不同养护制度下大掺量石灰石煅烧黏土UHPC早期水化及力学性能发展

硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (6): 1879-1887.

所属专题：水泥混凝土

不同养护制度下大掺量石灰石煅烧黏土UHPC早期水化及力学性能发展

董烨民^1,2, 胡传林^1,2

1.武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070;
2.武汉理工大学材料科学与工程学院,武汉 430070

收稿日期:2022-01-28 修订日期:2022-03-21 出版日期:2022-06-15 发布日期:2022-07-01
通信作者: 胡传林,研究员。E-mail:chuanlin@whut.edu.cn
作者简介:董烨民(1995—),男,硕士研究生。主要从事绿色高性能混凝土性能研究。E-mail:aqdym250@163.com
基金资助:
国家重点研发计划政府间国际科技创新合作重点专项(2018YFE0106300)

Hydration and Mechanical Properties Development of UHPC with Large Substitution Level ofLimestone and Calcined Clay at Early Stage under Different Curing Regimes

DONG Yemin^1,2, HU Chuanlin^1,2

1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China;
2. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China

Received:2022-01-28 Revised:2022-03-21 Online:2022-06-15 Published:2022-07-01

摘要/Abstract

摘要： 采用大掺量(60%,质量分数)石灰石煅烧黏土替代水泥熟料设计制备了超高性能混凝土(UHPC),通过抗压强度测试、X射线衍射(XRD)分析、等温量热分析以及综合热分析研究了其在标准养护和蒸汽养护下的早期水化行为和力学性能发展。研究发现,蒸汽养护显著改善了由高水泥替代量造成的1 d及3 d抗压强度损失,标准养护则使7 d抗压强度更为优异,煅烧黏土和石灰石质量比为2∶1时各个龄期的强度发展最佳。在蒸汽养护条件下水化进程得到大幅提前,出现明显的铝酸盐相反应放热峰。蒸汽养护加剧了煅烧黏土对氢氧化钙的消耗,煅烧黏土和石灰石质量比为2∶1时才检测到单碳型碳铝酸盐的形成,表明在低水胶比环境下,早期煅烧黏土与石灰石的协同作用主要取决于活性组分煅烧黏土的含量。

关键词: 石灰石, 煅烧黏土, 超高性能混凝土, 火山灰效应, 抗压强度, 水化产物, 水化动力学, 蒸汽养护

Abstract: Ultra-high performance concrete (UHPC) was designed and prepared by using large substitution level (60%, mass fraction) of limestone and calcined clay instead of cement. Its early hydration behavior and mechanical properties under standard curing and steam curing were studied by compressive strength test, X-ray diffraction (XRD) analysis, isothermal calorimetry analysis and comprehensive thermal analysis. It is found that steam curing significantly improves the loss of compressive strength caused by high cement substitution at 1 d and 3 d, while standard curing brings more excellent compressive strength at 7 d. When the mass ratio of calcined clay to limestone is 2 ∶1, the strength development of each age is the best. The hydration process is greatly accelerated under the condition of steam curing, and there is an obvious exothermic peak of aluminate phase reaction. Steam curing intensifies the consumption of calcium hydroxide by calcined clay, and the formation of monocarboaluminate is detected only when the mass ratio of calcined clay to limestone is 2 ∶1, indicating that in the environment of low water to binder ratio, the synergistic effect of early calcined clay and limestone mainly depends on the content of calcined clay.

Key words: limestone, calcined clay, ultra-high performance concrete, pozzolanic effect, compressive strength, hydration product, hydration kinetics, steam curing

中图分类号:

TU528

董烨民, 胡传林. 不同养护制度下大掺量石灰石煅烧黏土UHPC早期水化及力学性能发展[J]. 硅酸盐通报, 2022, 41(6): 1879-1887.

DONG Yemin, HU Chuanlin. Hydration and Mechanical Properties Development of UHPC with Large Substitution Level ofLimestone and Calcined Clay at Early Stage under Different Curing Regimes[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(6): 1879-1887.

参考文献

[1] 钟蕴为,吴永魁,文许高媛,等.超高性能混凝土(UHPC)基本性能研究综述[J].混凝土与水泥制品,2021(9):1-4.
ZHONG Y W, WU Y K, WEN X G Y, et al. Summary of research on basic performance of ultra-high performance concrete[J]. China Concrete and Cement Products, 2021(9): 1-4 (in Chinese).
[2] AHMAD S. Use of alternative waste materials in producing ultra-high performance concrete[J]. MATEC Web of Conferences, 2017, 120: 03014.
[3] CHEN Y, MATALKAH F, SOROUSHIAN P, et al. Optimization of ultra-high performance concrete, quantification of characteristic features[J]. Cogent Engineering, 2019, 6(1): 1558696.
[4] DU J, MENG W N, KHAYAT K H, et al. New development of ultra-high-performance concrete (UHPC)[J]. Composites Part B: Engineering, 2021, 224: 109220.
[5] YU R, SPIESZ P, BROUWERS H J H. Mix design and properties assessment of ultra-high performance fibre reinforced concrete (UHPFRC)[J]. Cement and Concrete Research, 2014, 56: 29-39.
[6] WONG H H C, KWAN A K H. Packing density of cementitious materials: part 1—measurement using a wet packing method[J]. Materials and Structures, 2008, 41(4): 689-701.
[7] GRAYBEAL B. Material property characterization of ultra-high performance concrete[R]. FHWA-HRT-06-103, 2006.
[8] RICHARD P, CHEYREZY M. Composition of reactive powder concretes[J]. Cement and Concrete Research, 1995, 25(7): 1501-1511.
[9] KORPA A, KOWALD T, TRETTIN R. Phase development in normal and ultra high performance cementitious systems by quantitative X-ray analysis and thermoanalytical methods[J]. Cement and Concrete Research, 2009, 39(2): 69-76.
[10] MUZENDA T R, HOU P K, KAWASHIMA S, et al. The role of limestone and calcined clay on the rheological properties of LC3[J]. Cement and Concrete Composites, 2020, 107: 103516.
[11] MARTIRENA F, FAVIER A, SCRIVENER K. Calcined clays for sustainable concrete[M]. Dordrecht: Springer Netherlands, 2018.
[12] PUERTA-FALLA G, BALONIS M, SAOUT G, et al. The influence of metakaolin on limestone reactivity in cementitious materials[C]//Calcined Clays for Sustainable Concrete, 2015.
[13] ZHANG D, JAWORSKA B, ZHU H, et al. Engineered cementitious composites (ECC) with limestone calcined clay cement (LC3)[J]. Cement and Concrete Composites, 2020, 114: 103766.
[14] ANTONI M, ROSSEN J, MARTIRENA F, et al. Cement substitution by a combination of metakaolin and limestone[J]. Cement and Concrete Research, 2012, 42(12): 1579-1589.
[15] SUN Y, YU R, WANG S Y, et al. Development of a novel eco-efficient LC2 conceptual cement based ultra-high performance concrete (UHPC) incorporating limestone powder and calcined clay tailings: design and performances[J]. Journal of Cleaner Production, 2021, 315: 128236.
[16] MO Z Y, WANG R, GAO X J. Hydration and mechanical properties of UHPC matrix containing limestone and different levels of metakaolin[J]. Construction and Building Materials, 2020, 256: 119454.
[17] MITCHELL J K, SOGA K. Fundamentals of soil behavior[M]. 3rd ed. Wiley, 2005.
[18] FERNANDEZ R, MARTIRENA F, SCRIVENER K L. The origin of the pozzolanic activity of calcined clay minerals: a comparison between kaolinite, illite and montmorillonite[J]. Cement and Concrete Research, 2011, 41(1): 113-122.
[19] MENG W N, KHAYAT K H. Effect of hybrid fibers on fresh properties, mechanical properties, and autogenous shrinkage of cost-effective UHPC[J]. Journal of Materials in Civil Engineering, 2018, 30(4): 04018030.
[20] SHAH V, PARASHAR A, MISHRA G, et al. Influence of cement replacement by limestone calcined clay pozzolan on the engineering properties of mortar and concrete[J]. Advances in Cement Research, 2020, 32(3): 101-111.
[21] VANCE K, AGUAYO M, OEY T, et al. Hydration and strength development in ternary Portland cement blends containing limestone and fly ash or metakaolin[J]. Cement and Concrete Composites, 2013, 39: 93-103.
[22] IPAVEC A, GABROVŠEK R, VUK T, et al. Carboaluminate phases formation during the hydration of calcite-containing Portland cement[J]. Journal of the American Ceramic Society, 2011, 94(4): 1238-1242.
[23] HUANG W, KAZEMI-KAMYAB H, SUN W, et al. Effect of replacement of silica fume with calcined clay on the hydration and microstructural development of eco-UHPFRC[J]. Materials & Design, 2017, 121: 36-46.
[24] AVET F, SCRIVENER K. Investigation of the calcined kaolinite content on the hydration of limestone calcined clay cement (LC3)[J]. Cement and Concrete Research, 2018, 107: 124-135.
[25] 杜惠惠,倪文,高广军.水淬高钛高炉渣制备C40全固废混凝土试验研究[J].材料导报,2020,34(24):24055-24060.
DU H H, NI W, GAO G J. Experimental study on preparation of C40 concrete with industrial solid wastes from high-titanium blast furnace slag[J]. Materials Reports, 2020, 34(24): 24055-24060 (in Chinese).
[26] 胡建城,吕阳,何晨昊,等.纳米二氧化硅粉末对水泥-粉煤灰体系泡沫混凝土力学性能及水化的影响[J].硅酸盐通报,2019,38(5):1390-1394.
HU J C, LYU Y, HE C H, et al. Effect of nano-silica on mechanical properties and hydration of foamed concrete in the cement-fly ash system[J]. Bulletin of the Chinese Ceramic Society, 2019, 38(5): 1390-1394 (in Chinese).
[27] 张旭龙.水泥基材料水化热动力学研究[D].武汉:武汉理工大学,2011.
ZHANG X L. Thermokinetic study on hydration of cementitious materials[D]. Wuhan: Wuhan University of Technology, 2011 (in Chinese).

不同养护制度下大掺量石灰石煅烧黏土UHPC早期水化及力学性能发展

Hydration and Mechanical Properties Development of UHPC with Large Substitution Level ofLimestone and Calcined Clay at Early Stage under Different Curing Regimes

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