欢迎访问《硅酸盐通报》官方网站,今天是

硅酸盐通报 ›› 2017, Vol. 36 ›› Issue (11): 3925-3931.

• • 上一篇    下一篇

用硅钙渣烧制水泥熟料的研究

李辉;洪宁   

  1. 西安建筑科技大学材料与矿资学院,西安 710055;陕西省生态水泥混凝土工程技术研究中心,西安 710055
  • 出版日期:2017-11-15 发布日期:2021-01-18
  • 基金资助:
    国家自然科学基金(51672207)%陕西省自然科学基金(2012JM6001)

Research on Preparing Cement Clinker by Utilizing Silicate-Calcium Slag

LI Hui;HONG Ning   

  • Online:2017-11-15 Published:2021-01-18

摘要: 用不同比例的硅钙渣替代石灰石和黏土掺入水泥生料中,在不同的烧成温度(1200℃、1250℃、1300℃、1350℃、1400℃和1450℃)下进行煅烧,对烧成熟料的易烧性、矿物组成及矿物相的微观形貌进行分析.研究结果表明:在生料中掺加硅钙渣有助于液相形成、降低水泥熟料的烧成温度和改善生料的易烧性,更有利于烧成贝利特熟料,不利于烧成阿利特熟料.在生料中硅钙渣的掺量较高(60%)时,硅钙渣中微量氧化钠的存在使生料在烧成时形成不利于C3 S晶体形成和成长的碱性液相及价键较强AlO5-4和FeO5-4四面体,从而使烧成熟料中的C3 S矿物不论从外观还是Ca/Si摩尔比都接近C2 S矿物.

关键词: 硅钙渣;水泥熟料;熟料矿物相

Abstract: Calcium silicate slag (CSC)with different proportion instead of limestone and clay in cement raw material was calcined at different temperature (1200 ℃,1250 ℃,1300 ℃,1350 ℃,1400 ℃ and 1450 ℃),and the burnability,the mineral composition and the micro morphology of the clinker were analyzed. The results indicate that the addition of CSC in the raw material contributes to the formation of liquid phase,reduces the calcination temperature,improves the burnability of raw material,and is more conducive to the production of Belite,however,is not good for the formation of Alite. When the incorporation of CSC in the raw material is high (60%),the presence of microscale sodium in CSC make raw materials form alkaline liquid phase and valence bond strong AlO5-4 and FeO5-4 tetrahedron which are not conducive to the formation and growth of C3 S crystals,so that the C3 S mineral of clinker is close to C2 S whether the appearance or Ca/Si molar ratio.

Key words: silicate-calcium slag(SCS);cement clinker;clinker mineral phase

中图分类号: