硅酸盐通报 ›› 2026, Vol. 45 ›› Issue (6): 1924-1936.DOI: 10.16552/j.cnki.issn1001-1625.2025.1281
李悦1(
), 周光辉1(
), 杨斌1, 晋凯凯1, 蒋泽洲1, 邱梓恒1, 邵伟伟1,2
收稿日期:2025-12-22
修订日期:2026-01-19
出版日期:2026-06-15
发布日期:2026-07-14
通信作者:
周光辉,硕士研究生。E-mail:zhough@emails.bjut.edu.cn作者简介:李悦(1972—),男,教授。主要从事高性能混凝土材料和新型建筑材料的研究。E-mail:liyue@bjut.edu.cn
基金资助:
LI Yue1(
), ZHOU Guanghui1(
), YANG Bin1, JIN Kaikai1, JIANG Zezhou1, QIU Ziheng1, SHAO Weiwei1,2
Received:2025-12-22
Revised:2026-01-19
Published:2026-06-15
Online:2026-07-14
摘要:
为制备适用于高海拔山区隧道用喷射混凝土,本文采用正交试验研究了早强掺合料掺量、水胶比、速凝剂掺量和砂率对喷射混凝土坍落度、8 h和28 d抗压强度的影响。结果表明,早强掺合料掺量和水胶比对喷射混凝土的流动性能和抗压强度影响显著,砂率对喷射混凝土的流动性能、早期及后期抗压强度均有影响,但影响相对较小,速凝剂掺量对喷射混凝土早期及后期抗压强度影响较小。其次,通过极差分析和灰靶决策理论得到较优的喷射混凝土配合比:早强掺合料掺量为26%(质量分数),水胶比为0.30,速凝剂掺量为7%(质量分数),砂率为50%。最后,通过XRD、TG和SEM微观测试分析了速凝剂和早强掺合料对喷射混凝土性能的影响机制,二者具有协同作用,可大幅提升水泥浆体早期强度。研究成果为高海拔艰险山区隧道喷射混凝土的优化设计与制备提供了技术支撑。
中图分类号:
李悦, 周光辉, 杨斌, 晋凯凯, 蒋泽洲, 邱梓恒, 邵伟伟. 高海拔山区隧道喷射混凝土配合比优化设计及性能研究[J]. 硅酸盐通报, 2026, 45(6): 1924-1936.
LI Yue, ZHOU Guanghui, YANG Bin, JIN Kaikai, JIANG Zezhou, QIU Ziheng, SHAO Weiwei. Optimization Design and Performance Study of Shotcrete Mix Proportion for Tunnels in High-Altitude Mountainous Regions[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(6): 1924-1936.
| Material | Mass fraction/% | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| CaO | SiO2 | Al2O3 | Fe2O3 | SO3 | TiO2 | MgO | K2O | Other | |
| OPC | 63.22 | 18.57 | 5.57 | 4.35 | 3.32 | 2.17 | 1.58 | 0.58 | 0.64 |
| ESA | 55.39 | 30.49 | 3.10 | 1.71 | 4.09 | 0.57 | 2.83 | 0.61 | 1.21 |
表1 原材料的化学组成
Table 1 Chemical composition of raw materials
| Material | Mass fraction/% | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| CaO | SiO2 | Al2O3 | Fe2O3 | SO3 | TiO2 | MgO | K2O | Other | |
| OPC | 63.22 | 18.57 | 5.57 | 4.35 | 3.32 | 2.17 | 1.58 | 0.58 | 0.64 |
| ESA | 55.39 | 30.49 | 3.10 | 1.71 | 4.09 | 0.57 | 2.83 | 0.61 | 1.21 |
| Material | Mass fraction/% | ||||||
|---|---|---|---|---|---|---|---|
| C3S | C2S | CaCO3 | C4AF | AFt | C3A | Amorphous | |
| OPC | 57.17 | 13.72 | 6.80 | 10.18 | 0 | 6.83 | 5.30 |
| ESA | 50.06 | 14.09 | 13.58 | 6.23 | 1.54 | 1.48 | 13.02 |
表2 胶凝材料定量XRD分析结果
Table 2 Quantitative XRD analysis results for cementitious materials
| Material | Mass fraction/% | ||||||
|---|---|---|---|---|---|---|---|
| C3S | C2S | CaCO3 | C4AF | AFt | C3A | Amorphous | |
| OPC | 57.17 | 13.72 | 6.80 | 10.18 | 0 | 6.83 | 5.30 |
| ESA | 50.06 | 14.09 | 13.58 | 6.23 | 1.54 | 1.48 | 13.02 |
| Setting time/min | Compressive strength/MPa | Flexural strength/MPa | |||
|---|---|---|---|---|---|
| Initial setting | Final setting | 3 d | 28 d | 3 d | 28 d |
| 189 | 246 | 26.6 | 48.3 | 5.2 | 7.3 |
表3 OPC的物理力学性能
Table 3 Physical and mechanical properties of OPC
| Setting time/min | Compressive strength/MPa | Flexural strength/MPa | |||
|---|---|---|---|---|---|
| Initial setting | Final setting | 3 d | 28 d | 3 d | 28 d |
| 189 | 246 | 26.6 | 48.3 | 5.2 | 7.3 |
| Level | A/% | B | C/% | D/% |
|---|---|---|---|---|
| 1 | 20 | 0.30 | 6 | 48 |
| 2 | 23 | 0.33 | 7 | 50 |
| 3 | 26 | 0.36 | 8 | 52 |
表4 正交试验因素水平
Table 4 Factor levels of orthogonal experiment
| Level | A/% | B | C/% | D/% |
|---|---|---|---|---|
| 1 | 20 | 0.30 | 6 | 48 |
| 2 | 23 | 0.33 | 7 | 50 |
| 3 | 26 | 0.36 | 8 | 52 |
| Sample No. | Mass/kg | ||||||
|---|---|---|---|---|---|---|---|
| OPC | ESA | Water | FA | CA | SA | WR | |
| N1 | 458.15 | 80.85 | 161.70 | 768.53 | 832.58 | 32.34 | 7.55 |
| N2 | 431.00 | 108.00 | 161.70 | 795.15 | 795.15 | 43.15 | 7.55 |
| N3 | 404.25 | 134.75 | 161.70 | 829.77 | 765.95 | 37.73 | 7.55 |
| N4 | 458.15 | 80.85 | 178.00 | 818.48 | 755.52 | 43.15 | 7.55 |
| N5 | 431.00 | 108.00 | 178.00 | 758.12 | 821.30 | 37.73 | 7.55 |
| N6 | 404.25 | 134.75 | 178.00 | 792.41 | 792.40 | 32.34 | 7.55 |
| N7 | 458.15 | 80.85 | 194.04 | 781.69 | 781.69 | 37.73 | 7.55 |
| N8 | 431.00 | 108.00 | 194.04 | 815.76 | 753.01 | 32.34 | 7.55 |
| N9 | 404.25 | 134.75 | 194.04 | 747.82 | 810.14 | 43.15 | 7.55 |
表5 正交试验喷射混凝土配合比
Table 5 Mix proportion of shotcrete for orthogonal experiment
| Sample No. | Mass/kg | ||||||
|---|---|---|---|---|---|---|---|
| OPC | ESA | Water | FA | CA | SA | WR | |
| N1 | 458.15 | 80.85 | 161.70 | 768.53 | 832.58 | 32.34 | 7.55 |
| N2 | 431.00 | 108.00 | 161.70 | 795.15 | 795.15 | 43.15 | 7.55 |
| N3 | 404.25 | 134.75 | 161.70 | 829.77 | 765.95 | 37.73 | 7.55 |
| N4 | 458.15 | 80.85 | 178.00 | 818.48 | 755.52 | 43.15 | 7.55 |
| N5 | 431.00 | 108.00 | 178.00 | 758.12 | 821.30 | 37.73 | 7.55 |
| N6 | 404.25 | 134.75 | 178.00 | 792.41 | 792.40 | 32.34 | 7.55 |
| N7 | 458.15 | 80.85 | 194.04 | 781.69 | 781.69 | 37.73 | 7.55 |
| N8 | 431.00 | 108.00 | 194.04 | 815.76 | 753.01 | 32.34 | 7.55 |
| N9 | 404.25 | 134.75 | 194.04 | 747.82 | 810.14 | 43.15 | 7.55 |
| Sample No. | A/% | B | C/% | D/% | Slump/mm | 8 h compressivestrength/MPa | 28 d compressivestrength/MPa |
|---|---|---|---|---|---|---|---|
| N1 | 20 | 0.30 | 6 | 48 | 230 | 8.7 | 47.5 |
| N2 | 20 | 0.33 | 8 | 50 | 230 | 7.5 | 45.7 |
| N3 | 20 | 0.36 | 7 | 52 | 235 | 5.8 | 44.1 |
| N4 | 23 | 0.30 | 8 | 52 | 160 | 7.7 | 51.6 |
| N5 | 23 | 0.33 | 7 | 48 | 200 | 6.4 | 48.5 |
| N6 | 23 | 0.36 | 6 | 50 | 210 | 5.5 | 46.8 |
| N7 | 26 | 0.30 | 7 | 50 | 190 | 11.8 | 54.9 |
| N8 | 26 | 0.33 | 6 | 52 | 210 | 7.9 | 50.2 |
| N9 | 26 | 0.36 | 8 | 48 | 190 | 9.1 | 49.1 |
表6 正交试验方案及结果
Table 6 Orthogonal experiment design and results
| Sample No. | A/% | B | C/% | D/% | Slump/mm | 8 h compressivestrength/MPa | 28 d compressivestrength/MPa |
|---|---|---|---|---|---|---|---|
| N1 | 20 | 0.30 | 6 | 48 | 230 | 8.7 | 47.5 |
| N2 | 20 | 0.33 | 8 | 50 | 230 | 7.5 | 45.7 |
| N3 | 20 | 0.36 | 7 | 52 | 235 | 5.8 | 44.1 |
| N4 | 23 | 0.30 | 8 | 52 | 160 | 7.7 | 51.6 |
| N5 | 23 | 0.33 | 7 | 48 | 200 | 6.4 | 48.5 |
| N6 | 23 | 0.36 | 6 | 50 | 210 | 5.5 | 46.8 |
| N7 | 26 | 0.30 | 7 | 50 | 190 | 11.8 | 54.9 |
| N8 | 26 | 0.33 | 6 | 52 | 210 | 7.9 | 50.2 |
| N9 | 26 | 0.36 | 8 | 48 | 190 | 9.1 | 49.1 |
| Parameter | 8 h compressive strength/MPa | 28 d compressive strength/MPa | ||||||
|---|---|---|---|---|---|---|---|---|
| A | B | C | D | A | B | C | D | |
| k1 | 7.33 | 9.40 | 7.37 | 8.07 | 45.77 | 51.33 | 48.17 | 48.37 |
| k2 | 6.53 | 7.27 | 8.00 | 8.27 | 48.97 | 48.13 | 49.17 | 49.13 |
| k3 | 9.60 | 6.80 | 8.10 | 7.13 | 51.40 | 46.67 | 48.80 | 48.63 |
| R | 3.07 | 2.60 | 0.73 | 1.13 | 5.63 | 4.67 | 1.00 | 0.77 |
表7 抗压强度极差分析
Table 7 Range analysis for compressive strength
| Parameter | 8 h compressive strength/MPa | 28 d compressive strength/MPa | ||||||
|---|---|---|---|---|---|---|---|---|
| A | B | C | D | A | B | C | D | |
| k1 | 7.33 | 9.40 | 7.37 | 8.07 | 45.77 | 51.33 | 48.17 | 48.37 |
| k2 | 6.53 | 7.27 | 8.00 | 8.27 | 48.97 | 48.13 | 49.17 | 49.13 |
| k3 | 9.60 | 6.80 | 8.10 | 7.13 | 51.40 | 46.67 | 48.80 | 48.63 |
| R | 3.07 | 2.60 | 0.73 | 1.13 | 5.63 | 4.67 | 1.00 | 0.77 |
| Parameter | Slump/mm | ||
|---|---|---|---|
| A | B | D | |
| k1 | 231.67 | 193.30 | 206.67 |
| k2 | 190.00 | 213.33 | 210.00 |
| k3 | 196.67 | 211.67 | 201.67 |
| R | 41.67 | 20.00 | 8.33 |
表8 坍落度极差分析
Table 8 Range analysis for slump
| Parameter | Slump/mm | ||
|---|---|---|---|
| A | B | D | |
| k1 | 231.67 | 193.30 | 206.67 |
| k2 | 190.00 | 213.33 | 210.00 |
| k3 | 196.67 | 211.67 | 201.67 |
| R | 41.67 | 20.00 | 8.33 |
| Sample No. | Mass/g | ||||
|---|---|---|---|---|---|
| OPC | ESA | Water | SA | WR | |
| G1 | 1 000 | 0 | 300.0 | 0 | 10 |
| G2 | 1 000 | 0 | 269.2 | 70 | 10 |
| G3 | 740 | 260 | 300.0 | 0 | 10 |
| G4 | 740 | 260 | 269.2 | 70 | 10 |
表9 水泥净浆试验配合比
Table 9 Mix proportion of cement paste for testing
| Sample No. | Mass/g | ||||
|---|---|---|---|---|---|
| OPC | ESA | Water | SA | WR | |
| G1 | 1 000 | 0 | 300.0 | 0 | 10 |
| G2 | 1 000 | 0 | 269.2 | 70 | 10 |
| G3 | 740 | 260 | 300.0 | 0 | 10 |
| G4 | 740 | 260 | 269.2 | 70 | 10 |
| Sample No. | Initial setting time/min | Final setting time/min | Fluidity/mm |
|---|---|---|---|
| G1 | 135 | 390 | 140 |
| G2 | 2.00 | 3.50 | |
| G3 | 105 | 360 | 130 |
| G4 | 1.50 | 3.25 |
表10 水泥净浆各组凝结时间及流动度
Table 10 Setting time and fluidity of cement paste in each group
| Sample No. | Initial setting time/min | Final setting time/min | Fluidity/mm |
|---|---|---|---|
| G1 | 135 | 390 | 140 |
| G2 | 2.00 | 3.50 | |
| G3 | 105 | 360 | 130 |
| G4 | 1.50 | 3.25 |
| Sample No. | Mass loss rate at different temperature ranges/% | Ca(OH)2 mass fraction/% | |||
|---|---|---|---|---|---|
| 25~200 ℃ | 350~460 ℃ | 550~800 ℃ | |||
| 8 h | G1 | 4.19 | 0.53 | 0.93 | 3.73 |
| G2 | 4.93 | 0.61 | 0.77 | 3.82 | |
| G3 | 5.93 | 0.45 | 0.55 | 2.75 | |
| G4 | 5.97 | 0.42 | 0.70 | 2.89 | |
| 1 d | G1 | 6.68 | 2.43 | 4.66 | 17.82 |
| G2 | 7.96 | 1.25 | 3.91 | 11.71 | |
| G3 | 7.12 | 2.21 | 5.62 | 18.52 | |
| G4 | 9.45 | 1.15 | 4.35 | 12.03 | |
| 28 d | G1 | 8.12 | 3.36 | 5.36 | 22.81 |
| G2 | 9.28 | 2.57 | 5.33 | 19.52 | |
| G3 | 8.29 | 2.49 | 6.90 | 21.83 | |
| G4 | 10.56 | 1.74 | 4.70 | 15.05 | |
表11 各组水泥净浆在不同温度范围的质量损失率
Table 11 Mass loss rate of cement paste in each group at different temperature ranges
| Sample No. | Mass loss rate at different temperature ranges/% | Ca(OH)2 mass fraction/% | |||
|---|---|---|---|---|---|
| 25~200 ℃ | 350~460 ℃ | 550~800 ℃ | |||
| 8 h | G1 | 4.19 | 0.53 | 0.93 | 3.73 |
| G2 | 4.93 | 0.61 | 0.77 | 3.82 | |
| G3 | 5.93 | 0.45 | 0.55 | 2.75 | |
| G4 | 5.97 | 0.42 | 0.70 | 2.89 | |
| 1 d | G1 | 6.68 | 2.43 | 4.66 | 17.82 |
| G2 | 7.96 | 1.25 | 3.91 | 11.71 | |
| G3 | 7.12 | 2.21 | 5.62 | 18.52 | |
| G4 | 9.45 | 1.15 | 4.35 | 12.03 | |
| 28 d | G1 | 8.12 | 3.36 | 5.36 | 22.81 |
| G2 | 9.28 | 2.57 | 5.33 | 19.52 | |
| G3 | 8.29 | 2.49 | 6.90 | 21.83 | |
| G4 | 10.56 | 1.74 | 4.70 | 15.05 | |
| [1] |
《中国公路学报》编辑部. 中国交通隧道工程学术研究综述·2022[J]. 中国公路学报, 2022, 35(4): 1-40.
DOI |
| Editorial Department of China Journal of Highway and Transport. Review on China’s traffic tunnel engineering research: 2022[J]. China Journal of Highway and Transport, 2022, 35(4): 1-40 (in Chinese). | |
| [2] |
YANG R H, HE T S, XU Y D. Preparation of alkali free liquid accelerator for shotcrete with fluorosilicic acid waste liquid and its accelerating mechanism[J]. Cement and Concrete Composites, 2022, 131: 104600.
DOI URL |
| [3] |
PRUDÊNCIO L R. Accelerating admixtures for shotcrete[J]. Cement and Concrete Composites, 1998, 20(2/3): 213-219.
DOI URL |
| [4] |
GALAN I, BALDERMANN A, KUSTERLE W, et al. Durability of shotcrete for underground support: review and update[J]. Construction and Building Materials, 2019, 202: 465-493.
DOI URL |
| [5] |
SALVADOR R P, CAVALARO S H P, CINCOTTO M A, et al. Parameters controlling early age hydration of cement pastes containing accelerators for sprayed concrete[J]. Cement and Concrete Research, 2016, 89: 230-248.
DOI URL |
| [6] |
GARBA M J, TIAN Y, SHALABY Y, et al. Effects of liquid accelerators on long-term mechanical strength development and microstructural changes of wet-mixed shotcrete[J]. Journal of Building Engineering, 2024, 97: 110926.
DOI URL |
| [7] |
XU H Y, HUANG Y, FENG S Z, et al. Utilization of limestone powder and silica fume as sustainable cement replacements in shotcrete: experimental, molecular dynamics simulations, and microstructural analysis[J]. Powder Technology, 2026, 467: 121493.
DOI URL |
| [8] | 王家滨, 张凯峰, 侯泽宇, 等. 西北复合盐侵蚀环境衬砌喷射混凝土离子扩散研究[J]. 土木工程学报, 2020, 53(11): 21-35. |
| WANG J B, ZHANG K F, HOU Z Y, et al. Ion diffusion in shotcrete lining under compound salt corrosion environment saline soil in Northwest China[J]. China Civil Engineering Journal, 2020, 53(11): 21-35 (in Chinese). | |
| [9] | 宁逢伟, 蔡跃波, 丁建彤, 等. C50补偿收缩喷射混凝土的配合比设计及耐久性研究[J]. 新型建筑材料, 2020, 47(1): 1-5+26. |
| NING F W, CAI Y B, DING J T, et al. Study on mix design and durability of C50 compensating-shrinkage shotcrete[J]. New Building Materials, 2020, 47(1): 1-5+26 (in Chinese). | |
| [10] | 曾鲁平, 乔敏, 赵爽, 等. 乙烯-醋酸乙烯酯共聚物对喷射混凝土力学强度、渗透性能及水化微观结构的影响[J]. 材料导报, 2025, 39(5): 165-173. |
| ZENG L P, QIAO M, ZHAO S, et al. Effect of ethylene-vinyl-acetate copolymer on mechanical strength, permeability properties, and hydrated microstructure of sprayed concrete[J]. Materials Reports, 2025, 39(5): 165-173 (in Chinese). | |
| [11] | 濮俊缘, 李克庆, 张思奇. 多因素影响下湿喷混凝土的强度与配比优化[J]. 矿业研究与开发, 2022, 42(11): 153-157. |
| PU J Y, LI K Q, ZHANG S Q. Strength and mix proportion optimization of wet shotcrete under multiple factors[J]. Mining Research and Development, 2022, 42(11): 153-157 (in Chinese). | |
| [12] | 何晓雁, 张智鑫, 赵燕茹, 等. 基于灰靶决策对BFCC力学性能及抗渗性能的评估[J]. 材料导报, 2021, 35(20): 20035-20039+20051. |
| HE X Y, ZHANG Z X, ZHAO Y R, et al. Evaluation of permeability and mechanical properties of BFCC based on gray target decision[J]. Materials Review, 2021, 35(20): 20035-20039+20051 (in Chinese). | |
| [13] |
YANG B, LI Y, ZHOU Y X, et al. Mix proportion design and analysis of underground continuous wall concrete based on hybrid grey target decision theory[J]. Construction and Building Materials, 2025, 501: 144317.
DOI URL |
| [14] |
XU J T, QIN X, LIN Y K, et al. Research on performance deterioration of internally cured pavement concrete under the coupling effect of salt freeze-thaw[J]. Polymers, 2023, 15(3): 476.
DOI URL |
| [15] |
JIN H S, XU H Y, YANG S Y, et al. Grey target decision analysis of optimum mixing ratio of LWAS based on the comprehensive performance[J]. Construction and Building Materials, 2020, 262: 120570.
DOI URL |
| [16] |
ZHANG Z, ZHANG H L, MA J, et al. Multi-objective optimization, shrinkage and fracture properties of unsaturated polyester resin modified concrete for bridge deck pavement based on system theory[J]. Construction and Building Materials, 2024, 443: 137694.
DOI URL |
| [17] | 於成龙, 元强, 周晓丰, 等. 纳米C-S-H晶核对早高强喷射混凝土性能的影响及应用[J]. 铁道科学与工程学报, 2025, 22(11): 5040-5051. |
| YU C L, YUAN Q, ZHOU X F, et al. Effects of nano C-S-H seeds on properties of early and high-strength shotcrete and its application[J]. Journal of Railway Science and Engineering, 2025, 22(11): 5040-5051 (in Chinese). | |
| [18] |
SALVADOR R P, CAVALARO S H P, SEGURA I, et al. Early age hydration of cement pastes with alkaline and alkali-free accelerators for sprayed concrete[J]. Construction and Building Materials, 2016, 111: 386-398.
DOI URL |
| [19] |
HERRERA-MESEN C, SALVADOR R P, CAVALARO S H P, et al. Effect of gypsum content in sprayed cementitious matrices: early age hydration and mechanical properties[J]. Cement and Concrete Composites, 2019, 95: 81-91.
DOI URL |
| [20] |
LI G X, ZHANG J B, NIU M D, et al. The mechanism of alkali-free liquid accelerator on the hydration of cement pastes[J]. Construction and Building Materials, 2020, 233: 117296.
DOI URL |
| [21] |
HAN J G, WANG K J, WANG Y, et al. Study of aluminum sulfate and anhydrite on cement hydration process[J]. Materials and Structures, 2016, 49(4): 1105-1114.
DOI URL |
| [22] |
ZHANG Z W, NIU M D, LIU Z T, et al. The mechanism of accelerator types on calcium leaching in shotcrete[J]. Construction and Building Materials, 2024, 457: 139353.
DOI URL |
| [23] |
WANG L, HE X X, SHU C X, et al. Research on the working performance and the corresponding mechanical strength of polyaluminum sulfate early strength alkali-free liquid accelerator matrix cement[J]. Materials, 2022, 15(22): 8086.
DOI URL |
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