粉体热压法制备As2Se3硫系玻璃研究

硅酸盐通报 ›› 2022, Vol. 41 ›› Issue (11): 3761-3767.

所属专题：玻璃

粉体热压法制备As₂Se₃硫系玻璃研究

马成^1,2, 杨安平¹, 李雷², 陈倩¹, 田康振¹, 刘自军³, 沈祥³, 杨志勇^1,2

1.江苏师范大学物理与电子工程学院,江苏省先进激光材料与器件重点实验室,徐州 221116;
2.杭州光学精密机械研究所,杭州 311421;
3.宁波大学高等技术研究院,红外材料及器件实验室,宁波 315211

收稿日期:2022-08-11 修订日期:2022-09-05 出版日期:2022-11-15 发布日期:2022-12-12
通信作者: 杨安平,博士,副教授。E-mail:apyang@jsnu.edu.cn
作者简介:马成(1998—),男,硕士研究生。主要从事红外玻璃的研究。E-mail:2482831426@qq.com
基金资助:
国家自然科学基金区域发展联合基金(U21A2056);浙江省重点研发计划(2021C01025)

Preparation of As₂Se₃ Chalcogenide Glasses by Powder Hot Pressing Method

MA Cheng^1,2, YANG Anping¹, LI Lei², CHEN Qian¹, TIAN Kangzhen¹, LIU Zijun³, SHEN Xiang³, YANG Zhiyong^1,2

1. Jiangsu Key Laboratory of Advanced Laser Materials and Devices, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
2. Hangzhou Institute of Optics and Fine Mechanics, Hangzhou 311421, China;
3. Laboratory of Infrared Materials and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China

Received:2022-08-11 Revised:2022-09-05 Online:2022-11-15 Published:2022-12-12

摘要/Abstract

摘要： 本研究尝试将As₂Se₃红外硫系透镜生产过程中产生的块体玻璃废料进行回收利用,首先将清洗后的块体玻璃废料球磨成粉体,然后采用粉体热压技术实现高光学质量As₂Se₃玻璃片的制备。研究了粉体粒度、热压参数对制备的As₂Se₃玻璃光学性能的影响,对比了粉体热压法和熔融淬冷法制备的As₂Se₃玻璃的性能,评估了通过粉体热压途径制备红外硫系玻璃的可行性。结果表明:随着球磨时间的延长,As₂Se₃玻璃粉体的平均颗粒尺寸逐渐减小,且颗粒尺寸的分布趋于更加均匀;使用平均颗粒尺寸为9.7 μm的粉体(球磨10 min),在压力为40 MPa、热压温度为250 ℃、热压时间为10 min的条件下获得的热压玻璃的致密度达到99.8%,其折射率与熔融淬冷法制备的玻璃的折射率接近(在10 μm波长的折射率差仅为0.003),在10 μm波长的透过率达61%(理论透过率为63.7%)。通过进一步提高玻璃粉体的纯度和尺寸均匀性,有望制备出与熔融淬冷法制备的玻璃性能相当的热压玻璃。

关键词: 硫系玻璃, 球磨, 热压, 红外透镜, 热成像, 红外技术

Abstract: This research attempts to recycle the bulk glass waste produced in the production of As₂Se₃ infrared chalcogenide lenses. First, the cleaned bulk glass waste was ground into powder, and then the powder hot pressing technique was used to achieve the high optical quality As₂Se₃ glass disks. The effects of powder size and hot pressing parameters on the optical properties of hot-pressed As₂Se₃ glasses were studied, the properties of As₂Se₃ glasses prepared by powder hot pressing method and melt quenching method were compared, and the feasibility of preparing infrared chalcogenide glass by powder hot pressing technique was evaluated. The experimental results show that the mean particle size of As₂Se₃ glass powder decreases gradually with the prolongation of milling time, and the distribution of particle size tends to be more uniform. Using the powder with mean particle size of 9.7 μm (the milling time is 10 min), a glass disk with compactness of 99.8% is obtained under the conditions of pressure of 40 MPa, hot pressing temperature of 250 ℃ and holding time of 10 min. The refractive index of the hot-pressed glass is close to that of the glass prepared by melt quenching method (the difference is only 0.003 at 10 μm), and its transmittance is as high as 61% at 10 μm (the theoretical transmittance is 63.7%). By further improving the purity and size uniformity of glass powder, it is expected to prepare hot-pressed glass with the same performance as the glass prepared by melt quenching method.

Key words: chalcogenide glass, ball milling, hot pressing, infrared lens, thermal imaging, infrared technology

中图分类号:

TN213

马成, 杨安平, 李雷, 陈倩, 田康振, 刘自军, 沈祥, 杨志勇. 粉体热压法制备As₂Se₃硫系玻璃研究[J]. 硅酸盐通报, 2022, 41(11): 3761-3767.

MA Cheng, YANG Anping, LI Lei, CHEN Qian, TIAN Kangzhen, LIU Zijun, SHEN Xiang, YANG Zhiyong. Preparation of As₂Se₃ Chalcogenide Glasses by Powder Hot Pressing Method[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(11): 3761-3767.

参考文献

[1] SEDDON A B, NAPIER B, LINDSAY I, et al. Prospective on using fibre mid-infrared supercontinuum laser sources for in vivo spectral discrimination of disease[J]. The Analyst, 2018, 143(24): 5874-5887.
[2] MOHD ALI M, HASHIM N, AZIZ S A, et al. Emerging non-destructive thermal imaging technique coupled with chemometrics on quality and safety inspection in food and agriculture[J]. Trends in Food Science & Technology, 2020, 105: 176-185.
[3] GLOWACZ A. Fault diagnosis of electric impact drills using thermal imaging[J]. Measurement, 2021, 171: 108815.
[4] 孙继平,范伟强.矿井红外热成像远距离测温误差分析与精确测温方法[J].煤炭学报,2022,47(4):1709-1722.
SUN J P, FAN W Q. Error analysis and accurate temperature measurement method of infrared thermal imaging long-distance temperature measurement in underground mine[J]. Journal of China Coal Society, 2022, 47(4): 1709-1722 (in Chinese).
[5] ZHU J Q, ZHU H, XU H L, et al. Ge-based mid-infrared blocked-impurity-band photodetectors[J]. Infrared Physics & Technology, 2018, 92: 13-17.
[6] KARAMI E, TAVOOSI M, GHASEMI A, et al. Fabrication of IR windows grade zinc selenide by the reactive diffusive process[J]. Ceramics International, 2019, 45(6): 7956-7960.
[7] CHOI J H, CHA D H, KIM J H, et al. Development of thermally stable and moldable chalcogenide glass for flexible infrared lenses[J]. Journal of Materials Research, 2016, 31(12): 1674-1680.
[8] KIM W H, NGUYEN V Q, SHAW L B, et al. Recent progress in chalcogenide fiber technology at NRL[J]. Journal of Non-Crystalline Solids, 2016, 431: 8-15.
[9] 刘永华,祖成奎,赵华,等.红外热成像系统用硫系玻璃的熔制技术[J].红外与激光工程,2015,44(5):1472-1476.
LIU Y H, ZU C K, ZHAO H, et al. Melting technology of chalcogenide glass for infrared thermal imaging system[J]. Infrared and Laser Engineering, 2015, 44(5): 1472-1476 (in Chinese).
[10] LAVANANT E, CALVEZ L, CHEVIRÉ F, et al. Radial gradient refractive index (GRIN) infrared lens based on spatially resolved crystallization of chalcogenide glass[J]. Optical Materials Express, 2020, 10(4): 860.
[11] CHA D H, KIM H J, HWANG Y, et al. Fabrication of molded chalcogenide-glass lens for thermal imaging applications[J]. Applied Optics, 2012, 51(23): 5649-5656.
[12] DENOUE K, LECOQ D, CALERS C, et al. New synthesis route for glasses and glass-ceramics in the Ga₂S₃Na₂S binary system[J]. Materials Research Bulletin, 2021, 142: 111423.
[13] YANG A P, QIU J H, REN J, et al. 1.8~2.7 μm emission from As-S-Se chalcogenide glasses containing ZnSe ∶Cr²⁺ particles[J]. Journal of Non-Crystalline Solids, 2019, 508: 21-25.
[14] XIA K L, LIU Z J, YUAN Y, et al. Broadband mid-infrared emission from Cr²⁺ in crystal-in-glass composite glasses by hot uniaxial pressing[J]. Journal of the American Ceramic Society, 2019, 102(11): 6618-6625.
[15] WOOLLAM J A, JOHS B D, HERZINGER C M, et al. Overview of variable-angle spectroscopic ellipsometry (VASE): I. Basic theory and typical applications[C]//SPIE's International Symposium on Optical Science, Engineering, and Instrumentation. Proc SPIE 10294, Optical Metrology: A Critical Review, Denver, CO, USA. 1999, 10294: 3-28.
[16] YANG Y, YANG Z Y, LUCAS P, et al. Composition dependence of physical and optical properties in Ge-As-S chalcogenide glasses[J]. Journal of Non-Crystalline Solids, 2016, 440: 38-42.
[17] REUX V, CALVEZ L, BILLON S, et al. High refractive index IR lenses based on chalcogenide glasses molded by spark plasma sintering[J]. Optical Materials Express, 2021, 11(6): 1622.
[18] SHIRYAEV V S, CHURBANOV M F. Recent advances in preparation of high-purity chalcogenide glasses for mid-IR photonics[J]. Journal of Non-Crystalline Solids, 2017, 475: 1-9.
[19] 陈国荣,程继健.高纯透红外硫系玻璃材料的制备[J].硅酸盐通报,1997,16(4):63-69.
CHEN G R, CHENG J J. Preparation of high purity chalcogenide glasses as an IR transmitting material[J]. Bulletin of Thechinese Ceramic Society, 1997, 16(4): 63-69 (in Chinese).
[20] LUCAS P, COLEMAN G J, JIANG S B, et al. Chalcogenide glass fibers: optical window tailoring and suitability for bio-chemical sensing[J]. Optical Materials, 2015, 47: 530-536.
[21] NAKAMOTO K. Comprar infrared and Raman spectra of inorganic and coordination compounds, part A, theory and applications in inorganic chemistry[M]. 6th ed. Hoboken, New Jersey: John Wiley & Sons, Inc., 2009: 174-175.
[22] LI W Y, SEAL S, RIVERO C, et al. Role of S/Se ratio in chemical bonding of As-S-Se glasses investigated by Raman, X-ray photoelectron, and extended X-ray absorption fine structure spectroscopies[J]. Journal of Applied Physics, 2005, 98(5): 053503.

粉体热压法制备As₂Se₃硫系玻璃研究

Preparation of As₂Se₃ Chalcogenide Glasses by Powder Hot Pressing Method

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