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硅酸盐通报 ›› 2025, Vol. 44 ›› Issue (12): 4325-4331.DOI: 10.16552/j.cnki.issn1001-1625.2025.0615

• 水泥混凝土 • 上一篇    下一篇

Na2SO4对瓦斯封孔复合水泥性能的影响

朱加锋1, 梁雪燕2, 杨文旺3   

  1. 1.潞安化工集团有限公司,长治 046204;
    2.安徽理工大学土木建筑学院,淮南 232001;
    3.安徽理工大学安全科学与工程学院,淮南 232001
  • 收稿日期:2025-06-24 修订日期:2025-08-07 出版日期:2025-12-15 发布日期:2025-12-30
  • 通信作者: 杨文旺,博士,副教授。E-mail:33766176@qq.com
  • 作者简介:朱加锋(1984—),男,高级工程师。主要从事瓦斯防治和新型封孔材料方面的研究。E-mail:jf_zhu_l@163.com
  • 基金资助:
    国家自然科学基金委员会国家重大科研仪器研制项目(部门推荐)(52227901)

Influence of Na2SO4 on Performance of Gas Sealing Composite Cement

ZHU Jiafeng1, LIANG Xueyan2, YANG Wenwang3   

  1. 1. Lu’an Chemical Group Co., Ltd., Changzhi 046204, China;
    2. School of Civil Engineering and Architecture, Anhui University of Science and Technology, Huainan 232001, China;
    3. School of Safety Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China
  • Received:2025-06-24 Revised:2025-08-07 Published:2025-12-15 Online:2025-12-30

摘要: 本文研究了Na2SO4对瓦斯封孔复合水泥(普通硅酸盐水泥和硫铝酸盐水泥)凝结时间、扩展度、水化热、膨胀率、抗压强度和微观力学性质的影响。结果表明,Na2SO4加速了复合水泥的凝结和水化过程,其促凝效果与掺量(0.5%~2.0%,质量分数)呈正相关。同时,复合水泥的膨胀率和抗压强度也随Na2SO4掺量的增大而提高。通过掺入0.5%~2.0%的Na2SO4,复合水泥的抗压强度提升率为23.3%~100.0%(1 d)、10.4%~30.8%(3 d)、6.8%~23.9%(7 d)和11.0%~29.9%(28 d)。通过微观力学性质分析,发现复合水泥水化较为充分,弹性模量分布更均匀,凝胶类低弹性模量产物形成量增大。本文的研究结果可为高性能瓦斯封孔材料的性能调控提供技术依据。

关键词: 瓦斯封孔材料, 复合水泥, 凝结时间, 微观力学性质, 抗压强度

Abstract: This paper investigated the effects of Na2SO4 on setting time, slump flow, hydration heat, expansion rate, compressive strength, and micromechanical properties of gas sealing composite cement (composed of ordinary Portland cement and sulphoaluminate cement). The results show that Na2SO4 accelerated the setting and hydration processes of composite cement, and its setting acceleration effect is positively correlated with the dosage (0.5%~2.0%, mass fraction). Meanwhile, both the expansion rate and compressive strength of composite cement increase with the increase in Na2SO4 dosage. By incorporating 0.5%~2.0% Na2SO4, the increase rates of compressive strength of the composite cement are 23.3%~100.0% (1 d), 10.4%~30.8% (3 d), 6.8%~23.9% (7 d), and 11.0%~29.9% (28 d). Micromechanical property analysis indicates that the hydration of composite cement is more complete, with a more uniform distribution of elastic modulus and a notable increase in the formation of gel-like products with low elastic modulus. These findings provide a technical basis for performance regulation of high-performance gas sealing materials.

Key words: gas sealing material, composite cement, setting time, micromechanical property, compressive strength

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