锌镁替换铝硅酸盐玻璃的玻璃转变和晶化行为探索

硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (11): 3806-3812.

所属专题：玻璃

锌镁替换铝硅酸盐玻璃的玻璃转变和晶化行为探索

黄欣, 王兵兵, 顾少轩, 乔昂, 陶海征

武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070

收稿日期:2022-03-23 修订日期:2022-05-23 出版日期:2022-11-15 发布日期:2022-12-12
通信作者: 乔昂,博士,研究员。E-mail:aq@whut.edu.cn;陶海征,博士,研究员。E-mail:thz@whut.edu.cn
作者简介:黄欣(1997—),女,硕士研究生。主要从事非晶态玻璃材料的研究。E-mail:2536101390@qq.com
基金资助:
国家自然科学基金面上项目(22175135,52172007)

Exploration on Glass Transition and Crystallization Behavior in Aluminosilicate Glasses with Substitution of MgO by ZnO

HUANG Xin, WANG Bingbing, GU Shaoxuan, QIAO Ang, TAO Haizheng

State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China

Received:2022-03-23 Revised:2022-05-23 Online:2022-11-15 Published:2022-12-12

摘要/Abstract

摘要： 作为重要的透明微晶玻璃体系,含镁锌的铝硅酸盐玻璃展现了优异的力学、光学特性。大量研究关注该体系的核化和晶体生长过程,但锌镁替换对铝硅酸盐玻璃玻璃转变和晶化行为影响的物理机理尚不明晰。本研究以xZnO·(11-x)MgO·22Al₂O₃·67SiO₂(x%=0%,2.2%,5.5%,8.8%,11.0%,摩尔分数)玻璃为研究对象,探究锌镁替换对铝硅酸盐玻璃的玻璃转变和晶化行为的调控规律。结果表明:随着锌逐步替换镁,玻璃转变温度慢慢下降,这是由于Zn²⁺较弱的场强和多一个电子层的屏蔽作用,玻璃网络骨架整体键合强度降低;析出晶相从单一的莫来石相转变为莫来石与锌铝尖晶石的混合相,这是由于Zn²⁺具有促进铝硅酸玻璃分相的作用;析晶温度降低,这主要是由于析晶温度附近黏温曲线变得更陡峭和析晶活化能降低。

关键词: 铝硅酸盐玻璃, ZnO, 玻璃转变, 晶化行为, 结构, 微不均匀性

Abstract: As an important transparent glass ceramic system, ZnO-MgO-Al₂O₃-SiO₂ glass exhibits excellent mechanical and optical properties. Numerous studies have focused on the mechanism of controllable nucleation and crystal growth, but the physical mechanism of the substitution of MgO by ZnO on glass transition and crystallization behavior of aluminosilicate glass is not clear. In this work, the effect of the substitution of MgO by ZnO on the glass transition and crystallization behaviors of xZnO·(11-x)MgO·22Al₂O₃·67SiO₂ (x%=0%, 2.2%, 5.5%, 8.8%, 11.0%, mole fraction) glasses was studied. The results show that the glass transition temperature of studied glasses decreases with the substitution of MgO by ZnO, and it can be ascribed to the decrease of the average bonding strength of the glass network, which is induced by the weaker field strength and shielding effect of an extra electron layer in Zn²⁺ compared to Mg²⁺. The crystallization phases transfer from singe mullite to the mixture of mullite and zinc aluminate gahnite due to the addition of ZnO causing the phase separation of aluminosilicate glass. The substitution of MgO by ZnO causes a steeper viscosity curve around crystallization temperature and decreases the crystallization activation energy of the glasses, resulting in the shift of crystallization peaks to lower temperature.

Key words: aluminosilicate glass, ZnO, glass transition, crystallization behavior, structure, inhomogeneity

中图分类号:

TQ171

黄欣, 王兵兵, 顾少轩, 乔昂, 陶海征. 锌镁替换铝硅酸盐玻璃的玻璃转变和晶化行为探索[J]. 硅酸盐通报, 2022, 41(11): 3806-3812.

HUANG Xin, WANG Bingbing, GU Shaoxuan, QIAO Ang, TAO Haizheng. Exploration on Glass Transition and Crystallization Behavior in Aluminosilicate Glasses with Substitution of MgO by ZnO[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3806-3812.

参考文献

[1] 李子煌,高运周,范仕刚,等.超低膨胀微晶玻璃中飞秒激光直写波导探索[J].硅酸盐通报,2021,40(11):3784-3790.
LI Z H, GAO Y Z, FAN S G, et al. Femtosecond laser direct written waveguides in ultra-low expansion glass-ceramics[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(11): 3784-3790 (in Chinese).
[2] 王琰,高运周,陶海征,等.铝酸钙准二元玻璃硬度和抗碎裂性组成依赖的结构起源探究[J].硅酸盐通报,2021,40(10):3504-3510.
WANG Y, GAO Y Z, TAO H Z, et al. Structural origin revealing of dependence of hardness and crack resistance on composition in CaO-Al₂O₃ pseudo-binary glass system[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(10): 3504-3510 (in Chinese).
[3] 丁志松,王兵兵,王振涛,等.铝硅准二元玻璃硬度和抗碎裂性演化的结构起源[J].硅酸盐学报,2022,50(4):894-901.
DING Z S, WANG B B, WANG Z T, et al. Structural origin of hardness and crack resistance in aluminosilicate glass[J]. Journal of the Chinese Ceramic Society, 2022, 50(4): 894-901 (in Chinese).
[4] DITTMER M, RÜSSEL C. Colorless and high strength MgO/Al₂O₃/SiO₂ glass-ceramic dental material using zirconia as nucleating agent[J]. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 2012, 100B(2): 463-470.
[5] SEIDEL S, DITTMER M, HÖLAND W, et al. High-strength, translucent glass-ceramics in the system MgO-ZnO-Al₂O₃-SiO₂-ZrO₂[J]. Journal of the European Ceramic Society, 2017, 37(7): 2685-2694.
[6] DENG B H, SHI Y, ZHOU Q, et al. Revealing the structural role of MgO in aluminosilicate glasses[J]. Acta Materialia, 2022, 222: 117417.
[7] SMEDSKJAER M M, YOUNGMAN R E, MAURO J C. Impact of ZnO on the structure and properties of sodium aluminosilicate glasses: comparison with alkaline earth oxides[J]. Journal of Non-Crystalline Solids, 2013, 381: 58-64.
[8] CORMIER L, DELBES L, BAPTISTE B, et al. Vitrification, crystallization behavior and structure of zinc aluminosilicate glasses[J]. Journal of Non-Crystalline Solids, 2021, 555: 120609.
[9] MIRHADI B, MEHDIKHANI B, ASKARI N. Effect of zinc oxide on microhardness and sintering behavior of MgO-Al₂O₃-SiO₂ glass-ceramic system[J]. Solid State Sciences, 2012, 14(4): 430-434.
[10] DUMAS T, PETIAU J. EXAFS study of titanium and zinc environments during nucleation in a cordierite glass[J]. Journal of Non-Crystalline Solids, 1986, 81(1/2): 201-220.
[11] KE X F, SHAN Z T, LI Z H, et al. Toward hard and highly crack resistant magnesium aluminosilicate glasses and transparent glass-ceramics[J]. Journal of the American Ceramic Society, 2020, 103(6): 3600-3609.
[12] YUE Y Z, VON DER OHE R, JENSEN S L. Fictive temperature, cooling rate, and viscosity of glasses[J]. The Journal of Chemical Physics, 2004, 120(17): 8053-8059.
[13] SOLIMAN A A. Thermal stability of Cu_0.3(SSe₂₀)_0.7 chalcogenide glass by differential scanning calorimetry[J]. Thermochimica Acta, 2004, 423(1/2): 71-76.
[14] LEŚNIAK M, PARTYKA J, SITARZ M. Impact of ZnO on the structure of aluminosilicate glazes[J]. Journal of Molecular Structure, 2016, 1126: 251-258.
[15] WEIGEL C, LE LOSQ C, VIALLA R, et al. Elastic moduli of XAlSiO₄ aluminosilicate glasses: effects of charge-balancing cations[J]. Journal of Non-Crystalline Solids, 2016, 447: 267-272.
[16] NEUVILLE D R, CORMIER L, MASSIOT D. Al coordination and speciation in calcium aluminosilicate glasses: effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy[J]. Chemical Geology, 2006, 229(1/2/3): 173-185.
[17] 王振涛,顾少轩,丁志松,等.碱土替换铝硅酸盐玻璃硬度和玻璃转变温度反向演化的结构起源[J].硅酸盐学报,2022,50(4):879-885.
WANG Z T, GU S X, DING Z S, et al. Atomic-scale structural origin of reverse relationship between hardness and glass transition temperature of peraluminous aluminosilicate glasses with alkaline earth ions[J]. Journal of the Chinese Ceramic Society, 2022, 50(4): 879-885 (in Chinese).
[18] TOPLIS M J, KOHN S C, SMITH M E, et al. Fivefold-coordinated aluminum in tectosilicate glasses observed by triple quantum MAS NMR[J]. American Mineralogist, 2000, 85(10): 1556-1560.
[19] GREAVES G N, SEN S. Inorganic glasses, glass-forming liquids and amorphizing solids[J]. Advances in Physics, 2007, 56(1): 1-166.
[20] GUI H, LI C, LIN C W, et al. Glass forming, crystallization, and physical properties of MgO-Al₂O₃-SiO₂-B₂O₃ glass-ceramics modified by ZnO replacing MgO[J]. Journal of the European Ceramic Society, 2019, 39(4): 1397-1410.
[21] BECHGAARD T K, SCANNELL G, HUANG L P, et al. Structure of MgO/CaO sodium aluminosilicate glasses: Raman spectroscopy study[J]. Journal of Non-Crystalline Solids, 2017, 470: 145-151.
[22] NEUVILLE D R, CORMIER L, MASSIOT D. Al environment in tectosilicate and peraluminous glasses: a ²⁷Al MQ-MAS NMR, Raman, and XANES investigation[J]. Geochimica et Cosmochimica Acta, 2004, 68(24): 5071-5079.
[23] 张联盟,黄学辉,宋晓岚.材料科学基础[M].2版.武汉:武汉理工大学出版社,2008:189-190.
ZHANG L M, HUANG X H, SONG X L. Fundamentals of material science[M]. 2nd ed. Wuhan: Wuhan University of Technology Press, 2008: 189-190 (in Chinese).
[24] KISSINGER H E. Variation of peak temperature with heating rate in differential thermal analysis[J]. Journal of Research of the National Bureau of Standards, 1956, 57(4): 217-221.

锌镁替换铝硅酸盐玻璃的玻璃转变和晶化行为探索

Exploration on Glass Transition and Crystallization Behavior in Aluminosilicate Glasses with Substitution of MgO by ZnO

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	梁锐, 孔森, 张琰, 刘佳龙. 梳状纳米二氧化硅分散液的制备及对水泥基材料性能的提升[J]. 硅酸盐通报, 2023, 42(4): 1183-1193.
[2]	齐晓, 肖前慧, 邱继生, 刘书林. 冻融循环与硫酸盐侵蚀共同作用下再生混凝土的微观结构研究[J]. 硅酸盐通报, 2023, 42(4): 1194-1204.
[3]	殷实, 李北星, 陈鹏博, 金德川. 再生砂混凝土毛细吸水特性研究[J]. 硅酸盐通报, 2023, 42(4): 1205-1216.
[4]	郭毅松, 刘乐冕, 陈剑锋. 油茶粕绿色发泡剂制备泡沫混凝土的试验研究[J]. 硅酸盐通报, 2023, 42(4): 1226-1232.
[5]	周程涛, 陈波, 高志涵. 冻融环境下泡沫混凝土的单轴压缩特性[J]. 硅酸盐通报, 2023, 42(4): 1233-1241.
[6]	张虹宇, 郑玉龙, 陆春华. 两种养护制度下C100高强混凝土韧性对比试验研究[J]. 硅酸盐通报, 2023, 42(4): 1252-1259.
[7]	张劲竹, 刘华新, 王家贺, 柳根金, 王学志. 混杂纤维混凝土高温后性能劣化分析与强度预测[J]. 硅酸盐通报, 2023, 42(4): 1260-1269.
[8]	孙悦, 刘小青, 何峰, 邓玉华, 李润国, 张超, 郑现明, 谢峻林. 煅烧温度对低品位黏土物相和结构的影响[J]. 硅酸盐通报, 2023, 42(4): 1309-1314.
[9]	胡彪, 李先海, 晏祥政, 赵永庆. 热活化煤矸石粉对基体-骨料界面过渡区性能的影响[J]. 硅酸盐通报, 2023, 42(4): 1315-1322.
[10]	何俊, 管家贤, 吕晓龙, 张驰. 纳米硅粉改良碱渣-矿渣固化淤泥的抗硫酸镁侵蚀性能[J]. 硅酸盐通报, 2023, 42(4): 1344-1352.
[11]	刘扬, 陈湘, 王柏文, 鲁乃唯, 肖欣欣, 罗冬. 碱激发粉煤灰-矿渣-电石渣基地聚物的制备及强度机理[J]. 硅酸盐通报, 2023, 42(4): 1353-1362.
[12]	郑聪聪, 何峰, 张兵, 曹秀华, 张勇强, 魏明杰, 董鹏, 谢峻林. 铜浆料用ZnO-B₂O₃-SiO₂-BaO玻璃的结构和性能[J]. 硅酸盐通报, 2023, 42(4): 1475-1487.
[13]	周剑峰, 杨涛, 张菁燕, 周文平, 高璇. 早期水热养护对铝酸钙水泥结构稳定性的影响[J]. 硅酸盐通报, 2023, 42(3): 802-807.
[14]	张占强, 陈平, 李顺凯, 明阳, 刘荣进, 李航, 赵欢. 氧化镁膨胀剂对UHPC浆体早期孔结构演变的影响[J]. 硅酸盐通报, 2023, 42(3): 871-877.
[15]	葛成龙, 周海龙, 陈岩, 吕志刚. 不同MB值机制砂混凝土的性能和微观孔隙结构[J]. 硅酸盐通报, 2023, 42(3): 888-897.