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硅酸盐通报 ›› 2018, Vol. 37 ›› Issue (5): 1563-1567.

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流化床法除碳对微硅粉性能影响

侯思懿;铁生年;刘延杰;彭毛卓玛   

  1. 青海大学新能源光伏产业研究中心,西宁,810016
  • 出版日期:2018-05-15 发布日期:2021-01-18
  • 基金资助:
    青海省重点实验室发展专项资金(2015-Z-Y02,2016)%材料复合新技术国家重点实验室(武汉理工大学)开放基金(2017-KF-4)

Effect of Removing Carbon by Fluidized Bed Method on Properties of Silica Fume

HOU Si-yi;TIE Sheng-nian;LIU Yan-jie;PENG MAO Zhuo-ma   

  • Online:2018-05-15 Published:2021-01-18

摘要: 利用流化床法对微硅粉进行除碳,通过单因素实验确定最佳工艺条件为反应温度800℃,反应时间3 h.在此条件下微硅粉中SiO2的含量由75.64%增加到83.16%,游离碳的含量由4.14%降低到0.15%,去除率达到96.38%.利用XRD、SEM、BET等手段对流化前后的微硅粉进行分析.结果表明:流化后的微硅粉仍呈非晶态结构;颗粒表面光滑且呈规则圆球形;由于流化过程中气体将细小颗粒带出,流化后的微硅粉粒径变大,比表面积稍有减小;流化后微硅粉的流动性优于流化前,更有利于工业生产.

关键词: 流化;微硅粉;除碳;性能

Abstract: Fluidied bed method was used to removing carbon from silica fume .The optimal process condition was the reaction temperature of 800 ℃ and reaction time of 3 h through single factor experiments.In this condition, the content of silicon dioxide in silica fume increased from 75.64% to 83.16%, the content of free carbon in silica fume drops from 4.14% to 0.15%, removal rate can reach 96.38%.The silica fume before and after fluidization were analyzed by X -ray powder diffraction, scanning electronic microscopy, brunauer-emmett-teller and other tests.The results show that the silica fume after fluidization is still non-crystalline structure and the particles are smooth and have a regular spherical shape.After being fluidized,the particle size of silica fume is increased , the specific surface area is slightly reduced because of fine particles are taken out in the process of fluidization .The fluidity of silica fume after fluidization is better than that before fluidization , it is more conducive to industrial production.

Key words: fluidization;silicon fume;carbon removal;property

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