早期水热养护对铝酸钙水泥结构稳定性的影响

硅酸盐通报 ›› 2023, Vol. 42 ›› Issue (3): 802-807.

所属专题：水泥混凝土

早期水热养护对铝酸钙水泥结构稳定性的影响

周剑峰¹, 杨涛², 张菁燕¹, 周文平¹, 高璇²

1.常州市建筑科学研究院集团股份有限公司,常州 213000;
2.盐城工学院材料科学与工程学院,盐城 224051

收稿日期:2022-10-18 修订日期:2022-12-08 出版日期:2023-03-15 发布日期:2023-03-31
通信作者: 杨涛,博士,副教授。E-mail:taoyang1121@ycit.edu.cn
作者简介:周剑峰(1974—),男。主要从事建筑材料研发、工程事故分析等方面的研究。E-mail:1093802847@qq.com
基金资助:
国家自然科学基金青年基金(51702278);江苏省“青蓝工程”优秀青年骨干教师

Effect of Early-Age Hydrothermal Curing on Structural Stability of Calcium Aluminate Cement

ZHOU Jianfeng¹, YANG Tao², ZHANG Jingyan¹, ZHOU Wenping¹, GAO Xuan²

1. Changzhou Architectural Research Institute Group Co., Ltd., Changzhou 213000, China;
2. School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China

Received:2022-10-18 Revised:2022-12-08 Online:2023-03-15 Published:2023-03-31

摘要/Abstract

摘要： 稠油热采常使用具有早强和耐高温特性的铝酸钙特种水泥完成固井作业,为保证固井安全和采油效率,需明确早期水热养护对水泥硬化体结构稳定性的影响。本文研究了20、50、80 ℃下水泥的强度发展、矿物相组成和微观结构。结果表明,水热养护过程中铝酸钙水泥中的钙铝黄长石、CAH₁₀和C₂AH₈等主要矿物相逐步转变为胶结性差的颗粒状水榴石,导致硬化体结构疏松多孔,进而引发硬化体抗压强度衰退。掺入粉煤灰和矿渣无法有效抑制晶型转变和结构破坏,但六偏磷酸钠改性可使矿物相保持结构稳定性,六偏磷酸钠溶出的Na⁺、HPO^-₄与铝酸钙水泥溶出的Ca²⁺、[AlO₄]^5-反应生成水化磷铝酸钠钙(N-C-A-P-H)凝胶相产物,进一步提高了硬化体的致密度和胶结特性。

关键词: 铝酸钙水泥, 固井, 稠油热采, 矿相转变, 微观结构, 稳定性

Abstract: Calcium aluminate special cement with rapid early-age strength development and high-temperature resistance is frequently utilized for well cementing operations in heavy oil thermal recovery. It is essential for understanding the effect of early-age hydrothermal curing on the structural stability of cement binder to maintain cementing safety and oil recovery effectiveness. The strength development, mineral composition, and microstructure of cement cured at 20, 50 and 80 ℃ were investigated. The results show that the main mineral phases formed in calcium aluminate cement, such as gehlenite, CAH₁₀ and C₂AH₈, gradually transform into granular hydrogarnet with poor cementation during hydrothermal curing, resulting in loose and porous structure of cement binder, which leads to the decline in compressive strength. The incorporation fly ash and slag can not effectively prevent the crystal transformation and structural damage. The modification of sodium hexametaphosphate maintains the structural stability of mineral phases, and the dissolved Na⁺ and HPO^-₄ ions released from hexametaphosphate react with Ca²⁺ and [AlO₄]^5- ions released from cement to generate sodium calcium aluminophosphate hydrate (N-C-A-P-H) gel phase products, which further enhances the density and cementation performance of cement binder.

Key words: calcium aluminate cement, well cementing, heavy oil thermal recovery, mineral transformation, microstructure, stability

中图分类号:

TQ172

周剑峰, 杨涛, 张菁燕, 周文平, 高璇. 早期水热养护对铝酸钙水泥结构稳定性的影响[J]. 硅酸盐通报, 2023, 42(3): 802-807.

ZHOU Jianfeng, YANG Tao, ZHANG Jingyan, ZHOU Wenping, GAO Xuan. Effect of Early-Age Hydrothermal Curing on Structural Stability of Calcium Aluminate Cement[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(3): 802-807.

参考文献

[1] 李早元, 张松, 张弛, 等. 热力采油条件下粉煤灰改善铝酸盐水泥石耐高温性能及作用机理研究[J]. 硅酸盐通报, 2012, 31(5): 1101-1105.
LI Z Y, ZHANG S, ZHANG C, et al. Study on aluminates cement with fly ash for heavy crude oil thermal recovery in well cementation[J]. Bulletin of the Chinese Ceramic Society, 2012, 31(5): 1101-1105 (in Chinese).
[2] 周晓义, 肖武林, 王美成, 等. 新疆风城油田稠油热采高温封堵剂研究与现场试验[J]. 石油钻探技术, 2021, 49(6): 113-117.
ZHOU X Y, XIAO W L, WANG M C, et al. Study and field test on a high temperature plugging agent for the thermal recovery of heavy oil in Fengcheng oilfield, Xinjiang[J]. Petroleum Drilling Techniques, 2021, 49(6): 113-117 (in Chinese).
[3] 李早元, 伍鹏, 吴东奎, 等. 稠油热采井固井用铝酸盐水泥浆体系的研究及应用[J]. 钻井液与完井液, 2014, 31(5): 71-74+100.
LI Z Y, WU P, WU D K, et al. Study on and application of aluminate cement slurry in cementing heavy oil thermal recovery well[J]. Drilling Fluid & Completion Fluid, 2014, 31(5): 71-74+100 (in Chinese).
[4] UKRAINCZYK N, MATUSINOVIĆ T. Thermal properties of hydrating calcium aluminate cement pastes[J]. Cement and Concrete Research, 2010, 40(1): 128-136.
[5] GOERGENS J, MANNINGER T, GOETZ-NEUNHOEFFER F. In-situ XRD study of the temperature-dependent early hydration of calcium aluminate cement in a mix with calcite[J]. Cement and Concrete Research, 2020, 136: 106160.
[6] TIAN H W, STEPHAN D, LOTHENBACH B, et al. Influence of foreign ions on calcium silicate hydrate under hydrothermal conditions: a review[J]. Construction and Building Materials, 2021, 301: 124071.
[7] PANCHMATIA P, OLVERA R, GENEDY M, et al. Shrinkage behavior of Portland and geopolymer cements at elevated temperature and pressure[J]. Journal of Petroleum Science and Engineering, 2020, 195: 107884.
[8] IRISAWA K, GARCIA-LODEIRO I, KINOSHITA H. Influence of mixing solution on characteristics of calcium aluminate cement modified with sodium polyphosphate[J]. Cement and Concrete Research, 2020, 128: 105951.
[9] 陈钰婷, 王中平, 彭相, 等. 高温与碳化对铝酸盐水泥水化产物氯离子结合稳定性的影响[J]. 建筑材料学报, 2022, 25(7): 715-721.
CHEN Y T, WANG Z P, PENG X, et al. Effect of high temperature and carbonization on chloride binding stability in calcium aluminate cement[J]. Journal of Building Materials, 2022, 25(7): 715-721 (in Chinese).
[10] SUGAMA T, PYATINA T. Self-healing, re-adhering, and carbon-steel corrosion mitigating properties of fly ash-containing calcium aluminum phosphate cement composite at 300 ℃ hydrothermal temperature[J]. Cement and Concrete Composites, 2019, 99: 1-16.
[11] American Petroleum Institute. Cements and materials for well cementing: API specification 10A—2019[S]. Washington D C: American Petroleum Institute, 2019.
[12] 王思纯, 廖宜顺, 万世辉. 不同温度下矿渣对铝酸盐水泥早期水化行为的影响[J]. 硅酸盐通报, 2022, 41(4): 1343-1351+1368.
WANG S C, LIAO Y S, WAN S H. Effect of GGBFS on early hydration behavior of calcium aluminate cement at different temperatures[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(4): 1343-1351+1368 (in Chinese).

[1]	齐晓, 肖前慧, 邱继生, 刘书林. 冻融循环与硫酸盐侵蚀共同作用下再生混凝土的微观结构研究[J]. 硅酸盐通报, 2023, 42(4): 1194-1204.
[2]	张虹宇, 郑玉龙, 陆春华. 两种养护制度下C100高强混凝土韧性对比试验研究[J]. 硅酸盐通报, 2023, 42(4): 1252-1259.
[3]	张劲竹, 刘华新, 王家贺, 柳根金, 王学志. 混杂纤维混凝土高温后性能劣化分析与强度预测[J]. 硅酸盐通报, 2023, 42(4): 1260-1269.
[4]	胡彪, 李先海, 晏祥政, 赵永庆. 热活化煤矸石粉对基体-骨料界面过渡区性能的影响[J]. 硅酸盐通报, 2023, 42(4): 1315-1322.
[5]	何俊, 管家贤, 吕晓龙, 张驰. 纳米硅粉改良碱渣-矿渣固化淤泥的抗硫酸镁侵蚀性能[J]. 硅酸盐通报, 2023, 42(4): 1344-1352.
[6]	刘扬, 陈湘, 王柏文, 鲁乃唯, 肖欣欣, 罗冬. 碱激发粉煤灰-矿渣-电石渣基地聚物的制备及强度机理[J]. 硅酸盐通报, 2023, 42(4): 1353-1362.
[7]	余海燕, 徐晴, 王英翔, 董德宇. 不同环境下碳铝酸钙的稳定性研究[J]. 硅酸盐通报, 2023, 42(3): 845-853.
[8]	陈文瑶, 张卓翔, 孟二从, 黎强. 膨润土和玄武岩纤维改性水泥砂浆的防渗抗裂性能[J]. 硅酸盐通报, 2023, 42(2): 439-447.
[9]	樊璐洋, 金子豪, 苏英, 崔程嘉, 王斌. 基于响应面法的半水磷石膏复合胶凝材料优化设计及性能研究[J]. 硅酸盐通报, 2023, 42(2): 626-636.
[10]	王济伟, 李家科, 刘欣, 江和栋, 郭平春, 朱华, 王艳香. 核桃壳粉为碳源制备C@ZrSiO₄黑色色料[J]. 硅酸盐通报, 2023, 42(2): 657-665.
[11]	彭全敏, 陈炳蔚, 张彦, 鹿群, 刘洛源, 郭晓宇. 废PET塑料纤维对再生混凝土基本性能的影响[J]. 硅酸盐通报, 2023, 42(2): 666-673.
[12]	宋绍辉, 李亚伟, 廖宁, 张思思, 刘文静, 李月英, 铁生年. 基于水氯镁石合成水合硅酸镁及其在镁质浇注料的应用[J]. 硅酸盐通报, 2023, 42(2): 751-760.
[13]	姜同辉, 杨雄峰, 阳佳丁, 钱枫华, 平乐, 杨腾宇, 王晶, 张营, 冷发光. 石粉种类及含量对C60机制砂混凝土性能的影响[J]. 硅酸盐通报, 2023, 42(1): 92-99.
[14]	徐伟, 鲁亚, 刘松柏, 肖民, 陈忠发, 魏琦, 严峻. 碱激发-碳养护对铜尾矿固化砖的作用机理研究[J]. 硅酸盐通报, 2023, 42(1): 188-195.
[15]	陆亚运, 罗旭, 刘川北. 不同减水剂对高强石膏浆体工作性的影响与作用机理[J]. 硅酸盐通报, 2023, 42(1): 205-212.

早期水热养护对铝酸钙水泥结构稳定性的影响

Effect of Early-Age Hydrothermal Curing on Structural Stability of Calcium Aluminate Cement

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价