Preparation of Si2N2O/SiC Composite Powders Using Carbothermal Reduction Nitridation Method for Diatomite

Abstract

Abstract: Silicon oxynitride (Si₂N₂O) is a high-performance refractory and high-temperature structural material, which has advantages such as excellent creep resistance, corrosion resistance, and oxidation resistance. In this work, diatomite was used as silicon source, acetylene carbon black was used as reducing agent, and the Si₂N₂O/SiC composite powders were synthesized in situ on the surface of diatomite through carbothermal reduction nitridation method. The samples were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and N₂ adsorption/desorption isotherms. The results indicate that under the condition of raw materials ratio m(diatomite)∶m(acetylene carbon black)=1∶1, the SiO₂ completely transforms into Si₂N₂O and β-SiC after calcination at 1 450 ℃ for 4 h, and the sample shows a spherical morphology with mesoporous structure, while a large number of layered small particles distribute around the large particles. As a high-performance high-temperature structural material, Si₂N₂O/SiC composite powders could be a promising candidate for application in the field of structural composite materials.

Key words: Si₂N₂O/SiC, diatomite, carbothermal reduction nitridation method, porous structure, high-temperature structural material, composite powder

CLC Number:

TQ424.22

WAN Gan, KUANG Meng, HUANG Siyuan, ZHANG Jinjun, WANG Ping, ZHANG Shengzhou. Preparation of Si₂N₂O/SiC Composite Powders Using Carbothermal Reduction Nitridation Method for Diatomite[J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(7): 2680-2684.

References

[1] QADIR A, BEN ZINE H R, PINKE P, et al. Tribology of Si₃N₄ containing in situ grown Si₂N₂O processed from oxidized α-Si₃N₄ powders[J]. Ceramics International, 2021, 47(12): 17417-17426.
[2] SÉVIN L, LOCHET N, BEAUDET-SAVIGNAT S. Influence of sintering aids on properties of dense Si₂N₂O ceramic developed by spark plasma sintering[J]. Journal of the European Ceramic Society, 2024, 44(1): 193-204.
[3] LIU Q, ZHAO B, YANG C P, et al. Fabrication of practically pure Si₂N₂O ceramic with high performance from amorphous BN surface modified nano-sized Si₃N₄ powders[J]. Journal of the European Ceramic Society, 2018, 38(1): 333-337.
[4] LUO J T, ZHANG K F, WANG G F, et al. Fabrication of fine-grained Si₃N₄-Si₂N₂O composites by sintering amorphous nano-sized silicon nitride powders[J]. Journal of Wuhan University of Technology-Mater Sci Ed, 2006, 21(3): 97-99.
[5] 裴雨辰, 李嘉禄, 于长清, 等. 原位无压烧结制备Si₂N₂O-Si₃N₄复相陶瓷[J]. 材料工程, 2008, 36(5): 4-6+12.
PEI Y C, LI J L, YU C Q, et al. Fabrication of Si₂N₂O-Si₃N₄ ceramics by in situ pressureless sintering process[J]. Journal of Materials Engineering, 2008, 36(5): 4-6+12 (in Chinese).
[6] XIAO R F, NG L C, JIANG C, et al. Preparation of silicon oxynitride (SiO_xN_y) thin films by pulsed laser deposition[J]. Thin Solid Films, 1995, 260(1): 10-13.
[7] TONG Q F, WANG J Y, LI Z P, et al. Preparation and properties of Si₂N₂O/β-cristobalite composites[J]. Journal of the European Ceramic Society, 2008, 28(6): 1227-1234.
[8] ISLAM S, KIM M S, LEE B T. Fabrication and characterization of porous unidirectional Si₂N₂O-Si₃N₄ composite[J]. Materials Letters, 2009, 63(2): 168-170.
[9] 匡猛, 王平, 罗秋云, 等. 凹凸棒石烧结硅藻土多孔陶器及吸附亚甲基蓝性能[J]. 硅酸盐通报, 2016, 35(9): 2986-2989.
KUANG M, WANG P, LUO Q Y, et al. Preparation of diatomite/palygorskite porous ceramics and performances of adsorption methylene blue[J]. Bulletin of the Chinese Ceramic Society, 2016, 35(9): 2986-2989 (in Chinese).
[10] 李晓雷, 王健, 季惠明, 等. Fe₂O₃对碳热还原氮化SiO₂合成Si₂N₂O的催化效应及机理[J]. 宇航材料工艺, 2012, 42(2): 95-98.
LI X L, WANG J, JI H M, et al. Catalytic effect and mechanism of Fe₂O₃ on synthesis of Si₂N₂O by carbothermal reduction and nitridation of SiO₂[J]. Aerospace Materials & Technology, 2012, 42(2): 95-98 (in Chinese).
[11] BROSSET C, IDRESTEDT I. Crystal structure of silicon oxynitride, Si₂N₂O[J]. Nature, 1964, 201: 1211.
[12] GENG Y Q, ZHAO Y X, YUE F, et al. A novel method to synthesize pure-phase Si₂N₂O powders in a fluidized bed reactor[J]. Ceramics International, 2022, 48(22): 33066-33071.
[13] FERNANDES Y L R L, SILVA M C L, RAIMUNDO R A, et al. Development of mesoporous ceramic membranes of diatomite/TiO₂/Nb₂O₅ nanocomposites for the treatment of contaminated water[J]. Journal of Environmental Chemical Engineering, 2023, 11(6): 111161.
[14] EMOTO H, MITOMO M, WANG C M, et al. Fabrication of silicon nitride-silicon oxynitride in situ composites[J]. Journal of the European Ceramic Society, 1998, 18(5): 527-533.
[15] YAO G S, LI Y, JIANG P, et al. Formation mechanisms of Si₃N₄ and Si₂N₂O in silicon powder nitridation[J]. Solid State Sciences, 2017, 66: 50-56.
[16] JIANG L W, SHI P, ZHANG C H, et al. First-principles study on interfacial structure and strength of SiC/VC nano-layered hard coatings[J]. Computational Materials Science, 2023, 230: 112532.
[17] 王文仲, 孙建波, 秦湘阁. 陶瓷烧结过程显微组织演化的模型化与模拟[J]. 农业机械学报, 2005, 36(10): 152-155.
WANG W Z, SUN J B, QIN X G. Modeling and simulation of microstructure evolution in ceramic sintering[J]. Transactions of the Chinese Society of Agricultural Machinery, 2005, 36(10): 152-155 (in Chinese).
[18] KOPPARTHY S D S, NETRAVALI A N. Review: green composites for structural applications[J]. Composites Part C: Open Access, 2021, 6: 100169.
[19] ZHANG J J, KUANG M, CAO Y X, et al. Environment-friendly ternary ZnO/ZnFe₂O₄/TiO₂ composite photocatalyst with synergistic enhanced photocatalytic activity under visible-light irradiation[J]. Solid State Sciences, 2022, 129: 106913.
[20] PAVARAJARN V, PRECHARYUTASIN R, PRASERTHDAM P. Synthesis of silicon nitride fibers by the carbothermal reduction and nitridation of rice husk ash[J]. Journal of the American Ceramic Society, 2010, 93(4): 973-979.
[21] YU M J, TEMECHE E, INDRIS S, et al. Adjusting SiO₂∶C mole ratios in rice hull ash (RHA) to control carbothermal reduction to nanostructured SiC, Si₃N₄ or Si₂N₂O composites[J]. Green Chemistry, 2021, 23(19): 7751-7762.

Preparation of Si₂N₂O/SiC Composite Powders Using Carbothermal Reduction Nitridation Method for Diatomite

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	YANG Huajian, ZHAO Yuanyun. Preparation and Mechanism of AgCl/Ag Composite Powder Material [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2024, 43(7): 2697-2705.
[2]	CHEN Mengmeng, SONG Yakun, CUI Jiale, CAO Junying, LI Bing, LIU Junhui, LIU Zhen. Synergistic Catalytic Fenton-Like Reaction by Mesoporous CuCo/FeCeO_x Catalyst [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(8): 2985-2993.
[3]	LIU Zhi, REN Zijie, GAO Huimin, WANG Kang, SONG Yuhan, GUAN Junfang. Hydrothermal Synthesis of Calcium Silicate Hydrate from Different Siliceous Materials and Its Reaction Efficiency [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(3): 854-860.
[4]	GAO Bowen, ZHANG Xiaowei, LIU Yuan, LI Qiwang, CHEN Liuling, ZHANG Weike. Microwave Absorbing Properties of Mesoporous Heterogeneous SiO₂@SiC@C Microsphere Prepared by Magnesiothermic Reaction [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2023, 42(12): 4542-4551.
[5]	YANG Xinxin, LIU Fei, YAO Mengqin. CeO₂ Composite Modified ZSM-5 Molecular Sieve for Catalyzing Methanol to Propylene [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(7): 2549-2557.
[6]	LIU Kaizhi, LONG Yong, CHEN Luyi, LI Chen, WU Baihan, SHUI Zhonghe, YU Rui, FEI Shunxin. Preparation of High Stability Ultra-High Performance Concrete Matrix with Calcined Diatomite [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(6): 1888-1895.
[7]	DAI Shiyu, HAO Chunlai, QI Pengyuan, WANG Gang, ZHAO Mei, MA Weimin, ZHU Guangchao, TIAN Yiran, LI Ying. Microstructure Evolution and Pore Structure Change of Diatomite under Combined Treatment [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(6): 2209-2216.
[8]	WANG Qing, BAO Chonggao, LI Shijia, DONG Wencai, MA Haiqiang. Fabrication of Diatomite Slurries and Diatomite Porous Ceramics Based on Stereo Lithography Apparatus [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(4): 1416-1422.
[9]	ZHU Siyu, LI Li, LIU Ze, ZHANG Tong, HAN Fenglan, MA Zhenfei, LIU Jiayu. Hydrothermal Synthesis and Characterization of Zeolite NaA Based on Combination of Silico-Manganese Slag and Fly Ash [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(2): 634-639.
[10]	DUAN Ning, LI Chongrui, LU Chenglong, ZHANG Yinfeng, ZHANG Xiangtai, XIONG Jiangmin. Preparation and Photocatalytic Performance of TiO₂-Al₂O₃ Composite Powder [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(12): 4477-4486.
[11]	XU Zhaoyun, LUO Tuansheng, MA Dengjie, HAI Wanxiu, HE Silin. Stereotypes Package and Thermal Properties of Porous SiC Ceramics/Paraffin Composite Phase Change Materials [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2022, 41(10): 3658-3666.
[12]	XU Zezhong, ZOU Hui, CAO Xianzhi, WU Yang, HAN Chengliang. Synthesis and Photocatalytic Properties of SiO₂/g-C₃N₄ Composite Powders [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(8): 2748-2754.
[13]	ZHANG Zhaohong, LI Peipei, XING Lihua, WANG Zaixue, GOU Jialong, XU Yunhui. Study on Reinforcement of Diatomite/Silica Composite Filler [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(7): 2264-2269.
[14]	ZHAO Chunyang, WANG Enhui, FANG Zhi, GUO Chunyu, DUAN Xingjun, HOU Xinmei. Prediction of SiC Oxidation Reaction Behavior Based on Back Propagation Artificial Neural Network [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(10): 3213-3218.
[15]	FENG Lei, LOU Dai, RAN Ze, WEN Xiaodong, WANG Wei. Influence of Modified Diatomite on Cement-Based Humidity ControlMaterials Performance [J]. BULLETIN OF THE CHINESE CERAMIC SOCIETY, 2021, 40(1): 180-186.