膨胀型阻燃剂组份配比对阻燃性能的影响

硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (5): 1667-1672.

膨胀型阻燃剂组份配比对阻燃性能的影响

赵江平;吴丹;王亚超

西安建筑科技大学材料与矿资学院,西安,710055

出版日期:2017-05-15 发布日期:2021-01-18

Performance Influence on Different Component Formulas of Intumescent Flame Retardants

ZHAO Jiang-ping;WU Dan;WANG Ya-chao

Online:2017-05-15 Published:2021-01-18

摘要/Abstract

摘要： 本文分别选取聚磷酸铵、季戊四醇、尿素及聚酯树脂为膨胀型阻燃剂中的酸源、碳源、气源及成膜剂,基于正交试验,依据小室燃烧和氧指数测试法探索各个组分对阻燃性能的影响主次顺序,衡量在不同配方下的阻燃效果,结果表明组份影响顺序为m(聚磷酸铵)>m(聚酯树脂)>m(尿素)>m(季戊四醇);得到具有最优阻燃性能的阻燃剂,即9#配方A3B3C2D1,经该配方处理的试样,其氧指数明显提升至38%;同时,通过热重和电镜扫描分析其燃烧过程,解释阻燃机理.

关键词: 正交试验;热重分析;膨胀型阻燃剂

Abstract: Ammonium polyphosphate, pentaerythritol, urea and polyester resin were used as the intumescent flame retardants agent of acid source, carbon source, gas source and film former.Exploring the influence of each component on the flame retardant performance in primary and secondary order based on orthogonal experiment, the small chamber combustion and limit oxygen index test, measure the effect of the intumescent flame retardant under different formulas.The results show m(ammonium polyphosphate)>m(polyester resin)>m(urea)>m(pentaerythritol),which is 9# formula A3B3C2D1, samples treated by this formula, the oxygen index obviously rise to 38%.At the same time, the combustion process was analyzed through TG and SEM analysis, and the mechanism of the intumescent flame retardant was explained.

Key words: orthogonal experiment;TG analysis;intumescent flame retardant

中图分类号:

TU545

赵江平;吴丹;王亚超. 膨胀型阻燃剂组份配比对阻燃性能的影响[J]. 硅酸盐通报, 2017, 36(5): 1667-1672.

ZHAO Jiang-ping;WU Dan;WANG Ya-chao. Performance Influence on Different Component Formulas of Intumescent Flame Retardants[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2017, 36(5): 1667-1672.

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