SiC与耐热钢在高温真空中的界面反应机制研究

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (6): 2161-2171.

所属专题：陶瓷

SiC与耐热钢在高温真空中的界面反应机制研究

谢莹莹¹, 陈毛¹, 宋子杰¹, 范冰冰¹, 张锐^1,2, 陈勇强¹

1.郑州大学材料科学与工程学院,郑州 450001;
2.洛阳理工学院材料科学与工程学院,洛阳 471023

收稿日期:2023-03-27 修订日期:2023-03-27 出版日期:2023-06-15 发布日期:2023-06-25
通信作者: 陈勇强,博士,讲师。E-mail:chenyq@zzu.edu.cn
作者简介:谢莹莹(2000—),女。主要从事冶金用耐火材料方面的研究。E-mail:2428230514@qq.com
基金资助:
国家自然科学基金青年项目(52202072)

Interfacial Reaction Mechanism of Silicon Carbide and Heat Resistant Steel in High-Temperature Vacuum

XIE Yingying¹, CHEN Mao¹, SONG Zijie¹, FAN Bingbing¹, ZHANG Rui^1,2, CHEN Yongqiang¹

1. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China;
2. School of Materials Science and Engineering, Luoyang Institute of Science and Technology, Luoyang 471023, China

Received:2023-03-27 Revised:2023-03-27 Online:2023-06-15 Published:2023-06-25

摘要/Abstract

摘要： 碳化硅陶瓷可用作镁冶炼还原钢罐的内衬。在真空和1 200 ℃条件下,通过扩散偶试验,对SiC与耐热钢的界面反应进行了系统研究。结果表明,在反应初期,界面反应的主要产物为金属硅化物和石墨,其中分布在界面的片状石墨阻碍了界面反应。由于界面上低熔点硅镍化合物的熔化,片状石墨在Ni的催化作用下转变为纤维状石墨,失去了对碳化硅的保护作用。界面反应由固-固反应转变为固-液反应,界面反应过程加快,加速了钢对碳化硅的侵蚀。与耐热钢相比,SiC与纯铁的界面反应速率明显降低,金属熔化所需温度也显著升高。减少耐热钢中的Ni含量,可以有效阻止耐热钢和SiC之间的反应。

关键词: SiC, 耐热钢, 界面, 石墨, 固相反应

Abstract: Silicon carbide (SiC) ceramics can be used as inner lining of reduction tank for magnesium smelting. The interfacial reaction between SiC and heat resistant steel was systematically investigated by diffusion couple experiment under vacuum and 1 200 ℃. The results show that at the early stage of reaction, the main products of interfacial reaction are metal silicide and graphite, and the lamellar graphite distributing at the interface hinders the interfacial reaction. However, due to the melting of silicon-nickel compounds with low melting point at interface, the lamellar graphite is transformed into fibrous graphite under the catalysis of Ni, losing its protective effect on silicon carbide. In addition, the interface reaction changes from solid-solid reaction to solid-liquid reaction, and the interfacial reaction process is accelerated, which accelerates the corrosion of silicon carbide by steel. Compared with heat resistant steel, the interfacial reaction rate between SiC and pure iron is obviously decreased, and the temperature required for the reaction is obviously increased. Reducing Ni content in heat resistant steel can effectively prevent the reaction between heat resistant steel and SiC.

Key words: SiC, heat resistant steel, interfacial, graphite, solid phase reaction

中图分类号:

TQ174

谢莹莹, 陈毛, 宋子杰, 范冰冰, 张锐, 陈勇强. SiC与耐热钢在高温真空中的界面反应机制研究[J]. 硅酸盐通报, 2023, 42(6): 2161-2171.

XIE Yingying, CHEN Mao, SONG Zijie, FAN Bingbing, ZHANG Rui, CHEN Yongqiang. Interfacial Reaction Mechanism of Silicon Carbide and Heat Resistant Steel in High-Temperature Vacuum[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(6): 2161-2171.

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SiC与耐热钢在高温真空中的界面反应机制研究

Interfacial Reaction Mechanism of Silicon Carbide and Heat Resistant Steel in High-Temperature Vacuum

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