BULLETIN OF THE CHINESE CERAMIC SOCIETY ›› 2026, Vol. 45 ›› Issue (8): 2956-2966.DOI: 10.16552/j.cnki.issn1001-1625.2026.0247
• Road Materials • Previous Articles
ZONG Wei(
), LIU Cheng, ZHENG Wuxi, ZHANG Qixin, DONG Xianzheng
Received:2026-03-18
Revised:2026-04-14
Online:2026-08-15
Published:2026-09-01
CLC Number:
ZONG Wei, LIU Cheng, ZHENG Wuxi, ZHANG Qixin, DONG Xianzheng. Road Performance of Base with Phosphogypsum Replacing Coarse/Fine Aggregates[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(8): 2956-2966.
| Condensation time /min | Compressive strength/MPa | Flexural strength/MPa | |||
|---|---|---|---|---|---|
| Initial coagulation | Final coagulation | 3 d | 28 d | 3 d | 28 d |
| 193.0 | 254.0 | 26.6 | 49.8 | 6.6 | 9.3 |
Table 1 Main technical parameters of cement
| Condensation time /min | Compressive strength/MPa | Flexural strength/MPa | |||
|---|---|---|---|---|---|
| Initial coagulation | Final coagulation | 3 d | 28 d | 3 d | 28 d |
| 193.0 | 254.0 | 26.6 | 49.8 | 6.6 | 9.3 |
| Index | Specification requirement | Assay result | Test procedure | |
|---|---|---|---|---|
| Specific surface area/(m2·kg-1) | ≥400 | 489 | GB/T 18046—2017 | |
| Activity index/% | 7 d | ≥70 | 89 | |
| 28 d | ≥95 | 102 | ||
Table 2 Main technical parameters of slag
| Index | Specification requirement | Assay result | Test procedure | |
|---|---|---|---|---|
| Specific surface area/(m2·kg-1) | ≥400 | 489 | GB/T 18046—2017 | |
| Activity index/% | 7 d | ≥70 | 89 | |
| 28 d | ≥95 | 102 | ||
| Composition | CaO | SO3 | SiO2 | P2O5 | Fe2O3 | Al2O3 | F | Na2O | K2O | MgO | TiO2 |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Mass fraction/% | 44.1 | 39.4 | 9.3 | 0.9 | 0.7 | 0.9 | 0.6 | 0.1 | 0.3 | 0.2 | 0.1 |
Table 3 Main chemical composition of phosphogypsum
| Composition | CaO | SO3 | SiO2 | P2O5 | Fe2O3 | Al2O3 | F | Na2O | K2O | MgO | TiO2 |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Mass fraction/% | 44.1 | 39.4 | 9.3 | 0.9 | 0.7 | 0.9 | 0.6 | 0.1 | 0.3 | 0.2 | 0.1 |
| Type | Density/(g·cm-3) | Water absorption/% | Soft stone content/% | Cylinder compressive strength/MPa | Crushing value/% | Boiling mass loss/% |
|---|---|---|---|---|---|---|
| Phosphogypsum artificial aggregate | 1.58 | 18.32 | 14.49 | 5.82 | 42.14 | 4.62 |
| Crushed stone | 2.76 | 1.34 | 1.39 | 15.96 | 18.64 | 0.89 |
Table 4 Comparison of indexes between phosphogypsum artificial aggregate and crushed stone
| Type | Density/(g·cm-3) | Water absorption/% | Soft stone content/% | Cylinder compressive strength/MPa | Crushing value/% | Boiling mass loss/% |
|---|---|---|---|---|---|---|
| Phosphogypsum artificial aggregate | 1.58 | 18.32 | 14.49 | 5.82 | 42.14 | 4.62 |
| Crushed stone | 2.76 | 1.34 | 1.39 | 15.96 | 18.64 | 0.89 |
| Type | Unconfined compressive strength/MPa | Splitting tensile strength/MPa | Flexural tensile strength/MPa | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| 7 d | 28 d | 90 d | 180 d | 360 d | 90 d | 180 d | 360 d | 90 d | 180 d | 360 d | |
| Phosphogypsum artificial aggregate base | 4.02 | 5.51 | 6.24 | 6.58 | 6.96 | 0.77 | 0.89 | 0.91 | 1.38 | 1.54 | 1.68 |
| Phosphogypsum composite stabilized crushed stone base | 6.82 | 9.03 | 10.00 | 11.32 | 13.08 | 0.92 | 1.17 | 1.24 | 1.74 | 1.88 | 2.09 |
Table 5 Test results of mechanical strength
| Type | Unconfined compressive strength/MPa | Splitting tensile strength/MPa | Flexural tensile strength/MPa | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| 7 d | 28 d | 90 d | 180 d | 360 d | 90 d | 180 d | 360 d | 90 d | 180 d | 360 d | |
| Phosphogypsum artificial aggregate base | 4.02 | 5.51 | 6.24 | 6.58 | 6.96 | 0.77 | 0.89 | 0.91 | 1.38 | 1.54 | 1.68 |
| Phosphogypsum composite stabilized crushed stone base | 6.82 | 9.03 | 10.00 | 11.32 | 13.08 | 0.92 | 1.17 | 1.24 | 1.74 | 1.88 | 2.09 |
| Type | Unconfined compressive strength/MPa | Mass change rate/% | |
|---|---|---|---|
| Unfrozen specimen | Freeze-thaw specimens | ||
| Phosphogypsum artificial aggregate base | 5.51 | 4.88 | 2.71 |
| Phosphogypsum composite stabilized crushed stone base | 9.03 | 8.77 | 0.03 |
Table 6 Test results of freeze-thaw cycles
| Type | Unconfined compressive strength/MPa | Mass change rate/% | |
|---|---|---|---|
| Unfrozen specimen | Freeze-thaw specimens | ||
| Phosphogypsum artificial aggregate base | 5.51 | 4.88 | 2.71 |
| Phosphogypsum composite stabilized crushed stone base | 9.03 | 8.77 | 0.03 |
| Type | Unconfined compressive strength/MPa | Mass change rate/% | |
|---|---|---|---|
| 28 d cured specimen | Dry-wet cycled specimen | ||
| Phosphogypsum artificial aggregate base | 5.51 | 5.37 | 1.86 |
| Phosphogypsum composite stabilized crushed stone base | 9.03 | 10.26 | 0.52 |
Table 7 Test results of dry-wet cycles
| Type | Unconfined compressive strength/MPa | Mass change rate/% | |
|---|---|---|---|
| 28 d cured specimen | Dry-wet cycled specimen | ||
| Phosphogypsum artificial aggregate base | 5.51 | 5.37 | 1.86 |
| Phosphogypsum composite stabilized crushed stone base | 9.03 | 10.26 | 0.52 |
| Item | pH | Concentration/(mg·L-1) | ||||||
|---|---|---|---|---|---|---|---|---|
| P | F | Pb | Cd | Cr | As | Hg | ||
| Phosphogypsum | 5.68 | 41.90 | 17.20 | ND | ND | ND | 0.016 80 | 0.000 310 |
| Phosphogypsum artificial aggregate | 8.83 | ND | 2.69 | ND | ND | ND | 0.000 35 | 0.000 360 |
| Phosphogypsum artificial aggregate base | 8.01 | 0.02 | 0.21 | ND | ND | ND | ND | ND |
| Phosphogypsum composite stabilized crushed stone base | 9.86 | 0.07 | 0.37 | ND | ND | ND | ND | 0.000 054 |
| (GB 3838—2002) Class Ⅲ | 6~9 | 0.2 | 1 | 0.05 | 0.005 | 0.05 | 0.05 | 0.000 1 |
| (GB/T 18484—2017) Class Ⅲ | 6.5~8.5 | — | 1 | 0.01 | 0.005 | 0.05 | 0.01 | 0.001 0 |
Table 8 Test results of characteristic pollutants
| Item | pH | Concentration/(mg·L-1) | ||||||
|---|---|---|---|---|---|---|---|---|
| P | F | Pb | Cd | Cr | As | Hg | ||
| Phosphogypsum | 5.68 | 41.90 | 17.20 | ND | ND | ND | 0.016 80 | 0.000 310 |
| Phosphogypsum artificial aggregate | 8.83 | ND | 2.69 | ND | ND | ND | 0.000 35 | 0.000 360 |
| Phosphogypsum artificial aggregate base | 8.01 | 0.02 | 0.21 | ND | ND | ND | ND | ND |
| Phosphogypsum composite stabilized crushed stone base | 9.86 | 0.07 | 0.37 | ND | ND | ND | ND | 0.000 054 |
| (GB 3838—2002) Class Ⅲ | 6~9 | 0.2 | 1 | 0.05 | 0.005 | 0.05 | 0.05 | 0.000 1 |
| (GB/T 18484—2017) Class Ⅲ | 6.5~8.5 | — | 1 | 0.01 | 0.005 | 0.05 | 0.01 | 0.001 0 |
| [1] | 侯江, 郭卫广, 雍毅, 等. 基于文献计量学方法剖析磷石膏研究及进展[J]. 磷肥与复肥, 2021, 36(1): 32-35. |
| HOU J, GUO W G, YONG Y, et al. Analysis of research and development of phosphogypsum based on bibliometric method[J]. Phosphate & Compound Fertilizer, 2021, 36(1): 32-35 (in Chinese). | |
| [2] | 吴泳霖, 张伟, 奠波, 等. 磷石膏热分解研究现状[J]. 硅酸盐通报, 2022, 41(9): 3129-3137. |
| WU Y L, ZHANG W, DIAN B, et al. Research status of phosphogypsum pyrolysis[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(9): 3129-3137 (in Chinese). | |
| [3] | 唐向阳, 何新建, 谢陈鑫, 等. 磷石膏资源化研究现状及展望[J]. 无机盐工业, 2025, 57(6): 18-26. |
| TANG X Y, HE X J, XIE C X, et al. Research status and prospects of phosphogypsum resource utilization[J]. Inorganic Chemicals Industry, 2025, 57(6): 18-26 (in Chinese). | |
| [4] | CUI Y, BAI J D, CHANG I S, et al. A systematic review of phosphogypsum recycling industry based on the survey data in China-applications, drivers, obstacles, and solutions[J]. Environmental Impact Assessment Review, 2024, 105: 107405. |
| [5] | 宗 炜, 王远辉, 许 亮, 等. 工业固废磷石膏路面基层材料路用性能研究[J]. 硅酸盐通报, 2024, 43(2): 766-773. |
| ZONG W, WANG Y H, XU L, et al. Pavement performance of industrial solid waste phosphogypsum pavement base material[J]. Bulletin of the Chinese Ceramic Society, 2024, 43(2): 766-773 (in Chinese). | |
| [6] | 张家豪, 赵丽华, 高奥东, 等. 水泥稳定大掺量改性磷石膏的制备与性能研究[J]. 公路, 2024, 69(8): 107-113. |
| ZHANG J H, ZHAO L H, GAO A D, et al. Preparation and performance study of cement stabilized high content modified phosphogypsum[J]. Highway, 2024, 69(8): 107-113 (in Chinese). | |
| [7] | 孙奇奇. 大掺量磷石膏应用:磷石膏用于路面基层的研究[D]. 合肥:安徽建筑大学, 2024. |
| SUN Q Q.Application of heavily doped phosphogypsum: a study on the use of phosphogypsum for pavement base layers[D]. Hefei: Anhui Jianzhu University, 2024 (in Chinese). | |
| [8] | 胡彪, 吴赤球, 吕伟, 等. 改性磷石膏矿渣水泥在混凝土和路基材料中的应用研究[J]. 混凝土与水泥制品, 2022(4): 94-99. |
| HU B, WU C Q, LV W, et al. Study on the application of modified phosphogypsum slag cement in concrete and roadbed materials[J]. China Concrete and Cement Products, 2022(4): 94-99 (in Chinese). | |
| [9] | 何兆益, 邹萌, 姚启文, 等. 高掺量磷石膏-水泥-固化剂稳定碎石基层材料的性能及强度形成机理[J]. 硅酸盐通报, 2026, 45(1): 346-358. |
| HE Z Y, ZOU M, YAO Q W, et al. Performance and strength formation mechanism of high dosage phosphogypsum-cement-curing agent stabilized crushed stone base layer material[J]. Bulletin of the Chinese Ceramic Society, 2026, 45(1): 346-358 (in Chinese). | |
| [10] | 刘超, 赵德强, 马倩, 等. 水泥-磷石膏稳定碎石路面基层材料的研究与应用[J]. 硅酸盐通报, 2023, 42(6): 2121-2130. |
| LIU C, ZHAO D Q, MA Q, et al. Research and application of cement-phosphogypsum stabilized crushed stone pavement base material[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(6): 2121-2130 (in Chinese). | |
| [11] | 陈文义, 郑少鹏, 陈亮亮, 等. 固化剂改性磷石膏路用基层基本力学及稳定性能分析[J]. 材料导报, 2025, 39(增刊1): 411-416. |
| CHEN W Y, ZHENG S P, CHEN L L, et al. Analysis on basic mechanics and stability properties of curing agent modified phosphogypsum road base[J]. Materials Reports, 2025, 39(issue 1): 411-416 (in Chinese). | |
| [12] | 肖心, 李敬伟, 侯祥山, 等. 固废基硫铝系高活性材料改性磷石膏制备路面基层材料试验研究[J]. 环境卫生工程, 2023, 31(4): 63-69. |
| XIAO X, LI J W, HOU X S, et al. Study on properties of pavement base material prepared using phosphogypsum modified by solid waste-based sulfoaluminate high-activity material[J]. Environmental Sanitation Engineering, 2023, 31(4): 63-69 (in Chinese). | |
| [13] | 谭文明, 胡浪, 张飞, 等. 富水环境下高掺量磷石膏公路基层材料长期力学性能及体积稳定性研究[J]. 材料导报, 2025, 39(增刊1): 405-410. |
| TAN W M, HU L, ZHANG F, et al. Study on the long-term mechanical properties and volume stability of highway base material with high content of phosphogypsum in water-rich environment[J]. Materials Reports, 2025, 39(issue 1): 405-410 (in Chinese). | |
| [14] | 杜辉, 贾敬鹏, 李晓龙, 等. 磷石膏再生骨料路面基层路用性能研究[J]. 公路, 2026, 71(1): 51-57. |
| DU H, JIA J P, LI X L, et al. Research on the road performance of phosphogypsum recycled aggregate in pavement base courses[J]. Highway, 2026, 71(1): 51-57 (in Chinese). | |
| [15] | 吕伟, 吴赤球, 龚文辉, 等. 改性磷石膏轻骨料在路基材料中的应用研究[J]. 混凝土与水泥制品, 2022(6): 82-86. |
| LV W, WU C Q, GONG W H, et al. Research on the application of modified phosphogypsum lightweight aggregate in subgrade materials[J]. China Concrete and Cement Products, 2022(6): 82-86 (in Chinese). | |
| [16] | 金飞龙. 半刚性基层损伤特性及服役状态评价[D]. 哈尔滨: 哈尔滨工业大学, 2019. |
| JIN F L. Half -rigid grass-roots damage characteristics and service status evaluation[D]. Harbin: Harbin University of Technology, 2019 (in Chinese). | |
| [17] | 徐刚敏. 干湿循环下磷石膏稳定土强度特性及机理研究[D]. 贵州: 贵州大学, 2024. |
| XU G M. Study on strength characteristics and mechanism of phosphogypsum-stabilized soil under dry-wet cycles[D]. Guizhou: Guizhou University, 2024 (in Chinese). | |
| [18] | 王金山. 粗粒盐渍土盐胀及力学特性研究[D]. 乌鲁木齐: 新疆大学, 2021. |
| WANG J S. Study on the characteristics of thick -grained salt salt and mechanics [D]. Urumqi: Xinjiang University, 2021 (in Chinese). | |
| [19] | 李冰雁, 李晨, 游晨, 等. 磷石膏堆场区域水环境中主要污染物分布特征及其风险评价[J]. 化工环保, 2024(2): 279-285. |
| LI B Y, LI C, YOU C, et al. Distribution characteristics and risk assessment of major pollutants in regional water environment of phosphogypsum yard[J]. Environmental Protection of Chemical Industry, 2024(2): 279-285 (in Chinese). | |
| [20] | 孙兆辉, 许志鸿, 王铁斌, 等. 水泥稳定碎石基层材料干缩及影响因素分析[J]. 建筑材料学报, 2006, 9(2): 166-171. |
| SUN Z H, XU Z H, WANG T B, et al. Research on dry shrinkage deformation properties of cement-stabilized macadam base course materials[J]. Journal of Building Materials, 2006, 9(2): 166-171 (in Chinese). | |
| [21] | 陈冠.改性磷石膏胶结充填体污染元素固化机制及其耐久性研究[D]. 武汉: 武汉科技大学, 2024. |
| CHEN G. Study on solidification mechanism of polluting elements of modified phosphogypsum cemented backfill and its durability[D]. Wuhan: Wuhan University of Science and Technology, 2024 (in Chinese). |
| [1] | TANG Pei, ZHU Meiyi, RONG Pengjie, CHEN Wei. Performance Enhancement of Excess-Sulfate Phosphogypsum-Slag Cement Through Electrochemically Activated Red Mud [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(8): 2806-2816. |
| [2] | CHENG Xiao, WU Fade, WANG Hongxia, SONG Xiaoguang, GAO Chunyong, GUO Junhua, LI Fan. Influence Mechanism of Additives on Mildew of Phosphogypsum [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(8): 2839-2849. |
| [3] | TANG Pei, LIU Jiaxin, QU Bo, RONG Pengjie, CHEN Wei. Thermally Activated Coal Gangue and Its Application in Phosphogypsum Slag Cement [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(8): 2829-2838. |
| [4] | ZHANG Xuemei, JIN Qingqing, CHANG Shuo, WANG Lu, LI Zhaoqi, ZHANG Xingzhao, LIU Shuhua. Chemical Shrinkage Characteristics of Supersulfated Cement [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(7): 2215-2225. |
| [5] | LIU Xin, LI Mingyang, ZHANG Xihe, LAN Shaoding, GAO Xu. Durability and Microstructure of Phosphogypsum-Slag-Based All-Solid-Waste Cementitious Material Regulated by Red Mud and Recycled Cement Powder [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(7): 2478-2490. |
| [6] | JIN Zihao, ZOU Ziyong, HE Xingyang, SU Ying, CHEN Shuqin. Effect of Wet Grinding Carbonized Steel Slag on Properties and Microstructure of Beta-Hemihydrate Phosphogypsum [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(7): 2347-2356. |
| [7] | REN Jun, YAN Yunxiao, LI Miaoyuan, TIAN Zhenhe, ZHAO Lixing, WANG Dafu. Effect of Microbial-Modified Phosphogypsum on Properties of Supersulfated Cement [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(5): 1671-1681. |
| [8] | CHEN Zihan, GUO Yudong, LYU Qinfei, LIANG Yongning, JI Tao. Effect of Alkali Equivalent on Properties of Phosphogypsum- Alkali-Activated Slag Foam Concrete [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(4): 1315-1323. |
| [9] | ZHANG Shaobo, MA Jianyun, ZHANG Xinyong, GAO Xinwen, CHEN Qian. Research Progress on Composition and Performance Evaluation of Fiber-Modified Micro-Surfacing for Road [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(1): 309-324. |
| [10] | HE Zhaoyi, ZOU Meng, YAO Qiwen, CAO Dongwei, QIN Meng. Performance and Strength Formation Mechanism of High Dosage Phosphogypsum-Cement-Curing Agent Stabilized Crushed Stone Base Layer Material [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2026, 45(1): 346-358. |
| [11] | LI Yisheng, LYU Wei, WU Chiqiu, YU Zhengkang, HE Jing, SHUI Zhonghe. Hardened Body Preparation and Performance Adjustment of High Content Phosphogypsum Cementitious Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(8): 2944-2954. |
| [12] | DENG Xinghui, XU Guihong, BAO Lixin, XU Weihong, CHEN Ziwei, YANG Bulei. Mechanical Properties and Pores Three-Parameter Distribution of Phosphogypsum-Based Extruded Special-Shaped Brick (PG-ESB) [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(6): 2240-2249. |
| [13] | YU Hailong, BAI Wending, LIU Meifang, HU Liqun, BAO Yingbo. Effect of Basalt Fiber on Mechanical Properties of Cement Stabilized Macadam with Suspended Dense Structure [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(6): 2343-2352. |
| [14] | SU Ying, GONG Wei, LIU Chuanbei, ZHANG Jun. Mix Ratio Design and Mechanical Properties of Phosphogypsum Lightweight Aggregate Concrete Based on Machine Learning [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(5): 1656-1665. |
| [15] | REN Jun, YU Yongkun, MAO Wenting, ZHANG Yu, WANG Dafu. Performance of Mortar Based on Phosphogypsum-Based Fine Lightweight Aggregate [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2025, 44(4): 1420-1427. |
| Viewed | ||||||
|
Full text |
|
|||||
|
Abstract |
|
|||||