光固化ZrO2陶瓷料浆的流变性能研究

硅酸盐通报 ›› 2021, Vol. 40 ›› Issue (6): 1965-1971.

光固化ZrO₂陶瓷料浆的流变性能研究

韩卓群¹, 李伶², 刘时浩², 邱坤¹, 王守兴², 刘福田¹

1.济南大学材料科学与工程学院,济南 250022;
2.山东工业陶瓷研究设计院有限公司,淄博 255000

收稿日期:2021-03-22 修回日期:2021-05-21 出版日期:2021-06-15 发布日期:2021-07-08
通讯作者: 刘福田,博士,教授。E-mail:mse_liuft@ujn.edu.cn
作者简介:韩卓群(1994—),男,博士研究生。主要从事陶瓷光固化3D打印的研究。E-mail:765849056@qq.com
基金资助:
国家重点研发计划(2017YFB0310400);山东省重大科技创新工程项目(2019JZZY010440)

Research on Rheological Properties of Stereolithography ZrO₂ Ceramic Slurry

HAN Zhuoqun¹, LI Ling², LIU Shihao², QIU Kun¹, WANG Shouxing², LIU Futian¹

1. School of Materials Science and Engineering, University of Jinan, Jinan 250022, China;
2. Shandong Industrial Ceramics Research & Design Institute Co., Ltd., Zibo 255000, China

Received:2021-03-22 Revised:2021-05-21 Online:2021-06-15 Published:2021-07-08

摘要/Abstract

摘要： 围绕陶瓷粉体在光敏树脂中的分散,研究了粉体性质、分散剂种类及其掺加量、固含量对光固化ZrO₂陶瓷料浆流变性能的影响。结果表明:粉体性质对料浆的流变性能有着显著影响,比表面积小、球形度高的ZrO₂陶瓷粉体更有利于配制低粘度、高固含量的料浆;料浆的流变性能以及稳定性主要受分散剂种类及其掺加量的控制,以相对粉体质量4%的X-100分散剂制备的陶瓷料浆的流变性及稳定性更佳;固含量与粘度之间的关系满足Krieger-Dougherty模型。本文对分散剂的作用机理进行了分析探讨,为光固化ZrO₂陶瓷料浆高精度固化成型提供了试验基础。

关键词: ZrO₂陶瓷, 光固化, 料浆, 成型, 流变性能

Abstract: This paper focuses on the dispersion of ceramic powder in photosensitive resin. The effects of powder properties, dispersant type and dosage, and solid content on the rheological properties of stereolithography ZrO₂ ceramic slurry were studied. The result shows that the properties of the powder have a significant impact on the rheological properties of the slurry, the use of ZrO₂ powder with a smaller specific surface area and higher sphericity is more conducive to the preparation of low viscosity and high solid content slurry. The rheological properties and stability of the slurry are mainly controlled by the type and dosage of dispersant, using X-100 with a relative powder mass of 4% as a dispersant, the rheological properties and stability of the prepared ceramic slurry are better. The experimental result of the solid content of the slurry shows that the relationship between the solid content of the slurry and the viscosity satisfies the Krieger-Dougherty model. And the dispersion mechanism of the dispersant has been studied. By the research of this experiment, the foundation has been laid for the high-precision molding of the light-cured ZrO₂ ceramic slurry.

Key words: ZrO₂ ceramic, stereolithography, slurry, molding, rheological property

中图分类号:

TQ174

韩卓群, 李伶, 刘时浩, 邱坤, 王守兴, 刘福田. 光固化ZrO₂陶瓷料浆的流变性能研究[J]. 硅酸盐通报, 2021, 40(6): 1965-1971.

HAN Zhuoqun, LI Ling, LIU Shihao, QIU Kun, WANG Shouxing, LIU Futian. Research on Rheological Properties of Stereolithography ZrO₂ Ceramic Slurry[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(6): 1965-1971.

参考文献

[1] 陈守刚,尹衍升,周春华,等.氧化锆相变稳定机制的研究进展及应用[J].硅酸盐通报,2004,23(3):73-76.
CHEN S G, YIN Y S, ZHOU C H, et al. Application and study on the mechanism of the phase-stabilized zirconia[J]. Bulletin of the Chinese Ceramic Society, 2004, 23(3): 73-76 (in Chinese).
[2] 李伶,高勇,王重海,等.陶瓷部件3D打印技术的研究进展[J].硅酸盐通报,2016,35(9):2892-2897.
LI L, GAO Y, WANG C H, et al. Research development of 3D printing ceramic parts[J]. Bulletin of the Chinese Ceramic Society, 2016, 35(9): 2892-2897 (in Chinese).
[3] ECKEL Z C, ZHOU C Y, MARTIN J H, et al. Additive manufacturing of polymer-derived ceramics[J]. Science, 2016, 351(6268): 58-62.
[4] ZHANG S, SHA N, ZHAO Z. Surface modification of α-Al₂O₃ with dicarboxylic acids for the preparation of UV-curable ceramic suspensions[J]. Journal of the European Ceramic Society, 2017, 37(4): 1607-1616.
[5] LICCIULLI A, ESPOSITO CORCIONE C, GRECO A, et al. Laser stereolithography of ZrO₂ toughened Al₂O₃[J]. Journal of the European Ceramic Society, 2005, 25(9): 1581-1589.
[6] GRIFFITH M L, HALLORAN J W. Freeform fabrication of ceramics via stereolithography[J]. Journal of the American Ceramic Society, 1996, 79(10): 2601-2608.
[7] LEWIS J A. Colloidal processing of ceramics[J]. Journal of the American Ceramic Society, 2004, 83(10): 2341-2359.
[8] FRENCH R H. Origins and applications of London dispersion forces and hamaker constants in ceramics[J]. Journal of the American Ceramic Society, 2004, 83(9): 2117-2146.
[9] MORRISON I D, ROSS S. Colloidal dispersions: suspensions, emulsions, and foams[J]. New York: Wiley-Interscience. 2002:563-576.
[10] GOSWAMI A, K A, BALASHANMUGAM N, et al. Optimization of rheological properties of photopolymerizable alumina suspensions for ceramic microstereolithography[J]. Ceramics International, 2014, 40(2): 3655-3665.
[11] HERSCHEL W H, BULKLEY R. Konsistenzmessungen von gummi-benzollösungen[J]. Kolloid-Zeitschrift, 1926, 39(4): 291-300.
[12] ZHANG K Q, HE R J, XIE C, et al. Photosensitive ZrO₂ suspensions for stereolithography[J]. Ceramics International, 2019, 45(9): 12189-12195.
[13] 韩卓群.光固化3D打印ZrO₂陶瓷制备技术研究[D].济南:济南大学,2020:36-37.
HAN Z Q. Research on preparation technology of 3D printing ZrO₂ ceramic[D]. Jinan: University of Jinan, 2020: 36-37 (in Chinese).

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光固化ZrO₂陶瓷料浆的流变性能研究

Research on Rheological Properties of Stereolithography ZrO₂ Ceramic Slurry

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