用于腐蚀保护的NO-2-LDHs自愈微胶囊的制备及性能研究

doi:10.16552/j.cnki.issn1001-1625.2024.1195

摘要/Abstract

摘要： 针对混凝土易开裂、难修复,裂后钢筋锈蚀快的工程难题,本文采用锐孔固浴法制备了以桐油(TO)为芯材,海藻酸钠(SA)和亚硝酸改性镁铝水滑石(NO^-₂-LDHs)为壁材的微胶囊。以包覆率为响应指标,通过响应面分析,对不同TO和SA的质量比、SA浓度及乳化剂浓度这3个因素进行优化。测试了钢筋的极化曲线,并对比了掺加0%和1%(质量分数)微胶囊的砂浆试件在干燥养护(干养)和浸水养护(湿养)条件下的强度恢复率。结果表明:当TO和SA的质量比为9:1、SA浓度为1.69%(质量分数)、十二烷基苯磺酸钠(SDBS)浓度为0.95%(质量分数)时,微胶囊对TO的最大包覆率为74.03%;制备的微胶囊具有一定的缓蚀效果,当微胶囊掺量为溶液质量的6%时,缓蚀效率为93.35%;自修复实验结果表明,掺入微胶囊可以显著提高砂浆试件的抗压强度恢复率,干养试件的28 d恢复率(80%)高于湿养试件(76%)。

关键词: 微胶囊, 缓蚀剂, 水滑石, 桐油, 水泥基材料, 自修复

Abstract: Aiming at the engineering problem of concrete easy to crack, difficult to repair, and fast corrosion of reinforcement after cracking, microcapsules with tung oil (TO) as the core material, sodium alginate (SA) and nitrite-modified magnesium-aluminum hydrotalcites (NO^-₂-LDHs) as the wall material were prepared in this paper by using the sharp-pore solid-bath method. Three factors, namely, different TO and SA mass ratios, SA concentration, and emulsifier concentration were optimized by response surface analysis using the encapsulation rate as the response index. The polarization curves of the reinforcement were tested and the strength recovery rates of mortar specimens with microcapsules dosed at 0% and 1% (mass fraction) were compared under dry and wet cured conditions. The results show that the maximum encapsulation rate of microcapsules on TO is 74.03% when the mass ratio of TO and SA is 9:1, the concentration of SA is 1.69% (mass fraction), and the concentration of sodium dodecyl benzene sulfonate (SDBS) is 0.95% (mass fraction). The prepared microcapsules have a certain degree of corrosion inhibition effectiveness, and the efficiency of corrosion inhibition at 6% dosing of solution mass is 93.35%. The results of self-repair experiments show that microcapsules can significantly improve the compressive strength recovery rate of mortar specimens, and the 28 d recovery rate of dry cured specimens (80%) is higher than that of wet cured specimens (76%).

Key words: microcapsule, corrosion inhibitor, hydrotalcite, tung oil, cement-based material, self-healing

中图分类号:

TU528

田沛丰, 温勇, 郭晓琦, 林海孟. 用于腐蚀保护的NO^-₂-LDHs自愈微胶囊的制备及性能研究[J]. 硅酸盐通报, 2025, 44(5): 1622-1633.

TIAN Peifeng, WEN Yong, GUO Xiaoqi, LIN Haimeng. Preparation and Properties of NO^-₂-LDHs Self-Healing Microcapsules for Corrosion Protection[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(5): 1622-1633.

参考文献

[1] MOHAMED A, ZHOU Y H, BERTOLESI E, et al. Factors influencing self-healing mechanisms of cementitious materials: a review[J]. Construction and Building Materials, 2023, 393: 131550.
[2] GUPTA S, PANG S D, KUA H W. Autonomous healing in concrete by bio-based healing agents: a review[J]. Construction and Building Materials, 2017, 146: 419-428.
[3] DA ROCHA GOMES S, FERRARA L, SÁNCHEZ L, et al. A comprehensive review of cementitious grouts: composition, properties, requirements and advanced performance[J]. Construction and Building Materials, 2023, 375: 130991.
[4] GROSSKURTH K P, PERBIX W. Force transmitting filling of wet and water filled cracks in concrete structures by means of crack injection with newly developed epoxy resins[M]//Structural Engineering, Mechanics and Computation. Amsterdam: Elsevier, 2001: 1251-1258.
[5] 房国豪, 陈锦妹, 王琰帅, 等. 微胶囊自修复混凝土研究进展[J]. 硅酸盐学报, 2023, 51(9): 2423-2432.
FANG G H, CHEN J M, WANG Y S, et al. Research development on microencapsulated self-healing concrete[J]. Journal of the Chinese Ceramic Society, 2023, 51(9): 2423-2432 (in Chinese).
[6] WHITE S R, SOTTOS N R, GEUBELLE P H, et al. Autonomic healing of polymer composites[J]. Nature, 2001, 409(6822): 794-797.
[7] ORLOVA Y, HARMON R E, BROADBELT L J, et al. Review of the kinetics and simulations of linseed oil autoxidation[J]. Progress in Organic Coatings, 2021, 151: 106041.
[8] 张微, 张志刚, 付广艳, 等. 基于自修复涂料的脲醛树脂微胶囊的制备及其表征[J]. 材料保护, 2017, 50(4): 64-68.
ZHANG W, ZHANG Z G, FU G Y, et al. Preparation and characterization of urea-formaldehyde resin microcapsules for self-healing coatings[J]. Materials Protection, 2017, 50(4): 64-68 (in Chinese).
[9] 李海燕, 崔业翔, 王晴, 等. 溶剂挥发法制备聚砜包覆桐油自修复微胶囊[J]. 中国塑料, 2016, 30(5): 34-40.
LI H Y, CUI Y X, WANG Q, et al. Preparation of polysulfone containing tung oil self-healing microcapsules by solvent evaporation method[J]. China Plastics, 2016, 30(5): 34-40 (in Chinese).
[10] WANG X G, J L, ZOU F B, et al. CaAl-NO₂ LDH hybrid self-healing microcapsules with chloride triggering: towards synergistic corrosion resistance[J]. Composites Part B: Engineering, 2023, 264: 110902.
[11] RUIZ-RIANCHO N, GARCIA A, GROSSEGGER D, et al. Properties of Ca-alginate capsules to maximise asphalt self-healing properties[J]. Construction and Building Materials, 2021, 284: 122728.
[12] MAZZA K E L, COSTA A M M, DA SILVA J P L, et al. Microencapsulation of marjoram essential oil as a food additive using sodium alginate and whey protein isolate[J]. International Journal of Biological Macromolecules, 2023, 233: 123478.
[13] SUN J Y, LI W, LI N, et al. Effect of surface modified nano-SiO₂ particles on properties of TO@CA/SR self-healing anti-corrosion composite coating[J]. Progress in Organic Coatings, 2022, 164: 106689.
[14] KIM D H, LEE S B, PARK H D. Effect of air-blast drying and the presence of protectants on the viability of yeast entrapped in calcium alginate beads with an aim to improve the survival rate[J]. Applied Microbiology and Biotechnology, 2017, 101(1): 93-102.
[15] X G, J L, LEI Y X, et al. Synthesis and characterization of layered double hydroxides hybrid microcapsules for anticorrosion via self-healing and chloride ion adsorption[J]. Applied Clay Science, 2022, 221: 106481.
[16] 生秋平. 水滑石对钢筋混凝土的缓蚀防护研究进展[J]. 四川建材, 2022, 48(2): 3-4.
SHENG Q P. Research progress on corrosion inhibition and protection of reinforced concrete by hydrotalc[J]. Sichuan Building Materials, 2022, 48(2): 3-4 (in Chinese).
[17] YANG Q R, PENG M, LIU W J, et al. Molecular-level insights into the corrosion protection mechanism of Mg/Al CO^2-₃-LDH films on steel in aqueous chloride environments[J]. Applied Clay Science, 2023, 245: 107137.
[18] CAO Y H, DONG S G, ZHENG D J, et al. Multifunctional inhibition based on layered double hydroxides to comprehensively control corrosion of carbon steel in concrete[J]. Corrosion Science, 2017, 126: 166-179.
[19] XU J X, TAN Q P, MEI Y J. Corrosion protection of steel by Mg-Al layered double hydroxides in simulated concrete pore solution: effect of SO^2-₄[J]. Corrosion Science, 2020, 163: 108223.
[20] WANG J L, XIAO L N, CHENG R F, et al. Chloride sorption kinetics and corrosion-resistant mechanism of MgAl-NO₂ LDH[J]. Journal of Industrial and Engineering Chemistry, 2024, 135: 522-531.
[21] MA G X, XU J X, HAN L, et al. Enhanced inhibition performance of NO^-₂ intercalated MgAl-LDH modified with nano-SiO₂ on steel corrosion in simulated concrete pore solution[J]. Corrosion Science, 2022, 204: 110387.
[22] WANG X G, J L, ZOU F B, et al. Ca-Al LDH hybrid self-healing microcapsules for corrosion protection[J]. Chemical Engineering Journal, 2022, 447: 137125.
[23] AL-MANSOORI T, GARCIA A. Study of the mechanical properties and self-healing ability of asphalt mixture containing calcium-alginate capsules[J]. Construction and Building Materials, 2016, 123: 734-744.
[24] 林冰. 模拟碳化混凝土孔隙液中几种有机缓蚀剂对碳钢的缓蚀作用[D]. 北京: 北京化工大学, 2019.
LIN B. Study on inhibition effect of some organic inhibitors on carbon steel in carbonated simulatied concrete pore solutions[D]. Beijing: Beijing University of Chemical Technology, 2019 (in Chinese).
[25] WISSAM Z, SAMER H. Encapsulation of flaxseed oil extract in alginate-salep system by ionic gelation[J]. Brazilian Journal of Pharmaceutical Sciences, 2019, 55: 12.
[26] 张玉荣, 倪浩然, 吴琼, 等. 茶树精油微胶囊包埋工艺优化及表征[J]. 河南工业大学学报(自然科学版), 2024, 45(5): 33-40.
ZHANG Y R, NI H R, WU Q, et al. Optimization and characterization of tea tree essential oil microcapsule embedding process[J]. Journal of Henan University of Technology (Natural Science Edition), 2024, 45(5): 33-40 (in Chinese).
[27] 郭娜, 朱桂兰, 刘兴运, 等. 蓝莓花青素微胶囊制备及其性质分析[J]. 食品与发酵工业, 2019, 45(23): 109-114.
GUO N, ZHU G L, LIU X Y, et al. Preparation and characterization of blueberry anthocyanin microcapsules[J]. Food and Fermentation Industries, 2019, 45(23): 109-114 (in Chinese).
[28] AKONJUEN B M, ARYEE A N A. Development of protein isolate-alginate-based delivery system to improve oxidative stability of njangsa (Ricinodendron heudelotii) seed oil[J]. Food Bioscience, 2023, 53: 102768.
[29] 林京, 关晋平, 陈国强, 等. 丁香油微胶囊的制备及表征[J]. 印染助剂, 2022, 39(2): 27-31.
LIN J, GUAN J P, CHEN G Q, et al. Preparation and characterization of clove oil microcapsules[J]. Textile Auxiliaries, 2022, 39(2): 27-31 (in Chinese).
[30] ZUO J D, WU B, DONG B Q, et al. Effects of nitrite ion intercalated CaAl and MgAl layered double hydroxides on the properties of concrete mortar[J]. Cement and Concrete Composites, 2024, 145: 105306.
[31] ZUO J D, WU B, LUO C Y, et al. Preparation of MgAl layered double hydroxides intercalated with nitrite ions and corrosion protection of steel bars in simulated carbonated concrete pore solution[J]. Corrosion Science, 2019, 152: 120-129.
[32] CUSTÓDIO J, VIEIRA M, MESQUITA A, et al. Estimation of maximum temperature attained during concrete cure for internal sulfate reaction prevention in structures[J]. Procedia Structural Integrity, 2022, 37: 644-651.
[33] BENNACEF C, DESOBRY-BANON S, PROBST L, et al. Advances on alginate use for spherification to encapsulate biomolecules[J]. Food Hydrocolloids, 2021, 118: 106782.
[34] CHEN M Q, LONG A L, ZHANG W, et al. Recent advances in alginate-based hydrogels for the adsorption-desorption of heavy metal ions from water: a review[J]. Separation and Purification Technology, 2025, 353: 128265.
[35] ZHOU X, YANG H Y, WANG F H. Investigation on the inhibition behavior of a pentaerythritol glycoside for carbon steel in 3.5% NaCl saturated Ca(OH)₂ solution[J]. Corrosion Science, 2012, 54: 193-200.
[36] YOHAI L, SCHREINER W, VÁZQUEZ M, et al. Phosphate ions as effective inhibitors for carbon steel in carbonated solutions contaminated with chloride ions[J]. Electrochimica Acta, 2016, 202: 231-242.
[37] TANG Y M, ZHANG F, HU S X, et al. Novel benzimidazole derivatives as corrosion inhibitors of mild steel in the acidic media. Part I: gravimetric, electrochemical, SEM and XPS studies[J]. Corrosion Science, 2013, 74: 271-282.
[38] ZHANG X, FU C H, ZHAN Q W, et al. Self-healing properties and improvement methods of mortar cracks in marine corrosive environments[J]. Journal of Building Engineering, 2023, 78: 107676.
[39] SUJITHA S V, B R, XAVIER J R. Effect of superabsorbent polymer hydrogels in the advancement of cementitious materials: a review[J]. Journal of Polymers and the Environment, 2023, 31(7): 2761-2778.

用于腐蚀保护的NO^-₂-LDHs自愈微胶囊的制备及性能研究

Preparation and Properties of NO^-₂-LDHs Self-Healing Microcapsules for Corrosion Protection

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