Effect of B2O3 on Structure and Properties of Low Expansion Borosilicate Glass

Abstract

Abstract: The low expansion borosilicate glass was prepared by using Na₂O-B₂O₃-SiO₂ low expansion glass system and gradually replacing SiO₂ with B₂O₃ by high temperature melting method. The microstructure of borosilicate glass was analyzed by infrared spectrum and scanning electron microscopy. The content of bridged oxygen and non-bridged oxygen was analyzed by X-ray photoelectron spectroscopy. The effects of the content of B₂O₃ on the mechanical properties, thermal expansion properties and UV-Vis transmittance of borosilicate glass were studied. The results show that [BO₃] in glass structure increases with the increase of B₂O₃ content, and the phase separation of glass becomes more and more serious. The glass system has good mechanical properties, with microhardness up to 802 kg/mm² and flexural strength up to 147 MPa. The transition temperature and softening temperature decreased gradually, and the thermal expansion coefficient increased gradually. The visible light transmittance of the glass sample is about 90% without an obvious rule. The increase of [BO₃] increases the content of non-bridged oxygen in the glass structure, and the UV-vis transmittance of the glass decreases gradually.

Key words: B₂O₃, UV-Vis transmittance, low expansion glass, thermal expansion property, mechanical property

CLC Number:

TQ171

ZHANG Pan, ZHANG Qinyu, JIANG Hong, MA Yanping. Effect of B₂O₃ on Structure and Properties of Low Expansion Borosilicate Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(5): 1685-1691.

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Effect of B₂O₃ on Structure and Properties of Low Expansion Borosilicate Glass

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