 龙门石窟渗水病害机理分析及防渗材料试验研究[D]. 武汉: 中国地质大学, 2006.
SUN B. Mechanism analysis of seepage disease in Longmen grottoes and experimental study on impervious materials[D]. Wuhan: China University of Geosciences, 2006 (in Chinese).
[2] 方云, 刘祥友, 胡学军, 等. 龙门石窟防渗灌浆试验研究[J]. 石窟寺研究, 2010(1): 221-243.
FANG Y, LIU X Y, HU X J, et al. Study on grouting experimental against seepage of the Longmen grottoes[J]. Studies of the Cave Temples, 2010(1): 221-243 (in Chinese).
[3] 李心坚. 龙门石窟保护中的灌浆技术[J]. 雕塑, 2008(6): 36-37.
LI X J. The grouting technique of protecting the Longmen grottoes[J]. Sculpture, 2008(6): 36-37 (in Chinese).
[4] 方云, 王金华, 赵岗. 心系石窟: 岩土文物保护研究论文选[M]. 武汉: 中国地质大学出版社, 2017.
FANG Y, WANG J H, ZHAO G. Xinxi grottoes: selected papers on the protection of geotechnical cultural relics[M]. Wuhan: China University of Geosciences Press, 2017 (in Chinese).
[5] 严绍军, 皮雷, 方云, 等. 龙门石窟偏高岭土-超细水泥复合灌浆材料研究[J]. 石窟寺研究, 2013(1): 393-404.
YAN S J, PI L, FANG Y, et al. Research on metakaolin and micro fine cement composite grouting material in Longmen grottoes[J]. Studies of the Cave Temples, 2013(1): 393-404 (in Chinese).
[6] 封孝信, 冯乃谦. 水泥及混凝土中的有害碱与无害碱[J]. 混凝土, 2000(10): 3-7.
FENG X X, FENG N Q. Deleterious alkali and non-deleterious alkali in cement and concrete[J]. Concrete, 2000(10): 3-7 (in Chinese).
[7] 莫祥银, 许仲梓, 唐明述. 国内外混凝土碱集料反应研究综述[J]. 材料科学与工程, 2002, 20(1): 128-132
MO X Y, XU Z Z, TANG M S. Review of alkali aggregate reaction and its research progress[J]. Materials Science and Engineering, 2002, 20(1): 128-132 (in Chinese).
[8] 贾耀东. 大掺量矿物掺合料混凝土的碳化特性研究[D]. 北京: 清华大学, 2012.
JIA Y D. Study on carbonation characteristics of concrete with large amount of mineral admixture[D]. Beijing: Tsinghua University, 2012 (in Chinese).
[9] VASCONCELOS R G W, WALKLEY B, DAY S, et al. 18-month hydration of a low-pH cement for geological disposal of radioactive waste: the cebama reference cement[J]. Applied Geochemistry, 2020, 116: 104536.
[10] CHENG A, LIN W T, CHAO S J, et al. Composition and selected properties of low pH mortars and concretes for radioactive waste repositories[J]. MATEC Web of Conferences, 2020, 322: 01033.
[11] KHAN K, ULLAH M F, SHAHZADA K, et al. Effective use of micro-silica extracted from rice husk ash for the production of high-performance and sustainable cement mortar[J]. Construction and Building Materials, 2020, 258: 119589.
[12] 罗旌旺, 卢都友, 许涛, 等. 偏高岭土对硅酸盐水泥浆体干燥收缩行为的影响及机理[J]. 硅酸盐学报, 2011, 39(10): 1687-1693.
LUO J W, LU D Y, XU T, et al. Effect of metakaolin on drying shrinkage behaviour of Portland cement pastes and its mechanism[J]. Journal of the Chinese Ceramic Society, 2011, 39(10): 1687-1693 (in Chinese).
[13] 喻巍. 偏高岭土对水泥石的水化产物影响机理研究[D]. 武汉: 武汉理工大学, 2013.
YU W. Study on the influence mechanism of metakaolin on hydration products of cement paste[D]. Wuhan: Wuhan University of Technology, 2013 (in Chinese).
[14] 许博超. 偏高岭土对水泥水化过程影响的机理研究[D]. 北京: 北京建筑大学, 2015.
XU B C. Study on mechanism of metakaolin's influence on cement hydration process[D]. Beijing: Beijing University of Civil Engineering and Architecture, 2015 (in Chinese).
[15] MOSTAFA N Y, BROWN P W. Heat of hydration of high reactive pozzolans in blended cements: isothermal conduction calorimetry[J]. Thermochimica Acta, 2005, 435(2): 162-167.
[16] WEI J Q, GENCTURK B. Hydration of ternary Portland cement blends containing metakaolin and sodium bentonite[J]. Cement and Concrete Research, 2019, 123: 105772.
[17] 钱觉时, 余金城, 孙化强, 等. 钙矾石的形成与作用[J]. 硅酸盐学报, 2017, 45(11): 1569-1581.
QIAN J S, YU J C, SUN H Q, et al. Formation and function of ettringite in cement hydrates[J]. Journal of the Chinese Ceramic Society, 2017, 45(11): 1569-1581 (in Chinese).
[18] 杨南如, 钟白茜, 董攀, 等. 钙矾石的形成和稳定条件[J]. 硅酸盐学报, 1984, 12(2): 155-165.
YANG N R, ZHONG B Q, DONG P, et al. Formation and stability conditions of ettringite[J]. Journal of the Chinese Ceramic Society, 1984, 12(2): 155-165 (in Chinese).
[19] 曹德光, 苏达根, 杨占印, 等. 偏高岭石的微观结构与键合反应能力[J]. 矿物学报, 2004, 24(4): 366-372.
CAO D G, SU D G, YANG Z Y, et al. Microstructure and bonding reaction ability of metakaolinite[J]. Acta Mineralogica Sinica, 2004, 24(4): 366-372 (in Chinese).
[20] KUZIELOVÁ E, SLANÝ M, ŽEMLIČKA M, et al. Phase composition of silica fume: portland cement systems formed under hydrothermal curing evaluated by FTIR, XRD, and TGA[J]. Materials, 2021, 14(11): 2786.
[21] GARCÍA C J, SÁNCHEZ M M, ALONSO A M, et al. Study of the microstructure evolution of low-pH cements based on ordinary Portland cement (OPC) by mid- and near-infrared spectroscopy, and their influence on corrosion of steel reinforcement[J]. Materials, 2013, 6(6): 2508-2521.
[22] CODINA M, CAU-DIT-COUMES C, LE BESCOP P, et al. Design and characterization of low-heat and low-alkalinity cements[J]. Cement and Concrete Research, 2008, 38(4): 437-448.
[23] SONG F, YU Z L, YANG F L, et al. Strätlingite and calcium hemicarboaluminate hydrate in belite-calcium sulphoaluminate cement[J]. Ceramics-Silikaty, 2014, 58(4): 269-274.
[24] HONG S Y, GLASSER F P. Alkali sorption by C-S-H and C-A-S-H gels[J]. Cement and Concrete Research, 2002, 32(7): 1101-1111.
[25] BACH T T H, CHABAS E, POCHARD I, et al. Retention of alkali ions by hydrated low-pH cements: mechanism and Na⁺/K⁺ selectivity[J]. Cement and Concrete Research, 2013, 51: 14-21.

用于石窟岩体裂隙防渗的偏高岭土复合灌浆材料水化性能研究

Hydration Properties of Metakaolin Composite Grouting Materials for Anti-Seepage of Grottoes Rock Fissures

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李学亮, 赵庆朝, 李伟光, 李勇, 朱阳戈, 宋厚彬, 杨浩, 张艳平. 煤系偏高岭土对混凝土力学性能及微观结构的影响机理[J]. 硅酸盐通报, 2023, 42(9): 3221-3230.
[2]	邱伟, 孔德文, 崔庚寅, 黄莹蓥, 王玲玲. 偏高岭土-磷石膏基复合胶凝材料性能试验研究[J]. 硅酸盐通报, 2023, 42(9): 3267-3276.
[3]	罗哲, 黄敦文, 彭晖. 碱激发偏高岭土-矿渣砂浆的碱骨料反应机理研究[J]. 硅酸盐通报, 2023, 42(8): 2830-2836.
[4]	张熠爽, 周健, 李辉, 徐名凤. 硅酸盐水泥-富铝材料复合体系Cl^-结合能力的研究进展[J]. 硅酸盐通报, 2023, 42(5): 1672-1687.
[5]	范小春, 汪阳, 高旭, 张宇, 袁波. 亚硝酸钙与富铝矿相协同调控碱矿渣氯离子固化能力研究[J]. 硅酸盐通报, 2023, 42(4): 1148-1155.
[6]	李威, 刘豫, 李慧, 于欣欣, 朱建平. 新拌石灰石粉-偏高岭土-水泥系统流变特性研究[J]. 硅酸盐通报, 2023, 42(2): 411-419.
[7]	顾立龙, 商怀帅, 吴亚月, 孟维广, 侯关豪. 偏高岭土在人造水硬性石灰修复砂浆中的应用研究[J]. 硅酸盐通报, 2023, 42(12): 4351-4359.
[8]	罗仁, 芦雨薇, 许源, 樊晋源, 刘怀, 段平. 改性5A沸石对偏高岭土地聚物微观结构及抗泛碱性能的影响[J]. 硅酸盐通报, 2023, 42(10): 3633-3642.
[9]	李方, 杨健, 李粒珲. 废玻璃粉作为辅助胶凝材料对砂浆性能影响及作用机理[J]. 硅酸盐通报, 2022, 41(9): 3208-3218.
[10]	史伟超, 戚栋, 赵轶, 山晓莉, 张文军. 偏高岭土对模拟商混站强碱性废泥基人造石强度的影响[J]. 硅酸盐通报, 2022, 41(6): 2024-2030.
[11]	张涛, 耿健, 柳根金, 杨余迪, 刘慈军. 水泥-粉煤灰-矿粉-偏高岭土四元胶凝材料氯离子固化机理研究[J]. 硅酸盐通报, 2022, 41(6): 2063-2070.
[12]	刘艳玲, 廖宜顺, 李亚刚. 超细矿渣粉和偏高岭土对硫铝酸盐水泥早期收缩性能的影响[J]. 硅酸盐通报, 2022, 41(6): 2090-2097.
[13]	袁正平, 耿新洋, 王富林. 碱激发冶炼铅渣-偏高岭土复合胶凝材料的制备及水化机理[J]. 硅酸盐通报, 2022, 41(5): 1724-1733.
[14]	韦琦, 刘艳, 耿海宁, 马浩森, 陈伟, 王东文, 潘社奇, 李秋. 聚合硫酸铝改性低碱度水泥性能研究[J]. 硅酸盐通报, 2022, 41(4): 1237-1244.
[15]	杨光, 赵宇, 朱伶俐, 武喜凯. 碱激发偏高岭土基地质聚合物的制备及抗压强度研究[J]. 硅酸盐通报, 2022, 41(3): 894-902.