Preparation and Corrosion Resistance Performance of Graphene Oxide/SiO2 Coatings on LAS Glass

Abstract

Abstract: In the present work, the graphene oxide (GO)/tetraethyl orthosilicate (TEOS) aqueous solution was prepared by the sol-gel method after investigating the dispersibility of GO in water and ethanol, the complex dispersion of GO powder and its water solution in the hydrolysate of TEOS. The surface and cross section morphology, element distributions of the composite film were analyzed. The influence of GO/SiO₂ film on the corrosion resistance of the glass was studied. The results show that 0.05 g GO can be well dispersed into 15 mL deionized water, and a uniform coating solution can be obtained with further TEOS hydrolysate addition. After heat treatment at 600 ℃ for 2 h and under N₂ atmosphere, dense GO/SiO₂ film can be obtained. The carbon element analysis shows graphene oxide was homogeneously distributed in the film. The corrosion behavior comparison of non-coated, SiO₂ film coated and GO/SiO₂ composite film coated LAS glass in HCl (1 mol/L) solution and NaOH (5％, mass fraction) solution confirmed that GO/SiO₂ composite film can improve the acid corrosion resistance of LAS glass.

Key words: thin film, LAS glass, graphene oxide, tetraethyl orthosilicate, glass corrosion resistance, uniform dispersion

CLC Number:

TQ171.79

CHANG Xizheng, ZHANG Jihong, HE Jianxiong, LI Junge, XIE Jun. Preparation and Corrosion Resistance Performance of Graphene Oxide/SiO₂ Coatings on LAS Glass[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(8): 3034-3044.

References

[1] DOREMUS R H. Interdiffusion of hydrogen and alkali ions in a glass surface[J]. Journal of Non-Crystalline Solids, 1975, 19: 137-144.
[2] VIENNA J D, RYAN J V, GIN S, et al. Current understanding and remaining challenges in modeling long-term degradation of borosilicate nuclear waste glasses[J]. International Journal of Applied Glass Science, 2013, 4(4): 283-294.
[3] STONE-WEISS N, YOUNGMAN R E, THORPE R, et al. An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments[J]. Physical Chemistry Chemical Physics: PCCP, 2020, 22(4): 1881-1896.
[4] CHEN K, CHEN M H, YU Z D, et al. Corrosion of SiO₂-B₂O₃-Al₂O₃-CaF₂-R₂O (R=Na and K) enamels with different content of ZrO₂ in H₂SO₄ and NaOH solutions[J]. Ceramics International, 2019, 45(12): 14958-14967.
[5] 马洁. 氧化铈对包钢高炉渣玻璃陶瓷析晶机理及耐腐蚀特性的影响[D]. 内蒙古科技大学, 2021.
MA J. Effect of cerium oxide on crystallization mechanism and corrosion resistance of glass ceramics from blast furnace slag of clad steel[D]. Inner Mongolia University of Science and Technology, 2021 (in Chinese).
[6] 刘志, 张勇, 张彬, 等. 玻璃纤维/聚氨酯复合材料耐腐蚀和耐UV研究[J]. 聚氨酯工业, 2020, 35(1): 26-28.
LIU Z, ZHANG Y, ZHANG B, et al. Study on corrosion-resistance and UV-resistance of glass fiber/polyurethane composites[J]. Polyurethane Industry, 2020, 35(1): 26-28 (in Chinese).
[7] 王乔方, 王冲文, 郑万祥, 等. 不同环境条件下磷酸盐玻璃滤光片腐蚀特性研究[J]. 红外技术, 2020, 42(10): 947-952.
WANG Q F, WANG C W, ZHENG W X, et al. Corrosion properties of phosphate glass filter under different environments[J]. Infrared Technology, 2020, 42(10): 947-952 (in Chinese).
[8] 顾凤麟, 乔乾, 余家欣, 等. 摩擦诱导次表面损伤对硼硅酸盐玻璃化学腐蚀的影响[J]. 硅酸盐学报, 2021, 49(12): 2797-2808.
GU F L, QIAO Q, YU J X, et al. Effect of friction-induced subsurface damage on chemical dissolution of borosilicate glass[J]. Journal of the Chinese Ceramic Society, 2021, 49(12): 2797-2808 (in Chinese).
[9] 蒲永平, 许宁, 吴胜红. 玻璃组成对Li₂O-Al₂O₃-SiO₂微晶玻璃热膨胀系数的影响[J]. 硅酸盐学报, 2009, 37(5): 738-742.
PU Y P, XU N, WU S H. Influence of composition on the coefficient of thermal expansion of Li₂O-Al₂O₃-SiO₂ glass-ceramic[J]. Journal of the Chinese Ceramic Society, 2009, 37(5): 738-742 (in Chinese).
[10] GUEDES M, FERRO A C, FERREIRA J M F. Nucleation and crystal growth in commercial LAS compositions[J]. Journal of the European Ceramic Society, 2001, 21(9): 1187-1194.
[11] ZHANG Y M, LI B B, LI D, et al. Microstructure, cytocompatibility, and chemical durability of chemically strengthened LAS (Li₂O-Al₂O₃-SiO₂) glass-ceramic materials[J]. Journal of the European Ceramic Society, 2022, 42(13): 6110-6118.
[12] 胥利先, 孙继红, 马重芳, 等. 纳米改性涂料的研究进展[J]. 化工进展, 2005, 24(4): 341-349.
XU L X, SUN J H, MA C F, et al. Research progress of nanomodification coating[J]. Chemical Industry and Engineering Progress, 2005, 24(4): 341-349 (in Chinese).
[13] 陈阳, 张梓澜, 隋志军, 等. 氢氧化镍纳米线/三维石墨烯复合材料的制备及其电化学性能[J]. 物理化学学报, 2015, 31(6): 1105-1112.
CHEN Y, ZHANG Z L, SUI Z J, et al. Preparation and electrochemical performance of Ni(OH)₂ nanowires/three-dimensional graphene composite materials[J]. Acta Physico-Chimica Sinica, 2015, 31(6): 1105-1112 (in Chinese).
[14] 翟倩楠, 冯树波. 氧化石墨烯的制备、结构控制与应用[J]. 化工进展, 2020, 39(10): 4061-4072.
ZHAI Q N, FENG S B. Preparation, structure control and application of graphene oxide[J]. Chemical Industry and Engineering Progress, 2020, 39(10): 4061-4072 (in Chinese).
[15] 槐抗抗, 谷琦琦, 郭何云, 等. 石墨烯改性水性丙烯酸树脂涂料的制备与性能[J]. 材料保护, 2017, 50(1): 40-44.
HUAI K K, GU Q Q, GUO H Y, et al. Preparation and property of water-based acrylic resin coating modified with graphene[J]. Materials Protection, 2017, 50(1): 40-44 (in Chinese).
[16] 孙丽娟, 杨程. 原料纯度对氧化石墨烯性能的影响[J]. 材料导报, 2015, 29(增刊2): 321-324.
SUN L J, YANG C. Effect of raw material purity on properties of graphene oxide[J]. Materials Reports, 2015, 29(supplement 2): 321-324 (in Chinese).
[17] 单国荣, 张宁. 氧化石墨烯复合水凝胶研究进展[J]. 化工学报, 2018, 69(2): 535-545.
SHAN G R, ZHANG N. Research progress on graphene oxide composite hydrogels[J]. CIESC Journal, 2018, 69(2): 535-545 (in Chinese).
[18] 钟丽华, 张何. 氧化石墨烯在纺织品领域的抗菌应用[J]. 包装工程, 2019, 40(23): 94-100.
ZHONG L H, ZHANG H. Antibacterial application of graphene oxide in textiles[J]. Packaging Engineering, 2019, 40(23): 94-100 (in Chinese).
[19] 彭晚军, 丁纪恒, 夏伟军, 等. 石墨烯分散液对环氧树脂稀释效果及热性能的影响[J]. 塑料科技, 2017, 45(10): 71-75.
PENG W J, DING J H, XIA W J, et al. Influence of graphene dispersion on dilution effect and thermal properties of epoxy resin[J]. Plastics Science and Technology, 2017, 45(10): 71-75 (in Chinese).
[20] QAMAR S, YASIN S, RAMZAN N, et al. Preparation of stable dispersion of graphene using copolymers: dispersity and aromaticity analysis[J]. Soft Materials, 2019, 17(2): 190-202.
[21] 易响. 萘系非离子表面活性剂的制备及其对石墨烯分散性探究[D]. 武汉: 武汉理工大学, 2016.
YI X. Preparation of naphthalene nonionic surfactants and their dispersion on graphene[D]. Wuhan: Wuhan University of Technology, 2016 (in Chinese).
[22] 桑琦, 何丽红, 周超, 等. 氧化石墨烯水性粘结涂层性能研究[J]. 应用化工, 2022, 51(9): 2501-2504+2510.
SANG Q, HE L H, ZHOU C, et al. Study on the mechanical properties of graphene oxide to adhesive layer coatings[J]. Applied Chemical Industry, 2022, 51(9): 2501-2504+2510 (in Chinese).
[23] 涂欣, 邓健怡, 吴文栋, 等. 石墨烯改性环氧涂层的制备与防护性能研究[J]. 热固性树脂, 2023, 38(4): 40-43+48.
TU X, DENG J Y, WU W D, et al. Preparation and protective properties of graphene modified epoxy coatings[J]. Thermosetting Resins, 2023, 38(4): 40-43+48 (in Chinese).
[24] 杨旭宇, 王安龙, 杨嵩. 氧化石墨烯与石墨烯在溶剂中的分散性能研究[J]. 炭素技术, 2014, 33(3): 30-32.
YANG X Y, WANG A L, YANG S. Study on the dispersibility of GO and RGO in different solvents[J]. Carbon Techniques, 2014, 33(3): 30-32 (in Chinese).
[25] 祖恩东, 李茂材, 张鹏翔. 二氧化硅类玉石的显微拉曼光谱研究[J]. 昆明理工大学学报, 2000(3): 77-78+84.
ZU E D, LI M C, ZHANG P X, et al. Study on micro Raman spectroscopy of silica jade[J]. Journal of Kunming University of Science and Technology, 2000(3): 77-78+84 (in Chinese).
[26] VELÁZQUEZ J J, MOSA J, GORNI G, et al. Transparent SiO₂-GdF₃ sol-gel nano-glass ceramics for optical applications[J]. Journal of Sol-Gel Science and Technology, 2019, 89(1): 322-332.
[27] REN Y F, LI W T, CAO Z H, et al. Robust TiO₂ nanorods-SiO₂ core-shell coating with high-performance self-cleaning properties under visible light[J]. Applied Surface Science, 2020, 509: 145377.
[28] DESTINO J F, DUDUKOVIC N A, JOHNSON M A, et al. 3D printed optical quality silica and silica-titania glasses from sol-gel feedstocks[J]. Advanced Materials Technologies, 2018, 3(6): 1700323.
[29] 黄颖. 巴西金刚石表面微形貌及光谱学特征[D]. 中国地质大学(北京), 2021.
HUANG Y. Micromorphology and spectral characteristics of diamond surface in Brazil[D]. China University of Geosciences (Beijing), 2021 (in Chinese).
[30] 商宜美, 柳颖, 姜健准. 拉曼光谱在超声剥离石墨烯中的应用[J]. 石化技术, 2022, 29(2): 143-144+185.
SHANG Y M, LIU Y, JIANG J Z. Application of Raman spectroscopy in ultrasonic stripping of graphene[J]. Petrochemical Industry Technology, 2022, 29(2): 143-144+185 (in Chinese).
[31] MALARD L M, PIMENTA M A, DRESSELHAUS G, et al. Raman spectroscopy in graphene[J]. Physics Reports, 2009, 473(5/6): 51-87.
[32] CANÇADO L G, JORIO A, FERREIRA E H, et al. Quantifying defects in graphene via Raman spectroscopy at different excitation energies[J]. Nano Letters, 2011, 11(8): 3190-3196.
[33] 祝祖送, 张柳军, 穆小燕, 等. 光干涉效应对石墨烯拉曼散射G峰强度的影响[J]. 安庆师范大学学报(自然科学版), 2021, 27(4): 16-19.
ZHU Z S, ZHANG L J, MU X Y, et al. Effect of optical interference on Raman scattering G peak intensity of graphene[J]. Journal of Anqing Normal University (Natural Science Edition), 2021, 27(4): 16-19 (in Chinese).
[34] MAFRA D L, KONG J, SATO K, et al. Using gate-modulated Raman scattering and electron-phonon interactions to probe single-layer graphene: a different approach to assign phonon combination modes[J]. Physical Review B, 2012, 86(19): 195434.
[35] 李侣, 李宇捷, 李黎, 等. 碱性腐蚀对超疏水涂层绝缘强度的影响[J]. 绝缘材料, 2023, 56(9): 83-88.
LI L, LI Y J, LI L, et al. Effect of alkaline corrosion on insulating strength of superhydrophobic coatings[J]. Insulating Materials, 2023, 56(9): 83-88 (in Chinese).
[36] 姜宇哲. 离子辐照导致硼硅酸盐玻璃浸出性能变化的机理研究[D]. 兰州: 兰州大学, 2022.
JIANG Y Z. Study on the mechanism of leaching property change of borosilicate glass caused by ion irradiation[D]. Lanzhou: Lanzhou University, 2022 (in Chinese).
[37] 马瑞锋. 金属表面含氧化石墨烯复合钝化膜层的制备及耐蚀性研究[D]. 西安: 西安石油大学, 2022.
MA R F. Preparation and corrosion resistance of composite passivation film containing graphene oxide on metal surface[D]. Xi’an: Xi’an Shiyou University, 2022 (in Chinese).
[38] CUBIDES Y, CASTANEDA H. Corrosion protection mechanisms of carbon nanotube and zinc-rich epoxy primers on carbon steel in simulated concrete pore solutions in the presence of chloride ions[J]. Corrosion Science, 2016, 109: 145-161.
[39] 黎晓琳. 氧化石墨烯在水溶液和水性富锌环氧涂层中对Q235钢腐蚀行为影响的研究[D]. 广州: 华南理工大学, 2022.
LI X L. Effect of graphene oxide on corrosion behavior of Q235 steel in aqueous solution and waterborne zinc-rich epoxy coating[D]. Guangzhou: South China University of Technology, 2022 (in Chinese).

Preparation and Corrosion Resistance Performance of Graphene Oxide/SiO₂ Coatings on LAS Glass

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