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硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (11): 3819-3825.

所属专题: 玻璃

• 微晶玻璃 • 上一篇    下一篇

锂铝硅透明微晶玻璃析晶动力学研究

彭志钢1,2, 袁坚1,2, 杜晓欧2, 郑伟宏1,2, 张茂森2, 薛瑞锋2, 史连莹2   

  1. 1.武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070;
    2.河北省沙河玻璃技术研究院,邢台 054100
  • 收稿日期:2022-08-13 修订日期:2022-08-30 出版日期:2022-11-15 发布日期:2022-12-12
  • 通信作者: 袁 坚,博士,教授。E-mail:248725407@qq.com
  • 作者简介:彭志钢(1983—),男,高级工程师。主要从电子玻璃/微晶玻璃方面的研究。E-mail:gangzhp@163.com
  • 基金资助:
    硅酸盐建筑材料国家重点实验室(武汉理工大学)开放基金(2011DA105356)

Crystallization Kinetics of Lithium Aluminum Silicate Transparent Glass-Ceramics

PENG Zhigang1,2, YUAN Jian1,2, DU Xiaoou2, ZHENG Weihong1,2, ZHANG Maosen2, XUE Ruifeng2, SHI Lianying2   

  1. 1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China;
    2. Shahe Glass Technology Research Institute, Xingtai 054100, China
  • Received:2022-08-13 Revised:2022-08-30 Online:2022-11-15 Published:2022-12-12

摘要: 本文利用经典方程(Johnson-Mehl-Avrami)分析了非化学计量的锂铝硅Li2O-Al2O3-SiO2-ZrO2-P2O5透明微晶玻璃的析晶动力学,采用DSC、XRD和SEM研究了晶化温度对玻璃析晶行为的影响。结果表明:在较低的起始析晶温度下Li2Si2O5和Li2SiO3析出,随晶化温度的升高,主晶相转变为LiAlSi4O10,Li2SiO3晶相消失,晶体尺寸变小,在550 nm处微晶玻璃透过率由89.3%升高到90.6%;利用Kissinger方法计算出的Li2Si2O5和LiAlSi4O10的析晶活化能分别为349.5 kJ/mol和184.2 kJ/mol,平均晶体生长指数分别为3.05和1.42。

关键词: Li2O-Al2O3-SiO2-ZrO2-P2O5, 透明微晶玻璃, 析晶动力学, 析晶行为, 活化能

Abstract: The crystallization kinetics of lithium aluminum silicate Li2O-Al2O3-SiO2-ZrO2-P2O5 transparent glass-ceramics was analyzed by using the classical equation (Johnson-Mehl-Avrami). The influence of crystallization temperature on the crystallization behavior of glass was studied by DSC, XRD and SEM. The results show that Li2Si2O5 and Li2SiO3 precipitate at lower initial crystallization temperature. With the increase of crystallization temperature, the main crystal phase changes to LiAlSi4O10, Li2SiO3 disappears and the crystal size decreases, and the transmittance of glass-ceramics increases from 89.3% to 90.6% at 550 nm. The activation energies of crystallization of Li2Si2O5 and LiAlSi4O10 are calculated by Kissinger method to be 349.5 kJ/mol and 184.2 kJ/mol, and the average crystal growth indices are 3.05 and 1.42, respectively.

Key words: Li2O-Al2O3-SiO2-ZrO2-P2O5, transparent glass-ceramics, crystallization kinetics, crystallization behavior, activation energy

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