玻璃工业窑炉节能减排热化学再生设计

硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (11): 3886-3892.

所属专题：玻璃

玻璃工业窑炉节能减排热化学再生设计

曾红杰^1,2, 张纲^1,2, 马立云^1,2, 官敏^1,2, 周文彩^1,2, 王川申^1,2, 左泽方^1,2

1.国家玻璃新材料创新中心,蚌埠 233000;
2.中国建材国际工程集团有限公司,上海 200063

收稿日期:2022-10-10 修订日期:2022-11-01 出版日期:2022-11-15 发布日期:2022-12-12
通信作者: 左泽方,教授级高级工程师。E-mail:zzfks@126.com
作者简介:曾红杰(1982—),男,博士。主要从事节能减排的研究。E-mail:pepsi.100@163.com
基金资助:
国家玻璃新材料创新中心自立课题(K22008)

Thermo-Chemical Regeneration Design for Energy Saving and Emission Reduction of Glass Industry Furnace

ZENG Hongjie^1,2, ZHANG Gang^1,2, MA Liyun^1,2, GUAN Min^1,2, ZHOU Wencai^1,2, WANG Chuanshen^1,2, ZUO Zefang^1,2

1. National Innovation Center for Advanced Glass Materials, Bengbu 233000, China;
2. China Triumph International Engineering Co. Ltd., Shanghai 200063, China

Received:2022-10-10 Revised:2022-11-01 Online:2022-11-15 Published:2022-12-12

摘要/Abstract

摘要： 燃料燃烧是玻璃工业碳排放的主要来源。热化学再生技术能够显著降低玻璃窑炉熔化能耗,减少碳排放。本文通过计算和模拟研究了玻璃窑炉热化学重整反应的可行性,设计参数对重整反应的影响,气体转化率对玻璃窑炉节能效率的影响以及重整反应时间对气体转化率和产量的影响。结果表明:甲烷与水蒸气自发反应温度大于617.82 ℃,与二氧化碳自发反应温度大于641.27 ℃;当重整反应温度大于1 000 ℃,反应时间超过10 s,甲烷与窑炉废气流量比(摩尔比)接近1时,热化学重整反应能够充分进行。

关键词: 玻璃窑炉, 节能减排, 热化学再生, 节能效率, 反应温度, 反应时间

Abstract: Fuel combustion is the main source of carbon emission in glass industry. Thermo-chemical regeneration technology can significantly reduce the melting energy consumption and carbon emission of glass furnace. In this paper, the feasibility of thermo-chemical reforming reaction in glass furnace, the effects of design parameters on thermo-chemical reforming reaction, the effect of gas conversion on energy saving efficiency of glass furnace and the effect of thermo-chemical reforming reaction time on gas conversion and yield were studied through calculation and simulation. The results show that the spontaneous reaction temperature of methane and water vapour is more than 617.82 ℃, and the spontaneous reaction temperature of methane and carbon dioxide is more than 641.27 ℃. In addition, when the reforming reaction temperature is greater than 1 000 ℃, the reaction time is greater than 10 s, and the flow ratio (molar ratio) of methane to furnace waste gas is close to 1, the thermo-chemical reforming reaction can be fully carried out.

Key words: glass furnace, energy saving and emission reduction, thermo-chemical regeneration, energy efficiency, reaction temperature, reaction time

中图分类号:

TQ171.62

曾红杰, 张纲, 马立云, 官敏, 周文彩, 王川申, 左泽方. 玻璃工业窑炉节能减排热化学再生设计[J]. 硅酸盐通报, 2022, 41(11): 3886-3892.

ZENG Hongjie, ZHANG Gang, MA Liyun, GUAN Min, ZHOU Wencai, WANG Chuanshen, ZUO Zefang. Thermo-Chemical Regeneration Design for Energy Saving and Emission Reduction of Glass Industry Furnace[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3886-3892.

参考文献

[1] 张景焘,张佰恒.中国平板玻璃工业发展现状、未来走势及对策[J].玻璃,2004,31(5):10-20.
ZHANG J T, ZHANG B H. Development status, future trend and countermeasures of China's flat glass industry [J]. Glass, 2004, 31(5): 10-20 (in Chinese).
[2] 崔兴光,王均光,沈建兴,等.玻璃窑炉节能减排技术改造及应用[J].玻璃搪瓷与眼镜,2022,50(4):24-29+10.
CUI X G, WANG J G, SHEN J X, et al. Technical improvement and application of energy conservation and pollution reduction for glass furnace[J]. Glass Enamel ＆ Ophthalmic Optics, 2022, 50(4): 24-29+10 (in Chinese).
[3] 胡安锋,王沛钊.玻璃工业节能减排的可持续性思考[J].玻璃搪瓷与眼镜,2020,48(5):41-42+25.
HU A F, WANG P Z. The sustainable thoughts on energy-saving and emission reduction in the glass industry[J]. Glass Enamel ＆ Ophthalmic Optics, 2020, 48(5): 41-42+25 (in Chinese).
[4] 赵旭辉,陈松林,冯中起,等.我国玻璃工业和玻璃窑用硅砖的现状及发展趋势[J].玻璃,2011,38(3):16-19.
ZHAO X H, CHEN S L, FENG Z Q, et al. Technology situation and development trend of China's glass industry and silica brick used in glass furnace[J]. Glass, 2011, 38(3): 16-19 (in Chinese).
[5] 赵万帮.中国日用玻璃产业现状与发展前景[J].硅酸盐通报,2015,34:21-29.
ZHAO W B. Current status and development prospect of China's daily glass industry[J]. Bulletin of the Chinese Ceramic Society, 2015, 34: 21-29 (in chinese).
[6] 赵万帮.“十三五”日用玻璃行业节能减排形势分析[J].玻璃与搪瓷,2016,44(3):47-52.
ZHAO W B. Analysis of situation of energy saving and emission reduction in domestic glass industry during the period of 13th five year plan[J]. Glass ＆ Enamel, 2016, 44(3): 47-52 (in Chinese).
[7] 沈洋.《硅酸盐学报》“能源材料”专题前言[J].硅酸盐学报,2021,49(7):1245-1246.
SHEN Y. Preface to “energy materials” in Journal of the Chinese Ceramic Society[J]. Journal of the Chinese Ceramic Society, 2021, 49(7): 1245-1246 (in Chinese).
[8] 李晓曦.玻璃窑炉中石油焦粉富氧燃烧特性研究[D].北京:北京交通大学,2012.
LI X X. Oxygen-enriched combustion characteristics of petroleum coke in glass furnace[D]. Beijing: Beijing Jiaotong University, 2012 (in Chinese).
[9] 王保平.液晶玻璃基板生产负压澄清技术探讨[J].玻璃与搪瓷,2019,47(5):25-28.
WANG B P. Discussion on the negative pressure refining technology for liquid crystal glass substrate[J]. Glass ＆ Enamel, 2019, 47(5): 25-28 (in Chinese).
[10] 黄利光,任志威,吴加锋.负压澄清浮法玻璃熔窑设计探讨[J].玻璃,2013,40(6):13-15.
HUANG L G, REN Z W, WU J F. Discussion on the design of negative pressure refining of float glass furnace[J]. Glass, 2013, 40(6): 13-15 (in Chinese).
[11] 陈旭晔,丁明,张洪涛,等.浮法玻璃熔窑烟气治理和利用[J].材料科学与工程学报,2012,30(1):145-149.
CHEN X Y, DING M, ZHANG H T. Processing and utilization for flue gas of float glass furnace[J]. Journal of Materials Science and Engineering, 2012, 30(1): 145-149 (in Chinese).
[12] 谭汀.玻璃熔窑烟气余热利用项目综合效益评价[D].北京:清华大学,2017:2-10.
TAN T. Comprehensive benefit evaluation of waste heat utilization project in glass furnace[D]. Beijing: Tsinghua University, 2017: 2-10 (in Chinese).
[13] 张端.玻璃生产中优化问题的研究:窑炉保温优化设计和玻璃配合料优化计算[D].杭州:浙江大学,2002:1-5.
ZHANG D. Two optimization techniques about glass industry: optimum design of heat insulation of glass furnaces and optimization of batch calculation of glass[D]. Hangzhou: Zhejiang University, 2002: 1-5 (in Chinese).
[14] GONZALEZ A, SOLORZANO E, LAGOS C, et al. Optimelt^TM regenerative thermo-chemical heat recovery for oxy-fuel glass furnaces[M]//75th Conference on Glass Problems. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2015: 113-120.
[15] VAN VALBURG M, SPERRY E, HOLLAND L, et al. Design and implementation of Optimelt^TM heat recovery for an oxy-fuel furnace at libbey leerdam[J]. Ceramic Engineering and Science Proceedings, 2018, 39(1): 89-97.
[16] VAN VALBURG M, SCHUURMANS F, SPERRY E, et al. Operating experience with the OPTIMELT^TM heat recovery technology on a tableware glass furnace[M]//79th Conference on Glass Problems. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2019: 201-211.
[17] VAN VALBURG M, SCHUURMANS F, DE DIEGO J, et al. OPTIMELT operating data from an OPTIMELT^TM thermo-chemical regenerator system on a tableware glass furnace at Libbey Leerdam [J]. Glass Machine Plants and Accessories, 2021(1): 28-32.
[18] POPOV S K, SVISTUNOV I N, GARYAEV A B, et al. The use of thermochemical recuperation in an industrial plant[J]. Energy, 2017, 127: 44-51.
[19] AMIN M H, SUDARSANAM P, FIELD M R, et al. Effect of a swelling agent on the performance of Ni/porous silica catalyst for CH₄-CO₂ reforming[J]. Langmuir: the ACS Journal of Surfaces and Colloids, 2017, 33(40): 10632-10644.
[20] DE MIGUEL S R, VILELLA I M J, MAINA S P, et al. Influence of Pt addition to Ni catalysts on the catalytic performance for long term dry reforming of methane[J]. Applied Catalysis A: General, 2012, 435/436: 10-18.
[21] SANG L X, SUN B, TAN H Y, et al. Catalytic reforming of methane with CO₂ over metal foam based monolithic catalysts[J]. International Journal of Hydrogen Energy, 2012, 37(17): 13037-13043.
[22] KIM G J, CHO D S, KIM K H, et al. The reaction of CO₂ with CH₄ to synthesize H₂ and CO over nickel-loaded Y-zeolites[J]. Catalysis Letters, 1994, 28(1): 41-52.
[23] HASSAN AMIN M. A mini-review on CO₂ reforming of methane[J]. Progress in Petrochemical Science, 2018, 2(2): 161-165.

玻璃工业窑炉节能减排热化学再生设计

Thermo-Chemical Regeneration Design for Energy Saving and Emission Reduction of Glass Industry Furnace

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	曹永丹, 赵天悦, 曹钊, 张金山, 董红娟. 脱硫石膏制备硫酸钙晶须的试验研究[J]. 硅酸盐通报, 2022, 41(5): 1765-1773.
[2]	毛利民, 李庆元, 杨海云, 曾海军, 刘继旺, 卿晓斌, 王智勇, 朱伟, 杨智超. 含Y₂O₃熔铸41^#AZS材料抗玻璃液侵蚀性能研究[J]. 硅酸盐通报, 2022, 41(4): 1195-1201.
[3]	胡盛, 张明浩, 胡卫兵. 反应时间对镁铝水滑石制备及其吸附性能的影响[J]. 硅酸盐通报, 2021, 40(3): 1022-1028.
[4]	钱敏, 邹兆松, 唐景平, 蒋亚丝, 徐永春, 胡丽丽. 用于低损耗特种玻璃熔炼的高纯致密锆英石的研制[J]. 硅酸盐通报, 2020, 39(12): 4003-4009.
[5]	孟旭;谢祥兵;李广慧;张攀;栗鹏;赵文辉. 基于正交灰关联分析的纳米碳粉/橡胶粉复合改性沥青制备工艺试验研究[J]. 硅酸盐通报, 2019, 38(8): 2642-264.
[6]	张楠;郑伍魁;丁松雄;李辉. 悬浮态干法造粒工艺制备陶瓷墙地砖坯体粉料的工艺参数研究[J]. 硅酸盐通报, 2018, 37(3): 831-836.
[7]	刘义;王军华;郝斌;闫世友;陈朝阳. 类蛭石结构纳米层状硅酸盐材料的水热法合成[J]. 硅酸盐通报, 2017, 36(1): 257-261.
[8]	王俊杰;魏丽颖;汪澜. 水泥行业节能减排技术评价体系研究[J]. 硅酸盐通报, 2014, 33(5): 1268-1274.
[9]	胡昌盛;张毅. 玻璃窑炉局部富氧燃烧的研究[J]. 硅酸盐通报, 2012, 31(4): 1002-1005.
[10]	李慧勤. 水热合成Zn1-xCrxO稀磁半导体晶体的研究[J]. 硅酸盐通报, 2011, 30(2): 474-477.
[11]	李会平;顾骏伟. 氧含量对富氧燃烧玻璃熔窑热工特性的影响[J]. 硅酸盐通报, 2010, 29(5): 1197-1201.
[12]	韩韬;刘宗明;李贤松;赵蔚琳;张铁柱. 单元玻璃窑炉富氧燃烧空间的数值模拟研究[J]. 硅酸盐通报, 2010, 29(1): 77-82.
[13]	于颖;陈志武;胡建强;何新华;卢振亚. 钛酸铋纳米粉体的水热合成及表征[J]. 硅酸盐通报, 2009, 28(z1): 86-89.
[14]	汪潇;黄金亮;杨留栓;王秋珂;殷镖. Bi1.5ZnNb1.5O7纳米粉体的水热合成与表征[J]. 硅酸盐通报, 2007, 26(4): 691-694.
[15]	王干一;吴春诚;吴相林. 玻璃窑炉的无模型自适应控制[J]. 硅酸盐通报, 2007, 26(1): 159-161.