Preparation of SiO2 Composite Materials Loaded with Different Air-Entraining Agents and Their Application in Cement-Based Materials

Abstract

Abstract: SiO₂ nanoparticles loaded with air-entraining agents were prepared with four different anionic air-entraining agents as the templating agent. The introduction of (3-aminopropyl) triethoxysilane during the hydrolysis of silicon sources can attract more anionic air-entraining agents to SiO₂ through electrostatic interaction. The feasibility of preparation method for loading various anionic air-entraining agents was verified. Meanwhile, the influences of structure of air-entraining agents on structure and application of products were investigated. The results show that all SiO₂ composite materials loaded with air-entraining agents present a release of air-entraining agents in solution and improve the bubble stability in mortars. The addition of SiO₂ composite materials to cement mortar results in a low loss of air content within 2 h, also optimizing the air-void parameters of hardened mortars. The volume of surfactant molecules and micelles significantly affects the particle size and the load of surfactants in products, which in turn influences the air content of SiO₂ composite materials in solutions and the enhancement of bubble stability in mortars.

Key words: SiO₂, air-entraining agent, slow-release, bubble stability, air-void, cement mortar

CLC Number:

TU528

SHEN Fei, QIAO Min, SHAN Guangcheng, WU Qingyong. Preparation of SiO₂ Composite Materials Loaded with Different Air-Entraining Agents and Their Application in Cement-Based Materials[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(9): 3157-3163.

References

[1] 罗祥, 王玲, 王振地. 混凝土中气泡的产生与发展:机理和影响因素[J]. 材料导报, 2021, 35(增刊2): 213-217.
LUO X, WANG L, WANG Z D. Formation and development of bubbles in concrete: mechanism and influencing factors[J]. Materials Reports, 2021, 35(supplement 2): 213-217 (in Chinese).
[2] EBRAHIMI K, DAIEZADEH M J, ZAKERTABRIZI M, et al. A review of the impact of micro- and nanoparticles on freeze-thaw durability of hardened concrete: mechanism perspective[J]. Construction and Building Materials, 2018, 186: 1105-1113.
[3] DU L X, FOLLIARD K J. Mechanisms of air entrainment in concrete[J]. Cement and Concrete Research, 2005, 35(8): 1463-1471.
[4] ATAHAN H N, CARLOS C J, CHAE S, et al. The morphology of entrained air voids in hardened cement paste generated with different anionic surfactants[J]. Cement and Concrete Composites, 2008, 30(7): 566-575.
[5] ŁAŹNIEWSKA P B. The influence of selected new generation admixtures on the workability, air-voids parameters and frost-resistance of self compacting concrete[J]. Construction and Building Materials, 2012, 31: 310-319.
[6] PLANK J, SAKAI E, MIAO C W, et al. Chemical admixtures: chemistry, applications and their impact on concrete microstructure and durability[J]. Cement and Concrete Research, 2015, 78: 81-99.
[7] 乔敏, 单广程, 高南箫, 等. 混凝土气泡调控型表面活性剂的研究进展[J]. 材料导报, 2022, 36(18): 66-72.
QIAO M, SHAN G C, GAO N X, et al. Research progress of concrete air controlled surfactants[J]. Materials Reports, 2022, 36(18): 66-72 (in Chinese).
[8] CZAJKA A, HAZELL G, EASTOE J. Surfactants at the design limit[J]. Langmuir: the ACS Journal of Surfaces and Colloids, 2015, 31(30): 8205-8217.
[9] MA J F, SHANG Y Z, PENG C J, et al. Synthesis and foaming performance of one high-efficient air content regulator of concrete[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 586: 124245.
[10] TUNSTALL L E, SCHERER G W, PRUD'HOMME R K. Studying AEA interaction in cement systems using tensiometry[J]. Cement and Concrete Research, 2017, 92: 29-36.
[11] QIAO M, SHAN G C, CHEN J, et al. Effects of salts and adsorption on the performance of air entraining agent with different charge type in solution and cement mortar[J]. Construction and Building Materials, 2020, 242: 118188.
[12] BALTRUS J P, LACOUNT R B. Measurement of adsorption of air-entraining admixture on fly ash in concrete and cement[J]. Cement and Concrete Research, 2001, 31(5): 819-824.
[13] CHEN J, QIAO M, GAO N X, et al. Sulfonic gemini surfactants: synthesis, properties and applications as novel air entraining agents for concrete[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2017, 522: 593-600.
[14] SHAN G C, ZHAO S, QIAO M, et al. Synergism effects of coconut diethanol amide and anionic surfactants for entraining stable air bubbles into concrete[J]. Construction and Building Materials, 2020, 237: 117625.
[15] YI S H, ZHENG J N, LV P, et al. Controlled drug release from cyclodextrin-gated mesoporous silica nanoparticles based on switchable host-guest interactions[J]. Bioconjugate Chemistry, 2018, 29(9): 2884-2891.
[16] FERREIRA A, VECINO X, FERREIRA D, et al. Novel cosmetic formulations containing a biosurfactant from lactobacillus paracasei[J]. Colloids and Surfaces B, Biointerfaces, 2017, 155: 522-529.
[17] KUMAR N, MANDAL A. Surfactant stabilized oil-in-water nanoemulsion: stability, interfacial tension, and rheology study for enhanced oil recovery application[J]. Energy & Fuels, 2018, 32(6): 6452-6466.
[18] 王浩川, 冯攀, 冉千平, 等. 混凝土外加剂的控制释放技术[J]. 硅酸盐学报, 2021, 49(2): 420-428.
WANG H C, FENG P, RAN Q P, et al. Controlled release technology of concrete admixtures: a short review[J]. Journal of the Chinese Ceramic Society, 2021, 49(2): 420-428 (in Chinese).
[19] ZHONG X, LI C C, PU H, et al. Increased nonionic surfactant efficiency in oil recovery by integrating with hydrophilic silica nanoparticle[J]. Energy & Fuels, 2019, 33(9): 8522-8529.
[20] ALSMAEIL A W, HAMMAMI M A, ENOTIADIS A, et al. Encapsulation of an anionic surfactant into hollow spherical nanosized capsules: size control, slow release, and potential use for enhanced oil recovery applications and environmental remediation[J]. ACS Omega, 2021, 6(8): 5689-5697.
[21] SHEN F, QIAO M, SHAN G C, et al. Enhancement of bubble stability in cement-based materials by a sustained-release effect of silica nanoparticles[J]. Construction and Building Materials, 2023, 362: 129739.
[22] 陈康, 王海洋, 蔡清, 等. 介孔二氧化硅的制备及应用进展[J]. 安徽化工, 2022, 48(6): 9-11.
CHEN K, WANG H Y, CAI Q, et al. Progress in preparation and application of mesoporous silica[J]. Anhui Chemical Industry, 2022, 48(6): 9-11 (in Chinese).
[23] 陈炫来, 严国超, 阳湘琳, 等. SDS/SDBS对无烟煤润湿性影响的分子动力学模拟[J]. 煤炭科学技术, 2022, 50(12): 185-193.
CHEN X L, YAN G C, YANG X L, et al. Molecular dynamics simulation of the effect of SDS/SDBS on the wettability of anthracite[J]. Coal Science and Technology, 2022, 50(12): 185-193 (in Chinese).
[24] ELSEN J, LENS N, VYNCKE J, et al. Quality assurance and quality control of air entrained concrete[J]. Cement and Concrete Research, 1994, 24(7): 1267-1276.

Preparation of SiO₂ Composite Materials Loaded with Different Air-Entraining Agents and Their Application in Cement-Based Materials

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